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Springer Series in Optical Sciences 233 Andreas Heinrich  Editor 3D Printing of Optical Components Springer Series in Optical Sciences Volume 233 Founded by H. K. V. Lotsch Editor-in-Chief William T. Rhodes, Florida Atlantic University, Boca Raton, FL, USA Series Editors Ali Adibi, School of Electrical and Computer Engineering, Georgia Institute of Technology, Atlanta, GA, USA Toshimitsu Asakura, Toyohira-ku, Hokkai-Gakuen University, Sapporo, Hokkaido, Japan Theodor W. Hänsch, Max Planck Institute of Quantum Optics, Garching b. München, Bayern, Germany Ferenc Krausz, Max Planck Institute of Quantum Optics, Garching b. München, Bayern, Germany Barry R. Masters, Cambridge, MA, USA Katsumi Midorikawa, Laser Tech Lab, RIKEN Advanced Science Institute, Saitama, Japan Herbert Venghaus, Fraunhofer Institute for Telecommunications, Berlin, Germany Horst Weber, Berlin, Germany Harald Weinfurter, München, Germany Kazuya Kobayashi, Dept. EECE, Chuo University, Bunkyo-ku, Tokyo, Japan Vadim Markel, Department of Radiology, University of Pennsylvania, Philadelphia, PA, USA Springer Series in Optical Sciences is led by Editor-in-Chief William T. Rhodes, Florida Atlantic University, USA and provides an expanding selection of research monographs in all major areas of optics: – lasers and quantum optics – ultrafast phenomena – optical spectroscopy techniques – optoelectronics – information optics – applied laser technology – industrial applications and – other topics of contemporary interest. With this broad coverage of topics the series is useful to research scientists and engineers who need up-to-date reference books. More information about this series at http://www.springer.com/series/624 AndreasHeinrich   Editor 3D Printing of Optical Components Editor Andreas Heinrich Center for Optical Technologies Aalen University Aalen, Germany ISSN 0342-4111 ISSN 1556-1534 (electronic) Springer Series in Optical Sciences ISBN 978-3-030-58959-2 ISBN 978-3-030-58960-8 (eBook) https://doi.org/10.1007/978-3-030-58960-8 © Springer Nature Switzerland AG 2021 This work is subject to copyright. All rights are reserved by the Publisher, whether the whole or part of the material is concerned, specifically the rights of translation, reprinting, reuse of illustrations, recitation, broadcasting, reproduction on microfilms or in any other physical way, and transmission or information storage and retrieval, electronic adaptation, computer software, or by similar or dissimilar methodology now known or hereafter developed. The use of general descriptive names, registered names, trademarks, service marks, etc. in this publication does not imply, even in the absence of a specific statement, that such names are exempt from the relevant protective laws and regulations and therefore free for general use. The publisher, the authors, and the editors are safe to assume that the advice and information in this book are believed to be true and accurate at the date of publication. Neither the publisher nor the authors or the editors give a warranty, expressed or implied, with respect to the material contained herein or for any errors or omissions that may have been made. The publisher remains neutral with regard to jurisdictional claims in published maps and institutional affiliations. This Springer imprint is published by the registered company Springer Nature Switzerland AG The registered company address is: Gewerbestrasse 11, 6330 Cham, Switzerland Preface In recent years, the development of additive manufacturing methods has progressed rapidly. Much of the earlier work focused on realizing mechanical components. But additive manufacturing technology also holds great potential in the field of optics because it offers new degrees of design freedom, which allows completely new approaches to be explored. High-precision two-photon polymerization is one example of how optical com- ponents can be manufactured additively. Among other things, this technique enables the production of microlenses with complex shapes. These microlenses are charac- terized by high optical quality and do not require post-processing after being manu- factured. By contrast, realizing larger optical components or elements with very different material properties has proven to be a challenge. Conventional 3D-printing systems are used as an alternative. These systems can be used both to produce trans- missive optics from glass or plastic and to realize reflective metallic objects. Such printing systems can be used to develop macroscopic optical elements; however, they typically achieve lower optical quality than two-photon polymerization. The objective of this book is to present the current possibilities and characteristic properties of the additive manufacturing of optical components, as well as the cur- rent challenges and future prospects of this field. Additive manufacturing is shown to enable completely new solutions in optics, solutions that can be expected to become even more diverse in future. Chapter 1 of this book introduces additive manufacturing, with a particular focus on conventional 3D-printing processes. The key concepts, typical materials, and various methods of additive manufacturing are described, and their potential appli- cations are discussed. The additive manufacturing of reflectors using the SLM process is presented in Chap. 2. For each application, the lighting requirements are presented and used to deduce the design parameters of the product. The light distribution produced by a macroreflector is simulated and validated as an example. The entire additive manu- facturing process chain is also examined. Chapter 3 examines the potential of 3D-printed polymer optics. The key focus of the chapter is a discussion of several completely different examples of additively vii viii Preface manufactured optics to illustrate the potential and limitations of additive manufac- turing in this area. The 3D printing of macroscopic optical elements such as light guides, liquid lenses, luminescent optics, random lasers, and mirror elements is dis- cussed, as well as the inkjet printing of microscopic lenses. This chapter also exam- ines the development of new additive manufacturing technologies, such as robot-based printing and the detuning of inkjet-printed lenses within an electric field. Chapter 4 discusses the additive manufacturing of glass. Glass has shaped the optics and photonics like no other material. Once silicate glasses became available for 3D printing, two main approaches emerged: direct 3D printing of low-melting glasses at high temperatures and indirect glass printing of glass precursors using technologies borrowed from polymer 3D printing. This chapter discusses how pre- cursors can be printed at room temperature then converted into transparent glass by a heat treatment process. The high-precision 3D-printing technique of 3D lithography by two-photon or multi-photon absorption is discussed in Chap. 5. This area has developed signifi- cantly over the past two decades and opens up new possibilities in a wide variety of photonic applications. Chapter 5 describes the principles of this process, as well as the materials that can be used for it. It discusses how this method is not only able to realize refractive and diffractive optics, but also meta-optics extending from the sub-micrometer range to the millimeter range. This is demonstrated with printed optics intended for direct use as well as master models for replication. Chapter 6 presents direct femtosecond laser writing for the manufacturing of micro-optical components and systems. This chapter primarily focuses on the design of such components. A selection of imaging and lighting optics are presented and discussed to demonstrate the potential of this manufacturing technology. The quality of additively manufactured optics depends on the properties of the materials that are used. Accordingly, the final Chap. 7 discusses hybrid polymers. Hybrid polymers are a class of optical materials that combine the properties of inor- ganic glass and organic polymers. The properties of such polymers can be specifi- cally adapted, which is desperately needed when printing micro-optical elements. This chapter therefore considers the chemical concepts of hybrid polymers, as well as their synthesis and processing. Applications of hybrid polymers to produce micro-optical and photonic elements using established water scale processes, inkjet methods, and direct laser writing with two-photon polymerization are also discussed. The editor would like to thank all contributors to this book for their remarkable chapters. Special thanks to Dr. Sam Harrison, Editor at Springer, for his assistance with the creation of this book, and Mr. Murugesan Tamilsevan, Project Coordinator at Springer, for his skillful management of the production process. Aalen, Germany Andreas Heinrich Contents 1 Introduction to Additive Manufacturing . . . . . . . . . . . . . . . . . . . . . . . 1 Miranda Fateri and Andreas Gebhardt 1.1 Characteristics of Additive Manufacturing Processes . . . . . . . . . . . 1 1.2 Additive Manufacturing Processes . . . . . . . . . . . . . . . . . . . . . . . . . 3 1.2.1 Stereolithography (SLA) . . . . . . . . . . . . . . . . . . . . . . . . . . . 4 1.2.2 Selective Laser Sintering (SLS)/Selective Laser Melting (SLM)/Laser Powder Bed Fusion (LPBF) . . . . . . . 6 1.2.3 Fused Layer Modeling (FLM), Commercially: Fused Deposition Modeling (FDM). . . . . . . . . . . . . . . . . . . 9 1.2.4 Powder-Binder Bonding (3DP) . . . . . . . . . . . . . . . . . . . . . . 13 1.2.5 Layer Laminate Manufacturing (LLM)/Selective Deposition Lamination (SDL) . . . . . . . . . . . . . . . . . . . . . . . 15 1.3 Processing Materials . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 19 1.4 Characteristics of Additive Manufactured Parts . . . . . . . . . . . . . . . 20 References . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 22 2 Selective Laser Melting of Reflective Optics . . . . . . . . . . . . . . . . . . . . 23 Georg Leuteritz, Marcel Philipp Held, and Roland Lachmayer 2.1 Adjusting Optics Manufacturing . . . . . . . . . . . . . . . . . . . . . . . . . . . 23 2.2 Requirements for Reflective Optics . . . . . . . . . . . . . . . . . . . . . . . . . 24 2.2.1 Applications for Reflective Optics . . . . . . . . . . . . . . . . . . . . 25 2.2.2 Geometry . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 26 2.2.3 Relation Between Design Parameters and Functionality . . . 26 2.2.4 Reflector Design for Additive Manufacturing . . . . . . . . . . . 29 2.3 Additive Manufacturing: Selective Laser Melting . . . . . . . . . . . . . . 29 2.4 Additive Manufacturing of a Reflector Array . . . . . . . . . . . . . . . . . 35 2.4.1 Design of a Reflector Array . . . . . . . . . . . . . . . . . . . . . . . . . 35 2.4.2 Validation of a Process Configurator . . . . . . . . . . . . . . . . . . 38 2.5 Challenges for SLM of Reflective Optics . . . . . . . . . . . . . . . . . . . . 42 References . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 43 ix x Contents 3 3D Printing of Optics Based on Conventional Printing Technologies . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 45 Manuel Rank, Andre Sigel, Yannick Bauckhage, Sangeetha Suresh-Nair, Mike Dohmen, Christian Eder, Christian Berge, and Andreas Heinrich 3.1 Introduction . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 46 3.2 Materials Used for the Additive Manufacturing of Optics Using Polymerization . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 47 3.2.1 Photopolymerization Categorized According to the Reacting Species . . . . . . . . . . . . . . . . . . . . . . . . . . . . 47 3.2.2 Resin Composition . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 49 3.3 Analysis of Additively Manufactured Optics . . . . . . . . . . . . . . . . . . 53 3.3.1 Analysis of the Printing Process . . . . . . . . . . . . . . . . . . . . . 54 3.3.2 Analysis of the Shape and Surface of Additively Manufactured Optics . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 56 3.3.3 Dip Coating to Improve the Surface of Additively Manufactured Optical Elements . . . . . . . . . . . . . . . . . . . . . 60 3.3.4 Analysis of the Optical Properties of Additively Manufactured Elements . . . . . . . . . . . . . . . . . . . . . . . . . . . . 64 3.4 Additively Manufactured Macroscopic Optics . . . . . . . . . . . . . . . . 69 3.4.1 Light-Guiding Elements. . . . . . . . . . . . . . . . . . . . . . . . . . . . 69 3.4.2 Lens Systems . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 75 3.4.3 Liquid Lenses . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 80 3.4.4 Freeform Lenses. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 84 3.4.5 Volumetric Displays Using Additive Manufacturing Processes . . . . . . . . . . . . . . . . . . . . . . . . . . . 91 3.4.6 Additively Manufactured Mirror Elements . . . . . . . . . . . . . 94 3.5 Additively Manufactured Microlenses . . . . . . . . . . . . . . . . . . . . . . . 104 3.5.1 Additive Manufacturing of Spherical Microlenses . . . . . . . 105 3.5.2 Individualized Microlenses . . . . . . . . . . . . . . . . . . . . . . . . . 109 3.6 Additively Manufactured Light Sources . . . . . . . . . . . . . . . . . . . . . 113 3.6.1 Organic LEDs . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 113 3.6.2 Additively Manufactured Optical Converter and Random Laser . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 116 3.6.3 Additive Manufacturing of Photoluminescent Optics . . . . . 121 3.7 New Approaches to the Additive Manufacturing of Optics . . . . . . . 131 3.7.1 Robot-Based Additive Manufacturing . . . . . . . . . . . . . . . . . 131 3.7.2 DMD-Based Additive Manufacturing of Optical Components . . . . . . . . . . . . . . . . . . . . . . . . . . . . 151 3.7.3 3D Printing of Multiple Materials . . . . . . . . . . . . . . . . . . . . 157 3.8 Summary . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 161 References . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 162

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