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Trace element abundances and Sr-Nd-Pb isotopic constraints PDF

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UC San Diego UC San Diego Electronic Theses and Dissertations Title Trace element abundances and Sr-Nd-Pb isotopic constraints on the petrogenesis of Juan Fernandez lavas Permalink https://escholarship.org/uc/item/0vk39489 Author Truong, Thi Bich Publication Date 2015 Peer reviewed|Thesis/dissertation eScholarship.org Powered by the California Digital Library University of California UNIVERSITY OF CALIFORNIA, SAN DIEGO Trace element abundances and Sr-Nd-Pb isotopic constraints on the petrogenesis of Juan Fernandez lavas A thesis submitted in partial satisfaction of the requirements for the degree Master of Science in Earth Sciences by Thi Bich Truong Committee in charge: Professor Paterno Castillo, Chair Professor James Day Professor David Hilton 2015 Copyright Thi Bich Truong, 2015 All rights reserved. The Thesis of Thi Bich Truong is approved, and it is ac- ceptable in quality and form for publication on microfilm and electronically: Chair University of California, San Diego 2015 iii DEDICATION Dedicated to my parents Thuy Nguyen and Hung Truong. iv EPIGRAPH There is no good way to comprehend any one aspect of geology without studying the wider matrix in which it rests. John McPhee v TABLE OF CONTENTS Signature Page ..................................................... iii Table of Contents ................................................... vi List of Figures ...................................................... vii List of Tables....................................................... viii Acknowledgements .................................................. ix Abstract ........................................................... x 1 Introduction..................................................... 1 1.1 Geologic Background......................................... 6 1.2 Samples .................................................... 9 2 Methods and Results ............................................. 13 2.1 Analytical Methods .......................................... 13 2.2 Results..................................................... 19 2.2.1 Trace Elements ....................................... 19 2.2.2 Radiogenic Isotopes ................................... 21 3 Discussion ...................................................... 27 3.1 Major Element Variations .................................... 28 3.2 Incompatible Trace Element Variation.......................... 30 3.3 The Sr-Nd-Pb composition of the Juan Fernandez mantle source ... 34 3.4 The geochemistry of Juan Fernandez Islands compared to some Pacific island chains.......................................... 38 3.5 The volcanologic evolution of Juan Fernandez islands............. 40 3.6 Implications for the origin of the high-3He/4He signature of Juan Fernandez lavas ............................................. 43 3.6.1 The MORB-like 3He/4He of group III lavas ............... 45 3.6.2 The difference in 3He/4He between group I and group II lavas 47 3.6.3 The nature of 3He/4He in Juan Fernandez lavas ........... 49 4 Conclusions ..................................................... 52 References ......................................................... 54 vi LIST OF FIGURES Figure 1.1: Bathymetric Map and Location of Juan Fernandez Islands..... 5 Figure 1.2: Sample map of Robinson Crusoe and Alexander Selkirk Islands 7 Figure 1.3: 3He/4He (R ) versus Ba/Zr, Zr versus Nb ................... 12 A Figure 2.1: Chondrite-normalized rare earth element (REE) patterns ...... 22 Figure 2.2: Primitive mantle-normalized incompatible element spidergram . 23 Figure 2.3: 87Sr/86Sr versus 143Nd/144Nd .............................. 24 Figure 2.4: 206Pb/204Pb-207Pb/204Pb, 206Pb/204Pb-208Pb/204Pb ........... 25 Figure 3.1: MgO (wt.%) versus major element oxides ................... 29 Figure 3.2: Na O (wt. %) versus FeO* (wt. % )........................ 31 2 Figure 3.3: Magmatic process identification diagrams ................... 35 Figure 3.4: 3He/4He (R ) versus 87Sr/86Sr ............................. 37 A Figure 3.5: Proposed stages of the volcanologic evolution of the Juan Fer- nandez Archipelago ...................................... 41 Figure 3.6: 3He/4He (R ) versus TITAN Anomalies..................... 44 A vii LIST OF TABLES Table 2.1: Trace element abundance data.............................. 15 Table 2.2: Sr-Nd-Pb isotope composition data.......................... 17 Table 3.1: Helium isotope recalculations............................... 48 viii ACKNOWLEDGEMENTS Iwouldliketothank,firstandforemost,myadvisorforthisproject,Professor Paterno Castillo for his constant availability and encouragement through 4 years of work. Thank you to my committee members, James Day and David Hilton for offering their expertise time and time again for my own benefit. Thanks to everyone at SIO who made this research possible: Joshua Reeves with my degree requirements, and Chris MacIsaac for the guidance in the lab, and especially for saving my first strontium cut in the TIMS when it grew legs. Thank you to Lisa Tauxe for the suggestion in programming class that we should learn LaTeX. I am also grateful for the help of UCSD librarians who were able to elucidate the nuances of accessing obscure articles. ix

Description:
Figure 1.2: Sample map of Robinson Crusoe and Alexander Selkirk Islands of partial melting plus fractional crystallization account for group II. Robinson. Crusoe lavas exhibit more radiogenic Pb isotopes (206Pb/204Pb: 19.163-19.292) than .. elements and by mass spectrometry for Sr-Nd isotopes.
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