Table Of Content

Journal of Organometallic Chemistry 585 (1999) 363-365 Contents of Volume 585 Regular Papers New rhodium complexes with P,N-ligands possessing a hydroxy or methoxy group. Synthesis, characterization and application to hydroformylation of styrene EE Ee ee ee” ee er a a. er ee n-Bonding in B—O ring species: Lewis acidity of Me,B,0,, synthesis of amine Me,B,O, adducts, and the crystal and molecular structure of Me,B,0,NH5Bu: MeB(OH), M.A. Beckett, D.S. Brassington, P. Owen, M.B. Hursthouse, M.E. Light, K.M.A. Malik, K.S. Varma ................. Bis(dicyclohexylammonium) (oxalato)(pyridine-2,6-dicarboxylato)dibutylstannate 3.5 hydrate, the first crystallographic example of a mixed-chelate diorganotin(IV) compound rn + sib bo OAR REO EE OD ED O48 oT OCW CSE PRT OER CERO WESTER Ss 18 803 4503s Re Aa 12 Si,Me,-bridged zirconocene dichlorides: crystal and molecular structure of meso-Si,Me,(3-SiMe,—C,H,),ZrCl, O. Pérez-Camacho, S. Ya. Knjazhanski, G. Cadenas, M.J. Rosales-Hoz, M.A. Leyva ..............0.. 0000554 e eee Synthesis of several functionalized cis-diisocyanide and fac-triisocyanide metal complexes a Ci oo bs oe a4 ed ee OO os ne FO 6 OSS Oe 00k 6660s 6 Ore os ee oe 26 Evidence of single electron transfer in the diastereoselective synthesis of B-stannylketones FE ee eee oe ECCT EET TER TCL TEC Tee Toe 35 Stereoselective reactivity of diastereotopic carbon-carbon triple bonds induced by chiral orthosubstituted arene tricarbonyl chromium complexes. Diastereoselective Co,(CO), complexation and LiAIH, reduction - Coe, B.4. Boece cena, F. Remers Come, FF. RPO. oo ss + tc ae ks 0 oe oh mae ob 0 8 one Oe bas 8 eh oe 68 43 The first alkyne-dicobaltcarbonyl complex with a bidentate chiral ligand with Co—P and Co—N coordination J. Castro, A. Moyano, M.A. Pericas, A. Riera, A. Alvarez-Larena, J.F. Piniella......0..2..2.0 .e. ee.e .ee. e.ee e 53 Synthesis and crystal structure of bis(2-dimethylaminoethylindenyl) divalent organolanthanides (Ln = Sm, Yb) ae OR GBO G Rr ee ae ee ee eee oe ere ee Oe ee ee Oe ae ee 59 Facile synthesis of o,p-iminoacyl bridged butterfly clusters (u-RE)(o,p-ArC=NAr’)Fe,(CO), (E = S, Se) i i 5 5 eo og CASO SO O6 8O OCRDESE O42 TRS RRESD OEE US EARORERES DOS DED ES OO EOE 63 Investigation of the reactivity of the phosphorus—hydrogen bond in Cp’RuL,L,Cl complexes with diphenylphosphine ligands R. Torres-Lubian, M.J. Rosales-Hoz, A.M. Arif, R.D. Ernst, M.A. Paz-Sandoval...... 2.2... 0.00... eee ee ee ee ees 68 Preparation of new acetylide and vinylidene complexes of ruthenium ee, a PE, es EE, OO I gg kt tt ce ee he ee eee CRO HHEH ER RO OREO SS © het 83 C-H activation of a MeN grouping in one of the CH,NMe, ortho substituents of a NCN ‘pincer’ ligand in tungsten chemistry: X-ray structure of [WCI,(NPh)(C,H,{CH,NMeCH,}-2-{CH,NMe,}-6)] J.A.M. Brandts, E. Kruiswiik, J. Boersma, A.L. Spek, G. vam Rotem... 1 ee ww ww wew ew ero were vans 93 Triruthenium clusters derived from the reactions of [Ru,(CO),,] with benzothiazole, pyrimidine-2-thione and benzimidazole-2-thione; X-ray structures of [Ru,(y-H)(u-2,3-n?-NSC,H,4)(CO),o] and [Ru,(u-H)(u3-n7-SN,C,H)(CO).] R. Dilshad, K.M. Hanif, M.B. Hursthouse, S.E. Kabir, K.M. Abdul Malik, E. Rosenberg ...... 2... 2.2.00 0 22 eee euee 100 The structure of bicyclic ferrocenylmethylene substituted 2-pyrazolines and their reactions with azodicarboxylic acid N-phenylimide E.I. Klimova, M. Martinez Garcia, T. Klimova Berestneva, C. Alvarez Toledano, R. Alfredo Toskano, L. Ruiz Ramirez ...... 106 The chemistry of metallacyclic alkenylcarbene complexes: Part 9. Synthesis and reactions of chelated n?-alkene- and 1n’-allyl-carbene complexes of cobalt, manganese and chromium a Cc... cece er ee See eR Re CROSS OR ae ee SASS Ck ORR ee eS 364 Contents of Volume 585 / Journal of Organometallic Chemistry 585 (1999) 363-365 Syntheses and solid-state structures of mono- and dialkyl(methylsulfonato)boranes R. Papp, F.B. Somoza, Jr., J. Sieler, S. Blaurock, E. Hey-Hawkins .. .. 0... cee ee ee twee eee eee eee eens 127 Reductive coupling of alkynes by oxobis(diethyldithiocarbamato)molybdenum(IV)—sodium borohydride a a SS er ee rrr Se 134 Reactions of thioarsines with metal carbonyls: synthesis and structural characterisation of [Fe,(CO),(u-AsMe,)(u-SPh)], [Fe.Cp,(CO),(p- AsPh,)(u-SPh)], [Mn,(CO),.(u-AsPh,)(u-SPh)] and [Co,(p1,-S)(u-AsPh,)(CO),AsPh,] G. Conole, J.E. Davies, J.D. King, M.J. Mays, M. McPartlin, H.R. Powell, P.R. Raithby...........0...0.....0500545. 141 Electronegativity equilibration and organometallic thermochemistry: the strengths of carbon—carbon bonds in metal alkyls eee ee rere ee eg eC Bel eae 8 5 i hp Ber ere ee eee 150 Sandwich and half-sandwich niobium imido complexes: X-ray crystal structure of [Nb(=NAr)Cp5Cl] (Cp’ = n°-C,H,SiMe,, Ar= C,H,OMe-4) A. Antifiolo, M. Fajardo, C. Huertas, A. Otero, S. Prashar, A.M. Rodriguez... .. 2... 0...ee e e es 154 An organometallic sol-gel route to layered zinc phenylphosphonate and encapsulation studies with n°-(C,H,)Cr(CO), re OS Ps 6 kee eee eh ORR RRD ESE ORS bed e eons heses + Oey OIE, 162 2,6-Dimethoxyphenylphosphetane sulfide—synthesis, structure and exploratory photochemistry es er A CUS OOS SS SI iB ls SN Ss eS ae ONO EEA ewer IE FL ht 167 First Sonogashira coupling reactions with the chlorobenzene-Cr(CO),PPh, complex Oe ee ee ee eee ee ee ee Te ET CLE TER CT CECE CTE TTT ee 174 Structure and reactivity of four-membered titanacycles—theoretical studies eS £ 6d & 5s ay Se bb -60 ) RG bo = Cees oe eo oe Ole ee Oe ee Ok Swe 8 B's 869 + be eee so BP 179 Head-to-head versus head-to-tail dimerizations of transient silenes—the synthesis and reactivity of 2-(8-dimethylamino-1-naphthyl)- and 2-(4-dimethylamino-1-naphthyl)-1,1-bis(trimethylsilyl)silene EES PY eee ee ee ee oe ee eee ee ee ee ee ee eee 189 Neen ek te eee le ele elB edi OB eke B86 Buble Oa 6 wib l'e & & be ee ok o 4 198 Regular Papers Crown compounds for anions. Spectroscopic and theoretical studies of complexation of borohydride anions with cyclic trimeric perfluoro-o-phenylenemercury L.N. Saitkulova, E.V. Bakhmutova, E.S. Shubina, I.A. Tikhonova, G.G. Furin, V.I. Bakhmutov, N.P. Gambaryan, A.L. Chistyakov, EE ee a ee ee eee ee ae ee a ee 201 Novel Si—Sn ring systems with distanna and tristanna moieties I ES Pe Fe eT a ee Or Pe oe ee ea ee a a ree 211 Seven-coordinate complexes of molybdenum(II) containing a trichlorogermyl ligand: X-ray crystal structure of a _ novel [Mo(GeCl,),(CO),(NCEt),] ok a a eS wap Web ree be Ooo Ke 6 O88 ee 6 ke eee ed 215 Koordinationschemie funktioneller Phosphane VIII. Tetracarbonylkomplexe des Wolframs und Molybdans mit 2-(Diphenylphos- phanyl)anilin-Liganden a as as as gy Wie, BW ke & A A ee bk ob ba bce 6 So8 boo ee a kn 225 Mononuclear halfsandwich rhodium complexes containing phenylchalcogenolato ligands: a multinuclear ('H, '*C, *'P, ’’Se, '°*Rh, '°Te) magnetic resonance study M. Herberhold, T. Daniel, D. Daschner, W. Milius, B. Wrackmeyer ...... 2... 2. ccccvecrcervvvvvsssecees 234 Palladium complexes with bridged and unbridged benzimidazolin-2-ylidene ligands Se are ee ee oe Sis ks wae a a EeB bw SsO 80 50 4 08 ee OD ae bk6 88 ee oe 241 Syntheses and characterization of a series of carbonylruthenium(I) and (II) complexes containing pyridyl ligands ee le Mg G26 dvs. pA a on 9s gt Cs ach ae ee we eae Mies oti bid Sahoo geB ele ee's OR BOs) eat Ot betel 246 La reaction de Diels—Alder catalysee par les sels de bismuth (III) ge ae De a hae ek ees kk ok keg okie eS ibe aes be 4a 253 Unexpected regioselective formation of internal n°-allylpalladium chloride complexes from terminal alkenes and palladium chloride in 1,2-dichloroethane SMa Ne a Bi a ot wat is pi alae Mal ghee “GsA ng Bt al oe ee le eR esa 256 Contents of Volume 585 / Journal of Organometallic Chemistry 585 (1999) 363-365 365 Modes of complexation of bis-aminals of linear tetraamines with Group 6 metal carbonyls G. Hervé, N. Le Bris, H. Bernard, J.-J. Yaouanc, H. des Abbayes, H. Handel .......0.00.00 .e.ee. e.ee. ee ns 259 Reactivity studies of trimethylaluminum, trimethylgallium, and trimethylindium with a series of five silylamines: molecular structure of trans-[Me,InN(Me)SiMe,], E.K. Styron, S.J. Schauer, C.H. Lake, C.L. Watkins, L.K. Krannich2.0.... .2.... ce .ewe.r e.ee .ce.ce .eee. en es 266 Synthesis and characterization of zirconium pentafluorophenyl complexes: X-ray crystal structures of [ZrCl,(C,F;); ~~] and [ZrF,(C,F.)2~ ] — = Re ee re Narr ar ee aaa ere Shenker iM Perr ore ree ary ra 275 The crystal structure of a trinuclear anion, [(t-Bu,Sb),Sb]~ formed by reaction of cyc/o-(t-Bu,Sb,) with potassium, and the four-membered rings, cyclo-(t-Bu,E,,Sb,_ ,,) (E = P, n=0-3; E= As, n=0-2) ee Fe ET Os Wee Oe. GU OE BONS pod eee ce ee se Hees eee eee eee bhe rede neceneecs 285 Complexes of Rh(I) with phosphite derivatives of codeine K.N. Gavrilov, A.V. Korostylev, O.G. Bondarev, A.I. Polosukhin, V.A. Davankov.................0200.02 .ee2 e.e e 290 Isocyanide—Group 5 complexes and metal-centred C—C coupling ns Gi. Cees, SG, SG, Gls UI, WO ED kg 5 ne nsn o Oue o 6 6 nie e400 0 660 b-0 b OOM BO Oe be eee 294 Alkylation of cyclopentadienyl rings in the reactions of nickelocene with organolithium compounds S. Pasynkiewicz, A. Pietrzykowski, L. Bukowska, L. Jerzykiewicz .. . 0... ww et te ee ee eee ee eee twee 308 Chirale Bisphosphane IX. Kationische Rhodium(I)-Komplexe mit (15,2S)-Cyclopentan-1 ,2-diyl-bis(dialkylphosphan)-Liganden, [(1S,2.S)- C;H,(PR,),Rh(1,5-COD)]O,SCF,: Synthesen, Strukturen und katalytische Anwendungen re i; MS. 5 0:6) ik a oon ee eee OT a aE Se Oe ae oe a ee Oko 0.0 6.8 8 6 ee ee aE es oe 315 On the structure and reaction with pyridine of o-methoxyphenyllead acetates Sees GU, GEE, CM, DR. BON, Te SE ns oe tte tet ee cece cesses ee eseteCeseaeebe 326 Keto-acid chloride and diketone intermediates in the acylation of ferrocene by arylene bis-acid chlorides. Crystal and molecular structure of 4-ferrocenylcarbonyl-4’-chlorocarbonylbiphenyl: intermolecular association by means of strong C—H---O hydrogen bonds and n:--n stacking interactions oe |e eee eee ee ee eee ee ee ee 331 Kondensationen von Silylhydrazinen und Estern zu Silylhydrazonen und Pyrazolnen a en, a , a Cs och Se 6 oe eh eS 6 SO RS OS 06k ob 646 ESS Ow CO Ber Ort 341 Priority Communication Combining N-heterocyclic carbenes and phosphines: improved palladium(II) catalysts for aryl coupling reactions Ss, Sac ees EE ES se cet eee CSD Oe wee CES @ eS. Oe sa Oe OS Wale énlee eee 348 ES eresg ll. kere: 353 ey er ogg. 5 ta aameaied weS ecs a sereines #6 oo 4b 6b @ Oo 0 06 6 0-080 hd 6 oe ee 355 NP Is Cibcmristeys 0 os oe FSS SUS COED Dip eee, ow ec e ee ether tee 6% Oo wes 357 ee Cie BE bd dc. gg oo HERD Che ae Oe Oe es che cc ee PORE TE Ce et 6 eee 363