Water and Climate Change Water and Climate Change Sustainable Development, Environmental and Policy Issues Edited by Trevor M. Letcher School of Chemistry, University of KwaZulu-Natal, Durban, South Africa Elsevier Radarweg29,POBox211,1000AEAmsterdam,Netherlands TheBoulevard,LangfordLane,Kidlington,OxfordOX51GB,UnitedKingdom 50HampshireStreet,5thFloor,Cambridge,MA02139,UnitedStates Copyright©2022ElsevierInc.Allrightsreserved. Nopartofthispublicationmaybereproducedortransmittedinanyformorbyanymeans,electronicormechanical, includingphotocopying,recording,oranyinformationstorageandretrievalsystem,withoutpermissioninwritingfromthe publisher.Detailsonhowtoseekpermission,furtherinformationaboutthePublisher’spermissionspoliciesandour arrangementswithorganizationssuchastheCopyrightClearanceCenterandtheCopyrightLicensingAgency,canbefound atourwebsite:www.elsevier.com/permissions. ThisbookandtheindividualcontributionscontainedinitareprotectedundercopyrightbythePublisher(otherthanasmay benotedherein). Notices Knowledgeandbestpracticeinthisfieldareconstantlychanging.Asnewresearchandexperiencebroadenour understanding,changesinresearchmethods,professionalpractices,ormedicaltreatmentmaybecomenecessary. Practitionersandresearchersmustalwaysrelyontheirownexperienceandknowledgeinevaluatingandusingany information,methods,compounds,orexperimentsdescribedherein.Inusingsuchinformationormethodstheyshouldbe mindfuloftheirownsafetyandthesafetyofothers,includingpartiesforwhomtheyhaveaprofessionalresponsibility. Tothefullestextentofthelaw,neitherthePublishernortheauthors,contributors,oreditors,assumeanyliabilityforany injuryand/ordamagetopersonsorpropertyasamatterofproductsliability,negligenceorotherwise,orfromanyuseor operationofanymethods,products,instructions,orideascontainedinthematerialherein. ISBN:978-0-323-99875-8 ForInformationonallElsevierpublications visitourwebsiteathttps://www.elsevier.com/books-and-journals Publisher:CandiceJanco AcquisitionsEditor:LouisaMunro EditorialProjectManager:MichelleFisher ProductionProjectManager:SruthiSatheesh CoverDesigner:MilesHitchen TypesetbyMPSLimited,Chennai,India Contents List of contributors..............................................................................................xvii Preface.................................................................................................................xix Section A Introduction..................................................................................... 1 Chapter 1:Introduction: water, the vital chemical.................................................... 3 Trevor M. Letcher 1.1 Introduction...........................................................................................................3 1.2 The unique chemical properties of water...............................................................4 1.2.1 The polar nature of water............................................................................4 1.2.2 The high enthalpy of vaporization of water................................................4 1.2.3 The high heat capacity of water..................................................................5 1.2.4 The anomalous density of frozen water.......................................................5 1.2.5 Water, the “universal” solvent....................................................................6 1.2.6 Acid(cid:1)base property....................................................................................7 1.2.7 High surface tension, low viscosity, and cohesive and adhesive properties....................................................................................................7 1.3 Water and climate change......................................................................................8 1.4 The origin of water on Earth..................................................................................9 1.4.1 The water cycle...........................................................................................9 1.5 The scarcity of water...........................................................................................10 1.6 Conclusions.........................................................................................................10 References...................................................................................................................10 Chapter 2:The root causes of climate change and the role played by water............. 13 Trevor M. Letcher 2.1 Introduction.........................................................................................................13 v vi Contents 2.2 Water and CO and the greenhouse effect...........................................................14 2 2.3 The main greenhouse gases of anthropogenic origin............................................16 2.4 Feedback mechanisms and tipping points............................................................18 2.5 Where are we in solving the problem of global heating?.....................................19 2.6 Solutions..............................................................................................................22 2.7 Conclusion...........................................................................................................25 References...................................................................................................................25 Chapter 3:Water resource planning and climate change........................................ 27 Rabee Rustum, Adebayo J. Adeloye and Quan Dau 3.1 Introduction.........................................................................................................27 3.2 Climate change and water budget components.....................................................28 3.3 Water reservoirs...................................................................................................29 3.3.1 Indices of reservoir performance...............................................................30 3.3.2 Reservoir operation...................................................................................31 3.3.3 Climate change effect on reservoir performance in the Indus Basin..........32 3.4 Conclusions.........................................................................................................38 References...................................................................................................................38 Chapter 4:Potential impacts of climate change on biogeochemical cycling................ 41 Daniel A. Vallero 4.1 Introduction.........................................................................................................41 4.2 Thermodynamics of cycling.................................................................................42 4.3 Partitioning..........................................................................................................45 4.3.1 Dissolution................................................................................................45 4.3.2 Sorption....................................................................................................47 4.4 Biochemodynamics..............................................................................................49 4.5 Biogeochemistry of oxygen in water....................................................................55 4.6 The carbon cycle and greenhouse effect..............................................................57 4.7 Conclusions.........................................................................................................59 References...................................................................................................................59 Further reading.............................................................................................................62 Section B Sustainable development and environmental issues.................. 63 Chapter 5:Water quality engineering: physical, chemical, and biological treatment for a sustainable future ....................................................... 65 Daniel A. Vallero 5.1 Introduction.......................................................................................................65 Contents vii 5.2 Water quality.....................................................................................................66 5.3 Chemical processes............................................................................................69 5.4 Wastewater treatment.........................................................................................73 5.5 Water treatment to manage risks........................................................................79 5.6 Disposal of sludge..............................................................................................80 5.7 Mixed reactors...................................................................................................82 5.8 Aerobic reactors.................................................................................................83 5.9 Anaerobic reactors.............................................................................................86 5.10 Treating contaminated ground water..................................................................89 5.11 Conclusions.......................................................................................................92 References...................................................................................................................92 Chapter 6:Urban water supplies in developing countries with a focus on climate change.................................................................................... 95 Josephine Treacy 6.1 Introduction.........................................................................................................95 6.2 Urbanization in developing countries...................................................................97 6.3 Urban water supplies...........................................................................................97 6.3.1 Source waters............................................................................................99 6.3.2 Other water sources innovative needs.....................................................100 6.3.3 Urban water supplies as a resource.........................................................101 6.3.4 Centralized and noncentralized water supplies........................................101 6.4 Climate change challenges and urban waters.....................................................102 6.4.1 Water Supplies and demand....................................................................103 6.5 Waste management and climate change and its impact on urban water.............104 6.6 Opportunities and global initiatives....................................................................104 6.6.1 Adaptation and mitigation.......................................................................105 6.6.2 Understanding the water baseline............................................................105 6.6.3 Environmental impact modeling risk......................................................105 6.7 Water security....................................................................................................106 6.7.1 Policy makers.........................................................................................106 6.8 Conclusions.......................................................................................................107 References.................................................................................................................109 Further reading...........................................................................................................112 Chapter 7: Water purity and sustainable water treatment systems for developing countries...........................................................................115 Joanne Mac Mahon 7.1 Introduction: access to clean water in developing countries...............................115 viii Contents 7.2 Environmental challenges to water purity in developing countries.....................118 7.3 WHO guidelines for water purity.......................................................................120 7.3.1 Microbial guidelines...............................................................................120 7.3.2 Chemical guidelines................................................................................121 7.3.3 Radiological guidelines...........................................................................122 7.3.4 Acceptability: taste, odor, appearance.....................................................122 7.3.5 Other considerations...............................................................................122 7.4 Water supply sources used in developing countries...........................................123 7.5 Water treatment systems used in developing countries......................................124 7.5.1 Centralized water treatment systems.......................................................124 7.5.2 Decentralized water treatment systems....................................................126 7.5.3 Water Safety Plans..................................................................................126 7.5.4 Commonly used water treatment methods...............................................128 7.5.5 Water storage..........................................................................................132 7.6 Sustainable water management systems.............................................................133 7.7 Conclusions.......................................................................................................135 References.................................................................................................................136 Chapter 8:Water purification techniques for the developing world........................145 Aniruddha B. Pandit and Jyoti Kishen Kumar 8.1 Introduction.....................................................................................................145 8.2 Water purification methodologies....................................................................147 8.3 Solar treatment and its intensification..............................................................147 8.4 Water disinfection by boiling...........................................................................150 8.5 Chemical treatment..........................................................................................152 8.6 Filtration techniques.........................................................................................154 8.6.1 Traditional filtration methods................................................................154 8.6.2 Recent advances/modifications in traditional filtration methods............156 8.6.3 Hybrid filtration methods......................................................................158 8.7 Natural treatment methods...............................................................................159 8.8 Cavitation-based water hand pumps.................................................................160 8.9 Sustainable disinfection of harvested rainwater................................................163 8.10 Recent research on emerging methods.............................................................166 8.10.1 Filtration.............................................................................................166 8.10.2 Solar disinfection................................................................................166 8.10.3 Hybrid techniques...............................................................................167 8.11 Impact of Covid 19 pandemic on the water sector in developing countries......168 8.12 Comparison of various purification techniques................................................170 8.13 Conclusions.....................................................................................................173 Contents ix 8.14 Recommendations for future work...................................................................174 References.................................................................................................................174 Chapter 9:Plastic pollution in waterways and in the oceans..................................179 Lei Mai, Hui He and Eddy Y. Zeng 9.1 Introduction.......................................................................................................179 9.2 Global marine plastic pollution..........................................................................180 9.2.1 Sources of marine plastic debris..............................................................180 9.2.2 Distribution of microplastics in the marine environment.........................182 9.3 Plastic pollution in rivers...................................................................................183 9.3.1 Distribution of plastics in global rivers...................................................183 9.3.2 Riverine transport of microplastics to coastal oceans/seas.......................187 9.4 Riverine plastic outflows...................................................................................188 9.4.1 Field measured riverine microplastic outflows........................................188 9.4.2 Comparison of riverine plastic outflows between measurements and model estimates................................................................................190 References.................................................................................................................192 Chapter 10: Desalination and sustainability........................................................197 Anju Vijayan Nair and Veera Gnaneswar Gude 10.1 Introduction.....................................................................................................197 10.2 Description of desalination processes...............................................................198 10.2.1 Solar stills...........................................................................................198 10.2.2 Multi-stage flash desalination..............................................................199 10.2.3 Multi-effect distillation.......................................................................199 10.2.4 Vapor compression.............................................................................199 10.2.5 Energy efficiency of thermal desalination...........................................200 10.2.6 Reverse osmosis..................................................................................200 10.2.7 Membrane distillation.........................................................................201 10.3 Desalination and sustainability.........................................................................203 10.3.1 Environmental footprint......................................................................203 10.3.2 Economics of desalination..................................................................205 10.3.3 Social aspects of desalination..............................................................206 10.4 Renewable energy integration..........................................................................207 10.4.1 Selection process of desalination process............................................209 10.5 Future of sustainable desalination....................................................................210 10.5.1 Desalination at household level...........................................................210 10.5.2 Desalination at community or municipal scale....................................211 References.................................................................................................................212 x Contents Chapter 11: Groundwater sustainability in a digital world....................................215 Ahmed S. Elshall, Ming Ye and Yongshan Wan 11.1 Introduction.....................................................................................................215 11.2 Groundwater sustainability...............................................................................217 11.3 Digital groundwater.........................................................................................220 11.4 Internet of Things(cid:1)based data collection.........................................................221 11.5 Web-based data sharing...................................................................................222 11.6 Workflow for data processing..........................................................................225 11.7 Scenarios for data usage..................................................................................228 11.8 Perspectives of web-based groundwater platforms...........................................230 11.9 Disclaimer........................................................................................................233 Acknowledgments......................................................................................................233 References.................................................................................................................234 Chapter 12: Economics of water productivity and scarcity in irrigated agriculture........................................................................241 James F. Booker 12.1 Introduction.....................................................................................................241 12.2 Productivity concepts as indicators..................................................................243 12.3 Production and scarcity in economics..............................................................248 12.4 Constructing water productivity indicators: physical and economic considerations..................................................................................................249 12.4.1 Physical considerations.......................................................................250 12.4.2 Economic considerations.....................................................................251 12.4.3 Net water productivity........................................................................252 12.5 Trends in water productivity............................................................................253 12.5.1 Physical and economic water productivity trends................................253 12.5.2 Economic net water productivity trends: value added, optimization, and hydroeconomic models...........................................254 12.5.3 Other economic approaches to water productivity and efficiency........256 12.6 Conclusions.....................................................................................................257 References.................................................................................................................258 Chapter 13: Potential of municipal wastewater for resource recovery and reuse....263 Manzoor Qadir 13.1 Introduction.....................................................................................................263 13.2 Wastewater as a water source..........................................................................264 13.3 Wastewater as a nutrient source.......................................................................265