Wabamun Lake Oil Spill August 2005: Data Report For Water And Sediment Quality The Pelagic Area In Of The Lake (August 4-5 to September 2005) 15, ydlbsrfa Environment Digitized by the Internet Archive 2015 in https://archive.org/details/wabamunlakeoilspOOande Wabamun Lake August 2005 Oil Spill Data Report for Water and Sediment Quality in the Pelagic Area of the Lake (August 4-5 to September 2005) 1 5, Prepared by: Anne-Marie Anderson, Ph.D., P.Biol. Limnologist/Water Quality Specialist Environmental Monitoring and Evaluation Branch Environmental Assurance Division April 2006 W0602 Pub. No: T/856 ISBN: 0-7785-4588-1 (Printed Edition) ISBN: 0-7785-4589-X (On-Line Edition) Web Site: http://environment.gov.ab.ca/info/home.asp Any comments, questions, or suggestions regarding the content of this document may be directed to: Environmental Monitoring and Evaluation Branch Alberta Environment 10th Floor, Oxbridge Place 9820- 106th Street Edmonton, Alberta T5K 2J6 Phone: (780)427-6278 Fax: (780)422-6712 Additional copies of this document may be obtained by contacting: Information Centre Alberta Environment Main Floor, Oxbridge Place 9820- 106*^ Street Edmonton, Alberta T5K 2J6 Phone: (780)427-2700 Fax: (780)422-4086 Email: [email protected] EXECUTIVE SUMMARY On August 3, 2005, petroleum hydrocarbons spilled into Wabamun Lake following the derailment of43 CN rail cars along the north shore ofthe lake, near the village of Whilewood Sands. The oil slick spread rapidly into the pelagic portion ofthe lake, but in the week following the spill, strong westerly winds and resulting wave action ensured that much ofthe oil drifted to the north, east and south-east shoreline. This report provides a summary ofthe chemical data (extractable and volatile priority pollutants, PAH, and trace metals) collected from water and sediments in the pelagic zone ofthe lake on the days and weeks following the spill. • The oil slick spread rapidly over the eastern and south-east portion ofthe lake, but in the week following the spill, strong westerly winds and wave action ensured that most ofthe oil drifted to the shoreline. Overall, water and sediments in the open water area ofthe lake were not contaminated with spilled hydrocarbons. Only very low levels ofBTEX and some PAHs were detected occasionally. • Results from the Paul Band site indicated some low-level water volatile hydrocarbon contamination that could possibly be related to recovery operations along the shoreline and/or wind patterns that may have resulted in the transport of hydrocarbons on the water surface to that area. • Hydrocarbons contained by a boom that had become unanchored were well in excess ofguidelines for the protection ofaquatic life. Potential escape ofoil towards the open water represents an ongoing risk to water quality and aquatic life. • There was no post-spill evidence ofan increase in water and sediment metal concentrations. Wabamun Lake Spill August 2005. Data Report for the Open Water Area of the Lake (August 4-5 to September 15, 2005) i 0 TABLE OF CONTENTS EXECUTIVE SUMMARY i LIST OF TABLES iii LIST OF FIGURES iii LIST OF APPENDICES iv ACKNOWLEDGEMENTS v INTRODUCTION 1.0 1 METHODS 2.0 2 2.1 Sampling Methods 2 2.1.1 Water Chemistry 2 2.1.2 Sediment Sampling 5 2.2 Laboratory Analyses 5 2.2.1 Trace Organic Compounds 5 2.2.2 Metals 8 2.2.3 Particle Size and TOCAnalysis 8 2.3 Data Presentation 8 RESULTS AND DISCUSSION 3.0 1 3.1 Water 10 3.1.1 Trace Organics in Water 10 3.1.2 Metals in Water 15 3.2 Sediments 21 3.2.1 Lake Sediment Characteristics 21 3.2.2 Trace Organics in Sediments 21 3.2.3 Metals 26 4.0 LITERATURE CITED 28 5.0 APPENDICES 30 Wabamun Lake Spill August 2005. Data Report for the Open Water Area of the Lake (August 4-5 to September 15, 2005) ii 6 LIST OF TABLES Table 1 Wabamun Lake 2005 sampling sites 4 Table 2a Valid method variable codes and detection limits for trace organic compounds in water 6 Table 2b Valid method variable codes and detection limits for trace organic compounds in sediments 7 Table 3 Valid method variable codes and detection limits for metals and other elements in water and sediments 9 Table 4 Trace organics in Wabamun Lake water: summary ofdetections and comparisons with guidelines 11 Table 5 Comparison of2005 metals concentrations in Wabamun Lake water with surface water quality guidelines and 2002 metals concentrations 1 PAH CCME Table 6 Comparison of concentrations detected in lake sediments with available sediment quality guidelines 23 Table 7 Comparison ofmetals detected in Wabamun Lake sediments with CCME sediment quality guidelines (all concentrations in )ig/g dry weight) 27 LIST OF FIGURES Figure 1 Wabamun Lake 2005 - sampling sites with site name and sampling schedule 3 Figure 2 Metal concentrations measured in Wabamun Lake water at sites sampled in 2005 before and after the Bunker C spill 17 Figure 3 Trace organics detected in Wabamun Lake sediments at sites sampled in 2005 and 2002 24 Wabamun Lake Spill August 2005. Data Report for the Open Water Area of the Lake (August 4-5 to September 15, 2005) Hi LIST OF APPENDICES Appendix 1 . List of samples collected from the pelagic area in Wabamun Lake, 2005 31 Appendix 2 Trace organic analyses in Wabamun Lake water, 2005 39 Appendix 3 Total metal concentrations in Wabamun Lake water, 2005 55 Appendix 4 Sediment characteristics for samples taken from Wabamun Lake, 2005 59 Appendix 5 Trace organic analyses in Wabamun Lake sediments, 2005 60 Appendix 6 Total (harsh extraction) and extractable (mild extraction) ofmetals in Wabamun Lake sediments 72 Appendix 7 Results ofQA/QC Sampling 76 Wabamun Lake Spill August 2005. Data Report for the Open Water Area of the Lake (August 4-5 to September 15, 2005) iv ACKNOWLEDGEMENTS This data report has benefited from the review comments of Leigh Noton (Environmental Monitoring and Evaluation Branch, Head Water Quality Team), and Lcanne Zrum (Limnologist, Alberta Environment, Central Region); both also had a leading role in the design and implementation ofthe study. Many staffmembers from Northern Region participated in the sampling program, in particular, Brian Jackson, Monica Polutranko, John Willis, and Chris Ware. The Analytical Chemistry Laboratory, Alberta Research Council, Vegreville conducted the chemical analysis ofwater and sediment samples under the supervision ofGrant Prill (Trace Organics Laboratory) and Frank Skinner (Inorganic Chemistry Laboratory). Doreen LeClair and Bridgette Halbig (Environmental Monitoring and Evaluation Branch) assisted in data management and report preparation. Wabamun Lake Spill August 2005. Data Report for the Open Water Area of the Lake (August 4-5 to September 15, 2005) V Wabamun Lake Spill August 2005. Data Report for the Open Water Area of the Lake (August 4-5 to September 15, 2005) vi