W Tungsten: Supplement Volume A 5 b Metal, Chemical Reactions with Nonmetals Nitrogen to Arsenic

211 Pages·1993·5.75 MB·English

by  Hermann Jehn

1
2 Hel 10 I Ne 18 I Ar 36 I Kr 54 I Xe 86 I Rn H,23
;
I H2 ~5 17 6 CI 357 Br 5,38 85 8a At I
~3 16 S 9 34 Se 10 5211 Te 84'2 Po 71 Lu 10371 Lr
~ 4 ~ 16 33 As 17 :~ 18 :~ 19 70 Vb 10271 No
I 6 14 C ~t 15 32 45 Ge 50 46 Sn ~:47 69 Tm 101 71 Md ---
3 5 6 7 8 1
m Numbers I ! I 5 B 1 13 AI 3 31 30 Zn 32 3Ga 48 49 Cd 33 In 3 80 81 TI 3H34 g 67 68 Er Ho 99WO 771 Fm Es
n Syste 29 Cu 60 47 A61 g 79 Au 62 66 Dy 9871 Cf
Gmeli 28 Ni 57 46 Pd 65 78 Pt 68 65 Tb 9771 Bk
e
with th 27 Co 58 45 64 Rh 77 Ir 67 64 Gd 9671 Cm
ments 26 Fe 59 44 63 Ru 76 Os 66 63 Eu 9571 Am
the Ele I I II I I I I ! I I I 25 56 Mn 43 Tc 69 75 Re 70 62 Sm 9471 Pu
Table of 24 Cr 52 42 M53 o 74 54 W 61 Pm 9371 Np
eriodic I I I I I I 23 V 48 41 49 Nb 73 Ta 50 10571 ,-- 60 Nd 9255 U
P ! 22 Ti 41 40 Zr 42 72 Hf 43 104 71 ------- 59 Pr 91 51 Pa
21 Sc 39 ~39 57** La 39 89*** Ac 40 58 Ce 9044 Th
I H 2 4 3 Li 20 26 Be 11 12 M27 21 gNa 20 19 * K 22 Ca 28 37 38 Sr 29 24 Rb 555630 25 Ba Cs 87 8831 25a FrRa fk*Lanthan ides 39 ~**Actinides
> J s-i Cl' [ s' i ;; ... Cir i' g i i ~ ~ ~ n ~
Gmelin Handbook of Inorganic
and Organometallic Chemistry
8th Edition
Gmelin Handbook of Inorganic
and Organometallic Chemistry
8th Edition
Gmelin Handbuch der Anorganischen Chemie
Achte, völlig neu bearbeitete Auflage
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CONTINUED BV E. H. E. Pietsch and A. Kotowski, and by
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kusen), Prof. Dr. H. Harnisch, Chairman (Hoechst AG, FrankfurtlMain-Höchst), Prof. Dr.
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Volumes published on "Tungsten" (Syst. No. 54)
Tungsten
Main Volume - 1933
Tungsten Suppt. Vot. A 1
Metal, Technology -1979
Tungsten Suppt. Vol. A 2
Physical Properties - 1987
Tungsten Suppt. Vol. A 3
Physical Properties - 1989
Tungsten Suppt. Vol. A 4
Surtace Properties. Electron Emission - 1993
Tungsten Suppt. Vot. A 58
Electrochemistry - 1990
Tungsten Suppt. Vol. A 5 b
Metal, Chemical Reactions wlth Nonmetals Nitrogen to Arsenic - 1993 (present volume)
Tungsten Suppt. Vot. A 68
Metal, Chemical Reactions with Metals Antimony to Barium - 1991
Tungsten Suppt. Vol. A 6b
Metal, Chemical Reactions with Metals Zinc to Lawrencium - 1988
Tungsten Suppt. Vot. A 7
Metal, Chemical Reactions with Inorganic and Organic Compounds - 1987
Tungsten Suppt. Vot. B 1
Systems with Noble Gases, Hydrogen, and Oxygen - 1978
Tungsten Suppt. Vot. B 2
Oxides - 1979
Tungsten Suppl. Vol. B 3
Compounds of Tungsten with Oxygen and Antimony, Bismuth; Alkali Tungstates - 1979
Tungsten Suppt. Vot. B 4
Tungstates of Group 11 A and 11 B Metals - 1980
Tungsten Suppt Vot. B 5
Tungstates of Group 111 A and 111 B Metals - 1984
Tungsten Suppl. Vot. B 6
Anhydrous Tungstates of Group IV A and VI B Metals - 1984
Gmelin Handbook of Inorganic
and Organometallic Chemistry
8th Edition
W
Tungsten
Supplement Volume A 5 b
Metal, Chemical Reactions with Nonmetals
Nitrogen to Arsenic
With 129 illustrations
AUTHORS Hermann Jehn
Forschungsinstitut tür Edelmetalle und Metallchemie,
Schwäbisch Gmünd (Chapter 1)
Gudrun Bär, Erich Best, Ernst Koch
EDITORS Jörn von Jouanne, Elisabeth Koch, Ernst Koch
CHIEF EDITORS Jörn von Jouanne, Ernst Koch
System Number 54
Springer-Verlag Berlin Heidelberg GmbH 1993
LITERATURE GLOSING DATE: MID 1991
IN SOME GASES MORE REGENT DATA HAVE BEEN GONSIDERED
Library 01 Congress Catalog Card Number: Agr 25-1383
ISBN 978-3-662-08686-5 ISBN 978-3-662-08684-1 (eBook)
DOI 10.1007/978-3-662-08684-1
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@ by Springer-Verlag Berlin Heidelberg 1993
Originally published by Springer-Verlag, Berlin in 1993.
Softcover reprint of the hardcover 8th edition 1993
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Preface
The present voLume describes the chemicaL behavior of eLementaL tungsten toward the non
metaLlic eLements nitrogen to arsenic (i.e., N, F, CL, Sr, I, S, Se, Te, Po, S, C, Si, P, and As).
The description of the chemicaL behavior starts with information on the phase diagrams
wh ich aLLow an overview of the existing stabLe compounds. The major part of the information in
this voLume is about the kinds of products, the experimentaL conditions, as weLL as the kinetics
and thermodynamics of their formation. Short descriptions of buLk diffusion in binary systems
compLement the kinetic data on the mostLy diffusion-controLLed reactions. Pure surface
phenomena on tungsten are not considered.
A Large chapter is devoted to the comprehensiveLy studied chemicaL processes and trans
port processes in tungsten-haLogen Lamps. Product formation in the tungsten-carbon and
tungsten-silicon systems is aLso of speciaL interest in view of possibLe appLications.
The present voLume concLudes the series of voLumes devoted to the chemicaL behavior of
eLementaL tungsten. Interactions and reactions with nobLe gases, hydrogen, and oxygen are
covered in "Wolfram" Erg.-Sd. S 1. Interactions and reactions with metaLlic eLements are
described in "Tungsten" SuppL. VoL. A 6a (eLements antimony to barium) and in "Tungsten"
SuppL. VoL. A 6 b (eLements zinc to actinides).
Frankfurt am Main Ernst Koch
October 1993 Jörn von Jouanne