W Tungsten: Metal, Chemical Reactions with Metals Zinc to Lawrencium

358 Pages·1987·7.112 MB·English

by  Wolfgang Kurtz, Hans Vanecek (auth.), Ernst Koch, Wolfgang Kurtz (eds.)

2 Hel 10 Ne I 18 Ar I 36 Kr I 54 Xe I 86 Rn I Hfll
~
I
2 5 6 7 8 a
I H 9 F 17 Cl 35 Br 53 I 85 At8
8 0 3 16 s 9 34 Se 10 52 Te II 84 p12 0 71 Lu 103 Lr 71
7 N 4 15 p 16 33 As 17 51 Sb 18 83 Bi 19 70 Yb 102 No 71
6 c 14 14 Si 15 32 Ge45 50 Sn 46 82 Pb 47 69 Tm 101 Md 71
bers 5 B 13 13 Al35 31 Ga36 49 ln 37 81 Tl 38 68 Er 100 Fm 71
m Num 30 Zn 32 48 Cd 33 80 Hg34 67 Ho 99 Es 71
n Syste 29 Cu 60 47 Ag 61 79 Au 62 66 Dy 98 Cf 71
e Gmeli 28 Ni 57 46 Pd 65 78 Pt 68 65 Tb 97 Bk71
with th 27 Co 58 45 Rh64 77 Ir 67 64 Gd 96 cm71
ments 26 Fe 59 44 Ru 63 76 Os 66 63 Eu 95 Am71
e
of the El ! 25 Mn 56 43 Tc 69 75 Re 70 62 Sm 94 Pu 71
Table 24 Cr 52 42 Mo 53 74 w54 61 Pm 93 71 Np
eriodic 23 V 48 41 Nb49 73 Ta 50 105 71 60 Nd 92 u 55
P :
22 Ti 41 40 Zr 42 72 Hf 43 104 71 59 Pr 91 Pa 51 --
21 Sc 39 39 39 y 57** La 39 89*** Ac40 58 Ce i~44 '
4 Be26 12 Mg27 20 Ca 28 38 Sr 29 56 Ba 30 88 Ra31 an ides 39 ides
I H 2 3 Li 20 II Na21 19 * K 22 37 Rb24 55 Cs 25 87 Fr25a *Lanth **Actin
* ~
l> E ... 0 ~ C"> i. ;;· j 3 ... ii'i' ~· g g. "' 1f ~ CO ... "' ""' (") ~
Gmelin Handbook of Inorganic Chemistry
8th Edition
Grnelin Handbook
of lnorganic Chemistry
8th Edition
Gmelin Handbuch der Anorganischen Chemie
Achte, völlig neu bearbeitete Auflage
Prepared Gmelin-Institut für Anorganische Chemie
and issued by der Max-Planck-Gesellschaft
zur Förderung der Wissenschaften
Director: Ekkehard Fluck
Founded by Leopold Gmelin
8th Edition 8th Edition begun under the auspices of the
Deutsche Chemische Gesellschaft by R. J. Meyer
Continued by E. H. E. Pietsch and A. Kotowski, and by
Margot Becke-Goehring
Springer-Verlag Berlin Heidelberg GmbH 1988
Gmelin-Institut für Anorganische Chemie
der Max-Planck-Gesellschaft zur Förderung der Wissenschaften
ADVISORY BOARD
Dr. G. Breit, Chairman (Ruhrchemie AG, Oberhausen-Holten), Prof. Dr. K. Dehnicke (Philipps
Universität, Marburg), Prof. Dr. N. N. Greenwood (University of Leeds), Prof. Dr. H. Grünewald
(Bayer AG, Leverkusen), Prof. Dr. H. Harnisch (Hoechst AG, Frankfurt/Main-Höchst), Prof. Dr.
H. Nöth (Universität München), Prof. Dr. H. Ottermanns (Degussa AG, Frankfurt/Main), Prof.
Dr. G. zu Putlitz (Universität Heidelberg), Prof. Dr. A. Rabenau (Max-Planck-Institut für Festkör
perforschung, Stuttgart), Prof. Dr. A. Sirnon (Max-Planck-Institut für Festkörperforschung,
Stuttgart), Prof. Dr. Dr. A. H. Staab (Präsident der Max-Planck-Gesellschaft, München), Prof.
Dr. Dr. h.c. mult. G. Wilke (Max-Planck-Institut für Kohlenforschung, Mülheim/Ruhr)
DIRECTOR DEPUTY DIRECTOR
Prof. Dr. Dr. h. c. Ekkehard Fluck Dr. W. Lippert
CHIEF EDITORS
Dr. K.-C. Buschbeck-Dr. H. Bergmann, J. Füssel, H. Hartwig, Dr. H. Katscher, Dr. R. Keim, Dr.
E. Koch, Dipl.-Phys. D. Koschel, Dr. U. Krüerke, Dr. H. K. Kugler, Dr. P. Merlet, Dr. E. Schleitzer
Rust, Dr. F. Schröder, Dr. A. Slawisch, Dr. W. Töpper
CORRESPONDENT MEMBERS OF THE SCIENTIFIC STAFF Dr. H. C. Andersen, Dr. W. F. McNamara,
Dr. V. Haase, Dipl.-Ing. G. Kirschstein,
Dr. K. Rumpf, Dr. U. Trobisch,
Dr. B. Vance
EMERITUS MEMBER OF THE INSTITUTE Prof. Dr. Dr. E. h. Margot Becke
CORRESPONDENT MEMBERS OF THE INSTITUTE Prof. Dr. Hans Bock
Prof. Dr. Dr. Alois Haas, Sc. D. (Cantab.)
STAFF GMELIN HANDBOOK
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I. Deim, Dipl.-Chem. H. Demmer, Dipl.-Geol. R. Ditz, R. Dowideit, Dipl.-Chem. M. Drößmar, Dr.
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H.-P. Hente, H. W. Herold, U. Hettwer, Dr. G. Hönes, Dr. W. Hoffmann, Dr. W. Huisl, R. Jonu
schat, Dr. R. Jotter, Dr. J. von Jouanne, Dr. B. Kalbskopf, Dipl.-Chem. W. Karl, H.-G. Karren
berg, Dipl.-Phys. H. Keller-Rudek, B. Kirchner, A. Klusch, C. Koeppel, Dipl.-Chem. H. Köttel
wesch, R. Kolb, E. Kranz, Dipl.-Chem. I. Kreuzbichler, Dr. A. Kubny, Dr. M. Kunz, Dr. W. Kurtz,
M. Langer, Dr. U. Lanzendörfer, Dr. B. Ledüc, Dr. A. Leonard, Dipl.-Chem. H. List, H. Mathis,
E. Meinhard, ~. Metz, K. Meyer, Dr. M. Mirbach, Dipl.-Chem. B. Mohsin, Dr. U. Neu-Becker,
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W. Petz, I. Rangnow, Dipl.-Phys. H.-J. Richter-Ditten, Dipl.-Chem. H. Rieger, E. Rieth, A. Ro
senberger, E. Rudolph, G. Rudolph, Dipl.-Chem. S. Ruprecht, Dr. B. Sarbas, Dr. D. Schiöberg,
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U. Taubald, M. Teichmann, Dr. D. Tille, Dipl.-lng. H. Vanecek, Dipl.-Chem. P. Velic, Dipl.-Ing.
U. VettGr, H.-M. Wagner, Dipl.-Phys. J. Wagner, R. Wagner, Dr. E. Warkentin, Dr. C. Weber, Dr.
A. Wietelmann, Dr. M. Winter, Dr. B. Wöbke, K. Wolff
STAFF GMELIN ONLINE DATA SYSTEM
Dr. R. Froböse, Dr. P. Kuhn, Dr. G. Olbrich
Volumes published on "Tungsten" (Syst. No. 54)
Tungsten
Main Volume - 1933
Tungsten Suppt. Vol. A 1
Meta!, Technology- 1979
Tungsten Suppt. VoL A 6b
Meta!, Chemical Reactions with Metals Zinc to Lawrencium-1988 (present volume)
Tungsten Suppt. Vol. A 7
Meta!, Chemical Reactions with lnorganic and Organic Compounds- 1987
Tungsten Suppt. VoL B 1
Systems with Noble Gases, Hydrogen, and Oxygen- 1978
Tungsten Suppt. Vol. B 2
Oxides - 1979
Tungsten Suppt. Vol. B 3
Compounds of Tungsten with Oxygen and Antimony, Bismuth; Alkali Tungstates- 1979
Tungsten Suppt. Vol. B 4
Tungstates of Group HA and 118 Metals- 1980
Tungsten Suppt. Vol. B 5
Tungstates of Group lilA and IIIB Metals- 1984
Tungsten Suppt. Vol. B 6
Anhydrous Tungstates of Group IV A to VI B Metals - 1984
Grnelin Handbook
of lnorganic Chemistry
8th Edition
w
Tungsten
Supplement Volume A 6 b
Metal, Chemical Reactions with Metals Zinc
to Lawrencium
With 89 illustrations
AUTHORS Wolfgang Kurtz, Hans Vanecek
EDITORS Ernst Koch, Wolfgang Kurtz
CHIEF EDITOR Ernst Koch
System Number 54
Springer-Verlag Berlin Heidelberg GmbH 1988
LITERATURE CLOSING DATE: 1986
IN SOME CASES MORE RECENT DATA HAVE BEEN CONSIDERED
Library of Congress Cetelog Card Numbar: Agr 25-1383
ISBN 978-3-662-08692-6 ISBN 978-3-662-08690-2 (eBook)
DOI 10.1007/978-3-662-08690-2
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© by Springer-Verlag Berlin Heldeiberg 1987
Originally published by Springer-Verlag Berlin Heldeiberg New York Tokyo in 1987
Softcover reprint of the hardcover 8th edition 1987
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Preface
The present volume continues the description of the chemical reactions of eiemental
tungsten started with "Tungsten" Suppl. Vol. A 7. It covers the reactions with the metallic
elements from zinc to actinoids.
The treatment includes phase diagrams, bulk reactions, and surface processes which again
are of outstanding importance in most systems.
The raader is referred to the introductory remarks on pp. X/XI.
Frankfurt am Main Ernst Koch
November 1987