ebook img

Van Nostrand’s Scientific Encyclopedia PDF

3529 Pages·1995·189.459 MB·English
Save to my drive
Quick download
Download
Most books are stored in the elastic cloud where traffic is expensive. For this reason, we have a limit on daily download.

Preview Van Nostrand’s Scientific Encyclopedia

Eighth Edition VAN NOSTRAND'S ENTIFIC Eighth Edition Animal Life Biosciences Chemistry Earth and Atmospheric Sciences Energy Sources and Power Techonology Mathematics and Information Sciences Materials and Engineering Sciences Medicine, Anatomy, and Physiology Physics Plant Sciences Space and Planetary Sciences DOUGLAS M. CONSIDINE, P.E. Editor GLENN D. CONSIDINE Managing Editor SPRINGER SCIENCE+BUSINESS MEDIA, LLC Copyright© 1995 by Springer Science+Business Media New York Originally published by Van Nostrand Reinhold in 1995 Softcover reprint ofthe hardcover 8th edition 1995 Ali rights reserved. N o part of this work covered by the copyright hereon may be reproduced or used in any form or by any means-graphic, electronic, or mechanical, including photocopying, recording, taping, or information storage and retrieval systems-without the written permission ofthe publisher. 1 2 3 4 5 6 7 8 9 1O ARCKP O1 00 99 98 97 96 95 94 Library of Congress Cataloging-in-Publication Data Van Nostrand's scientific encyclopedia 1 Douglas M. Considine, editor. Glenn D. Considine, managing editor.-8th ed. p. cm. Includes bibliographical references and index. ISBN 978-1-4757-6920-3 ISBN 978-1-4757-6918-0 (eBook) DOI 10.1007/978-1-4757-6918-0 1. Science - Encyclopedias. 2. Engineering-Encyclopedias. I. Considine, Douglas M. II. Title: Scientific encyclopedia. Q12l.V3 1994 94-29100 503-dc20 CIP REPRESENTATIVE TOPICAL COVERAGE ANIMAL LIFE Amphibians Coelenterates Mamals Protozoa Annelida Echinoderms Mesozoa Reptiles Arthropods Fishes Mollusks Rotifers Birds Insects Paleontology Zoology BIOSCIENCES Amino Acids Biophysics Genetics Proteins Bacteriology Cytology Hormones Recombinant DNA Biochemistry Enzymes Microbiology Viruses Biology Fermentation Molecular Biology Vitamins CHEMISTRY Acids and Bases Corrosion Inorganic Chemistry Oxidation-Reduction Catalysts Crystals Ions Photochemistry Chemical Elements Electrochemistry Macromolecular Science Physical Chemistry Colloid Systems Free Radicals Organic Chemistry Solutions and Salts EARTH AND ATMOSPHERIC SCIENCES Climatology Geodynamics Hydrology Tectonics Ecology Geology Meteorology Seismology Geochemistry Geophysics Oceanography Volcanology ENERGYSOURCESANDPOWERTECHNOLOGY Batteries Electric Power Nuclear Energy Steam Generation Biomass and Wastes Geothermal Energy Ocean Energy Resources Tidal Energy Coal Hydroelectric Power Petroleum Turbines Combustion Natural Gas Solar Energy Wind Power MATHEMATICS AND INFORMATION SCIENCES Automatic Control Computing Measurements Statistics Communications Data Processing Navigation and Guidance Units and Standards MATERIALS AND ENGINEERING SCIENCES Chemical Engineering Laser Technology Mining Process Engineering Civil Engineering Mechanical Engineering Microelectronics Structural Engineering Glass and Ceramics Metallurgy Plastics and Fibers Transportation MEDICINE, ANATOMY, AND PHYSIOLOGY Brain and Nervous System Genetic Disorders Ophthalmology Cancer and Oncology Gerontology Otorhinolaryngology/Dental Cardiovascular System Hematology Parasitology Chemotherapy Immunology Pharmacology Dermatology Infectious Diseases Reproductive System Diagnostics Kidney and Urinary Tract Respiratory System Digestive System Mental Illness Rheumatology Endocrine System Muscular System Skeletal System PHYSICS Atoms and Molecules Gravitation Optics Subatomic Particles Electricity Magnetism Radiation Surfaces Electronics Mechanics Solid State Theoretical Physics Fluid State Motion Sound Waves PLANT SCIENCES Agriculture Diseases and Pests Growth Modifiers Seeds and Germ Plasm Algae Fruits Nutritional Values Trees Botany Fungi Plant Breeding Yeasts and Molds SPACE AND PLANETARY SCIENCES Astrochemistry Astronautics Astrophysics Probes and Satellites Astrodynamics Astronomy Cosmology Solar System v Preface Advancements in science and engineering have occurred at a surprisingly rapid pace since the release of the seventh edition of this encyclopedia. Large portions of the reference have required comprehensive rewriting and new illustrations. Scores of new topics have been included to create this thoroughly updated eighth edition. The appearance of this new edition in 1994 marks the continuation of a tradition commenced well over a half-century ago in 1938 Van Nostrand's Scientific Encyclopedia, First Edition, was published and welcomed by educators worldwide at a time when what we know today as modern science was just getting underway. The early encyclopedia was well received by students and educators alike during a critical time span when science became established as a major factor in shaping the progress and economy of individual nations and at the global level. A vital need existed for a permanent science reference that could be updated periodically and made conveniently available to audiences that numbered in the millions. The pioneering VNSE met these criteria and continues today as a reliable technical information source for making private and public decisions that present a backdrop of technical alternatives. It is pertinent to note that over the years a number of successful scientists and engineers have given this single publication ( VNSE) much of the credit for initially inspiring their interest in science, sometimes leading to a lifetime career in science or, in other instances, stimulating scientific hobbies and participation in events of scientific concern at the community level. A majority of social and health issues today, for example, must be discussed in scientific terms in the interest of developing effective remedial actions. Frequently, the VNSE can serve as the basis of a forum for discussing conflicting professional viewpoints. As information processing capabilities expand, the editors' roles become more important and more difficult. With expanding masses of raw information, the tasks of sorting and weighing the relative importance of new data require increasing editorial judgment and skill. The editors not only have the task of identifying new information and of eliminating obsolete data, but even more importantly, they have the chore of providing the keys to the meaning of new data. Great care must be exercised by the editors to select and include numerous sources of additional reading on all important topics. References must be selected for their authenticity, their own particular vantage points, and notably for new content that augments and not simply repeats the content of the encyclopedia entry per se. SCOPE Six major categories of scientific endeavor are addressed by the VNSE, Energy and Environmental Sciences. Chemical Fuels, Environ Eighth Edition. In turn, each of these categories is divided into more ment, Fossil Fuels, Geothermal Energy, Hydropower, Nuclear Power, specialized fields. It is clearly evident, of course, that science is a Solar Energy, Tidal Energy highly interdisciplinary field of knowledge, a fact that tends to blur Materials Sciences. Chemical Engineering, Civil Engineering, Me rigid definitions. The six basic categories may be subdivided as fol chanical Engineering, Metallurgy, Mining, Solid State, Structural En lows: gineering, Synthetics and Polymers, Composites Earth and Space Sciences. Astrodynamics, Astronautics, Astron Physics and Chemistry. Acoustics, Atoms/Molecules, Crystals, omy, Cosmology, Geodesy, Geology, Geophysics, Hydrology, Meteor Electricity, Electronics, Fluids, Inorganics, Lasers, Magnetism, Me ology, Oceanography, Seismology, Spacecraft chanics, Optics, Organics, Particle Physics, Radiation, Thermodynam Life Sciences. Amphibians, Anatomy, Bacteriology, Biosciences, ics, Thin Films Birds, Diseases, Ecology, Fishes, Gene Sciences, Insects, Mammals, Mathematics and Information Sciences. Communications, Com Other Life, Paleontology, Physiology, Plants, Reptiles puters, Statistics, Standards VIGNETTES UTTER CHAOS. Since the formative years of science, the precepts you need to understand a system rises exponentially with the system's of classical mechanics were entrenched firmly in the pursuit of dy dimensionality, that is, the number of independent variables or degrees namic systems and guided by the unwavering notion that the behavior of fre~dom needed to describe it. Some of the projects involving what of complex systems could be predicted accurately provided that one had we thought would be simple questions have turned out to be very diffi enough information and intelligence. The concept (or theory) of chaos cult. And, of course, there's the problem of noise. In many cases, it may has challenged this historic approach. The ground rules are changing! be very hard to get data sets that are sufficiently tidy for understanding The "sufficient information" doctrine first was challenged at the chaos. On the other hand, chaos theory can help us learn the limits of atomic level by quantum mechanics in the 1920s. In the 1980s, prior predictability for very complex systems, such as the weather, and may tenets received another setback with the emergence of chaos theory. even give us new tools for controlling these systems. This theory holds that for microscopic or macroscopic systems, tiny The implications of chaos theory for electric power equipment and variations in initial conditions sometimes may create unexpected, radi networks are both disturbing and exciting. On the one hand, an unsus cally different outcomes, seemingly making it impossible to predict pected potential for instability may lurk among the operating condi fully the behavior of some systems. Perhaps most startling of all, such tions of systems thought to be well understood. Sudden voltage col behavior can arise in relatively simple systems governed by a few un lapses on power grids, for example, may indicate the presence of complicated equations. Thus, relatively simple or highly complex sys underlying chaotic dynamics. On the other hand, understanding chaos tems can exhibit chaos. During the course of the first score of years of may provide unprecedented control over some of the most complex and its existence, chaos theory generated wide interest in academia, but elusive natural processes, such as combustion, corrosion, and super relatively few practical examples. However, quite recently, the science conductivity. of system dynamics has entered a new era, one that is comparable to the Researchers observe, "The problem is how to distinguish 'determi time frame when quantum mechanics was "fleshing out." nistic chaos' from stochastic, or totally random behavior. Chaos has an A physicist at the Electric Power Research Institute recently ob underlying order, a pattern that's not periodic, but isn't completely ran served, "With chaos, we're on the brink of a new classical dynamics and dom either. In any real system, however, some stochastic processes are people thought that classical physics was dead." Another scientist has also likely to be present as noise. It's like looking for a fuzzy pattern observed, "It's called the curse of dimensionality"-the amount of data through a fog." vii VAST GALAXY DRIFT. Coma cluster of galaxies. Astronomers Tod R. Lauer (National Optical Astronomy Observatories) and Marc Postman (Space Telescope Science Institute) used the brightest galaxy in this cluster, and 118 other clusters like it, as stationary references for observing motion of our own Milky Way galaxy with respect to the universe. (National Optical Astronomy Observatories). Preface ix As early as 1899, Jules-Henri Poincare (France) recognized the pos new observations thus challenge our understanding of how the uni sibility fur chaotic behavior in dynamic systems. However, it was not verse evolved. until 1961 that the meteorologist, Edward Lorenz, observed the phe This surprising conclusion comes from the deepest systematic survey nomenon when he was attempting to construct a simple computer of galaxy distances to date, conducted by Dr. Tod R. Lauer of National model of weather on the basis of convection currents in the earth's at Optical Astronomy Observatories (NOAO) in Tucson, Arizona, and Dr. mosphere. Marc Postman of the Space Telescope Science Institute (STScl) in Bal Lorenz mapped a three-dimensional pattern (called a butterfly) that timore, Maryland. The two astronomers used NOAO telescopes at Kitt commonly appears when plotting chaotic data. The development of Peak National Observatory, near Tucson, Arizona, and at Cerro Tololo chaos science to where it is today is exquisitely summarized: "It took Inter-American Observatory, near La Serena, Chile, to study galaxy more than a decade and a half for this phenomenological pattern to gain motions over the entire sky out to a distance of over 500 million light enough recognition to be named and it took even longer for investiga years, thus exploring a volume of space about thirty times larger than tions of chaos to earn scientific respectability." has been surveyed previously. 1 Processes currently under investigation with reference to chaos in The expansion of the universe causes all galaxies to be moving clude fluidized-bed combustion, electric power grids, and chaos as re away from us. Galaxies at the far edge of the volume surveyed by lated to fractal geometry. Lauer and Postman (see accompanying photo) are receding from us See Mathematics (State of the Art Reviews). at 5 percent of the speed of light. The large flow that the astronomers discovered comes from looking at the galaxy motions "left over" once the expansion of the universe has been taken into account. This flow NEW GLASS PROCESS IS COOL. Traditional glass is an inor means that the nearby universe appears to be drifting in a particular ganic product of fusion that has cooled to a rigid solid without under direction with respect to the more distant universe, as well as expand going crystallization. Recently, sol-gel glass has been introduced to the ing. commercial market. Sol-gel processing is a chemically-based method Lauer and Postman have measured the drift of the Milky Way with for producing glass at a relatively low temperature. Low-temperature respect to 119 clusters of galaxies located all over the sky at distances processing offers numerous advantages, such as casting of net shapes as far as 500 million light years. The galaxy clusters are at a variety of and net surfaces, improved physical properties, and the production of a distances from us, and galaxies in the distant clusters appear dimmer new type of material, transparent porous glass matrices. than the ones in nearby clusters. However, once the various distances A sol is a dispersion of colloidal particles in a liquid. A gel is an are accounted for, the brightest galaxy in each cluster is always found interconnected rigid network of submicrometer dimensions. A gel can to give off roughly the same amount of light. Astronomers refer to such be formed from an array of discrete colloidal particles, or a three-di objects as "standard candles." In a uniformly expanding universe, the mensional network can be formed from the hydrolysis and condensa distances to the clusters are estimated by how fast they are moving away tion of liquid metal alkoxide precursors. from us.lfthe Milky Way Galaxy is drifting, however, its motion makes The ability to make optics without grinding or polishing and to rep measurement of the expansion speed depend on the direction we are licate surface features from a master solid with high accuracy (I part in looking, and the "standard candle" galaxies will appear to vary slightly I 04) is an important advance in optical glass technology offered by sol in brightness in a smooth pattern across the sky. Lauer and Postman gel processing. The fundamental advantages of these new glass proc used images of the cluster galaxies to detect this pattern and determine esses and products are rapidly becoming apparent. the motion of our own galaxy. See Glass. If the motion of the Milky Way is caused by galaxies closer in than the set of clusters, its motion with respect to the distant clusters should be essentially identical to that with respect to the microwave back ONCOLOGY-A SHIFTING CHALLENGE. Cancers were ground radiation. But the motion of the Milky Way that Postman and treated as early as 2000 B.C. in Egypt. Throughout the intervening years, Lauer measured from the distant clusters is in a completely different various forms of cancer therapy have resulted from an iterative process direction from that inferred from the microwave background. The most of intuition and guesstimation. Contemporary cancer therapy thus es likely solution to this dilemma is that the clusters themselves are mov sentially represents the empirical knowledge amassed by the profes ing with respect to the microwave background with an average velocity sionals over a very long time span, including millions of hours in labo of 425 miles per second toward that direction of the constellation of ratory and hospital settings. There are, however, growing signs of Virgo. Because of the enormous size of the volume containing the clus impatience among scientists and the lay public and a shift away from ters, however, this result would imply the existence of even more distant vertical avenues of study. One scientist has observed, "To comprehend and massive concentrations of matter if the motions are caused by the process of carcinogenesis is to understand, at the molecular level, gravitational forces. the nature and workings of the cells that constitute life itself." See Cosmology. The probable cause of cancer at the cellular level was first suggested by the German pathologist, Rudolf Virchow (1880). His intuitively de GENETIC MAPPING. After initial persuasion by the biochemical rived concept preceded by nearly a century the beginnings of molecular biology and the establishment of the gene sciences and genetic engi and genetic sciences community, the National Academy of Sciences (U. S.), in 1988, endorsed an effort to map and sequence the human neering. It was not until the 1970s that Frederick Sanger and coworkers unraveled the structures and functions of RNA and DNA. Nevertheless, genome.2 Genetic maps had been constructed from many different types of data using different techniques ranging back to the first genetic Virchow's proposal did add a new dimension to empirical cancer inves linkage map made as early as 1913. tigations. Genetic linkage maps are based on the coinheritance of allele combi In a relatively quiet way, cancer research and the financial support nations across multiple polymorphic loci. The primary source of link for such research is being reassessed. Confidence in the professionals age data is the observation of gametic allele combinations. has suffered erosion because of miscalculations made in connection with the diagnosis and treatment of breast cancer. A rise in prostate The allelic constitution of gametes for human linkage studies tradi tionally has been determined indirectly by family studies and statistical cancer remains unexplained. inference. Improvements in analytical methods in recent years has made See Cancer and Oncology. possible the direct molecular analysis of gametes and single chromo somes. The highest level of resolution for a molecularly-based physical VAST GALAXY DRIFT. Two astronomers have discovered that our own Milky Way Galaxy and most of its neighboring galaxies con 'National Optical Astronomy Observatories, Tucson, Arizona (March 21, tained within a huge volume of the universe, one billion light years 1994). Also The Astrophysical J. (April 20, 1994). in diameter, are drifting with respect to the more distant universe. 2The genetic constitution of an organism. One full set of the 24 distinct human This startling result may imply that the universe is "lumpier" on much chromosomes is estimated to contain -3 X 109 base pairs of DNA, throughout larger scales than can be readily explained by any current theory. The which are distributed -1 X 105 genes. x Preface map is the DNA sequence. This yields the linear order of nucleotides could become the strongest fibers in existence. The strength derives for each of the 24 distinct human chromosomes. Thus, a complete ref from the nature of carbon-carbon bonds, on the one hand, and the nearly erence sequence will contain -3 X I 09 bp of DNA. flawless structure of the tubular crystals, on the other. As of the publication date of this encyclopedia, most scientist inter See Carbon. ested in the Human Genome Project (HGP) are satisfied with the pro gress made to date, and some forecast that the project may be completed ahead of the original target date of about the year 2010. Much of the A BORING TRIUMPH. Tunnel engineering dates back to the an progress is attributed to the use of advanced, automated sequencing cient Egyptians, Assyrians, and Indians who constructed tunnels in equipment. A major thrust of HPG is the ultimate development of gene connection with tombs and temples. Later, aqueducts and highways and therapy for diseases that derive from faults in the human gene system. railways required tunnels for penetrating mountainous terrain and cre See Genetics and Gene Science. ating traffic pathways under water. The first attempt to bore a tunnel under the English Channel was MOLECULE OF THE DECADE. Traditionally, the principal forms made in 1880. The tunnel was almost 8 feet (2.4 m) in diameter. Engi of carbon have been ( 1) diamond with its tetrahedral arrangement of neering and financial problems halted construction in 1882, but over atoms, (2) graphite, whose structure resembles layers of chicken wire, the years the desirability of such a structure did not diminish. It was not and sometimes (3) a poorly defined grouping of carbons, simply called until the early-1980s that the French and British drew up a working plan amorphous. This latter classification was one more of convenience than for constructing the Eurotunnel with a completion target of the mid- grounded scientifically. However, by recent concensus, a third form of 1990s. The tunnel was opened to commercial traffic in 1994. carbon now is officially recognized, namely, thefullerenes, of which the Contrary to the common conception, the Eurotunnel is not simply a C60 so-called buckminsterfullerene or "buckyball" is the most thor tube lying on the sea bed exposed to the hazards of the North Sea, but oughly investigated example of its class. several tubes bored between 82 feet (25m) and 148 feet (45 m) below The less-than-scientific aura ascribed to the comparatively recent the sea bed. From Folkestone, past Dover and under the Channel for a discovery of a third form of carbon, the fullerenes, is reminiscent of total distance of about 30 miles ( 45 km), the multiple tunnels are bored flavors used a few years ago to describe the various kinds of quarks in through chalk marl, generally considered to be one of the most consis the field of high-energy physics. The technical literature on fullerenes, tently safe tunnelling mediums. As the tunnels approach the Folkestone as of early 1994, features such terms as buckyball, buckminsterfuller terminal, they pass through gault clay and other strata and, for the first ene, buckytube, carbon cage. dopey ball, hairy ball, Russian doll, eta!., 3.1 mi (5 km) from the Coquelles (France) terminal, the tunnels pass some of which terms are synonymous; others having specific connota through more faulted zones and sands and gravels. These materials tions. Considered as an entity, fullerene chemistry constitutes a major proved to be the most difficult to bore. breakthrough in the science of physics and chemistry of materials at the Highly specialized boring machines with an inside diameter of 24.9 molecular level. feet (7.6 m) performed multiple functions, including the creation of The absence of a formal nomenclature at this juncture is accompa hydraulically sound tunnel linings. In addition to passenger trains, nied by a somewhat fuzzy chronology pertaining to the discovery and trucks riding aboard specially-designed rail cars will carry freight. Co early research on the fullerenes. However, the isolation and confirma ordination of all supporting facilities, such as communications, safety, tion of the C all-carbon molecule sans any dangling bonds, as first 60 ventilation, and high-speed operation required the exceptional techni conjectured in 1985, was pivotal to subsequent research. cal leadership and management expertise comparable to the most com Materials engineers are becoming very interested in buckytubes be plex of space-age engineering projects. cause they perform better than graphite in carbon-carbon composites. See Tunnel Engineering. A theory of the electronic properties of doped fullerenes is proposed in which electronic correlation effects, within single fullerene mole NOTE: The foregoing brief comments refer to less than Ill OOOth cules, play a central role and qualitative predictions have been made, percent of the total VNS Encyclopedia. which, if verified, will support the hypothesis. Transmission electron microscopy has revealed the formation ofbuckytubes. These ultimately DOUGLAS M. CONSIDINE, Editor Acknowledgments Several hundred scientists, engineers, and educators, located worldwide, made this Eighth Edition of the Van Nostrand's Scientific Encyclopedia a reality. Their inputs ranged from detailed information, graphics, and editorial guidance to the creation of comprehensive manuscripts on complex subjects. The editors and staff of this encyclopedia gratefully acknowledge their excellent cooperation and stress that the following abridged list of over 250 individuals and groups could be much longer. NOTE: In the cases of relatively short articles, the authors' initials may be used instead of their full name. In the following list, such authors are indicated by an asterisk. For example: *R. C. Vickery (RCV). Adams, Mark Barr, R. Q. Bowen,R.G. Fisher Controls International, Inc. Climax Molybdenum Company Consulting Geologist Marshalltown, Iowa Greenwich, Connecticut Portland, Oregon Adlhart, 0. J. Barrett, W. T. Boyle, J. Engelhard Corporation Foote Mineral Company Giddings & Lewis Electronics Co. Menlo Park, Connecticut Exton, Pennsylvania Fond Du Lac, Wisconsin Albright, P. S. Bendel, E. Breen, J. M. Wichita, Kansas McDonnell Douglas Corporation Adaptive Intelligence Corporation Long Beach, California Milpitas, California Allen, D. NCR Corporation Benke, R. J. Bristol, E. H. Fort Collins, Colorado Westinghouse Electric Corporation The Foxboro Company Pittsburgh, Pennsylvania Foxboro, Massachusetts American Gas Association (The) Arlington, Virginia Bennett, W. 0. Brown, P.M. American Time Products American Forestry Association (The) Foote Mineral Company Woodside, New York Exton, Pennsylvania Washington, D.C. Bernath, M. S. Ames Research Center Browne, N. W. Gould, Inc. National Aeronautics and Space Davy McKee (Oil & Chemicals) Ltd. Andover, Massachusetts Administration London, United Kingdom Moffett Field, California Blackwell, J. Department of Macromolecular Science Brunner, R. Arnold, F. Semiconductor Products Sector Case Western Reserve University Kollmorgen Corporation Motorola Inc. Cleveland, Ohio Commack, New York Phoenix, Arizona Blaeser, J. A. Arum,H.R. Gould, Inc. Bureau International de l'Heure Designatronics, Inc. Andover, Massachusetts Paris, France New Hyde Park, New York BorgWarner Chemicals Burns,B.M. Auvray, P. Engineering Staff National Coal Association Levallois-Perret-Cedex, France Washington, West Virginia Washington, D.C. Baldwin, M. S. Westinghouse Electric Corporation Bouissieres, G. Busker, L. H. East Pittsburgh, Pennsylvania University of Paris Beloit Corporation Orsay, France Rockton, Illiniois Bakos, J. J. H. Fletcher & Company Boulton, R. S. Caianiello, E. R. Huntington, West Virginia Ministry of Works Instituto di Fisica Teorica Wellington, New Zealand Universita di Napoli Bane, D. Naples, Italy Jet Propulsion Laboratory Bounds, C. 0. California Institute of Technology St. Joe Minerals Corporation Canadian Petroleum Association Pasadena, California Monaca, Pennsylvania Calgary, Alberta xi

See more

The list of books you might like

Most books are stored in the elastic cloud where traffic is expensive. For this reason, we have a limit on daily download.