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Understanding and Predicting Gun Barrel Erosion Ian A. Johnston WeaponsSystems Division Defence ScienceandTechnologyOrganisation DSTO(cid:150)TR(cid:150)1757 ABSTRACT ·eAustralianDefenceForcewillsoonhavetocontendwithgunbarrelero- sionissuesarisingfromtheuseofnewlow-vulnerabilitygunpropellants,the acquisitionofnewammunitionandgunsystems,andpossiblemodi(cid:12)cations toexistingpropellingchargedesigns. Acritical,technicalreviewofadvances in gun barrel erosion research, mitigation, and assessment over the last (cid:12)f- teenyearsispresented. Knownandpostulatederosionmechanisms,obtained through recent experimental and numerical modelling work, are described and contrasted. New approaches to erosion mitigation and updated knowl- edge of existing methods are reviewed. Also included is an assessment of theutilityofthevariouserosionmodellingandexperimentaltechniques,and notesontheirpossibleusefordefenceapplicationsinAustralia. APPROVEDFORPUBLICRELEASE DSTO(cid:150)TR(cid:150)1757 Publishedby WeaponsSystemsDivision DSTODefenceScienceandTechnologyOrganisation POBox1500 Edinburgh,SouthAustralia,Australia5111 Telephone: (08)82595555 Facsimile: (08)82596567 'CommonwealthofAustralia2005 ARNo. 013-473 August,2005 APPROVED FORPUBLICRELEASE ii DSTO(cid:150)TR(cid:150)1757 Understanding and Predicting Gun Barrel Erosion EXECUTIVESUMMARY ·eerosionofgunbarrelsinserviceleadstoreducedgunperformanceandavailabil- ity, and the expense of barrel replacement over the lifetime of a gun system. It is partic- ularly problematic for those guns which operate in high performance ballistic regimes. AlthoughtheAustralianDefenceForcehaslonghadtocontendwiththeproblemofgun barrelerosion,ithasrecentlyreceivedreneweda(cid:145)ention.Anewdefenceinstructionman- dating the future use of low vulnerability (LOVA) propellants, the near- and medium- termacquisitionofnewammunitionandweaponsystems,andthepossiblemodi(cid:12)cation of existing propelling charge con(cid:12)gurations, all present the need for reliable prediction andassessmentoftheassociatedbarrelerosionrisks. ·is report is a critical, technical review of advances in gun barrel erosion research, mitigation, and assessment, over the last (cid:12)(cid:2)een years. Known and postulated erosion mechanisms, obtained through recent experimental and numerical modelling work, are describedandcontrasted.Newapproachestoerosionmitigationandupdatedknowledge of existing methods are reviewed. Also included is an assessment of the utility of the variouserosionmodelling andexperimental techniques,andnotesontheirpossibleuse for defence applications in Australia. A summary of key topics covered in the review follows. Inthepastitishasbeencommonlyheldthatho(cid:145)er-burninggunpropellantsaremore erosive,howeverthisisnotalwaystrue.Asigni(cid:12)cantnumberofcaseshavebeenreported whereerosiondoesnotincreasewith(cid:8)ametemperature,andchemicala(cid:145)ackofthebore bypropellantgasspecieshasbeentheprimarydeterminantoferosivity. Althoughthere issomecon(cid:8)icting evidence inthe literature, it isgenerally accepted that the most com- monLOVApropellantsaremoreerosivethanequivalentconventionalpropellants. Many LOVApropellantformulationscontainRDX,andithasbeenconvincinglyshownbysev- eralinvestigatorsthatRDXishighlychemicallyerosive. New,experimentallow-erosivityLOVApropellantshavebeenproducedbyreducing RDX content and introducing nitrogen-rich energetic binder or (cid:12)ller compounds. ·e resulting propellant combustion gases, rich in nitrogen, act to re-nitride bore surfaces during (cid:12)ring and inhibit erosive surface reactions. ·e result is increased bore hard- ness,increasedresistancetomelting,andreducedchemicalerosion. ·eloweredhydro- gen concentration in the combustion gas of some of these propellants may also reduce hydrogen-assisted cracking of the bore surface. Of the high-nitrogen propellants under development, the majority possess impetus and (cid:8)ame temperatures lower than RDX: a compromisebetweenperformance,sensitivenessanderosivitymustbereachedinthese cases. Signi(cid:12)cante(cid:11)orthasrecentlybeendirectedatunderstandingtheerosionmechanisms forbarrelscoatedwithprotectiverefractorymetals.·emostplausiblemechanismisthat microcracksinthecoatings,presentfromthetimeofmanufacture,propagateduetopres- sureandthermalstresscyclingandeventuallyreachthegunsteelsubstrate. ·roughnu- mericalmodellingandanalysisoferodedbarrels,anumberofinvestigatorshaveshown iii DSTO(cid:150)TR(cid:150)1757 thatoncecracksreachthesubstrate,chemicalerosion,gaswash,andhighinterfacialtem- peraturescausepi(cid:145)ingofthesubstrateandeventuallyunderminethecoating. Segments ofcoatingaresubsequentlyremovedbythe(cid:8)oworengagementwiththeprojectile,and atthispointtheerosionrateofcoatedbarrelsmayexceedthatofsteelbarrels. Anumber of ways to mitigate this erosion pathway have been suggested, including: development of be(cid:145)er coating techniques to avoid the initial microcracks, pre-nitriding the gun steel before coating to slow substrate erosion, introducing a protective interlayer, and con- trolledbarrelstorageandpost-(cid:12)ringtreatmenttopreventoxidationofexposedsubstrate. Modellingandexperimentshaveadditionallyshownthat,withthenotableexceptionof chromium, the erosion resistance of refractory metal coatings varies amongst di(cid:11)erent propellantgaschemistryenvironments. Due to very good wear characteristics and thermal resistance, ceramic barrel liners havebeenidenti(cid:12)edasapromisingtechnologyforsometime. Howeverthesusceptibil- ity of ceramics to fracture, driven by stress induced by the di(cid:11)erent thermal expansion propertiesofsteelandceramics,havepreventedtheirwidespreaduse. Newfunctionally gradedceramic-to-metalliners,whichavoidanabruptmismatchofthermalexpansionat theceramic/metalinterface,arebeingdevelopedtoaddressthisissue. Forsmallcalibres, fabricationofentirebarrelsusingcompositereinforcedceramicshasbeendemonstrated. Particularly for cooler propellants, it has been shown that charge arrangement can a(cid:11)ecttheseverityanddistributionoferosionduetogaswash,andthatcombustiblecases can reduce erosion through cooling-layer e(cid:11)ects. Several investigators have shown that propellantgasblow-bymarkedlyincreasesheattransfertothebore,andtherebythermal erosion. Over the last ten years there have been signi(cid:12)cant advances in computational mod- ellingoferosion,andtwocodescapableofsimulatingabroadrangeoferosionphenom- enahavebeenreviewed. Modellingresultsshowreasonableagreementwiththeerosion ofin-servicegunbarrelsandlaboratoryexperiments. Insomecases,however,signi(cid:12)cant calibrationviainputofexperimentaldatawasrequiredtoachievethisagreement. Atruly predictive and comprehensive erosion model, capable of supplanting experiment, does not yet exist. Nevertheless, in combination with experiment the existing computational erosion models have proved extremely useful in be(cid:145)er understanding how the various erosionmechanismsact. NeartermworkinAustraliawillmostlikelyfocusontheerosionassessmentofnew propellants,LOVApropellants,newandmodi(cid:12)edchargedesigns,andnewweaponsys- tems. Sincenumericalerosionmodelsrequireexperimentalvalidationanyway,itissug- gested that the limited resources available for research in this area are best directed to- wardsestablishingamodestexperimentalcapability. Ventedvesseltestinghaslongbeen theprimarysmall-scaleerosionresearchtool,butthequestionableapplicabilityofresults to full-scale gun barrel erosion has previously restricted their usefulness. New vented vessel testing methods, methodologies for the selection of appropriate and realistic test conditions,andempiricalrelationsdesignedtoreconcilevesselandgunresults,havesig- ni(cid:12)cantlyalleviatedthisdi(cid:14)culty,however. ·usaproperlydesignedventedvesseltest facility,togetherwithlimitedfull-scalegun(cid:12)rings,isrecommendedasthemoste(cid:14)cient approachtoperformingerosionresearchandassessmentwithrestrictedresources. iv DSTO(cid:150)TR(cid:150)1757 Contents Nomenclature vii 1 Introduction 1 2 ErosionMechanisms 3 2.1 ChemicalErosion . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 3 2.2 ·ermalErosion . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 8 2.3 MechanicalErosion . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 10 3 ErosionMitigation 12 3.1 AlternativePropellantFormulations . . . . . . . . . . . . . . . . . . . . . 12 3.2 Additives . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 14 3.3 SurfaceCoatingsandLiners . . . . . . . . . . . . . . . . . . . . . . . . . . 15 3.4 NovelErosionMitigation . . . . . . . . . . . . . . . . . . . . . . . . . . . 18 4 ErosionModellingandPrediction 19 4.1 Empirical . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 19 4.2 Computational . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 21 5 ExperimentalAssessmentTechniques 25 6 Conclusion 28 Appendices A WearCalculationsforthe5(cid:148)/54Gun 37 v DSTO(cid:150)TR(cid:150)1757 vi DSTO(cid:150)TR(cid:150)1757 Nomenclature APFSDS ArmourPiercingFinStabilizedDiscardingSabot CAB CelluloseAcetateButyrate CAN CelluloseAcetateNitrate CAZ ChemicallyA(cid:11)ectedZone CFD ComputationalFluidDynamics EFC E(cid:11)ectiveFullCharge HAC HydrogenAssistedCracking HAZ HeatA(cid:11)ectedZone IWTC In-Wall·ermocouple KE KineticEnergy LC LowContractile LOVA LowVulnerabilityAmmunition MOCVD Metal-OrganicChemicalVapourDeposition OR OriginofRi(cid:8)ing RAVEN SonicRarefactionWaveLowRecoilGun RDX CyclotrimethyleneTrinitramine A WearCoe(cid:14)cient[m]or[m/s] c v Speci(cid:12)cHeatatConstantVolume[J/(kgK)] d BoreDiameter[m] D E MolarActivationEnergy[J/mol] f SpeciesVolumeFraction[%] h 2 ConvectionHeatTransferCoe(cid:14)cient[W/(m K)] I PropellantImpetus[J/kg] k ·ermalConductivity[W/(mK)] m DynamicViscosity[Pas] m Mass[kg] M MolecularWeight[kg/mol] Nu NusseltNumber P Pressure[Pa] q 2 HeatFlux[W/m ] r 3 Density[kg/m ] R Speci(cid:12)cGasConstant[J/(kgK)] R UniversalGasConstant[J/(molK)] Re ReynoldsNumber T Temperature[K] t Time[s] T max MaximumBoreSurfaceTemperature[K] u Speed[m/s] V 3 Volume[m ] w DiametralWear[m] x Axialdistance[m] vii DSTO(cid:150)TR(cid:150)1757 viii DSTO(cid:150)TR(cid:150)1757 1 Introduction ·eerosionofgunbarrelsinserviceleadstotwoproblemsfortheAustralianDefence Force: (i)barrelreplacementcostsoverthelifespanof(cid:12)eldedweaponsystems,andpar- ticularly those guns frequently operating in high performance ballistic regimes, and (ii) reducedoperationale(cid:11)ectivenessduetovariablegunperformanceandavailability. ·e erosion of a gun barrel under normal (cid:12)ring conditions is typically manifested in damage to the bore surface, and a bore diameter which progressively increases [1]. Typicalerosionratesareintherangeof0.1(cid:150)200(cid:181)mper(cid:12)ring[2],withtheworstdamage usually occurring near the origin of ri(cid:8)ing (OR) position or, for smooth-bore barrels, at the analogous location. Erosion of the bore near the muzzle end is also o(cid:2)en reported, thoughitisusuallylessseverethanthatoccurringattheOR[3]. In some cases the rated fatigue life of a gun barrel, in terms of number of (cid:12)ring cy- cles, may be reached before the barrel is eroded past condemning limits, obviating ero- sion concerns. ·e possibility of immediate catastrophic fatigue failure, rather than the morebenigne(cid:11)ectsofprogressiveerosion,raisesevengreaterconcernsinthissituation. Normally, however, the rate of erosion exceeds the fatigue crack propagation rate [2], and erosion is the driving factor in barrel retirement. An example of an erosion-limited barrel is the M199 howi‚er cannon, which has a normal wear life of 2700 e(cid:11)ective full charge(EFC)roundsandafatiguelifeof10000EFCrounds,usingatriple-basepropelling charge[1]. Incomparison,theM126E1howi‚erhasanexpected wearlifeof30000EFC rounds and a fatigue limit of 7500 EFC rounds, using a slightly cooler single-base pro- pellant [1]. ·e wear limits for these 155 mm guns are 2.5 and 2.0 mm respectively. ·e condemningerosionlimitcanvaryconsiderablybetweenguns,primarilydependingon accuracyandperformancerequirements: forsomeindirect(cid:12)reweapons,erosionofupto 8%ofborediametermaybetolerable,butthetolerancefortankgunsistighterandtyp- icallyintherange0.5(cid:150)1%[2]. Aswouldbeintuitively expected, highperformance guns with high muzzle velocities usually wear fastest [4]. For example the 105 mmM68 tank gun, operating at a 1600 m/s muzzle velocity, has a normal wear life as low as 100 EFC rounds[1]. Ithasalsolongbeenassumedando(cid:2)enobservedthathotpropellants cause moreerosionthandosimilarly-performingcooler-burningpropellants. Althoughthisis o(cid:2)entrue,therearesigni(cid:12)cantexceptionswhichwillbediscussedlaterinthisreport. Barrelerosionisunlikelytocausecatastrophicfailure,andthuscondemninglimitsare primarilysettoensurethee(cid:11)ectsoferosionongunperformancedonotbecomeexcessive. ·ee(cid:11)ectsofanerodedboremayinclude[3,5]: (cid:15) rangeandrangeaccuracyloss, (cid:15) directionalstabilitylossandresultantdispersion, (cid:15) fuzemalfunctions, (cid:15) excessivetorsionalimpulse(ri(cid:8)edbarrels), (cid:15) propellantgasblow-by, (cid:15) reductioninbarrelfatiguelife, 1 DSTO(cid:150)TR(cid:150)1757 (cid:15) excessivemuzzle(cid:8)ash,and (cid:15) increasedblastoverpressure. Someoftheseconsequenceshavethepotentialtomarkedlyreduceoperationale(cid:11)ective- ness. AlthoughtheAustralianDefenceForcehaslonghadtocontendwiththeproblemof barrelerosion,ithasrecentlyreceivedreneweda(cid:145)entionforseveralreasons. First,anew defence instruction, InsensitiveMunitions [6], has mandated the use of low vulnerability ammunition(LOVA)forallnewexplosiveordnanceprocurement,unlessawaiverisob- tained. In addition, an implementation plan will be developed to address the issue of sensitiveness for munitions already in service. ·e resulting move to LOVA propelling chargesmeansthatitislikelythatnewpropellantswillbeintroducedtoservice. ·edif- ferent chemicalcomposition, (cid:8)ametemperature and(usuallyhigher)erosivity ofLOVA propellantsplacesincreasedemphasisonaddressingtheproblemoferosion. Second,the imminentupgradeoftheADIMulwalapropellantmanufacturingfacilitymayleadtothe production of new propellants with di(cid:11)erent erosive behaviour to those already in ser- vice. ·ird, procurementactivities suchasLand 17(replacement orenhancement of the Army howi‚er (cid:8)eet) and MARAP (medium artillery replacement ammunition project) will result in new barrel, propelling charge and projectile con(cid:12)gurations. ·ese new or upgraded systems will likely not exhibit the same erosive wear characteristics as is cur- rentlyencounteredinexistingsystems. Inthecontextofthesegunandpropellingchargereplacementsandupgrades,theca- pabilitytomodel,predict,test,measureandunderstandtheassociatederosionprocesses becomesimportant. Unfortunately, though, therehasbeenli(cid:145)lerecentworkinthesear- eas at DSTO. ·ere was no active Australian participation in the Technical Cooperation Program(TTCP)2000(cid:150)2003GunTubeWearandErosionresearchactivities[7],forexample. Onepossiblereasonforthe dearthofAustralianworkisalackofresourcestoapproach the complex, cross-discipline nature of gun barrel erosion research: it crosses the (cid:12)elds of material science and metallurgy, solid mechanics, compressible gas dynamics, chem- istry, interior ballistics, heat transfer, and statistical mechanics. Nevertheless, there will likelybeanear-termrequirementtoestablishatleastbasicerosionresearchcompetence tosupporttheactivitiesnotedabove. ·e aim of this report, then, is to describe and assess the current state of analytical, numerical, empirical and experimental approaches to gun barrel erosion research, with aviewtotheir practical usebyDefenceinAustralia. Research prior to 1988hasalready beenthoroughlyreviewed(cid:151)byAhmad[1]andBracuti[5]forexample(cid:151)anditisnotthe intentionofthisreporttore-examinethesameground. ·isreportwillfocusonmaterial omi(cid:145)ed from these reviews, and work that has been conducted since their publication. Section 2 beginswithareviewofknownandpostulated erosionmechanisms,andade- scriptionofinsightsobtainedthroughthemostrecentexperimentalandmodellingwork. Disagreementsintheliterature,includingtherelativeerosivityofthevariouspropellant gas species, the existence of protective species, and the e(cid:11)ect of (cid:8)ame temperature on erosion, will be addressed. Section 3 continues with a discussion of erosion mitigation methods. Withthebackgroundestablished,Sections4and5goontocriticallyassessthe utility of modern approaches to erosion modelling, prediction and experimental assess- ment. 2

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