Materials Science Eskin Eskin ULTRASONIC TREATMENT OF LIGHT ALLOY MELTS S E C O N D E D I T I O N U O “This book, written by two acknowledged experts in the field, presents L a most extensive overview of ultrasonic processing of light-metal melts, F T from basic fundamentals to practical applications.” R L —Joseph C. Benedyk, Light Metal Age A I G “… a must have in the library of any engineer or scientist who processes S light metals today. … I found the book to be a catalyzer of innovation.” H O —Bob Wagstaff, Novelis, Inc., Spokane, Washington, USA T N Spawned by growing interest in ultrasonic technology and new developments in A I C ultrasonic melt processing, the Second Edition of Ultrasonic Treatment of Light L Alloy Melts discusses use of ultrasonic melt treatment in direct-chill casting, L T shape casting, rapid solidification, zone refining, and more, exploring the effects O R of power ultrasound on melt degassing, filtration, and refinement in aluminum and magnesium alloys. The fully revised and restructured Second Edition: Y E A • Contains new, in-depth coverage of composite and nanocomposite M materials T • Provides a historical review of the last century of ultrasonic applications E M to metallurgy L E • Emphasizes the fundamentals, mechanisms, and applications of ultrasonic T melt processing in different light-metal technologies N S • Features new chapters on ultrasonic grain refinement, refinement of T primary solid phases, and semi-solid processing of billets with nondendritic structure • Includes significant updates reflecting results obtained over the past two decades on different scales, from laboratory to full-scale industrial E S D E implementations I C T Complete with many new figures and examples, Ultrasonic Treatment of Light O I Alloy Melts, Second Edition delivers a comprehensive treatise on ultrasonic O N melt processing and cavitation, presenting essential guidelines for practical use N D and further development of the technology. K16821 6000 Broken Sound Parkway, NW Suite 300, Boca Raton, FL 33487 711 Third Avenue an informa business New York, NY 10017 2 Park Square, Milton Park www.taylorandfrancisgroup.com Abingdon, Oxon OX14 4RN, UK K16821_cover_final.indd 1 7/10/14 11:45 AM ULTRASONIC TREATMENT OF LIGHT ALLOY MELTS S E C O N D E D I T I O N Advances in Metallic Alloys A series edited by D.G. Eskin, Brunel Centre for Advanced Solidification Technology (BCAST), Brunel University Volume 1 Liquid Metal Processing: Applications to Aluminum Alloy Production I.G. Brodova, P.S. Popel and G.I. Eskin Volume 2 Iron in Aluminum Alloys: Impurity and Alloying Elment N.W. Belov, A.A. Aksenov and D.G. Eskin Volume 3 Magnesium Alloy Containing Rare Earth Metals: Structure and Properties L.L. Rokhlin Volume 4 Phase Transformations of Elements Under High Pressure E.Yu Tonkov and E.G. Ponyatovsky Volume 5 Titanium Alloys: Russian Aircraft and Aerospace Applications Valentin N. Moiseyev Volume 6 Physical Metallurgy of Direct Chill Casting of Aluminum Alloys Dmitry G. Eskin Volume 7 Ultrasonic Treatment of Light Alloy Melts, Second Edition Georgy I. Eskin and Dmitry G. Eskin AdvAnces in MetAllic Alloys A series edited by d .G. eskin ULTRASONIC TREATMENT OF LIGHT ALLOY MELTS S E C O N D E D I T I O N Georgy I. Eskin Dmitry G. Eskin Boca Raton London New York CRC Press is an imprint of the Taylor & Francis Group, an informa business CRC Press Taylor & Francis Group 6000 Broken Sound Parkway NW, Suite 300 Boca Raton, FL 33487-2742 © 2015 by Taylor & Francis Group, LLC CRC Press is an imprint of Taylor & Francis Group, an Informa business No claim to original U.S. Government works Version Date: 20140501 International Standard Book Number-13: 978-1-4665-7799-2 (eBook - PDF) This book contains information obtained from authentic and highly regarded sources. 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Visit the Taylor & Francis Web site at http://www.taylorandfrancis.com and the CRC Press Web site at http://www.crcpress.com To Nelly Beloved wife and mama Contents Preface.......................................................................................................................xi Authors .....................................................................................................................xv Chapter 1 Historical Overview of Ultrasonic Applications to Metallurgy ...........1 References ..........................................................................................14 Chapter 2 Fundamentals of Ultrasonic Melt Processing ....................................17 2.1 Dynamic Means of Melt Processing .......................................17 2.2 Low-Frequency Vibrations and Ultrasound: Basic Equations ..............................................................................20 2.3 Propagation of Acoustic Waves in the Melt ............................26 2.4 Acoustic Cavitation in Liquid Metals ......................................32 2.4.1 Cavitation Strength of Liquids ...................................32 2.4.2 Cavity Dynamics ........................................................37 2.4.3 Cavitation Region in Liquids ......................................44 2.5 Acoustic Flows ........................................................................49 2.6 Experimental Studies of Cavitation in Liquid Metals .............55 2.7 Sonoluminescence in Melts .....................................................67 2.8 Accelerated Mixing and Dissolution of Components in the Melt ................................................................................69 References ..........................................................................................70 Chapter 3 Ultrasonic Degassing..........................................................................75 3.1 Cavitation and Degassing Nuclei .............................................75 3.2 Mechanism of Ultrasonic Degassing .......................................81 3.3 Ultrasonic Degassing in a Stationary Volume .........................90 3.4 Ultrasonic Degassing in the Flow ...........................................98 References ........................................................................................106 Chapter 4 Ultrasonic Filtration .........................................................................109 4.1 Effect of Ultrasound on Surface Tension and Wetting ..........109 4.2 Sonocapillary Effect ..............................................................113 4.3 Basics of Filtration .................................................................115 4.4 Mechanism of Ultrasonic Melt Filtration ..............................120 4.5 Filtering through Multilayer Screen Filters: Usfirals Process ...................................................................................122 References ........................................................................................128 vii viii Contents Chapter 5 Ultrasonic Grain Refinement ...........................................................129 5.1 Mechanisms of Ultrasonic Grain Refinement .......................129 5.2 Activation of Substrates .........................................................131 5.3 Deagglomeration and Dispersion of Particles .......................139 5.4 Refinement of Nucleating Intermetallics ...............................144 5.5 Dendrite Fragmentation .........................................................148 5.6 Nondendritic Solidification....................................................151 5.7 Ultrasonic Melt Processing in the Mold ................................162 5.8 Ultrasonic Melt Processing in the Melt Flow ........................166 References ........................................................................................168 Chapter 6 Refinement of Primary Particles ......................................................171 6.1 Formation of Primary Particles during Solidification ...........171 6.2 Effect of Ultrasound on Solidification of Intermetallic Compounds ............................................................................172 6.3 Effect of Ultrasound on the Solidification of Hypereutectic Al–Si Alloys ...................................................181 References ........................................................................................191 Chapter 7 Ultrasonic Processing during Direct-Chill Casting of Light Alloys ..............................................................................193 7.1 Direct-Chill Casting of Aluminum Alloys ............................194 7.1.1 Ultrasonic Processing in the Sump of a Billet .........194 7.1.2 Ultrasonic Melt Processing in the Launder ..............205 7.2 Direct-Chill Casting of Magnesium Alloys ..........................207 7.3 Effect of Ultrasonic Degassing and Filtration on Structure and Properties of Wrought Products .....................213 7.3.1 Ultrasonic Degassing................................................213 7.3.2 Ultrasonic Filtration .................................................215 7.4 Effect of Nondendritic Structure on Structure and Properties of Wrought Products ............................................216 7.4.1 Aluminum Wrought Alloys ......................................216 7.4.2 Magnesium Wrought Alloys ....................................225 7.5 Effect of Nondendritic Grain Structure on Homogenization .................................................................230 References ........................................................................................231 Chapter 8 Ultrasonic Melt Processing during Shape Casting of Light Alloys ...........................................................................................235 8.1 Technological Approaches to Shape Casting with Ultrasonic Processing ............................................................235
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