1.01 Origin of the Elements J. W. Truran, Jr. and A. Heger University of Chicago, IL, USA 1.01.1 INTRODUCTION 1 1.01.2 ABUNDANCESANDNUCLEOSYNTHESIS 2 1.01.3 INTERMEDIATEMASSSTARS:EVOLUTIONANDNUCLEOSYNTHESIS 3 1.01.3.1 ShellHeliumBurningand12CProduction 4 1.01.3.2 s-ProcessSynthesisinRedGiants 4 1.01.4 MASSIVE-STAREVOLUTIONANDNUCLEOSYNTHESIS 5 1.01.4.1 NucleosynthesisinMassiveStars 7 1.01.4.1.1 Hydrogenburning 7 1.01.4.1.2 Heliumburningandthes-process 7 1.01.4.1.3 Hydrogenandheliumshellburning 7 1.01.4.1.4 Carbonburning 8 1.01.4.1.5 Neonandoxygenburning 8 1.01.4.1.6 Siliconburning 8 1.01.4.1.7 Explosivenucleosynthesis 8 1.01.4.1.8 Thep-process 9 1.01.4.1.9 Ther-process 9 1.01.5 TYPEIaSUPERNOVAE:PROGENITORSANDNUCLEOSYNTHESIS 9 1.01.6 NUCLEOSYNTHESISANDGALACTICCHEMICALEVOLUTION 12 REFERENCES 14 1.01.1 INTRODUCTION Within galaxies, stars and supernovae play the dominant role both in synthesizing the elements Nucleosynthesis is the study of the nuclear from carbon to uranium and in returning heavy- processes responsible for the formation of the element-enrichedmattertotheinterstellargasfrom elements which constitute the baryonic matter of whichnewstarsareformed.Themassfractionof theUniverse.TheelementsofwhichtheUniverse oursolarsystem(formed,4.6Gyrago)intheform is composed indeed have a quite complicated ofheavyelementsis,1.8%,andstarsformedtoday nucleosynthesis history, which extends from the inourgalaxycanbeafactor2or3moreenriched firstthreeminutesoftheBigBangthroughtothe (Edvardsson et al., 1993). It is the processes of present. Contemporary nucleosynthesis theory nucleosynthesisoperatinginstarsandsupernovae associates the production of certain elements/ thatwewillreviewinthischapter.Wewillconfine isotopes or groups of elements with a number of ourattentiontothreebroadcategoriesofstellarand specificastrophysicalsettings,themostsignificant supernovasitewithwhichspecificnucleosynthesis of which are: (i) the cosmological Big Bang, products are understood to be identified: (ii) stars, and (iii)supernovae. (i) intermediate mass stars, (ii) massive stars and Cosmological nucleosynthesis studies predict associated type II supernovae, and (iii) type Ia thattheconditionscharacterizingtheBigBangare supernovae. The first two of these sites are the consistent with the synthesis only of the lightest straightforward consequence of the evolution elements:1H,2H,3He,4He,and7Li(Burlesetal., of single stars, while type Ia supernovae are 2001; Cyburt et al., 2002). These contributions understoodtoresultfrombinarystellarevolution. define the primordial compositions both of Stellar nucleosynthesis resulting from the galaxies and of the first stars formed therein. evolution of single stars is a strong function of 1 2 Origin ofthe Elements stellar mass (Woosley et al., 2002). Following 1.01.2 ABUNDANCESAND phases of hydrogen and helium burning, all stars NUCLEOSYNTHESIS consist of a carbon–oxygen core. In the mass The ultimate goal of nucleosynthesis theory is, range of the so-called “intermediate mass” stars ð1&M=M( &10Þ; the temperatures realized in of course, to explain the composition of the Universe, as reflected, for example, in the stellar theirdegeneratecoresneverreachlevelsatwhich and gas components of galaxies. Significant carbon ignition can occur. Substantial element progress has been achieved in this regard as a production occurs in such stars during the consequence of a wealth of new information of asymptotic giant branch (AGB) phase of evo- cosmic abundances—spectroscopic properties of lution,accompaniedbysignificantmassloss,and starsinourgalaxyandofgascloudsandgalaxies they evolve to white dwarfs of carbon–oxygen at high redshifts—pouring in from new ground- (or, less commonly, oxygen–neon) composition. and space-based observatories. Given that, it In contrast, the increased pressures that are remains true that the most significant clues to experienced in the cores of stars of masses M * nucleosynthesisarethoseprovidedbyourdetailed 10M( yield higher core temperatures that enable knowledge of the elemental and isotopic compo- subsequent phases of carbon, neon, oxygen, and sitionofsolarsystemmatter.Themassfractionsof silicon burning to proceed. Collapse of an iron the stable isotopes in the solar are displayed in core devoid of further nuclear energy then gives Figure1.Keyfeaturesthatreflectthenatureofthe risetoatype IIsupernovaandtheformationofa nuclearprocessesbywhichtheheavyelementsare neutron star or black hole remnant (Heger et al., formed include: (i) the large abundances of 12C 2003). The ejecta of type IIs contain the ashes of and 16O, the main products of stellar helium nuclear burning of the entire life of the star, but burning;(ii)thedominanceofthea-particlenuclei are also modified by the explosion itself. They arethesourceofmostmaterial(bymass)heavier throughcalcium(20Ne,24Mg,28Si,32S,36Ar,and than helium. 40Ca); (iii) the “nuclear statistical equilibrium” Observations reveal that binary stellar systems peakatthepositionof56Fe;and(iv)theabundance comprise roughly half of all stars in our galaxy. peaksintheregionpastironattheneutronclosed Single star evolution, as noted above, can leave shell positions (zirconium, barium, and lead), initswakecompactstellarremnants:whitedwarfs, confirming the occurrence of processes of neu- neutron stars, and black holes. Indeed, we have tron-capture synthesis. The solar system abunda- evidence for the occurrence of all three types of nce patterns associated specifically with the slow condensed remnant in binaries. In close binary (s-process) and fast (r-process) processes of systems, mass transfer can take place from an neutroncapturesynthesisareshowninFigure2. evolving companion onto a compact object. This Itisimportantheretocallattentiontotherevised naturally gives rise to a variety of interesting determinations of the oxygen and carbon abun- phenomena: classical novae (involving hydrogen dances in the Sun. Allende Prieto et al. (2001) thermonuclear runaways in accreted shells on derivedanaccurateoxygenabundancefortheSun white dwarfs (Gehrz et al., 1998)), X-ray bursts of log1ðOÞ¼8:69^0:05dex; a value approxi- (hydrogen/helium thermonuclear runaways on matelyafactorof2belowthatquotedbyAnders neutron stars (Strohmayer and Bildsten, 2003)), andGrevesse(1989).Subsequently,AllendePrieto and X-ray binaries (accretion onto black holes). et al. (2002) determined the solar carbon abun- For some range of conditions, accretion onto dance to be log1ðCÞ¼8:39^0:04dex; and the carbon–oxygen white dwarfs will permit growth ratioC=O¼0:5^0:07:Thebottomlinehereisa of the CO core to the Chandrasekhar limit reduction in the abundances of the two most MCh ¼1:4M(, and a thermonuclear runaway in abundant heavy elements in the Sun, relative to tocoreleadstoatypeIasupernova. hydrogen and helium, by a factor ,2. The Inthischapter,wewillreviewthecharacteristics implications of these results for stellar evolution, ofthermonuclearprocessinginthethreeenviron- nucleosynthesis,theformationofcarbonstars,and ments we have identified: (i) intermediate-mass galacticchemicalevolutionremaintobeexplored. stars;(ii)massivestarsandtypeIIsupernovae;and Guided by early compilations of the “cosmic (iii)typeIasupernovae.Thiswillbefollowedbya abundances” as reflected in solar system material brief discussion of galactic chemical evolution, (e.g.,SuessandUrey,1956),Burbidgeetal.(1957) whichillustrateshowthecontributionsfromeach and Cameron (1957) identified the nuclear pro- oftheseenvironmentsarefirstintroducedintothe cessesbywhichelementformationoccursinstellar interstellarmediaofgalaxies.Reviewsofnucleo- andsupernovaenvironments:(i)hydrogenburning, synthesisprocessesincludethosebyArnett(1995), which powers stars for ,90% of their lifetimes; Trimble (1975), Truran (1984), Wallerstein et al. (ii) helium burning, which is responsible for the (1997), and Woosley et al. (2002). An overview productionof12Cand16O,thetwomostabundant of galactic chemical evolution is presented by elementsheavierthanhelium;(iii)thea-process, Tinsley(1980). which we now understand as a combination of Intermediate Mass Stars:EvolutionandNucleosynthesis 3 Figure1 TheabundancesoftheisotopespresentinsolarsystemmatterareplottedasafunctionofmassnumberA (thesolarsystemabundancesfortheheavyelementsarethosecompiledbyPalmeandJones(seeChapter1.03). carbon, neon, and oxygen burning; (iv) the equilibrium process, by which silicon burning proceeds to the formation of a nuclear statistical equilibrium abundance peak centered on mass A¼56; (v) the slow (s-process) and rapid (r-process) mechanisms of neutron capture syn- thesisoftheheaviestelementsðA*60–70Þ;and (vi)thep-process,acombinationoftheg-process and the n-process, which we understand to be responsibleforthesynthesisofanumberofstable isotopes of nuclei on the proton-rich side of the valley of beta stability. Our subsequent discus- sionswillidentifytheastrophysicalenvironments in which these diverse processes are now under- stood tooccur. Figure 2 The s-process and r-process abundances in solarsystemmatter(basedupontheworkbyKa¨ppeler etal.,1989).Notethedistinctives-processsignatureat 1.01.3 INTERMEDIATEMASSSTARS: masses A,88, 138, and 208 and the corresponding EVOLUTIONAND r-processsignaturesatA,130and195,allattributable NUCLEOSYNTHESIS toclosed-shelleffectsonneutroncapturecross-sections. It is the r-process pattern thus extracted from solar Intermediate-mass red giant stars are under- system abundances that can be compared with the stoodtobetheprimarysourcebothof12Candof observed heavy element patterns in extremely metal- the heavy s-process (slow neutron capture) deficientstars(thetotalsolarsystemabundancesforthe heavy elements are those compiled by Anders and elements, as well as a significant source of 14N Grevesse, 1989), which are very similar to those from and other less abundant CNO isotopes. Their thecompilationofPalmeandJones(seeChapter1.03). contributions to galactic nucleosynthesis are 4 Origin ofthe Elements a consequence of the occurrence of nuclear are converted into 12C, followed by the reactions in helium shell thermal pulses on the 12C(a,g)16O reaction, which forms 16O at the AGB,thesubsequentdredge-upofmatterintothe expense of 12C. Core helium burning in massive hydrogen-rich envelope by convection, and mass stars ðM *10M(Þ occurs at high temperatures, loss.Thisisaverycomplicatedevolution.Current which increases the rate of the 12C(a,g)16O stellar models, reviewed by Busso et al. (1999), reaction and favors the production of oxygen. allow the formation of low mass ð,1:5M(Þ Typically, the 16O/12C ratio in the oxygen-rich carbon stars, which represent the main source of mantlesofmassivestarspriortocollapseisafactor s-process nuclei. A detailed review of the ,2–3 higher than the solar values. Massive stars nucleosynthesis products (chemical yields) for are thus the major source of oxygen, while low- low- and intermediate-mass stars is provided by and intermediate-mass stars dominate the pro- Marigo (2001). ductionofcarbon. Redgiantstarshaveplayedasignificantrolein Theadvantageoftheheliumshellsoflow-and the historical development of nucleosynthesis intermediate-mass stars for 12C production arises theory. While the pivotal role played by nuclear from the fact that, for conditions of incomplete reactions in stars in providing an energy source helium burning, the 12C/16O ratio is high. sufficienttopowerstarsliketheSunoverbillions Following a thermal pulse in the helium shell, of years was established in the late 1930s, it convective dredge-up of matter from the helium remained to be demonstrated that nuclear pro- shell brings helium, s-process elements, and a cesses in stellar interiors might play a role in the significant mass of 12C to the surface. It is the synthesis of heavy nuclei. The recognition that surface enrichment associated with this source of heavy-element synthesis is an ongoing processin 12C that leads to the condition that the envelope stellarinteriorsfollowedthediscoverybyMerrill 12C/16Oratioexceeds1,suchthat“carbonstar”is (1952)ofthepresenceoftheelementtechnetiumin born. Calculations of galactic chemical evolution red giant stars. Since technetium has no stable indicate that this source of carbon is sufficient to isotopes,andthelongest-livedisotopehasahalf- accountforthelevelof12Cingalacticmatter.The lifet1=2,4:6Myr;itspresenceinred-giantatmos- levels of production of 14N, 13C, and other CNO pheres indicates its formation in these stars. isotopesinthisenvironmentaresignificantlymore This confirmed that the products of nuclear difficult to estimate, and thus the corresponding reactions operating at high temperatures and contributions of AGB stars to the galactic densities in the deep interior can be transported abundances ofthese isotopesremain uncertain. by convection to the outermost regions of the stellarenvelope. The role of such convective “dredge-up” of 1.01.3.2 s-ProcessSynthesisinRedGiants matter in the red-giant phase of evolution of The formation of most of the heavy elements 1–10M( stars is now understood to be an occursinoneoftwoprocessesofneutroncapture: extremely complex process (Busso et al., 1999). the s-process or the r-process. These two broad On the first ascent of the giant branch (prior to divisions are distinguished on the basis of the helium ignition), convection can bring the pro- relative lifetimes for neutron captures (t) and ducts of CNO cycle burning (e.g., 13C, 17O, and electron decays ðt Þ: The condition thattn.t ; 14N) to the surface. A second dredge-up phase b n b wheret isacharacteristiclifetimeforb-unstable occurs following the termination of core helium b nuclei near the valley of b-stability, ensures that burning.Thecriticalthirddredgeup,occurringin as captures proceed the neutron-capture path will the aftermath of thermal pulses in the helium itselfremainclosetothevalleyofb-stability.This shells of these AGB stars, is responsible for the defines the s-process. In contrast, when t ,t ; transport of both 12C and s-process nuclei n b it follows that successive neutron captures (e.g., technetium) to the surface. The subsequent will proceed into the neutron-rich regions off lossofthisenrichedenvelopematterbywindsand the b-stable valley. Following the exhaustion of planetary nebula formation serves to enrich the theneutronflux,thecaptureproductsapproachthe interstellar media of galaxies, from which new position of the valley of b-stability by b-decay, stars are born. A brief review of the mechanisms forming the r-process nuclei. The s-process and ofproductionof12Candthe“main”componentof r-processpatternsinsolarsystemmatterarethose thes-processofneutroncapturenucleosynthesisis shown inFigure 2. presentedin the followingsections. Theenvironmentprovidedbythermalpulsesin theheliumshellsofintermediate-massstarsonthe AGB provides conditions consistent with the 1.01.3.1 ShellHeliumBurning and12CProduction synthesis of the bulk of the heavy s-process isotopes through bismuth. Neutron captures in Stellarheliumburningproceedsbymeansofthe AGBstarsaredrivenbyacombinationofneutron “triple-alpha” reaction in which three 4He nuclei sources: the 13C(a,n)16O reaction provides Massive-star Evolution and Nucleosynthesis 5 the bulk of the neutron budget at low-neutron densities, while the 22Ne(a,n) 25Mg operating at high temperatures helps to set the timescale for criticalreaction branches.Thiss-processsite(the main s-process component) is understood to operate in low-mass AGB stars ðM ,1–3M() and to be responsible for the synthesis of the s-process nuclei in the mass range A*90: Calculations reviewed by Busso et al. (1999) indicate a great sensitivity both to the character- istics of the 13C “pocket” in which neutron production occurs and to the initial metallicity of the star. In their view, this implies that the solar system abundances are not the result of a unique s-processbutrathertheconsequenceofacompli- Figure 3 Evolution of the central temperature and catedgalacticchemicalevolutionaryhistorywhich density in stars of 15M( and 25M( from birth as witnessedmixingoftheproductsofs-processingin hydrogenburningstarsuntilironcorecollapse(Table1). stars of different metallicity and a range of 13C Ingeneral,thetrajectoriesfollowalineofr/T3,but with some deviation downward (towards higher r pockets. We can hope that observations of the at a given T) due to the decreasing entropy of the s-processabundancepatternsinstarsasafunction core. Nonmonotonic behavior is observed when of metallicity will ultimately be better able to nuclear fuels are ignited and this is exacerbated in the guideandtoconstrainsuchtheoreticalmodels. 15M( model by partial degeneracy of the gas (source Woosleyetal.,2002). 1.01.4 MASSIVE-STAREVOLUTION ANDNUCLEOSYNTHESIS the bottom of burning region (central or shell burning) and depleting the fuel elsewhere in Generallyspeaking, theevolution ofamassive that region at the same time. As a result, shell starfollowsawell-understoodpathofcontraction burning of this fuel then commences outside that toincreasingcentraldensityandtemperature.The region. contractioniscausedbytheenergylossofthestar, Table 1 summarizes the burning stages and duetolightradiatedfromthesurfaceandneutrino theirdurationsfora20M( star.Thetimescalefor losses (see below). The released potential energy helium burning is ,10 times shorter than that of isinpartconvertedintointernalenergyofthegas hydrogen burning, mostly because of the lower (Virial theorem). This path of contraction is energyreleaseperunitmass.Thetimescaleofthe interrupted by nuclear fusion—first hydrogen is burning stages and contraction beyond central burned to helium, then helium to carbon and helium burning is greatly reduced by thermal oxygen. This is followed by stages of carbon, neutrino losses that carry away energy in situ, neon, oxygen, and silicon burning, until finally a instead of requiring that it be transported to the core of iron is produced, from which no more stellar surface by diffusion or convection. These energy can be extracted by nuclear burning. The lossesincreasewithtemperature(as /T9).When onsetsoftheseburningphasesasthestarevolves the star has built up a large-enough iron core, throughthetemperature–densityplaneareshown inFigure3,forstarsofmasses15M( and25M(: exceeding its effective Chandrasekhar mass (the maximum mass for which such a core can be Eachfuelburnsfirstinthecenterofthestar,then stable),thecorecollapsestoformaneutronstaror in one or more shells (Figure 4). Most burning ablackhole(seeWoosleyetal.(2002)foramore stages proceed convectively: i.e., the energy production rate by the burning is so large and extended review). A supernova explosion may centrally concentrated that the energy cannot be result (e.g., Colgate and White, 1966) that ejects transported by radiation (heat diffusion) alone, mostofthelayersoutsidetheironcore,including and convective motions dominate the heat trans- many of the ashes from the preceding burning port. The reason for this is the high-temperature phase. However, when the supernova shock front sensitivity of nuclear reaction rates: for travelsoutward,forabrieftimepeaktemperatures hydrogenburninginmassivestars,nuclearenergy are reached, that exceed the maximum tempera- generation has a /T18 dependence, and the turesthathavebeenreachedineachregioninthe dependence is even stronger for later burning preceding hydrostatic burning stages (Table 2). stages. The important consequence is that, due to This defines the transient stage of “explosive theefficientmixingcausedbytheconvection,the nucleosynthesis”thatiscriticaltotheformationof entire unstable region evolves essentially chemi- an equilibrium peak dominated by 56Ni (Truran cally homogeneously—replenishing the fuel at et al.,1967). 6 Origin ofthe Elements Figure4 Interiorstructureofa22M( starofsolarcompositionasafunctionoftime(logarithmoftimetillcore collapse)andenclosedmass.Greenhatchingandredcrosshatchingindicateconvectiveandsemiconvectiveregions. Convectiveregionsaretypicallywellmixedandevolvechemicallyhomogeneously.Blueshadingindicatesenergy generationandpinkshadingenergyloss.Bothtakeintoaccountthesumofnuclearandneutrinolosscontributions. Thethickblacklineatthetopindicatesthetotalmassofthestar,beingreducedbymasslossduetostellarwinds. Note that the mass loss rate actually increases at late times of the stellar evolution. The decreasing slope ofthetotalmassofthestarinthefigureisduetothelogarithmicscalechosenforthetimeaxis. Table 1 Hydrostatic nuclear burning stages in massive stars. The table gives burning stages, main and secon- daryproducts(ashes),typicaltemperaturesandburningtimescalesfora20M(star,andthemainnuclearreactions. An ellipsis (···) indicates more than one product of the double carbon and double oxygen reactions, and a chain ofreactionsleadingtothebuildupofirongroupelementsforsiliconburning. Fuel Mainproducts Secondaryproducts T Duration Mainreaction (109K) (yr) H He 14N 0.037 8.1£106 4H!4He(CNOcycle) He O,C 18O,22Ne 0.19 1.2£106 34He!12C s-Process 12Cþ4He!16O C Ne,Mg Na 0.87 9.8£102 12Cþ12C!··· Ne O,Mg Al,P 1.6 0.60 20Ne!16Oþ4He 20Neþ4He!24Mg O Si,S Cl,Ar, 2.0 1.3 16Oþ16O!··· K,Ca Si Fe Ti,V,Cr, 3.3 0.031 28Si!24Mgþ4He··· Mn,Co,Ni 28Siþ4He!24Mg··· Massive stars build up most of the heavy heavyelementsuptoatomicmassnumbers80–90 elements from oxygen through the iron group frominitialiron,convertinginitialcarbon,oxygen, fromtheinitialhydrogenandheliumofwhichthey and nitrogen into 22Ne, thus providing a neutron areformed.Theyalsomakemostofthes-process sourceforthes-process.Massivestarsareprobably