Trace Materials in Air, Soil, and Water

214 Pages·2016·6.527 MB·English

by  Society, American Chemical(Editor)

Trace Materials in Air, Soil,
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In Trace Materials in Air, Soil, and Water; Evans, Kendra R., et al.;
ACS Symposium Series; American Chemical Society: Washington, DC, 2015.
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In Trace Materials in Air, Soil, and Water; Evans, Kendra R., et al.;
ACS Symposium Series; American Chemical Society: Washington, DC, 2015.
1210
ACS SYMPOSIUM SERIES
Trace Materials in Air, Soil,
and Water
Kendra R. Evans, Editor
01 UniversityofDetroitMercy, Detroit, Michigan
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1 Elizabeth S. Roberts-Kirchhoff, Editor
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1/ Mark A. Benvenuto, Editor
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5 | d Katherine C. Lanigan, Editor
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AmericanChemicalSociety,Washington,DC
DistributedinprintbyOxfordUniversityPress
In Trace Materials in Air, Soil, and Water; Evans, Kendra R., et al.;
ACS Symposium Series; American Chemical Society: Washington, DC, 2015.
LibraryofCongressCataloging-in-PublicationData
Names:Evans,KendraR.,editor.|AmericanChemicalSociety.Divisionof
EnvironmentalChemistry.
Title:Tracematerialsinair,soil,andwater/KendraR.Evans,editor,
UniversityofDetroitMercy,Detroit,Michigan[andfourothers];
sponsoredbytheACSDivisionofEnvironmentalChemistry.
1
00 Description:Washington,DC:AmericanChemicalSociety,[2015]|Series:ACS
w
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2
1 9780841231108|ISBN9780841231092()
5-
1 Subjects:LCSH:Traceelements--Environmentalaspects.|Traceelementsin
0
k-2 water.|Soils--Traceelementcontent.|Radioactivepollutionofthe
1/b atmosphere.
02 Classification:LCCQH545.T7T72672015(print)|LCCQH545.T7(ebook)|DDC
1
0. 572/.515--dc23
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oi: LCrecordavailableathttp://lccn.loc.gov/2015045503
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In Trace Materials in Air, Soil, and Water; Evans, Kendra R., et al.;
ACS Symposium Series; American Chemical Society: Washington, DC, 2015.
Foreword
The ACS Symposium Series was first published in 1974 to provide a
mechanism for publishing symposia quickly in book form. The purpose of
the series is to publish timely, comprehensive books developed from the ACS
sponsoredsymposiabasedoncurrentscientificresearch. Occasionally,booksare
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In Trace Materials in Air, Soil, and Water; Evans, Kendra R., et al.;
ACS Symposium Series; American Chemical Society: Washington, DC, 2015.
Editors’ Biographies
Kendra R. Evans
Kendra R. Evans is an Associate Professor of Chemistry and Biochemistry
at the University of Detroit Mercy. Her research focuses on the development
and use of automated liquid chromatography-mass spectrometry methods to
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0 investigate long-term insulin secretion dynamics. Her research interests also
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0.ot include the detection of pesticides in water and animal tissue, as well as the
1
2 development of stability-indicating assays to monitor the forced degradation of
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15- pharmaceutical compounds. Evans received a B.S. in Chemistry from Western
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k-2 KentuckyUniversityandaPh.D.inAnalyticalChemistryfromtheUniversityof
1/b Michigan. ShejoinedthefacultyattheUniversityofDetroitMercyin2009.
2
0
1
0.
1
oi: Elizabeth S. Roberts-Kirchhoff
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2 Elizabeth Roberts-Kirchhoff is Professor of Chemistry and Biochemistry at
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er the University of Detroit Mercy. Her research interests include the mechanism
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m ofactionofcytochromeP450enzymes;theanalysisofmetalsinfoodandhealth
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ec supplements including kelp, clay, and protein powders; and the analysis of
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b): pesticides in water. Roberts-Kirchhoff received a B.S. in Chemistry from Texas
We A & M University and a Ph.D. in Biological Chemistry from the University
e ( of Michigan. After postdoctoral research at Wayne State University and the
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Mark A. Benvenuto
Mark Benvenuto is a Professor of Chemistry at the University of Detroit

MercyandaFellowoftheACS.Hisresearchthrustsspanawidearrayofsubjects,
but include the use of energy dispersive X-ray fluorescence spectroscopy to
determine trace elements in land-based and aquatic plant matter, food additives,
and ancient and medieval coins. Benvenuto received a B.S. in Chemistry from
the Virginia Military Institute, and after several years in the Army, a Ph.D. in
Inorganic Chemistry from the University of Virginia. After a post-doctoral
fellowship at the Pennsylvania State University, he joined the faculty at the
UniversityofDetroitMercyinlate1993.
©2015AmericanChemicalSociety
In Trace Materials in Air, Soil, and Water; Evans, Kendra R., et al.;
ACS Symposium Series; American Chemical Society: Washington, DC, 2015.
Katherine C. Lanigan
KatherineLanigan,isanAssociateProfessorofChemistryandBiochemistry
at the University of Detroit Mercy. Lanigan’s research includes analysis of
tracemetalaccumulationbothinplantsandinvertebratesandadsorptionstudies
of metal-complexed EDTA on metal oxide thin films by ATR-FTIR. Lanigan
receivedaB.S.degreeinChemistryfromtheUniversityofDaytonin1990anda
Ph.D. degree in Chemistry from the University of Iowa in 1996. She joined the
UniversityofDetroitMercyin1999.
Alexa Rihana-Abdallah
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ot Alexa Rihana-Abdallah is an Associate Professor of Environmental
10. Engineering at the University of Detroit Mercy. Her research interests
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5-1 include water and soil remediation, in particular contaminant fate pathways
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0 and remediation design for surface and groundwater polluted with metals or
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bk- chlorinated compounds, as well as energy sustainability and clean technology.
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2 Rihana-AbdallahreceivedaB.S.inElectricalEngineeringfromEcoleSupérieure
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0. des Ingénieurs de Beyrouth – Université St. Joseph and an M.S. and a Ph.D.
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oi: in Environmental Engineering from the University of Michigan. She joined the
5 | d facultyattheUniversityofDetroitMercyinlate2000.
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212
In Trace Materials in Air, Soil, and Water; Evans, Kendra R., et al.;
ACS Symposium Series; American Chemical Society: Washington, DC, 2015.
Preface
“Innaturenothingexistsalone.”
—RachelCarson,SilentSpring
When Rachel Carson, marine biologist and environmentalist, published
01 Silent Spring in 1962, she alerted her readers to the environmental impacts of
0
pr synthetic pesticides (1). Over a half century later, we are still exploring and
0.
21 discoveringthemanyeffectsofpesticidesandcountlessotherpollutantspresent
1
5- inourenvironment. Manybiomedicalresearchersarededicatedtoinvestigating
1
20 theeffectsofavarietyoflow-andhigh-concentrationenvironmentalpollutantson
k-
b humanandanimalhealth. Withthevastnumberofenvironmentalcontaminants,
1/
02 itwouldbechallengingtoprepareadocumentthatsummarizesthepollutantsand
1
0. theirnegativeimpactsonhealth,ecology,andtheenvironmentingeneral. But,to
1
oi: elicitchange—toconvincesocietythatthepollutantscanandmustberemediated
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5 | from our environment—the work of the biomedical research community must
1
0 be accompanied by evidence of the presence of such contaminants and must be
2
1, supported by valid means for remediating them. Many of these contaminants
ber are present at trace levels, where the term “trace” specifies low concentrations,
m
ce typicallyinthepartsperbillionorpartspertrillionrange(2). Thus,development
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D and validation of methods for quantitating, determining the origin of, and
eb): remediatingtracepollutantsinourenvironmentisoftheutmostimportance.
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e ( This volume is based on the Environmental Chemistry Division-sponsored
at symposium of the same name held at the 249th meeting of the American
D
n ChemicalSocietyinDenver,ColoradoinMarchof2015. Thefieldoftechniques
o
ati for preparing, preconcentrating, quantitating, tracking, and remediating trace
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bli pollutantsisvast. Itischallengingeventogatheralistofsuchcontaminantsand
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thetechniquesspecifiedabove. Thisvolumeisintendedtobeadiverse‘sampling’
of such methods, each chapter representing one specific field of environmental
chemistryanalyses.
Wehavedividedthepapersintothreecategories: air,soilandminerals,and
water. The air section includes studies on airborne particulate matter and other
pollutants present in trace levels. Bozlaker et al. describe the measurement of
traceelementcompositioninairborneparticulatematterinHouston,TXanditsuse
insourceapportionment. Shahriaretal. provideareviewofozonestudiesinthe
Houston-Galveston-BrazoriaNon-AttainmentArea. Kieferetal. presentareview
of the challenges associated with using retorts to minimize mercury exposure in
small-scale gold mining in Mozambique, Ecuador, and Guyana. Dewan et al.
describetheuseofstableleadandstrontiumisotopesfortracingdustsourcesin
CentralAsia. Inthesoilandmineralsection,Barakatetal. describetheuseofa
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In Trace Materials in Air, Soil, and Water; Evans, Kendra R., et al.;
ACS Symposium Series; American Chemical Society: Washington, DC, 2015.
handheld X-ray fluorescence spectrometer to analyze the elemental composition
of salts and salt substitutes. Olsen et al. present the use of mercury-thiourea
complexionchromatographywithinductivelycoupledplasma-massspectrometry
detectionforenvironmentalmercuryspeciationanalyses;theirsystemschemistry
approachcanbeusedtoperformspeciationanalysesinbothwaterandsediment
samples. The water section of the book includes a study on the fate of specific
contaminants in water, describes the development of a remediation method for
metalsinwater,andpresentstwohelpfultechniquesforquantitatingtracemetals
inwater. Specifically,Breytusetal. describethefateofchlorateandperchlorate
in high-concentration and dilute hypochlorite solutions used in drinking water
facilities. Kashatetal. presentthesynthesisofhighlymultidentatepodandligands
forremediationofmetalsinwater. Rihanaetal. describetheuseofcloudpoint
1 extraction for iron quantitation using flame atomic absorption spectrometry. In
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pr0 thefinalchapter,Meylemansetal. reporttheuseoffluorescentnanoparticlesfor
0. detectionoftracemetalsinwater.
1
2
1 Rachel Carson said that nothing in nature exists alone. What we have
5-
01 continuedtolearnisthattheexistenceofeventracelevelsofharmfulcontaminants
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k- can be detrimental to health and to the environment. The development
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1/ and validation of techniques for quantitating, tracing, and remediating trace
2
0
1 contaminants must continue; the knowledge gleaned from the use of these
0.
oi: 1 techniques is critical for progressing as society by minimizing the use of and
d remediatingharmfulchemicals. Thepapersgatheredhere, whichrepresentonly
15 | a dash of the vast field of environmental chemistry, are a key part of this larger,
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1, 2 continuingeffort.
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eb): 1. Carson,R.SilentSpring;HoughtonMifflin: Boston,MA,1962.
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e ( 2. Murray,K.E.;Thomas,S.M.;Bodour,A.A.PrioritizingResearchforTrace
at Pollutants and Emerging Contaminants in the Freshwater Environment.
D
n Environ. Pollut. 2010,158,3462–3471.
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DepartmentofChemistryandBiochemistry
UniversityofDetroitMercy
Detroit, Michigan48221

ElizabethS.Roberts-Kirchhoff
DepartmentofChemistryandBiochemistry
UniversityofDetroitMercy
Detroit, Michigan48221
MarkA.Benvenuto
DepartmentofChemistryandBiochemistry
UniversityofDetroitMercy
Detroit, Michigan48221
x
In Trace Materials in Air, Soil, and Water; Evans, Kendra R., et al.;
ACS Symposium Series; American Chemical Society: Washington, DC, 2015.
KatherineC.Lanigan
DepartmentofChemistryandBiochemistry
UniversityofDetroitMercy
Detroit, Michigan48221
AlexaRihana-Abdallah
DepartmentofCivilandEnvironmentalEngineering
UniversityofDetroitMercy
Detroit, Michigan48221
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In Trace Materials in Air, Soil, and Water; Evans, Kendra R., et al.;
ACS Symposium Series; American Chemical Society: Washington, DC, 2015.