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Pis’ma v ZhETF Topological superfluid 3He-B in magnetic field and Ising variable G.E. Volovik 1) LowTemperatureLaboratory,AaltoUniversity,SchoolofScienceandTechnology, P.O.Box15100,FI-00076AALTO,Finland LandauInstitute forTheoretical PhysicsRAS,Kosygina2,119334Moscow,Russia SubmittedJanuary16,2010 The topological superfluid 3He-B provides many examples of the interplay of symmetry and topology. Here we consider the effect of magnetic field on topological properties of 3He-B. Magnetic field violates the 0 time reversal symmetry. As a result, the topological invariant supported by this symmetry ceases to exist; 1 and thusthe gapless fermions on the surface of 3He-B are not protected any more bytopology: they become 0 fullygapped. Nevertheless,ifperturbationofsymmetryissmall,thesurfacefermionsremain relativisticwith 2 mass proportional to symmetry violating perturbation – magnetic field. The 3He-B symmetry gives rise to n the Ising variable I = ±1, which emerges in magnetic field and which characterizes the states of the surface a of 3He-B. This variable also determines the sign of the mass term of surface fermions and the topological J invariantdescribingtheireffectiveHamiltonian. Thelineonthesurface, whichseparatesthesurfacedomains 9 with different I, contains 1+1 gapless fermions, which are protected by combined action of symmetry and 1 topology. ] r e PACS:67.30.ht, 71.90.+q, 04.50.-h h t o 1. INTRODUCTION in 2+1 momentum space. The value of this invariant . at is determined by the Ising type variable I, which char- m Recently topological insulators, semimetals, super- acterizes the surface of 3He-B in the presence of mag- -conductors,superfluidsandothertopologicallynontriv- netic field. The surface of 3He-B can be in two states, dial gapless and gapped phases of matter have attracted with I = +1 and I = −1, and both states of the sur- na lot of attention, see e.g. [1, 2, 3, 4]. Superfluid 3He-B face have been recently probed by NMR experiments o crepresentsthe fully gapped topologicalsuperfluids with with 3He-B confined in a single micron-size slab [15]. [time reversalsymmetry[3,4,5]. This3+1systemcon- These experiments also detected the coexistence of the 5 tains 2+1gaplessAndreev boundstates onthe surface domains with different I on the surface of 3He-B; these voftheliquidorattheinterfacesbetweenthebulkstates domains are separated by the one-dimemsional domain 4with different topological invariants;these fermion zero walls(lines)onthesurface. Sincethedomainsarechar- 1modes resemble 2+1 Majorana fermions in relativistic acterizedbydifferentvaluesofthetopologicalinvariant, 5 quantum field theories [6, 7, 8]. Andreev bound states 1 the boundary line between the domains contains 1+1 .onthesurfaceof3He-Bwerediscussedtheoretically(see gapless fermions with “relativistic” spectrum. 1 e.g. [9, 10, 11]) and probed experimentally [12, 13, 14]. 0 0However,theMajoranasignatureofthesestateshasnot 1yet been observed. One of the possible tools for obser- :vationofthe“relativistic”spectrumoftheboundstates 2. DISTORTION OF ORDER PARAMETER v iisNMR,whichrequiresanexternalmagneticfield. The X Magnetic field destroys the rotational symmetry influence of magnetic field on Majorana fermions has r of 3He-B, leading to the anisotropic gap. The gap abeen recently discussed in [11]. Here we consider the anisotropy is also induced by the walls. The order pa- effect of magnetic field in more detail. The topologicalinvariantfor 3He-B which gives rise rameterin3He-Bis3×3matrixAαi [16]. Ittransforms as vector under spin rotation(the Greek index), and as to the 2+1 gapless fermion zero modes on its surface vectorunder orbitalrotation(the Latinindex). For the is supported by the time reversal symmetry [5]. Mag- distorted 3He-B it has the form netic field destroys this symmetry, as a result the An- dreev bound states acquire gap (mass) proportional to ∆ 0 0 the magnitude of magnetic field. The resulting massive k ∆ 2+1 Andreev-Majorana fermions also have nontrivial Aαi =RαiA(ij0) , A(ij0) = 0 ∆k 0  , q = ∆⊥ , k topology,describedbythenonzerotopologicalinvariant 0 0 ∆  ⊥ 1)[email protected].fi   (1) 1 2 G.E.Volovik where q is the distortion parameter with q = 1 in the lows that in the geometry of experiment, the distor- non-deformed B-phase and q = 0 in the planar state; tion parameter q at temperature T = 0.54T is about c ∆ isthegapforquasiparticlespropagatingindirection q ∼ 0.6−0.7. From this figure it also follows that in ⊥ along the normal to the wall; ∆ is the gap for quasi- coolingoneobtainsthreedifferentstates: thestatewith k particles propagating in directions parallel to the wall; I = +1 characterized by small positive frequency shift; R is rotation matrix, which connects spin and orbital the state with I = −1 characterized by large negative αi spaces. Assaid,thedistortionofthegapiscausedboth frequencyshift;andthestatewithcoexistingdomainsof by magnetic field and by boundaries. Let us introduce both orientations of the Ising variable, which is charac- the unit vectorhˆ =H/H in directionofmagnetic field, terized by two peaks in the NMR spectrum. The latter and the unit vector ˆl = hˆ R in the orbital space. statecontainsdomainwall(s)–theline(s)onthesurface i α αi The orbital vector ˆl shows the direction of the orbital separatingsurfacedomainswithoppositeorientationsof angular momentum of Cooper pairs (see e.g. [17, 18]) I. andplaystheroleoftheanisotropyaxisfortheuniaxial Letusalsoforcompletenessconsiderthefieldparal- deformation of the gap. lel to the plates. In this case theˆl-vector is perpendic- ular to the field and I =ˆl·hˆ = 0. The frequency shift is positive, ω(I =0)−ω =−(ω(I =−1)−ω )>0. L L 3. ISING VARIABLE PROBED BY NMR We have seen that the orientation of the magnetic field with respect to the Ising spin is crucial for the Let us consider NMR experiments with superfluid NMRexperiments. Letusconsidertheeffectoforienta- 3He-B confined in a single micron size slab [15], where the field is normal to the plates: H = Hˆz. Typical tion of the magnetic field on the spectrum of Majorana fermions. fields used for NMR exceed the dipole field (spin-orbit coupling). As a result the boundary conditions for ˆl- vector is that ˆl is normal to the walls, ˆl׈z = 0 [19]. 4. MAJORANA FERMIONS IN DISTORTED This boundary condition ensures that the anisotropy B-PHASE axis ˆz caused by the walls and anisotropy axisˆl caused by magnetic field coincide. Fermions in magnetic field are described by the fol- In a given geometry with the field being normal to lowing Hamiltonian: theplates,theprojectionoftheˆl-vectoronthemagnetic k2−k2 1 field direction H= Fτ − γH·σ+ I =ˆl·hˆ, (2) 2m∗ 3 2 k k k x y z τ ∆ (z)σ˜ +∆ (z)σ˜ +∆ (z)σ˜ , (4) represents the Ising variable. Thus is because only two 1 k xk k yk ⊥ zk orientationsofˆl-vectorwithrespecttomaneticfieldare (cid:18) F F F(cid:19) allowed by boundary conditions: I = +1, and I = −1. whereτi arePaulimatricesofBogolyubov-Nambuspin; σ arePaulimatricesof3Henuclearspin; γ isthegyro- The degeneracy is lifted by spin-orbit interaction. The α magnetic ratio ofthe 3He atom; andfinally σ˜ =σ R latter is small compared with all other energies but is i α αi are the Pauli matrices obtained from matrices σ by ro- important for the measured NMR frequency shift from tation. In the absence of magnetic field there is a topo- the Larmorvalue ω , whichisjust causedbyspin-orbit L logical invariant for 3He-B [5]: interaction. Themeasurementsofthefrequencyshiftal- lows to determine experimentally the value of the Ising e spin I on the surface. N = 24ijπk2 tr τ2 d3k H−1∂kiHH−1∂kjHH−1∂kkH . For the distorted 3He-B, the corresponding fre- (cid:20) Z (cid:21) (5) quency shifts can be found from equations (4.5) and At H=0, when the time reversal symmetry is pre- (4.10) of Ref. [20]. The frequency shift is positive when served, the integral (5) is invariant under deformations ˆl-vectoris parallelto the field, i.e. for I =+1,andneg- because the matrixτ anti-commuteswithHamiltonian ative for ˆl-vector antiparallel to field, i.e. for I = −1. H. The nonzero val2ue of this invariant supports gap- The ratio of the frequency shifts is less fermions at the interface between bulk states with ω(I =+1)−ω 1−q2 different values of N [6] and on the surface of 3He-B L ω −ω(I =−1) = 1+2q2 . (3) [8]. These fermions contribute to the ground-state spin L supercurrent [6]. Both positive and negative frequency shifts have been In the presence of magnetic field, the integral (5) observed in [15]. From Fig. 1 of [15] and Eq.(3) it fol- doesnotrepresentthetopologicalinvariantbecausethe Topological superfluid 3He-B in magnetic field and Ising variable 3 Paulitermdoesnotanti-commutewithτ ,andthegap- appears due to violation of the time reversal symme- 2 lessness ofthe Andreev bound states is notguaranteed. try by magnetic field. The mass (12) was obtained in ThePaulitermcanbeexpressedintermsoftherotated Ref. [11] only for the case of magnetic field normal to spin σ˜: the wall. However, as distinct from Ref. [11], in our case the equation (12) is valid for any orientation of H·σ =H σ =H R σ˜ =H ˆl·σ˜ =(ˆl·zˆ)Hσ˜ . (6) α α α αi i z magnetic field. This is because we consider relatively large magnetic fields used in NMR experiments, when Equation (6) demonstrates that the Hamiltonian (4) thespin-orbitinteractionisrelativelysmall: thoughthe does not depend on the orientation of magnetic field. spin-orbit interaction is responsible for the frequency It depends only on the Ising variableˆl·ˆz = ±1, which shift, it does not influence the orientation of the vector describestwopossibleorientationsofthevectorˆlonthe ˆlonthesurface. AsaresultthePauliterm(6)expressed surface. This is because in large fields used in experi- via the rotated spin does not depend on orientation of ments, the spin-orbit interaction can be neglected and magnetic field. the boundary conditions for the vectorˆl on the surface This is contrary to the effect of magnetic field dis- are fully determined by the orbital effects, which are cussed in Refs. [7, 11], where the magnetic field is as- invariant under rotation of the magnetic field together sumed to be so small that the boundary conditions are with the spin subsystem. solely determined by spin-orbit interaction. This leads Let us, however, consider the orientation of mag- to anisotropy of magnetic susceptibility [7, 11], which netic field along the axis z. This allows us to express the HamiltonianintermsofthevariableI =ˆl·hˆ in(2), however disappears in large fields. Note also that in our case the spin which enters the Hamiltonian (9) for which is regulated in NMR experiments in Ref. [15] Majorana fermions, is obtained from the real spin by where the orientation of the field normal to the plates rotations provided by the order parameter matrix R . is used: αi This means that in large fields, when the spin-orbit in- k2−k2 1 teractioncanbeneglected,thequantizationaxisforthe H= Fτ − γHIσ˜ + 2m∗ 3 2 z real spin of Majorana fermions is not fixed. kx ky kz The effective Hamiltonian (9) has nontrivial topol- τ ∆ (z)σ˜ +∆ (z)σ˜ +∆ (z)σ˜ . (7) 1(cid:18) k xkF k ykF ⊥ zkF(cid:19) ogy described by the topological invariant The second order secular equation (10) in [8] pro- 1 duces the following 2×2 Hamiltonian for fermion zero N = tr d2kdω G∂ G−1G∂ G−1G∂ G−1 , 2+1 4π2 kx ky ω modes: (cid:20)Z (cid:21) (13) H+(1+) H+(1−) =c −21γHI ky+ikx , (8) where G = 1/(iω − Hzm) is the Green’s function of H−(1+) H−(1−)! ky−ikx 21γHI ! fdeurcmeidoninzreerloatmivoidsteisc.2T+he1itnhveaorriaienst[(2123,)2w3,a2s4fi].rsIttiinstrroe-- which can be written as sponsible for quantization of Hall conductivity induced bytopologicalstructureofenergy-momentumspace,the γHI H =cˆz·(σ˜ ×k)− ˆz·σ˜ . (9) so-called intrinsic quantum Hall effect. It was later in- zm 2 dependently introducedforthe filmofsuperfluid3He-A This the so-called helical (see e.g. [21] and references in condensed matter [25, 26]. Under experimental con- therein)Hamiltonianproducestherelativisticspectrum ditions in Ref. [15], the value of this invariant is deter- of massive particles: mined by the Ising variable I in (2): E2 =c2k2+M2, (10) I N = . (14) 2+1 2 where the ‘speed of light’ [8] ∞dz∆k(z)exp − 2 zdz′∆ (z′) NMR experiments in Ref. [15] detected coexistence of c= 0 kF vF 0 ⊥ . (11) the surface domains with different I, which are thus R ∞dzexp −(cid:16)2 zRdz′∆ (z′) (cid:17) separated by the one-dimensional domain wall on the 0 vF 0 ⊥ surface. Sincethedomainshavedifferentvaluesoftopo- R (cid:16) R (cid:17) The mass of the surface fermions logicalinvariantN , then accordingto the index the- 2+1 orem (see e.g. [27]), the line separating two domains 1 M = γH, (12) contains gapless 1+1 fermion zero modes. 2 4 G.E.Volovik 5. DISCUSSION smoothly violated, etc. The Green’s function matrices with spin and band indices must be used for this clas- The symmetry of superfluid 3He-B is important sification, since they take into account interaction. In for its topological properties. Magnetic field violates this way we may finally obtain the full classification of isotropy of 3He-B: the gap become anisotropic with topological matter, including insulators, superconduc- ∆ −∆ ∝ H2. This distortion of the gap does not tors,magnets,liquids,andvacuaofrelativisticquantum k ⊥ change the topological invariant introduced in [5], and fields. thus cannot destroy the massless relativistic fermions The problem of the interplay of topology and sym- on the surface of 3He-B. However, the violation of the metry exists not only for the momentum-space topol- other symmetry of 3He-B by magnetic field – the time ogy,butalsoforthereal-spacetopology,whichconsiders reversal symmetry – is crucial. The topological invari- classification of topological defects and textures in sys- antsupportedbythissymmetryceasestoexistandthus tems with broken symmetry. For example, some values thegaplessfermionsonthesurfaceof3He-Barenotpro- ofthe windingnumberdescribingthe topologicaldefect tectedanymorebytopology: theybecomefullygapped. are notcompatible with symmetry ofthis defect, which Nevertheless, if perturbation of symmetry is small, the connectsforexamplethepointsrand−r. Thishappens surface fermions remain relativistic with mass propor- with monopoles [34]; disclinations – topological defects tional to symmetry violating perturbation – magnetic inliquidcrystals[35];vorticesinsuperfluids[17];cosmic field. strings; etc. One of the tasks there is the classification This is notthe whole story. The spontaneouslybro- oftopologicalobjectsinterms oftheirsymmetry. Simi- ken relative spin-orbit symmetry of 3He-B [28] – sym- larly we need the symmetry classificationof topological metry under relative rotations of spin subsystem with objects in momentum space, where the symmetry con- the respect to the orbital one [29] – gives rise to the nects different points in momentum space, say k and vector ˆl of orbital anisotropy in the presence of mag- −k [1]. netic field. This in turn leads to Ising variable I = ±1 The special role in classification of topological sys- whichcharacterizesthesurfaceof3He-B.TheIsingvari- tems is played by dimensional reduction. See for ex- abledeterminesthesignofthe masstermofthe surface ample Chapters 11 and 21 in [27] where the topological fermions and the topological invariant (14) describing invariantsfor the 2Dfully gappedsystemsareobtained their effectiveHamiltonian(9). Theline onthe surface, by dimensional reduction of the topological invariants whichseparatesdomains withdifferentI, containsgap- for the 3D gapless system; the dimensional reduction less fermions, which are protected by combined action hasbeenrecentlydiscussedin[36]. Thedimensionalre- of symmetry and topology. So, the superfluid 3He-B duction allows us to use for classificationof the gapped provides many examples of the interplay of symmetry systemsthescheme,whichwassuggestedbyHoravafor and topology. the classification of the topologically nontrivial nodes The other examples of the interplay of symmetry in spectrum [37]. But this also must be supplemented and topology in topological matter and in vacua of rel- by the symmetry analysis, and also by analysis of the ativistic quantum fields can be found in [27, 32, 33]. types ofthe emergentsymmetries whichnecessarilyap- Some topological invariants exists only due to symme- pear within some topological classes. try, while some values of the topological invariant are IowespecialthankstoJohnSaundersfordiscussion not compatible with symmetry. It is right time for the onthe experiments [15]and amgratefulto Shinsei Ryu general classification of topological matter in terms of and Liang Fu for discussion on symmetry and topol- its symmetry andtopology. The attemptofsuchclassi- ogy. This work is supported in part by the Academy of fication was made in [1, 2, 3, 4]. However, only non- Finland,CentersofExcellenceProgram2006–2011,and interacting systems were considered, and not all the the Khalatnikov–Starobinsky leading scientific school symmetries were exploited. 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