Time-Resolved Vibrational Spectroscopy: Proceedings of the 2nd International Conference, Emil-Warburg-Symposium, Bayreuth-Bischofsgrün, Fed. Rep. of Germany, June 3–7, 1985

307 Pages·1985·9.401 MB·English

by  M. Stockburger, A. Laubereau (auth.), Professor Dr. Alfred Laubereau, Dr. Manfred Stockburger (eds.)

4
Volume 1 Fluctuations and Sensitivity in Nonequilibrium Systems
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Volume 2 EXAFS and Near Edge Structure 1/1
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Volume 3 Nonlinear Phenomena in Physics
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Time-Resolved
Vibrational Spectroscopy
Proceedings of the 2nd International Conference
Emil-Warburg Symposium
Bayreuth-BischofsgrOn, Fed. Rep. of Germany
June 3-7, 1985
Editors
A. Laubereau and M. Stockburger
With 187 Figures
Spri nger- Verlag
Berlin Heidelberg New York Tokyo
Professor Dr. Alfred Laubereau
Universität Bayreuth, Universitätsstraße 30, Postfach 3008,
0-8580 Bayreuth, Fed. Rep. of Germany
Dr. Manfred Stockburger
Max-Planck-Institut für Biophysikalische Chemie, Postfach 2841,
0-3400 Göttingen, Fed. Rep. of Germany
ISBN 978-3-642-47545-0 ISBN 978-3-642-47541-2 (eBook)
DOI 10.1007/978-3-642-47541-2
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© Springer-Verlag Berlin Heidelberg 1985
Softcover reprint of the hardcover 1s t edition 1985
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2153/3150-54321 0
Preface
For more than two decades time-resolved vibrational spectroscopy (TRVS)
was only part of general conferences on solid-state physics, molecular spec
troscopy, photochemistry and photobiology. It was in 1982 when the first
meeting on TRVS was organized at Lake Placid. The conference met a strong
need among the workers in the field, and it was decided to continue with spe
cial conferences on this topic.
The 2nd International Conference on Time-Resolved Vibrational Spec
troscopy was held June 3-i, 1985 at Bayreuth-Bischofsgrun, Germany. Sci
entists from many disciplines came together to discuss their common interest
in time-resolved techniques and spectroscopic applications. The high qual
ity of the research presented, the enthusiasm of the participants, and the
attractive surroundings combined to an enjoyable atmosphere. Ample time
for discussions and the limited number of participants (approximately 100)
stimulated the formal and informal exchange of ideas.
"\'umerous people helped to make the conference run smoothly. Special
thanks are due to Mrs. Lenich for making the technical arrangements, and
to the program committee for the selection of the scientific presentations.
The meeting has benefited from several financial souces. The generous sup
port by the Emil-Warburg-Stiftung was particularly helpful. Financial aid of
the "Deutsche Forschungsgemeinschaft" and of the "Bayerisches Staatsmini
sterium fur U nterricht und K ultus" is also gratefully acknowledged.
Bayreuth and Gottingen A.Laubereau
August 1985 M. Stockburger
v
Contents
Introduction. By M. Stockburger and A. Laubereau ................... 1
Part I Techniques and Instrumentation
Energy-Partitioning Measurements in 0(1 D2) Reactions by Time
Resolved Fourier Transform Infrared Emission Spectroscopy
By P.M. Aker and J.J. Sloan (With 2 Figures) ......................... 6
High-Resolution Fourier Transform Raman Spectroscopy with
Ultrashort Laser Pulses
By H. Graener and A. Laubereau (With 2 Figures) .................... 11
Picosecond Transient Raman Spectroscopy Using the High Repetition
Rate, Amplified, Synchronously Pumped Dye Laser
By T.L. Gustafson, D.A. Chernoff, J.F. Palmer, and D.M. Roberts
(With 3 Figures) ......................................................... 15
Pulsed Multichannel Raman Technique
By A. Deffontaine, M. Delhaye, and M. Bridoux (With 3 Figures) .... 20
Fluorescence Rejection in Raman Spectroscopy. By N. Everall,
R.W. Jackson, J. Howard, and K. Hutchinson (With 5 Figures) ...... 25
Measurement of the Third-Order Electronic Susceptibility of GaP by
Picosecond CARS Spectroscopy
By J. Kuhl, B.K. Rhee, and W.E. Bran (With 3 Figures) ............. 30
Polarization Effects of Time-Resolved Coherent Raman Scattering in
Liquids. By N. Kohles and A. Laubereau (With 3 Figures) ........... 35
Part II Vibrational Dynamics of Molecules
Ultrafast Intramolecular Vibrational Redistribution and
Intermolecular Energy Dissipation of Polyatomic Molecules in
Solution. By W. Kaiser and A. Seilmeier (With 4 Figures) ........... 42
Time-Resolved Observation of Vibration ally Highly Excited
Polyatomic Molecules. By H. Hippler (With 8 Figures) ............... 45
VII
Time-Resolved Raman Spectroscopy of Highly Excited Vibrational
States of Polyatomic Molecules
By V.S. Letokhov and E.A. Ryabov (With 4 Figures) ................. 53
Transient Vibrational Excitation of Dye Molecules in a Solid Polymer
Matrix. By A. Seilmeier and W. Kaiser (With 2 Figures) ............. 59
Ultrafast Vibronic Dynamics of Dye Molecules Studied by
the Induced Grating Method. By P. Troeger, C.-H. Liu,
and A. Laubereau (With 4 Figures) ..................................... 62
Vibrational Fluorescence from Matrix-Isolated CO and NO Pumped
with a Color Center Laser, By J.P. Galaup, J.Y. Harbec, J.J. Zondy,
R. Charneau, and H. Dubost (With 3 Figures) ......................... 67
Vibrational Energy Decay of Surface Adsorbates. By E.J. Heilweil,
M.P. Casassa, R.R. Cavanagh, and J.C. Stephenson................... 71
Vibrational Energy Relaxation of Hydrogen Chloride in Liquid and
Solid Xenon. By J. Chesnoy (With 3 Figures) ......................... 76
Ultrafast IR Spectroscopy Studying Nearly-Free Induction Decay
By H.-J. Hartmann, K. Bratengeier, and A. Laubereau
(With 4 Figures) ......................................................... 81
Dephasing in Liquid N2 and in Binary Mixtures of N2 with Liquid
Argon. By D. Brandt, H.J. van Elburg, B.L. van Hensbergen,
and J.D.W. van Voorst (With 4 Figures) ....................... ........ 86
High Pressure Brillouin Scattering on Liquid Carbon Tetrachloride
and Benzene. By A. Asenbaum (With 3 Figures) ...................... 90
Part III Vibrational Dynamics in Solids
Vibrational Energy Relaxation in Solid Benzene
By R.M. Hochstrasser (With 3 Figures) ................................ 96
Time-Resolved Raman Spectroscopy of Laser-Heated Semiconductors.
By D. von der Linde (With 4 Figures) .................................. 100
Picosecond Vibrational Dynamics of Hydrogen Bonded Solids:
Phonons and Optical Damage. By J .R. Hill, T.J. Kosic,
E.L. Chronister, and D.D. Diott (With 6 Figures) ..................... 107
Time-Resolved Two-Color Optical Coherence Experiments
By K. Duppen, D.P. Weitekamp, and D.A. Wiersma
(With 6 Figures) ......................................................... 112
High Sensitivity Time-Resolved Study of the Coherence and
Parametric Instabilities of Two-Phonon States
By G. Gale, F. Vallee, and C. Flytzanis (With 3 Figures) ............. 117
VIII
Two-Phonon Bound States in '\1olecular Cryslals
By F. Bogani (With 6 Figures) .......................................... 124
Part IV Photochemical Reactions
Resonance Raman Studies of Transient Intermediates in
Photoreactions of Anthraquinone and Flavone Species
By J.:\'. Moore, D. Phillips, P.M. Killough, and R.E. Hester
(With 5 Figures) ......................................................... 132
Resonance Raman Spectra and Assignments of Deuterated Stilbene
Anion and Cation Radicals
By C. Richter and W. Hub (With 1 Figure) ............................ 137
Application of Time-Resolved Resonance Raman Spectroscopy to
Some Organic Photochemical Processes in Solution
By H. Hamaguchi (With 5 Figures) ..................................... 142
Time-Resolved Resonance Raman Studies of Photoenolization
of ortho-Alkyl Substituted Benzophenones. By H. Takahashi,
H. Ohkusa, H. Isaka, S. Suzuki, and S. Hirukawa (With 3 Figures) 147
Resonance CARS Spectra of Metastable '\1erocyanines Produced by
VV -Photolysis of Spirooxazines
By U. Kliiter, W. Hub, and S. Schneider (With 3 Figures) ............ 152
Photoisomerization of Stilbene and 1,4-Diphenylbutadiene in
Compressed Gases and Liquids - Density-Dependent Solvent Shift
and Transport Contributions. By G. Maneke, J. Schroeder, J. Troe,
and F. VoE (With 2 Figures) ............................................ 156
Part V Transient Species
Advantages of Resonance CARS for the Study of Short-Living
Radicals and Photoisomers. By A. Lau, W. Werncke, M. Pfeiffer,
H.-J. Weigmann, and J.T. Tscho (With 3 Figures) .................... 162
Resonance CARS Study of Q,w-Diphenylpolyenes in the Electronic
Excited States. By A. Kasama, M. Taya, T. Kamisuki, Y. Adachi,
and S. Maeda (With 4 Figures) ......................................... 166
l'ltraviolet Resonance Raman Studies of Electronic Excitations
By B.S. Hudson (With 2 Figures) ............... ............ ............ 170
Excited States of Polyenes Studied by Time-Resolved Resonance
Raman Spectroscopy. By F. W. Langkilde, N.-H. Jensen,
and R. Wilbrandt (With 1 Figure) ...................................... 175
Resonance Raman Spectra of the Triplet States and Anion Radicals
of Trans-Nitrostilbenes. By C. Richter and W. Hub (With 2 Figures) 179
IX
Resonance Raman Spectroscopy of Transient Species in the Pulse
Radiolytic Oxidation of Aqueous Aniline
By G.N.R. Tripathi, R.H. Schuler, and L. Qin (With 4 Figures) ...... 183
Intramolecular Kinetics of Vibration ally Excited Singlet and Triplet
States in Some Cyclic Hydrocarbons
By H.G. Li::ihmannsroben and K. Luther (With 2 Figures) ............ 189
In Situ Raman Studies of Homopolymerisation and Copolymerisation
Reactions. By H.J. Bowley, I.S. Biggin, and D.L. Gerrard............ 194
Time-Resolved Spontaneous Raman Scattering by Chrysene in Sl and
Incoherent CARS for T 2 Measurement
By T. Kobayashi, S. Koshihara, and T. Hattori (With 5 Figures) 196
Part VI Biological Systems
How Protein Structure Controls Oxygen Dissociation in
Haemoglobin: Implications of Picosecond Transient Raman Studies
By J.M. Friedman (With 2 Figures) .................................... 204
Resonance Raman Spectra of Reaction Intermediates of Heme
Enzymes. By T. Kitagawa, S. Hashimoto, and T. Ogura
(With 4 Figures) ......................................................... 211
Heme-Linked Ionization of Horseradish Peroxidase Compound II
Monitored by Changes in the Fe(IV)=O Resonance Raman Frequency.
By J. Terner, A.J. Sitter, and C.M. Reczek............................. 216
Resonance Raman Studies of Transient States in Bacterial
Reaction Centers. By B. Robert, W. Szponarski, and M. Lutz
(\Vith 2 Figures) ......................................................... 220
Energy-Transfer Between Dimeric Chlorophyll a and All-Trans (3-
Carotene in vitro as Resolved by Fluorescence Photoquenching
By N.E. Binnie, L.V. Haley, and J.A. Koningstein (With 6 Figures) .. 225
Using Time-Resolved Resonance Raman Spectroscopy to Map the
Reaction Pathway for Enzyme-Substrate Transients
By P.R. Carey (With 3 Figures) ......................................... 233
UV, IR, and Raman Spectroscopic Tracings of the B~Z Transitions
of Poly[d(GC)].poly[d(GC)]. By H. Takashima, S. Tate, M. Nakanishi,
Y. Nishimura, and M. Tsuboi (With 2 Figures) ........................ 237
Kinetic Studies on Bacteriorhodopsin by Resonance Raman
Spectroscopy. By M. Stockburger, Th. Alshuth, and P. Hildebrandt
(With 7 Figures) ......................................................... 240
Resonance Raman Study on the Role of Water in Bacteriorhodopsin
By P. Hildebrandt, A. Hagemeier, and M. Stockburger
(With 4 Figures) ......................................................... 246
x
Picosecond and Nanosecond Resonance Raman Evidence for
Structural Relaxation in Bacteriorhodopsin's Primary Photoproduct
By D. Stern and R. Mathies (With 3 Figures) ......................... 250
Picosecond Time-Resolved Resonance Raman Spectroscopy of
Bacteriorhodopsin Intermediates
By G.H. Atkinson, I. Grieger, and G. Rumbles (With 1 Figure) 255
Evidence from FTIR-Measurements for a Separation of the
Protonated Schiff Base from the Counterion into a Less Polar
Environment. By K. Gerwert, F. Siebert, J .A. Pardoen, C. Winkel,
and J. Lugtenburg (With 4 Figures) .................................... 259
Time-Resolved Infrared Spectroscopy Applied to Photobiological
Systems. By K. Gerwert, R. Rodriguez-Gonzalez, and F. Siebert
(With 6 Figures) ......................................................... 263
Part VII Theoretical Aspects
Electrontransfer and Vibrational Relaxation in Bridged Donor-
Acceptor Systems. By S.F. Fischer and I. NuSbaum (With 1 Figure) 270
Theory of Luminescence in the Three-Level System with Extension to
the Multistate Problem by Transform Methods
By A.C. Albrecht (With 3 Figures) ..................................... 274
Application of Time-Dependent Raman Theory to the Analysis of
Inorganic Photosystems
By D.E. Morris and W.H. Woodruff (With 1 Figure) .................. 280
Time-Dependent Quantum Dynamics of the Picosecond Vibrational
IR-Excitation of Polyatomic Molecules
By M. Quack, J. Stohner, and E. Sutcliffe (With 3 Figures) .......... 284
Decay Law in Conformational Relaxation. By A.A. Villaeys .......... 289
Stochastic Theory of Vibrational Dephasing and Transient CARS
Lineshapes. By R.F. Loring and S. Mukamel (With 3 Figures) 293
On the Lineshape of Molecular Aggregate Spectra
By P.O.J. Scherer and S.F. Fischer (With 2 Figures) .................. 297
Index of Contributors.. . . . . . .. .. . . . . . . .. .. . .. .. . .. . . ... .. .. .. . .. . .. .. . . 301
XI