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Thermal spray : meeting the challenges of the 21st century : proceedings of the 15th International Thermal Spray Conference, 25-29 May 1998, Nice, France PDF

1644 Pages·1998·206.836 MB·English
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Thermal Spray Meeting the challenges of the 21st Century Proceedings of the 15th International Thermal Spray Conference 25-29 May 1998 Nice,France Edited by Christian Coddet Organized by Commissariat a l'Energie Atomique Institut Polytechnique de Sevenans Universite de Limoges Ecole Nationale Superieure des Mines de Paris Ecole Centrale de Lyon Institut de Soudure on behalf of the Select Committee on Surfacing and Thermal Spraying of the International Institute of Welding Co-sponsored by The ASM Thermal Spray Society The German Welding Society The High Temperature Society of Japan Copyright 1998 by ASM International All rights reserved No part of this book may be reproduced, stored in a retrieval system, or transmitted, in any form or by any means, electronic, mechanical, photocopying, recording, or otherwise, without the written permission of the copyright owner. First printing, April 1998 Great care is taken in the compilation and production of this Volume, but it should be made clear that NO WARRANTIES, EXPRESS OR IMPLIED, INCLUDING, WITHOUT LIMITATION, WARRANTIES OF MER CHANTABILITY OR FITNESS FOR A PARTICULAR PURPOSE, ARE GIVEN IN CONNECTION WITH THIS PUBLICATION. Although this information is believed to be accurate by ASM, ASM cannot guarantee that favorable results will be obtained from the use of this publication alone. This publication is intended for use by persons having technical skill, at their sole discretion and risk. Since the conditions of product or material use are outside of ASM's control, ASM assumes no liability or obligation in connection with any use of this information. No claim of any kind, whether as to products or information in this publication, and whether or not based on negligence, shall be greater in amount than the purchase price of this product or publication in respect of which damages are claimed. THE REMEDY HEREBY PROVIDED SHALL BE THE EXCLUSIVE AND SOLE REMEDY OF BUYER, AND IN NO EVENT SHALL EITHER PARTY BE LIABLE FOR SPECIAL, INDIRECT OR CONSEQUENTIAL DAMAGES WHETHER OR NOT CAUSED BY OR RESULTING FROM THE NEGLIGENCE OF SUCH PARTY. As with any material, evaluation of the material under end-use conditions prior to specification is essential. Therefore, specific testing under actual conditions is recom mended. Nothing contained in this book shall be construed as a grant of any right of manufacture, sale, use, or reproduction, in connection with any method, process, apparatus, product, composition, or system, whether or not covered by letters patent, copyright, or trademark, and nothing contained in this book shall be construed as a defense against any alleged infringement of letters patent, copyright, or trademark, or as a defense against liability for such infringement. Comments, criticisms, and suggestions are invited, and should be forwarded to ASM International. Library of Congress Catalog-Card Number: 98-70374 ISBN: 0-87170-659-8 SAN: 204-7586 ASM International® Materials Park, OH 44073-0002 Printed in the United States of America PREFACE These proceedings contain most of the papers presented at the fifteenth International Thermal Spray Conference. These conferences have become the leading forum for the thermal spray community all over the world. Thermal spray technology is a dynamic, rapidly changing and expanding field. The 271 papers included in the proceedings cover theoretical aspects such as modelling and properties of coatings linked to spraying parameters or in-flight particle parameters, the different spraying processes, the process and quality control with an emphasis on on-line control and the practical aspects of the different coating applications, the latest world-wide developments in processes, equipment, materials and applications in thermal spray. They were grouped into 10 sessions on : - oxydation and corrosion, - wear and corrosion-alternatives to conventionnal coatings, - modeling and experimental characterization of jets and deposits, - properties of coatings and characterization, - diagnostic of jets and coatings : processes and products quality control, - industrial applications, - feedstock materials, composite structures and near net shape forming - spraying and associated processes, - thermal barrier and ceramic coatings, - thermal spray for the next millennium. Nine keynotes speakers have highlighted the knowledge and state of the art in the different topics and provided an excellent introduction to the different sessions, suited to newcomers as well as to old timers in the field. Beside the sessions, an industrial forum on thermal spraying has gathered professional people and end users (or potential ones). It has promoted thermal spraying and brought together thermal spray equipment/service firms and potential users. The execution of a large conference such as ITSC requires the efforts of many people. The Organizing Committee wants to thank all of the authors, session chairs, and symposia chairs, and the CEA staff who made the Conference a technical success. Particular thanks are due to the editor of these Proceedings. In addition to the technical sessions represented in these Proceedings, a large exhibition of thermal spray equipment, materials, services, and supporting technology was held. Attendees of the Conference were able to not only listen to outstanding technical presentations, but get an update on the state-of-the-art of the "tools of the trade". The support of the exhibitors added substantially to the success of the Conference and the value received by attendees. Certainly many thanks are due to the Exhibition committee and the CEA staff for the excellent Exhibition. Prof. P. FAUCHAIS Conference chairman ui CONFERENCE CHAIRMAN Pierre FAUCHAIS 60 years old. An engineer and graduate of "Ecole Nationale Superieure A6ronautique" (1963,. Poitiers), Doctor of Science (1968, Poitiers). Prof. P. FAUCHAIS has created the laboratory of ceramic materials and surface treatment LMCTS, associated with CNRS, at the Universityof Limoges in 1975. He has been involved in thermal spraying in general and plasma spraying in particular for more than thirty years. His group on thermal spraying comprises 10 permanent people and 10 PhD. NATIONAL ORGANIZING COMMITTEE CHAIRMAN Paul LUCCHESE 37 years old. An engineer and graduate of the "Ecole Centrale de Paris" (1983) in Nuclear engineering, he has been in charge of the R and D laboratory for thermal spray at the CEA (Commissariat a l'Energie Atomique) for 7 years. He has been appointed CEA expert in the field of thermal spray. In 1995, in conjunction with the "Ecole des Mines de Paris", he created the Communal Centre of Competence in Plasma Spray (C2P) located in Corbeil, France. He holds the position of Joint Director of C2P. SCIENTIFIC PROGRAM CHAIRMAN Christian CODDET 48 years old. Doctor of Science (1977) of the University of Grenoble.University Professor and head of the direction of Research - Polytechnic Institute of Sevenans (France). Head of the LERMPS Laboratory (Materials and Surface Properties Research Laboratory). Leading the Thermal Spray research group (40 people) in the Technological University of Sevenans since 1985. IV French Organizing Committee P. FAUCHAIS UNIVERSITE DE LIMOGES, Conference Chairman P. LUCCHESE COMMISSARIAT A L'ENERGIE ATOMIQUE, Chairman M. BRAMAT nw C. CODDET INSTITUT POLYTECHNIQUE DE SEVENANS M. DUCOS IIW, Select Committe B. HANSZ INSTTRJT POLYTECHNIQUE DE SEVENANS M. JEANDIN ECOLE DES MINES DE PARIS A. LEFORT COMMISSARIAT A L'ENERGIE ATOMIQUE J.M. LEGER CCRS, INSTITUT DE SOUDURE D. TREHEUX ECOLE CENTRALE DE LYON M. DEFER INSTITUT DE SOUDURE V International Advisory Commitee C. BERNDT THE THERMAL SPRAY LABORATORY, Stony Brook, USA E. LUGSCHEIDER AACHEN UNIVERSITY OF TECHNOLOGY, Germany A. OHMORI KINKI INSTITUTE, Japan W. MILEWSKI INSTITUTE OF PRECISION MECHANICS, Poland M. BOULOS UNIVERSITY OF SHERBROOKE, Canada T. MANTYLA TAMPERE UNIVERSITY OF TECHNOLOGY, Finland P. CHRASKA INSTITUTE OF PLASMA PHYSICS, Czech Republic T.W. CLYNE CAMBRIDGE UNIVERSITY, United Kingdom R.C. TUCKER PRAXAIR SURFACE TECHNOLOGIES and TSS President, USA Y.S. BORISOV E.O. PATON INSTITUTE OF ELECTRIC WELDING, Ukrain K.A. KHOR NANYANG TECHNOLOGICAL UNIVERSITY, Singapore R.W. SMITH MATERIALS RESSOURCES INC., USA vi French Scientific Committee C. CODDET INSTITUT POLYTECHNIQUE DE SEVENANS, Chairman A. SERTOLI CHROMALLOY France M. DUCOS IIW, Select Committee J.P. HUCHIN SOCHATA - SNECMA M. JEANDIN ECOLE DES MINES DE PARIS G. SCHNEDECKER COMMISSARIAT A L'ENERGIE ATOMIQUE J.M. LEGER AIR LIQUDDE P. NOEL MATRA L. PAWLOWSKI Universite d'Artois F. PELLERIN TURBOMECA D. TREHEUX ECOLE CENTRALE DE LYON A. VARDELLE UNIVERSITE DE LIMOGES vii Exhibition Committee J.M. LEGER AIR LIQUIDE, France, Chairman R. COOPER X-FORM, USA M. GUELDRY SNECMA, France C. HOWES MILLER THERMAL, USA F. TOURENNE MEDICOAT, France P. LUCCHESE COMMISSARIAT A L'ENERGIE ATOMIQUE, France A. LEFORT COMMISSARIAT A L'ENERGIE ATOMIQUE, France A. SAIDA EUROPEAN GAS TURBINES, France B. HANSZ INSTITUT POLYTECHNIQUE DE SEVENANS, France D. CORNU SEP, France J.P. DUHAMEL SULZER-METCO, France M. PRONER SNMI, France via Industrial Forum Committee B. HANSZ, President INSTITUT POLYTECHNIQUE DE SEVENANS, France F. BLEIN CEA, France N. LLORCA UNIVERSITY OF BARCELONA, Spain F. TOURENNE MEDICOAT, France P. LUCCHESE CEA, France Logistic Committee D. GUILLON CEA-LE RIPAULT, France E. MONTMAYEUL CEA-GRENOBLE, France C. IANNARELLI C2S, Saint-Cloud, France J. DI ROSA ASM, USA ix INTRODUCTION The papers contained within this book constitute the proceedings of the 15h International Thermal Spray Conference (i.e. the 15th ITSC). This conference was held in the Acropolis Center, Nice, FRANCE. It was held in conjunction with a Thermal Spray Exposition as well as an Industrial Forum which promoted discussions on major industrial issues between people of small and medium business enterprises and experts in the field. The conference was organized by the French Atomic Energy Commission (CEA) on behalf of the Select Committee on Surfacing and Thermal Spraying of the International Institute of Welding. The event was coorganized by the Institut Polytechnique de Sevenans, the Universite de Limoges, the Ecole des Mines de Paris, the Ecole Centrale de Lyon, the Institut de Soudure and was cosponsored by the ASM Thermal Spray Society, the German Welding Society and the High Temperature Society of Japan. Some 400 papers were accepted for the conference program. These two volumes contain 271 of these papers which turned out well in meeting the final deadline. For the first time in this series of conferences, all papers were reviewed with the help of the National and International Advisory Committee Members reinforced by some "volunteers". Numerous papers beneficiated from this contribution and where amended before publication. Therefore, besides all the authors who contributed to this book and to the success of the conference, the editor would especially thank the reviewers from all around the world for their unvaluable contribution to the quality of these proceedings. Special dedication should also be given to M. Coddet and S. Courpasson for their help in the management of such a large amount of papers and letters. The papers are presented in 10 chapters corresponding to the ten symposia of the congress. The first paper within each symposium is the keynote lecture. The three indexes at the back of each volume can be used to locate a paper according to the subject content (key words), authors or author affiliation. All authors and all institution/company affiliations of a paper have been indexed. It seems pertinent to set the 15th ITSC against the backdrops of this series of conferences that commenced in 1956. A listing of these meetings follows and show the continuing growing importance of Thermal Spray Science and Technology during these five decades. 1956 - lstlnternational Metal Spraying Conference, Hall (East Germany),Published in Schweisstechnik Total papers = 20. Attendees = 300 1958 - 2nd International Metal Spraying Conference, Birmingham (UK), Organized by the Association of Metal Sprayers. Total papers = 34. Attendees = 135 1962 - 3rd International Metal Spraying Conference, Madrid (Spain), Organized by the Instituto de la Soldadura Total papers = 23. Attendees = 100 x

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