THEK/TBOUNDARYOFGAMS(EASTERNALPS,AUSTRIA) ANDTHENATUREOFTERMINALCRETACEOUSMASSEXTINCTION The K/T boundary of Gams (Eastern Alps, Austria) and the nature of terminal Cretaceous mass extinction Andrei F. Grachev Editor AttheendoftheCretaceous(65Maago)theEarthsufferedthegreatbiologicalcrisis whenestimated60%oftheformerspecies,amongthemthedinosaurs,becameextinct. Morethan3000paperswerepublishedforthelast30years,concerningthediscussion thisquestionbutthedecisionremainsunresolved. Authorsproposethenewapproach tothisproblembasedonthedetailedmicropalaeontological,lithological,geochemical, nanomineralogical, isotopic and petromagnetic investigations of the unique sedimen- tary sequence at the Cretaceous-Paleogene boundary in the Gams area, Eastern Alps, Austria. Theconclusionsdrawnfromtheresultsofanalysisprincipallydifferfromallpreex- istingdataonthetransitionallayerbetweentheCretaceousandPaleogeneandprovide another look at the reasons for the mass extinction of living organisms at 65 Ma ago. These data eliminate the need for opposing volcanism to an impact event: both took place,butthechangesinthebiotawereinducedbyvolcanism,asalsowastheappear- anceoftheIranomalyitself,whereasthefallofacosmicbodyoccurredapproximately 500–800yearslater. AmEndederKreidezeit,vor65MillionenJahren,erlebtedieErdeeinebedeutende biologischeKrise: Gescha¨tzte60%derArtenstarbenaus, unterihnendieDinosaurier. Obwohlu¨ber3000PublikationenzudiesemThemaindenletzten30Jahrenerschienen sind,bliebdieUrsacheweiterimDunkeln. IndemvorliegendenBandwirddasThema anhand mikropala¨ontologischer, lithologischer, geochemischer, nanomineralogischer, isotopischer und petromagnetischer Untersuchungen neu beleuchtet. Grundlage ist dieeinzigartigeAbfolgedesGrenzbereichsKreide/Pala¨ogennahedesindenOstalpen (O¨sterreich)gelegenenOrtesGams. DieSchlußfolgerungenausdenUntersuchungenunterscheidensichprinzipiellvon fru¨heren Interpretationen der Genzschicht an der Kreide/Pala¨ogen-Grenze: Durch die neuen Ergebnisse wird die Diskussion Vulkanismus oder Impakt obsolet: Beide Vorga¨nge fanden statt, der große Einschnitt bei den Biota wurde so wie die Iridium- AnomaliejedochdurchdenVulkanismusverursachtundnichtdurcheinenkosmischen Ko¨rper. DieserhatseineSpurenerst500 800Jahrespa¨terhinterlassen. DOI:10.2205/2009-GAMSbook This book is published by The Geological Survey of Austria in cooperation with the Geophysical Center of the Russian Academy of Sciences. The camera-ready copy of this book is produced from electronic version composedusingLATEX2εtypesettingsystemundergamsbooktemplate. Preface Inmid-60softheXXcenturyIwasprivilegedtogetacquaintedwithLevGumiljevwho,at thattime,wasoverwhelmedbytheinfluenceofgeographicalenvironmentonthedevelop- ment of the society. His ideas, stating that such periodic catastrophes as sharp changes of the climate, leading to drought and the disappearance of natural environment for planting and breeding, had caused mass, up to the millions, migration of people, wars and changes of state boundaries. These ideas were revolutionary: they neglected “the role of classes” and“classstruggle”. WhiletalkingtoLevGumiljev,Iwasthinkingthatatimewouldcome when I also get into studying a similar problem related to the influence of geographical environmentonthebiosphereinthegeologicalPast. My professional preferences, as a geologist, were related to tectonics and magmatism, as wellasdisclosingtheevolutionoftheseprocessesinthehistoryoftheEarth. Inmylectures, which I had been delivering for 20 years in the Leningrad University, I, quite naturally, touchedupontheproblemofmassextinctionsinPhanerozoic. Theentiregeologicalchron- icle is devoted to them. Nevertheless, I was not focussing on this problem, being of the opinionthatthiswasapurelypalaeontologicalproblem. I became intrigued by the problem of catastrophic events in the history of the Earth much later, because of studying mantle plumes, especially one of its main manifestations – mag- maticactivity. Once,inasecond-handbook-shop,IboughtabookbyGeorgesCuvier“Cat- aclysmsonthesurfaceoftheEarth”(“Discourssurlesrevolutionsdelasurfaceduglobe”), translatedintoRussianbythePublishingHouse“Academy”in1937. Theideaabouttherole ofcatastrophicextinctionsinthehistoryoftheEarth,aspresentedbyG.Cuvier,stronglyop- posedtheviewsofCh. Lyellandhissuccessorsonslow-pacechangesofthebiosphere. Knowing that “Something is rotten in the state of Denmark,” I decided to find out how mantle plume volcanism influences the bioshpere. But, by this time, the ideas of G. Cuvier were unexpectedly supported by the study of L. Alvarez, Nobel prize-winner in physics. L. Alvarez and his colleagues identified anomalous concentrations of iridium, clearly ex- ceedingknownandmaximalpresencesoftheseelementsinthelithosphere,inthelayersof themountainrockattheK/Tboundary(65Mayago)intheGubbio(Italy)andStevns-Klint sections(Denmark). Theypresumedthatthoseanomalieswereconnectedtothecollisionof a large-sized meteorite (or an asteroid) with the Earth which could have happened at that time: suchbodieshavethesameamountofiridiumasthelayersattheK/Tboundary. Such event could have caused the conditions of a “nuclear winter” as its consequence, within its first days leading to the extinction of the majority of terrestrial and ocean organisms, and theprocessofphotosynthesiswouldhavebeenceasedformanyyears. ThereactionoftheglobalscientificcommunitytowardsthearticlepublishedbyL.Alvarez et al. was unanimous: according to numerous follow-up publications, a high presence of iridium was found in practically all cross-sections at the K/T boundary. Doubts expressed by a number of scientists were not taken into account, though there were obvious grounds forthem! In 2000 I published an article in the magazine “Earth and Universe”, where I presented the evidence of the connection between the volcanism of mantle plumes and mass extinctions withinthelast540Mar: thosecouldnotbeexplainedeverytimebythefallofasteroids. 3 4 Thedesiretofindbymyselfthesolutiontothisproblemledtothedecisiontostudyacross- section with a clearly expressed iridium anomaly. Inside Russia, after the collapse of the SovietUnion,itwasimpossibletofindafullcross-sectionattheK/Tboundary,andacross- section which was considered as closest to Moscow was located in Austria. In 2002, after having discussed the problem with O. Korchagin, paleontologist from the Geological Insti- tute of the Russian Academy of Sciences, and was specializing in studying of foraminifera – leading one-cellar organisms, which permit to identify the age of marine sediments, we decidedtocombineoureffortsinstudyingoneofsuchcross-sections. Twoimportantcircumstancescontributedtotherealizationofthisidea. The first one was of family nature. My wife, Vera, was a diplomat and worked at that time in Vienna. She was very helpful in organizing “the base”, as geologists say, and in creating ageneralatmospherefavorableforourwork. The second one was related to the Natural History Museum in Vienna, which provided us with a monolith cut out of a cross-section with an excellent and clearly expressed layer at the K/T boundary of Gams (officially Gams bei Hieflau) in Austria for the research. In the course of all those four years we have been enjoying the support and attention of our Austrian colleagues – Dr. Herbert Summesberger, Dr. Mathias Harzhauser, and Dr. Heinz Kollmann. Having the monolith we could study the transitional layer like the surgeon in operating theatre, that it was impossible to do at the outcrop. The first results presented to the wide audienceattheMuseumofNaturalhistoryinViennaon6February2006,wereunexpected: wefoundthatextinctionwasinducedbyvolcanismbeforeanimpactevent. In following years we studied another two outcrops in Gams to be sure that our results are correct. Allthesedataarepresentedinthisbook. We have to mention that we enjoyed constant attention to our research paid by the lead- erships of the National Park and European Geopark Eisenwurzen in St. Gallen: Reinhard Mitterbaeck and Katharina Weiskopf and the Mayors of Gams: Hermann Lußmann and ErichReiter. We are grateful to S. Lyapunov, I. Kamensky, A. Kouchinsky, B. Krupskaya, N. Gorkova, I. Ipat’eva, A. Savichev, V. Zlobin, N. Scherbatcheva, A. Nekrasov, A. Gorbunov from Geo- logicalInstitute,RussianAcademyofSciences,fortheirhelpinthepreparationsofsamples andthechemicalandisotopicalstudyoftheGamssectionsamples. The electroinc version of this book was prepared at the Geophysical Center RAS by V. Ne- chitailenko (developing of template and associated software and designing CD and online versions) and T. Prisvetlaya (initial typesetting and technical proofreading). I greatly ap- preciate to Vitaly Nechitailenko for his comments and advices related to publishing of this book. This study was financially supported by Program 5 “Interaction of a Mantle Plume with the Lithosphere” of the Division of Earth Sciences, Russian Academy of Sciences, and GrantRSH-1901.2003.5fromthePresidentoftheRussianFederationforsupportofresearch schoolsandGrant030564303oftheRussianBasicResearchFoundation. AndreiF.Grachev,Editor February2009,Moscow–Vienna Contents TheK/TBoundaryofGams(EasternAlps,Austria)andtheNatureofTerminalCretaceousMassExtinc- tion 1 Preface 3 Introduction byA.F.Grachev 7 Chapter 1. A Review of the Geology of the Late Cretaceous-Paleogene Basin of Gams (Eastern Alps, Austria) byH.A.Kollmann 9 1.1 Introduction . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 9 1.2 OutlineoftheTectonicHistory . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 9 1.3 TheCretaceous-PaleogeneBoundaryinAlpineDeposits . . . . . . . . . . . . . . . . . . . . . . . . 10 1.4 TheGosauGroupofGams . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 10 1.5 TerminationoftheGosauCycle . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 13 1.6 LocationsofSectionsStudiedandSamplesPreparation . . . . . . . . . . . . . . . . . . . . . . . . . 13 Chapter2. Biostratigraphy byO.A.KorchaginandH.A.Kollmann 19 2.1 Introduction . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 19 2.2 ForaminiferalAssemblages . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 19 2.3 PreservationofForaminifera. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 21 2.4 TerminalMaastrichtian . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 21 2.5 LowerPaleogene . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 22 2.6 AssociationofPlanktonicForaminifera . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 23 Chapter3. GeochemistryofRocksintheGamsStratigraphicSequence byA.F.Grachev 39 3.1 Introduction . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 39 3.2 MethodsofMaterialPreparationandStudying . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 39 3.3 WholeRockChemistry . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 41 3.4 TraceandRareEarthElements . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 43 3.5 IsotopicCompositionofHelium,Carbon,andOxygen . . . . . . . . . . . . . . . . . . . . . . . . . 54 Chapter4. MineralsoftheTransitionalLayerinGamsSections byA.F.Grachev, S.E.Borisovsky,andV.A.Tsel’movich 59 4.1 Introduction . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 59 4.2 SamplingProcedure,SamplePreparationTechniques,andStudyMethods . . . . . . . . . . . . . . 59 4.3 MineralParagenesisintheGamsTransitionalLayer . . . . . . . . . . . . . . . . . . . . . . . . . . . 61 4.3.1 Nativeelementsandmetallicalloys . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 61 4.3.2 Sulfides . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 69 4.3.3 Oxides . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 71 4.3.4 Carbonates . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 81 4.3.5 Sulphates . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 81 4.3.6 Phosphates . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 81 4.3.7 Silicates . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 82 4.3.8 Vertical mineralogical zonation as an indicator of environments of the transitional layer formation . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 87 4.4 Conclusion . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 88 5 Chapter5. MagneticPropertiesofRocksoftheGamsSection byD.M.Pechersky, D.K.Nourgaliev,andZ.V.Sharonova 89 5.1 Introduction . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 89 5.2 MethodsofPetromagneticStudies . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 90 5.3 ResultsofPetromagneticStudiesoftheRocksFromGams-1Section . . . . . . . . . . . . . . . . . . 95 5.3.1 Paramagneticmagnetization . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 111 5.3.2 Discussionofpetromagneticresults . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 111 5.4 CharacterizationoftheBoundaryLayerintheGamsSections . . . . . . . . . . . . . . . . . . . . . 113 5.5 ComparativeCharacterizationofSectionsIncludingtheK/TBoundary. . . . . . . . . . . . . . . . 123 5.6 Conclusion . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 133 Chapter6. CosmicDustandMicrometeorites: MorphologyandChemicalComposition byA.F.Grachev,O.A.Korchagin,andV.A.Tsel’movich 135 6.1 Introduction . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 135 6.2 ResultsofInvestigations . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 136 6.3 Discussion . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 143 6.4 Conclusion . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 143 Chapter7. MantlePlumesandTheirInfluenceontheLithosphere,Sea-levelFluctuations andatmosphere byA.F.Grachev 147 7.1 Introduction . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 147 7.2 MantlePlumesandLithosphere. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 147 7.3 Underplating,TopographyandSea-LevelChanges. . . . . . . . . . . . . . . . . . . . . . . . . . . . 152 7.4 MantlePlumesandAtmosphere . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 157 Chapter8. NatureoftheK/TBoundaryandMassExtinction byA.F.Grachev 165 8.1 Introduction . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 165 8.2 ATwo-StagesEvolutionoftheTransitionalLayer . . . . . . . . . . . . . . . . . . . . . . . . . . . . 166 8.3 MantlePlumesandMassExtinctions . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 167 8.3.1 ArsenicattheCretaceous-Paleogeneboundary. . . . . . . . . . . . . . . . . . . . . . . . . . 169 8.3.2 PoisoningbytoxicelementsattheK/Tboundary: Thekillingmechanismsensustricto. . . 170 Conclusion byA.F.Grachev 173 References 175 ElectronicSupplement 188 AuthorIndex 189 SubjectIndex 195 6 THEK/TBOUNDARYOFGAMS(EASTERNALPS,AUSTRIA)ANDTHE NATUREOFTERMINALCRETACEOUSMASSEXTINCTION Thegreattragedyofscience–theslaying ofabeautifulhypothesisbyanuglyfact. (T.H.Huxley,1870) Introduction ThediscoveryofanomaliesofIrandotherplatinum- an almost unanimous consensus was distorted by group elements in clays at the boundary between the some researchers who doubted the validity of the im- Cretaceous and Paleogene (the so-called Cretaceous- pacthypothesisandputforthargumentsinsupportof Tertiary, or K/T boundary) [Alvarez et al., 1980, 1984; magmatic (related to a mantle plume volcanism) rea- Ganapathyetal.,1981;Preisingeretal.,1986;Smit,Herto- sonsforthedevelopmentofthetransitionallayer[Of- gen, 1980] gave rise to the paradigm that the mass ex- ficer, Drake, 1985; Officer et al., 1987; Zoller et al., 1983]. tinction of the biota had been induced by an impact In particular, several scientists pointed to data on the eventandgaveanimpetusforstudyingthisboundary multiplicity of Ir anomalies and the possibility of ex- throughout the world (see A Rubey Colloquium, 2002). plaining the unusual geochemistry of the transitional Thishypothesiswassupportedbythereasonableidea layerattheK/Tboundarybytheeffectofvolcanicac- that high Ir concentrations, much higher than those tivity[Officeretal.,1987]. know in terrestrial rocks, were related to the fall of a Researchinearly1990sprovidednew,moredetailed meteorite(oranasteroid)[Alvarezetal.,1980]. information on transitional layers at the K/T bound- The establishment of the impact paradigm of the ary. Along with new finds of shocked quartz in the massextinctionwasfacilitatedbythediscoveryofthe transitional layers of different regions of the world, world’s largest Chicxulub crater in Yucatan, Mexico such high-pressure minerals as coesite and stishovite [Hildebrand et al., 1991; Smith et al., 1992]. Moreover, werefound,aswellasspinelwithhigh(>5%)Nicon- some rock units at the K/T boundary were found out centration and diamond [Leroux et al., 1995; Preisinger to bear shocked quartz and coesite [Bohor et al., 1984; et al., 2002; Carlisle, Braman, 1991; Hough et al., 1997]. Koeberl,1997;Preisingeretal.,1986;ARubeyColloquium, Although all of these materials considered together 2002,andseveralothers]. provided irrefutable evidence of an impact event, the Later papers by Alvarez et al. [1980] demonstrated mechanisms relating it to the mass extinction of the thattheIranomalyinthetransitionallayerattheK/T biotaremaineduncertain. boundary was present in virtually all of the inspected Meanwhile newly obtained data indicated that Ir rocksequences,bothincontinentsandindeep-seadri- anomaliescouldoccurbothbelowandabovetheK/T llingholesinoceans[Alvarezetal.,1992;Hsuetal.,1982; boundary[Ellwoodetal.,2003;Graup,Spettel,1989;Tan- Kyte,Bostwick,1995;andseveralothers]. don, 2002; Zhao et al., 2002; and others]. Furthermore, TheproblemofthemassextinctionattheCretaceous- Ir anomalies were found in rocks with no relation at Paleogene boundary seemed to be resolved, although all to the Cretaceous-Paleogene boundary [Dolenec et 7 8 al.,2000;Keller,Stinnesbeck,2000;andothers]. AsKeller than670km,i.e.,fromthelowermantleor,moreproba- hasrecentlyshown[Keller,2008],iridiumanomaliesare bly,fromthecore-mantleboundary(D”layer)[Grachev, not unique and therefore not infallible K/T markers. 2000;andreferencestherein]. Hence,theIranomalyitself,whichwasoriginallycon- In the latter instance, perhaps because no scientifi- sidered one of the milestone of the impact hypothesis cally plausible resolution of the mass extinction could forthemassextinctionoflivingorganismsattheK/T be found, it was proposed to regard mass extinction boundary [Alvarez et al., 1980], could not be anymore in the Phanerozoic as an accidental coincidence with (in light of newly obtained data) regarded as a geo- coeval plume magmatism and impact events [White, chemicalindicatorofsuchphenomena. Itisalsoperti- Saunders,2005]. nenttorecallthatdataonthePermian-Triassicbound- Nevertheless, the problem remains unsettled as of aryalsodidnotconfirmthatthereasonsfortheextinc- yet. How can one explain the fact that the study of tionofthatbiotawereofanimpact[Zhou,Kyte,1988]. the transitional layers at the K/T boundary over the Theideathatthefundamentalchangesinthebiotaat past25years,withtheuseofstate-of-the-artanalytical the K/T boundary were related to volcanic processes equipment and techniques, did not result in the solu- became topical again [Grachev, 2000a, 2000b], particu- tionofthisproblem? larlyafterthedetailedstudyingofanomaliesofIrand In our opinion, the answer to this question stems otherPGEinplume-relatedbasaltsinGreenland,atthe fromthemethodsemployedinthesestudies: thelayer BritishIslands,andDeccan[Phillipetal.,2001;Poweret wasinspectedasauniqueitem,anditscharacteristics al.,2003;Crocket,Poul,2004],whichmadeitpossibleto obtainedwithdifferenttechniqueswereascribedtothe explainthehighIrconcentrationsinsedimentsbythe whole thickness of this rock unit. Given the thickness transportation of this element by aerosols during vol- of the transitional layer at the K/T boundary varying canic eruptions, as was earlier hypothesized in [Zoller from 1 cm [Preisinger et al., 1986] to 20 cm [Luciani, etal.,1983]. 2002], sampling sites were commonly spaced 5–10 cm AllofthesediscrepanciesbecamesoobviousthatW. apart,or1–2cmapartneartheboundary[Gardin,2002; Alvarez,oneofthemainproponentsoftheimpacthy- Keller et al., 2002]. With regard for the known sedi- pothesis,admittedthat“...althoughIhavelongbeena mentation rates of about 2 cm per 1000 years [Stuben proponent of impact at the K/T boundary, I hold no etal.,2002andreferencestherein],thetransitionallay- grief for all extinctions being caused by impact. If the ers should have been produced over time spans from evidence for a flood-extinction link is compelling, we 500to10,000years. shouldacceptthatconclusion”[Alvarez,2002,p. 3]. He also wrote: “It would be useful to the community of The time during which an impact event could af- researchers to have a compilation of evidence for im- fect the character of sedimentation can be estimated pactandforvolcanismatprominentextinctionlevels. from the numerical simulations of the nuclear win- Thisisprobablysomethingthatshouldbepreparedby ter scenario, according to which the duration of this a group of workers experienced in the field” [Alvarez, event at the Earth’s surface should range from 10 to 2002,p. 4]. 30days[Turkoetal.,1984]. Becauseofthis,evenifsuch Itisalsoworthmentioningtwootherapproachesto eventstookplaceinthegeologicpast,andevenifsome the problem of relations between impact events and records of them could be discerned in sediments, evi- plumemagmatism. denceoftheseeventscannotbeidentifiedvisuallybut Inoneofthem,anattemptwasundertakentorelate requireadetailedandscrupulousinvestigation. the onset of plume magmatism to the decompression NearthebeginningofourinvestigationsintheGams andmeltingofdeeplithosphericlayersundertheeffect section (Eastern Alps, Austria) we have provided an- ofthedevelopmentofcratersofabout100kmdiame- other look at the reasons for the mass extinction at 65 ter. Here the impact itself is considered to be a trig- Ma [Grachev et al., 2005]. These first data rejected the gering mechanism for the origin of a plume [Jones et needforopposingvolcanismtoanimpactevent: both al.,2003;andothers]. Asidefromtheimplausibilityof took place, but the changes in the biota were induced thisprocessfromthephysicalstandpoint[Molodenskii, byvolcanismbeforeanimpactevent. Infollowingpa- 2005], there is direct and only one evidence of the im- pers we adduced a new proof suggested the truth of possibilityofthisprocess: theHeisotopicsignatureof suchpointofview[Grachevetal., 2006a, 2007a, 2007b, plume basalts. As is well known, these basalts have 2008a, 2008b, 2008c; Pecherskyetal., 2006a, 2008]. This a 3He/4He ratio more than 20×10−6, which could be monographsumsupallresultsofourinvestigationsof causedbytheupriseofthemeltsfromdepthsofmore theK/TboundaryintheGamsstratigraphicsequence. THEK/TBOUNDARYOFGAMS(EASTERNALPS,AUSTRIA)ANDTHE NATUREOFTERMINALCRETACEOUSMASSEXTINCTION Chapter 1. A Review of the Geology of the Late Cretaceous-Paleogene Basin of Gams (Eastern Alps, Austria) 1.1 Introduction croplate in the northwest of the Tethys Ocean [Mandl, 2000; Wagreich, 1993]. Deformation phases of folding and thrusting have removed the series of its crustal Gams,officiallybearingthesuffix“beiHieflau”(near basement and have created a nappe complex of 20– Hieflau)todistinguishitfromothercommunitieshav- 50 km in width and approximately 500 km in length. ing the same name, is a village of approximately 600 In the north, it rests with overthrust contact on the inhabitants. It is located in the north of the Austrian Rhenodanubian Flysch which had been deposited in provinceofStyriaamidtheNorthernCalcareousAlps the northern segment of the Penninic Ocean trough. which are rising in its surroundings up to 2600 m. To In the south it overlies, mostly with tectonic contact, ensure the protection of the area, Gams and other 5 the Variscan Greywacke Zone. A detailed description communities have merged to the Nature Park Styr- ofthecomplextectonicprocessesisgivenbyWagreich, ian Eisenwurzen. Because of its exceptional geologi- Decker[2002]. cal heritage and its public activities, the Nature Park Late Cretaceous uplift followed by significant sub- hasbeenacceptedasamemberoftheEuropeanGeop- sidencehasledtotheformationoflimitedareasofin- arksNetworkin2002andconsequentlyasamemberof creased subsidence during late Cretaceous-Paleogene the Global Geoparks Network of UNESCO. A perma- times (Figure 1.1). After the community of Gosau in nentexhibitionandtrailsinterpretingthelocalgeology UpperAustriawhichislocatedonthelargestofthese make Gams the centre of geological interpretation of sediment traps they are traditionally called Gosau thePark. Basins. Their sediments are summarized under the Ingeneral,thesignificanceofthegeologicalheritage lithostratigraphic term Gosau Group (Gosau Beds or becomes evident through scientific research. First ge- Gosauschichtenoftheearlierliterature).Dependingon ological explorations of the Park area date back to the thesubsidencehistory, thesedimentcontentofthein- firstquarterofthe19thcentury.Withtheaccumulation dividualbasinsandthetimeslicerepresentedbythem of knowledge, scientific methods and interpretations variesandboundariesbetweenlithostratigraphicunits havechangedalmostconstantly. Mostimpetuscomes arediachronous. from findings which contradict previous theories. We Resting unconformly on sediments which have un- believethattheobservationspresentedinthisvolume dergone earlier tectonic deformations, the Gosau sed- willstimulatethediscussionontheK/Tboundary. imentary cycle began in the Late Turonian and ended intheLowerEocene. TheGosauGroupissubdivided intotheLowerandtheUpperGosausubgroups[Faupl 1.2 OutlineoftheTectonicHistory et al., 1987; Piller et al., 2004]. The Lower Gosau Sub- group comprises a succession of continental to shal- The Northern Calcareous Alps extend from west to lowmarinesediments. Theywere depositedinsmall, eastalmostthroughthewholeofAustriaandadjacent partly fault-bounded extensional and/or pull-apart partsoftheGermanbundeslandBavaria. Theyforma basins [Sanders, 1998; Wagreich, 1993; Wagreich, Faupl, thrust belt which is part of the Austroalpine unit and 1994]. Facies and thickness of units changes horizon- hasoriginallybeendepositedontheAustroalpinemi- tallywithinshortdistances. 9 10 CHAPTER1 Figure 1.1. The distribution of Gosau Basins in the Eastern Alps [after Wagreich, Krenmayer, 1993]. TheUpperGosausubgroup(Santonian/Campanian boundary transition layer has been traced. From the –LowerEocene)ischaracterizedbypelagicsediments name-giving Basin of Gosau, which extends over the which indicate a general deepening [Wagreich, 1993, boundaries of the Austrian provinces Upper Austria 1995]. Thisresultedinanoversteppingoftheformerly and Salzburg, two sections have been described: the isolated basins. Subsidence during the deposition of ElendgrabenclosetothevillageofRußbach[Preisinger the Upper Gosau subgroup is explained with tectonic etal.,1986]andtheRotwandgraben[Perytetal.,1993]. erosion of the Austroalpine units as a consequence of Herm and others, provided a micro- and nannostrati- subduction and/or underthrusting [Wagreich, Decker, graphical frame for the K/T boundary layers of the 2002]. WasserfallgrabenintheLattengebirge(BavarianAlps). A study by Graup, Spettel, [1989], revealed three irid- iumpeaksinthissection,ofwhichoneislocated16cm 1.3 TheCretaceous-PaleogeneBoundary belowtheK/Tboundary. inAlpineDeposits The third Gosau basin is that of Gams which is the subject of this monograph. Lahodynsky [1988a, 1988b], hasprovidedadetailedlithologicalsectionthroughthe First indications on Paleogene in the Gosau Group K/T boundary of the Knappengraben (Gams 1 in this weregivenbyKu¨hn[1930]. HededucedaDanianage monograph)whichhehadexcavatedtogetherwithH. (consideredasterminalCretaceousatthattime)ofthe Stradnerin1986. Stradner, Ro¨gl[1988], reportedabout Zwieselalm Formation which forms the top of the se- themicrofaunaandnannofloraofthissectionandem- quence. Micropalaeontological studies in the Basin of phasizedthecompletenessofthestratigraphicalrecord. Gosau by Ganns, Knipscheer [1954], Ku¨pper [1956], and onGamsbyWicher[1956],gaveamorecomprehensive pictureofPaleogenedeposits. Byapplyingplanktonic 1.4 TheGosauGroupofGams foraminifera in a large scale, this was confirmed later byHerm[1962],andHillebrandt[1962],fortheLattenge- birge (Bavaria), Kollmann [1963, 1964], for the Gams Becauseofitsgenerallysoftclasticrocks,theGosau areaandbyWille-Janoschek[1996],forthewesternpart BasinofGams(forthelocationseeFigure1.1)formsa oftheGosauarea. morphologicaldepressionwithincarbonatesofearlier Stimulated by the world-wide discussion initiated Mesozoic age (Figure 1.2). The basin consists actually by Alvarez et al. [1980], the nature of the K/T bound- of two sedimentary areas of different subsidence his- ary was investigated in the Gosau Group in greater tory [Kollmann, 1963; Kollmann, Summesberger, 1982]. detail. There are three Gosau Basins where the K/T They are arranged in E-W direction and are sepa-