V O L U M E T E N H E ANDBOOK OF XPLORATION AND E G NVIRONMENTAL EOCHEMISTRY The Indian Ocean Nodule Field: Geology and Resource Potential HANDBOOK OF EXPLORATION AND ENVIRONMENTAL GEOCHEMISTRY Series Editor MARTIN HALE 1. Analytical methods in geochemicalprospecting 2. Stastistics and data analysis in geochemicalprospecting 3. Rock geochemistry in mineral exploration 4. Regolithexplorationgeochemistryintropicalandsub-tropicalterrains 5. Regolith exploration geochemistry in arctic and temperate terrains 6. Drainage geochemistry 7. Geochemical remote sensing of the sub-surface 8. Life cycle of the phosphoria formation: From deposition to the post-mining environment 9. Biogeochemistry in mineral exploration 10. The Indian Ocean nodule field: Geology and resource potential V O L U M E T E N H E ANDBOOK OF XPLORATION AND E G NVIRONMENTAL EOCHEMISTRY The Indian Ocean Nodule Field: Geology and Resource Potential RANADHIR MUKHOPADHYAY National Institute of Oceanography, Goa, India ANIL K. GHOSH University of Calcutta, Kolkata, India SRIDHAR D. IYER National Institute of Oceanography, Goa, India AMSTERDAM • BOSTON (cid:129) HEIDELBERG (cid:129) LONDON NEW YORK (cid:129) OXFORD (cid:129) PARIS (cid:129) SAN DIEGO SAN FRANCISCO (cid:129) SINGAPORE (cid:129) SYDNEY (cid:129) TOKYO Elsevier Radarweg29,POBox211,1000AEAmsterdam,TheNetherlands LinacreHouse,JordanHill,OxfordOX28DP,UK Firstedition2008 Copyright#2008Elsevier B.V. Allrightsreserved. Nopartofthispublicationmaybereproduced,storedinaretrievalsystemortransmittedinanyform orbyanymeanselectronic,mechanical,photocopying,recordingorotherwisewithouttheprior writtenpermissionofthePublisher. PermissionsmaybesoughtdirectlyfromElsevier’sScience&TechnologyRightsDepartmentin Oxford,UK:phone:(þ44)1865843830,fax:(þ44)1865853333,E-mail:permissions@elsevier. com.AlternativelyyoucansubmityourrequestonlinebyvisitingtheElsevierwebsiteathttp:// elsevier.com/locate/permissions,andselectingObtainingpermissiontouseElseviermaterial. Notice: Noresponsibilityisassumedbythepublisherforanyinjuryand/ordamagetopersonsorpropertyasa matterofproductsliability,negligenceorotherwise,orfromanyuseoroperationofanymethods, products, instructions or ideas contained in the material herein. Because of rapid advances in themedicalsciences,inparticular,independentverificationofdiagnosesanddrugdosagesshould bemade. LibraryofCongressCataloging-in-PublicationData AcatalogrecordforthisbookisavailablefromtheLibraryofCongress BritishLibraryCataloguinginPublicationData AcataloguerecordforthisbookisavailablefromtheBritishLibrary ISBN978-0-444-52959-6 ISSN1874-2734 ForinformationonallElsevierpublications visitourwebsiteatbooks.elsevier.com PRINTEDANDBOUNDINTHENETHERLANDS 08 09 10 11 12 10 9 8 7 6 5 4 3 2 1 C ONTENTS Preface vii SeriesEditor’sForeword xi AbouttheAuthors xiii 1. TheIndianOceanNoduleField 1 1. PhysiographyandGeology 5 2. Physics,ChemistryandBiology 25 3. EvolutionoftheIndianOceanNoduleField 31 2. TectonicsandGeomorphology 37 1. Ridge-NormalLineaments 40 2. RidgeParallelLineationsandAnomalies 45 3. Seamounts 54 3. Volcanics 67 1. MajorVolcanics 69 2. MinorVolcanics 86 3. AlterationofVolcanics 103 4. TectonicsandVolcanics:Interrelations 112 4. Sediments 115 1. DistributionandSource 117 2. SedimentaryProcesses 135 5. FerromanganeseDeposits 155 1. NoduleCharacteristics 157 2. FactorsInfluencingNoduleFormation 184 3. DynamicsofNoduleFormation 194 4. FerromanganeseEncrustation 205 5. TheWorldOceansScenario 211 v vi Contents 6. ResourceManagement 225 1. ResourceIdentification 225 2. MiningTechnology 231 3. EnvironmentalImpactAssessment 233 4. MetalExtractionandProcessing 249 5. LawoftheSea 254 6. GlobalPerspectives 255 References 261 AuthorIndex 283 SubjectIndex 289 ColourInsertbetweenpages18and19 P REFACE Oceans,withtheirenormityandmysterycovering259millionkm2andsome 72% of the earth’s surface, have always been a part of human consciousness. Climateandweather,andeventhequalityoftheairpeoplebreathe,dependin greatmeasureontheinterplaybetweentheoceanandtheatmosphereinways stillnotfullyunderstood.Besidesbeingaprimesourceofnourishmentforlifeit helpedtogenerate,theoceanisconsideredasastorehouseforseverallivingand non-livingresources.Makinguseofsuchresources,ingeneral,andminerals, inparticular,essentiallyneedsintelligentandsustainabletreatment.The1982 UnitedNationsConventionontheLawoftheSea,sinceitsentryintoforceon 16November1994,providedforthefirsttimeauniversallegalframeworkfor therationalmanagementofmarineresourcesandtheirconservation. TheCentralIndianOceanBasin(CIOB),borderedbytheIndianSubcon- tinent,theNinetyeastRidgeandtheIndianOceanRidgesystem,isthelargest andmostuniqueofallthebasinsintheIndianOcean.Becauseofitscomplex tectonic fabric, vastness and ferromanganese deposits, this basin has attracted the attention of oceanographers since long. However, in comparison to the quantumofinvestigationscarriedoutinthePacificandtheAtlanticoceans,the studyintheCIOBhasleftmuchtobedesired.Eventheinternationaldrilling programmes(DeepSeaDrillingProject,OceanDrillingProgramme)havenot extensivelycoveredthisbasin.Asaresult,apaucityofdatahaslimitedaproper understandingofthebasinandtheevaluationofitsresources. Duringthelasttwodecades,theCIOBwasexploredinsomedetailforits mineral resource potential, with India taking the lead. The broad objectives were to explore and delineate economically feasible manganese nodule- bearing areas, and ultimately concentrate on resource exploration from the Self-allocated area. Extensive exploration for the resources saw more than 50 oceanographic voyages to this basin. The amount and type of underway datacollectedareimmense,rangingfromsingle-beamtomulti-beambathym- etry, to seafloor magnetism and gravity and to underwater photography. A large number of manganese nodules, rocks, sediments and water column samples were recovered from an area more than 700,000km2, bordered (cid:1) (cid:1) 0 (cid:1) (cid:1) between 9 S and 16 30S and 72 E and 80 E. This helped delineate a nodule-richareatobelaterknownastheIndianOceanNoduleField(IONF). Subsequently, close-grid exploration, followed by the critical resource assessmentoftheIONF,identifiedthe‘firstgenerationminesite’.Globally, theIONFrepresentsthesecondlargestandsecondrichestdeep-seamanga- nese nodule resources after those of the Equatorial North Pacific. vii viii Preface A conservative estimate places the total manganese nodules availability in the IONF as more than 1400 million tons, with an average abundance of little more than 4.5kg of nodules per square metre. Considering the recovery capacity of available mining technology and metal extraction processes, the nodule resources are expected to last for many hundreds of years, and resource mining would be economically viable too. Thepublicationsresultingfromthefieldandlaboratorystudies,andcover- ing diverse aspects (such as evolution of the CIOB, structure and tectonics, volcanism, sedimentation, and resource characterisation and potential), are indeed numerous. Several workers from different institutions in various countries have published their important findings, but these are scattered in differentjournals,allofwhicharenoteasilyaccessibletoresearchersinterested inthenoduleresourcesoftheIndianOcean.Inthisscenario,thebasicpurpose of the present book is to collate the available information in a concise and systematicmanner,andcarryoutacriticalevaluationofsuchinformation.The necessityofthisbookisallthemorerelevantbecausethe currently available books on manganese nodules largely pertain to the Pacific and the Atlantic oceans,makinginadequatecoverageoftheIndianOcean,ingeneral,andthe IONF,inparticular.Hence,thisbookistargetedatstudentsandresearchersat the master’s and doctoral levels, and for all those interested in the marine geology and resource potentiality of the IONF. We hope that this book will serve as a ready reference to those involved in the development and managementofgeo-resources,andtoeconomistsandpolicyplanners. After introducing the IONF in the firstchapter, we discuss the geomor- phology and tectonics of this field in the second and volcanics in the third chapter.Thebottomsedimentaryregimes—sedimentsourceanditscharacter- istics,dynamics ofsedimentation—arediscussedin Chapter4. The distribu- tion, grade and processes of formation of ferromanganese deposits (both nodules and crusts) during the last 5–10 million years are discussed in Chapter 5. And finally in Chapter 6, we describe the equipment used for exploration,sketchonprobableminingmethods,assessenvironmentalimpli- cationsconcerningmining,discussmetallurgicaltechniquesandconverseon internationallegalconstraintsonexplorationandexploitationofthenodules. While writing this book, we received help from many quarters. The Council of Scientific & Industrial Research (CSIR) and the Ministry of EarthSciences,bothinNewDelhi,India,arethankedforallthelogisticand financial support—in the laboratory andat sea—during the last two decades through grants to the National Institute ofOceanography (NIO), Goa. The director, National Institute of Oceanography, and the vice-chancellor, University of Calcutta, are specially thanked for their support and encouragement.Weplaceonrecordwiththanksthegeneroussupportofall themembersoftheproject‘SurveysforPolymetallicNodules’inhelpingone wayortheotherduringcollectionandanalysisofsamples,anddatainterpre- tation. Many of them readily provided their reprints, preprints and other Preface ix unpublished material. The cooperation of the crew of the various ships, sometimesunderexcruciatingconditions,isacknowledged. India’s deep-sea mineral campaign owes a great deal to the vision and untiringeffortsofthelateDrHassanNasiemSiddiquie,theformerdirectorof theNationalInstituteofOceanography.Werespectfullyrememberhisinitia- tionofthemanganesenoduleprogrammeforIndia.Dr.S.Z.Qasim,asformer Secretary of the then Department of Ocean Development and ex- member, Planning Commission, Government of India, has always been a source of inspiration to the project. The earlier versions of the chapters received critical reviews and comments from A. L. Paropkari, G. V. Rajamanickam, J.N.Pattan,K.S.Krishna,M.ShyamPrasad,M.V.Ramana,N.H.Khadge, R.K.Drolia,R.P.Das,R.V.Karanth,andV.Ramaswamy.Wethankthem all. Besides, we had rewarding discussions with many of our colleagues at NIO and at the University of Calcutta. Technical help from A. K. Saran, A.Y.Mahale,R.Uchiland S.Akerkarisacknowledged. WethankElsevierforpublishingthisbookandalsoMartinHale,Series Editor, for patiently going through the manuscript and for writing the Foreword. We acknowledge the support (and patience) of Particia Massar, Pauline Riebeek and Tirza Van Daalen during preproduction stage, to Conny Krainz for supervising the production of the Title and Prasenjit Bakshi and his dedicated team for printing the book. Mostofthematerialspresentedhereareinpublicdomain.Manyofthe figureswerereprintedfromvariousbooksandjournals.Wethanktheauthors and publishers for kindly permitting us to reproducethese figures. Last but nottheleast,weexpressadeepsenseofappreciationtothesacrificeofour wivesSumita,JayantiandKamakshi,respectively,andtoourchildren. It is a pleasure to place on record our gratitude to our colleagues both from within and outside India who helped with literature support and liberalcommentstohelpcharacterisetheresourcesandtobetterunderstand theformationalregimesofferromanganesedepositintheIONF.However, any discrepancyregarding theviewsand opinions expressedinthis bookis solely the responsibility of the authors. 31 January 2007 Ranadhir Mukhopadhyay National Institute of Oceanography, Goa [email protected] Anil K. Ghosh University of Calcutta, Kolkata [email protected] Sridhar D. Iyer National Institute of Oceanography, Goa [email protected]
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