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The Hatfield Memorial Lectures PDF

244 Pages·2005·25.811 MB·English
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SEQ 0001 JOB IOM8627-000-013 PAGE-0001 PRELIMS REVISED 31JUL05 AT 22:03 BY TF DEPTH: 62.04 PICAS WIDTH 45.03 PICAS The Hatfield Memorial Lectures Volume III SEQ 0002 JOB IOM8627-000-013 PAGE-0002 PRELIMS REVISED 31JUL05 AT 22:03 BY TF DEPTH: 62.04 PICAS WIDTH 45.03 PICAS Dr William Herbert Hatfield FRS, 1882–1943. Courtesy of Sheffield Industrial Museums Trust SEQ 0013 JOB IOM8627-000-016 PAGE-0003 PRELIMS REVISED 04AUG05 AT 00:07 BY TF DEPTH: 62.04 PICAS WIDTH 45.03 PICAS The Hatfield Memorial Lectures Volume III Edited and Foreword by Peter Beeley Woodhead Publishing and Maney Publishing on behalf of The Institute of Materials, Minerals & Mining CRC Press Boca Raton Boston New York Washington, DC SEQ 0004 JOB IOM8627-000-013 PAGE-0004 PRELIMS REVISED 31JUL05 AT 22:03 BY TF DEPTH: 62.04 PICAS WIDTH 45.03 PICAS Woodhead Publishing Limited and Maney Publishing Limited on behalf of The Institute of Materials, Minerals & Mining Published by Woodhead Publishing Limited, Abington Hall, Abington, Cambridge CB1 6AH, England www.woodheadpublishing.com Published in North America by CRC Press LLC, 6000 Broken Sound Parkway, NW, Suite 300, Boca Raton, FL 33487, USA First published 2005, Woodhead Publishing Limited  IoM Communications Ltd, 2005 The authors have asserted their moral rights. This book contains information obtained from authentic and highly regarded sources. Reprinted material is quoted with permission, and sources are indicated. Reasonable efforts have been made to publish reliable data and information, but the author and the publishers cannot assume responsibility for the validity of all materials. Neither the author nor the publishers, nor anyone else associated with this publication, shall be liable for any loss, damage or liability directly or indirectly caused or alleged to be caused by this book. Neither this book nor any part may be reproduced or transmitted in any form or by any means, electronic or mechanical, including photocopying, microfilming and recording, or by any information storage or retrieval system, without permission in writing from Woodhead Publishing Limited. The consent of Woodhead Publishing Limited does not extend to copying for general distribution, for promotion, for creating new works, or for resale. Specific permission must be obtained in writing from Woodhead Publishing Limited for such copying. Trademark notice: Product or corporate names may be trademarks or registered trademarks, and are used only for identification and explanation, without intent to infringe. British Library Cataloguing in Publication Data A catalogue record for this book is available from the British Library. Woodhead Publishing ISBN-13: 978-1-84569-101-1 (book) Woodhead Publishing ISBN-10: 1-84569-101-6 (book) Woodhead Publishing ISBN-13: 978-1-84569-114-1 (e-book) Woodhead Publishing ISBN-10: 1-84569-114-8 (eook) CRC Press ISBN-10: 0-8493-9242-X CRC Press order number: WP9242 The publishers’ policy is to use permanent paper from mills that operate a sustainable forestry policy, and which has been manufactured from pulp which is processed using acid-free and elementary chlorine-free practices. Furthermore, the publishers ensure that the text paper and cover board used have met acceptable environmental accreditation standards. Typeset in the UK by Dorwyn Ltd, Wells, Somerset Printed by TJ International Ltd, Padstow, Cornwall, England SEQ 0007 JOB IOM8627-000-013 PAGE-0007 PRELIMS REVISED 31JUL05 AT 22:03 BY TF DEPTH: 62.04 PICAS WIDTH 45.03 PICAS Foreword This third volume of Hatfield Memorial Lectures comprises two groups. In the first of these the central theme is process metallurgy, the lectures encompassing technical aspects of plant design and operation, including associated research and development. Lectures in the second group address the organization of the iron and steel industry, including its general structure and economic circumstances. Although there is occasional overlap, these two broad themes complement the three contained in the two earlier volumes, to cover five fields as contemplated at the outset: Volume I is devoted to Properties and Behaviour of Materials and to Applications, and Volume II to the single theme of Metallography and the Structure of Iron and Steel. A similar system to that used in the earlier volumes has been adopted in the present case: the lectures are arranged in date sequence within each group, providing pictures of the respective subject areas over the whole period since the outset in 1946, when the first lecture was delivered by Dr Hatfield’s contemporary Dr George B. Waterhouse. This dealt with Hatfield’s own work and formed the introduction to the first volume, which also contained biographical notes on Hatfield himself; further aspects of his life and character were portrayed in Professor A. G. Quarrell’s personal recollections, which provided the introduction to Volume II. William Herbert Hatfield had been born in 1883 and had died in 1943. The Memorial Lecture series had been instituted by the University of Sheffield in 1944 as a joint project with the Royal Society and the Iron and Steel Institute. The fiftieth lecture, the most recent and last to be included in the present series of volumes, was delivered by Professor C. M. Sellars of the same University in December 2002. The annual Hatfield Lecture continues to draw large audiences from far afield and reflects the ongoing interest in the major metallurgical advances of our time. Many of the chosen topics have significance over the wider field of materials and across diverse branches of engineering. It is hoped that supplementary volumes will add to the record of these occasions at suitable intervals in future years, and will be arranged on a similar thematic basis. Peter Beeley P. R. Beeley DMet is a Life Fellow and former Senior Lecturer in metallurgy in the University of Leeds vii RS EE VQ IS 0 E0 D0 31JU8 JOB L05 IO AM T 2862 27 :0-0 30 BY0-01 TF3 P DAG EE PT-00 H0 : 628 PR .04EL PIM ICS AS W ID T H 4 5 .0 3 P IC A S A shot at leisure.A picture of W. H.Hatfield from the Firth Brown Photographic Collection.Courtesy of Sheffield Industrial Museums Trust (copyright) SEQ 0009 JOB IOM8627-000-013 PAGE-0009 PRELIMS REVISED 31JUL05 AT 22:03 BY TF DEPTH: 62.04 PICAS WIDTH 45.03 PICAS Printed Sources Listed below are the lecture numbers, titles and authors of each of the papers appearing in this volume. The original place and date of publication are also given. Seventh Lecture: Development in the Iron and Steel Industry in Great Britain during the last Twenty-Five years, by T. P. Colclough J. Iron Steel Inst., July 1954, 297 Sixteenth Lecture: Basic Knowledge, Discovery, and Invention in the Birth of New metallurgical Processes, by F. D. Richardson J. Iron Steel Inst., March 1965, 217 Nineteenth Lecture: Twenty-Five Years On, by H. M. Finniston J. Iron Steel Inst., February 1969, 145 Twenty-second Lecture: The Place of Mini-Steelworks in the World, by W. F. Cartwright J. Iron Steel Inst., April 1972, 221 Twenty-third lecture: Electroslag Remelting a Modern Tool in Metallurgy, by E. Plo¨ckinger J. Iron Steel Inst., August 1973, 533 Twenty-fourth Lecture: Eurosteelresearch, by R. S. Barnes Ironmaking Steelmaking, 1974, 1 (2), 61 Twenty-fifth Lecture: Materials and Malthus, by Sir Alan Cottrell Met. Mater., March 1975, 32 Twenty-eighth Lecture: From Invention to Industrial Development, by L. Coche Met. Mater., February 1979, 25 Thirty-fifth Lecture: European steel: what future? By Sir Robert Scholey Ironmaking Steelmaking 1987, 14, 267 Thirty-seventh Lecture: Net Shape Solidification Processing of Steel, 1945–1995, by M. C. Flemings Report from Cast Metals, 1990, 2 (4), 231 Forty-third Lecture: The New World of Steel, by J. Edington Ironmaking Steelmaking, 1997, 24 (1), 19 Forty-seventh Lecture: Iron, the hidden element: the role of iron and steel in the twentieth century, by R. Boom Steel World, 2000, 5, 1, 88 Forty-ninth Lecture: Technology: driving steel forward, by M. J. Pettifor Steel World, 2002, 7, 11 Fiftieth Lecture: Metallurgical Modelling of Thermomechanical Processing, by C. M. Sellars Previously unpublished ix SEQ 0003 JOB IOM8627-001-009 PAGE-0003 16TH LECTURE REVISED 19DEC04 AT 20:11 BY TF DEPTH: 62.04 PICAS WIDTH 45.03 PICAS THE SIXTEENTH HATFIELD MEMORIAL LECTURE Basic Knowledge, Discovery, and Invention in the Birth of New Metallurgical Processes F. D. Richardson At the time the lecture was given, Professor Richardson was Professor of Extraction Metallurgy at the Imperial College of Science and Technology. The lecture was presented at Church House, Great Smith Street, London, in the evening of Wednesday 25 November 1964. I am greatly honoured that you should have invited me to give this 16th Hatfield Memorial Lecture. Honoured because of the importance and standing throughout the metallurgical world of our Iron and Steel Institute, and honoured because of the distinction of the man to whom these lectures are a memorial. I was not privileged to know Dr Hatfield, but from all I have read and heard of his life, I realise that I missed knowing a truly remarkable man. Many remember him for his obvious achievements – his work on stainless and heat resisting steels, his post as Director of Firth Brown, his Chairmanship of three very important ISI Committees, his Fellowship of the Royal Society and his Bessemer Medal. But to those who worked personally with him there remains a lasting impression of enterprise, energy and openmindedness: an awareness of scientific ability in others, great intuition, and style in all things. When I came to consider a subject for this lecture I looked at Dr Hatfield’s Campbell Memorial Lecture1 given in the USA in 1928, and I was struck by his sharp interest in new ideas and new developments: by his recognition of the importance in this connexion of the growth of purely scientific knowledge and of the need for industrial enterprise and the state to ‘cast its bread upon the waters’ and help those who work, particularly in the universities, to develop the fundamental aspects of their subjects. I therefore came to thinking of the way new processes come about. I suppose that today people are searching as never before for new ideas which show promise of becoming new processes. At the same time most of us are unaware of how the new processes which surround us came to be developed. Although full details of existing processes are often available, the exact ways in which they have come about are rarely disclosed. I have always found the histories of new developments extraor- dinarily interesting and I think we can learn from them. I know that Halevy wrote ‘We learn from history that we do not learn from history’, and this pessimistic view may be true as regards politics and international affairs. But 3 SEQ 0004 JOB IOM8627-001-009 PAGE-0004 16TH LECTURE REVISED 19DEC04 AT 20:11 BY TF DEPTH: 62.04 PICAS WIDTH 45.03 PICAS 4 Hatfield Memorial Lectures Vol. III when it comes to scientific development I believe some greater optimism is justified. I have therefore decided to look at a number of new processes and to examine how they came about, and at what points basic knowledge, discovery, and invention had their own particular impacts. I have chosen extractive processes because they are my special interest. I shall include both ferrous and non-ferrous topics, because much of interest has been happening in the non-ferrous world, and because I consider we lose a great deal if we restrict our thoughts, or our reading, to one field or the other. It is difficult to acquire the detailed historic knowledge with which I am here con- cerned for it is not to be found in books. I am therefore personally indebted to those who have so kindly given me the information I have sought. But before I come to discuss those modern processes I wish to dwell shortly on the character of the men who bring about new processes – or what may be called the ‘flesh and blood’ aspect of development. THE INVENTIVE SPIRIT For a few minutes therefore let us go back to 1870 and to a young man of twenty, who was the first to look seriously at the chemistry of slags, and what more entrancing subject could you have than that! I refer to Sidney Gilchrist Thomas who in 1878 brought forth the basic steelmaking process. A lively, unfinished sketch of him is shown in Fig. 1. despite his frail physique, Thomas possessed exceptional enterprise, energy and intuition, and he coupled these with that singleness of purpose, which is usually needed for a great invention. At the age of twenty he had a mind uncluttered with irrelevant experience and he was able to think along lines which were closed to experienced metallurgists such as Percy and Lothian Bell. Thomas epitomises the human aspect of creating a new process. He had the character of an inventor; and was always looking for unsolved problems. We see him for example insisting, thirty five years before Haber’s synthesis, that ammonia should be produced from air and water because the elements hydrogen, nitrogen and oxygen were to be had for nothing from these sources. In 1870 Thomas was the clerk in the Thames police court, working to support his widowed mother and family. Chemistry was his hobby and he attended a course of lectures at the Birkbeck Institution, delivered by George Challenor. At this juncture Challenor justified all the lectures he ever gave, for, with Thomas in his class, he had occasion to say that the man who eliminated phosphorus from iron by means of the Bessemer converter would make his fortune. This challenge sank deeply into Thomas’s mind and inspired him to wrestle with the idea for eight years, excited as much by the commercial prospect as by the scientific challenge. One cannot but be reminded of the young Hall who was similarly inspired by Pro- fessor Jewetts when studying chemistry at Oberlin, Michigan. From then on Hall’s ambition was to find a way of producing aluminium cheaply and he invented the electrolytic process in 1886, simultaneously with He´roult in France but quite indepen- dently. I hope we university professors are as inspiring today as we were at the end of the SEQ 0731 JOB IOM8627-001-013 PAGE-0005 16TH LECTURE REVISED 06FEB05 AT 19:27 BY TF DEPTH: 62.04 PICAS WIDTH 45.03 PICAS Basic Knowledge, Discovery, and Invention 5 Fig. 1 Portrait of Sydney Gilchrist Thomas. last century! Sometimes I think that in teaching our students we lay too much stress on the unsolved theoretical problems and too little on the unsolved practical ones. We have a great opportunity to invent by proxy and we ought not to miss it! The problem of phosphorus elimination existed because there were great quantities of phosphoric ores; the orebody was providing the impulse for development as is so often the case in extractive metallurgy. The problem was solved in principle in the space of five years; during this time Thomas pieced together in an original way the available chemistry of phosphoric acid and silica, and of the slag–metal reactions which occur in the acid Bessemer and the old puddling processes. The problem was solved in practice after a further two or three years of dedicated work, during which Thomas obtained the help of his cousin Percy Gilchrist at Blaenavon steelworks in Wales. In this period Thomas ran, at first secretly, his tests with hot metal and developed the basic linings and the method of making lime additions. Most of the work was done at weekends, which started with a night’s journey from London to Blaenavon, and finished with a dash from the train home so Thomas could be in court on Monday morning. As Thomas wrote laconically in a letter to his cousin2 ‘I have not time enough to do. I only go home to sleep and eat. Most unsatisfactory’.

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