The Chemistry of Nonaqueous Solvents. Volume VA: Principles and Basic Solvents PDF
Preview The Chemistry of Nonaqueous Solvents. Volume VA: Principles and Basic Solvents
Contributors STEN AHRLAND DENISE BAUER ROBERT L. BENOIT PHILIPPE GAILLOCHET MARCEL JOZEFOWICZ CHRISTIAN LOUIS JEAN-MAXIME NIGRETTO E. PUNGOR K. TÓTH STANLEY WAWZONEK PETR ZUMAN THE CHEMISTRY OF NONAQIEOUS SOLVENTS Edited by J. J. LAGOWSKI DEPARTMENT OF CHEMISTRY THE UNIVERSITY OF TEXAS AT AUSTIN AUSTIN, TEXAS Volume VA PRINCIPLES AND BASIC SOLVENTS 1978 ACADEMIC PRESS New York San Francisco London A Subsidiary of Harcourt Brace Jovanovich, Publishers COPYRIGHT © 1978, BY ACADEMIC PRESS, INC. ALL RIGHTS RESERVED. NO PART OF THIS PUBLICATION MAY BE REPRODUCED OR TRANSMITTED IN ANY FORM OR BY ANY MEANS, ELECTRONIC OR MECHANICAL, INCLUDING PHOTOCOPY, RECORDING, OR ANY INFORMATION STORAGE AND RETRIEVAL SYSTEM, WITHOUT PERMISSION IN WRITING FROM THE PUBLISHER. ACADEMIC PRESS, INC. Ill Fifth Avenue, New York, New York 10003 United Kingdom Edition published by ACADEMIC PRESS, INC. (LONDON) LTD. 24/28 Oval Road, London NW1 7DX Library of Congress Cataloging in Publication Data Lagowski, J J ed. The chemistry of nonaqueous solvents. Includes bibliographies. CONTENTS: v. 1. Principles and techniques. - v. 2. Acidic and basic solvents.-v. 3. Inert, aprotic, and acidic solvents. [ etc. ] 1. Solvents. I. Title. TP247.5.L3 660.2'2'482 66-16441 ISBN 0-12-433805-4 (v. 5A) PRINTED IN THE UNITED STATES OF AMERICA List of Contributors Numbers in parentheses indicate the pages on which the authors' contributions begin. STEN AHRLAND, Inorganic Chemistry 1, Chemical Center, University of Lund, Lund, Sweden (1) DENISE BAUER, Laboratoire de Chimie Analytique, École Supérieure de Physique et de Chimie de Paris, Paris, France (251) ROBERT L. BENOIT, Département de Chimie, Université de Montréal, Montréal, Quebec, Canada (63) PHILIPPE GAILLOCHET, Laboratoire de Chimie Analytique, École Supérieure de Physique et de Chimie de Paris, Paris, France (251) MARCEL JOZEFOWICZ, Department of Chemistry, University of Paris, Ville- taneuse, France (179) CHRISTIAN LOUIS, Département de Chimie, Université de Montréal, Montréal, Quebec, Canada (63) JEAN-MAXIME NIGRETTO, Department of Chemistry, University of Paris, Villetaneuse, France (179) E. PUNGOR, Institute for General and Analytical Chemistry, Technical University, Budapest, Hungary (145) K. TÓTH, Institute for General and Analytical Chemistry, Technical Uni- versity, Budapest, Hungary (145) STANLEY WAWZONEK, Department of Chemistry, University of Iowa, Iowa City, Iowa (121) PETR ZUMAN, Department of Chemistry, Clarkson College of Technology, Potsdam, New York (121) Preface Volume V of this treatise completes the original plan established in 1965 to attempt a critical analysis of the subject from two points of view, viz., (1) a discussion of the theoretical aspects of nonaqueous solution chemistry independent of solvent and (2) a consideration of individual solvents or solvent types for which reasonably comprehensive information has been gathered to this point in time. Chapters 1-4 in this volume contribute to the first point of view whereas the remaining chapters, for the most part, contain information on individual solvent systems; there is, of course, some discussion of special aspects of theory in the latter class of chapters. Taken as a whole, the 38 chapters in the 5 volumes of this treatise would have been organized according to the following outline, if the Editor had been able to overcome the logistic problems associated with the personal work schedules of the contributors. The Chemistry of Nonaqueous Solvents Part I. Practical Aspects 1. Experimental Techniques for Low-Boiling Solvents, Jindfich Nassler, Ch. 6, Vol. I 2. Experimental Techniques in the Study of Fused Salts, R. A. Bailey and G. J. Jany, Ch. 7, Vol. I 3. Ion-Selective Electrodes in Nonaqueous Solvents, E. Pungor and K. Tóth, Ch. 4, Vol. VA 4. Electrochemical Methods, P. Zuman and W. Wawzonek, Ch. 3, Vol. VA 5. Conductivity in Nonaqueous Solvents, John H. Roberts, Ch. 1, Vol. IV 6. Solvent Extraction of Inorganic Species, Leonard T. Katzen, Ch. 5, Vol. I Part II. Theoretical Aspects 7. Lewis Acid-Base Interactions in Polar Nonaqueous Solvents, Devon W. Meek, Ch. 1, Vol. I 8. Bronsted Acid-Base Behavior in "Inert" Organic Solvents, Marion Maclean Davis, Ch. 1, Vol. Ill xi Xll PREFACE 9. Solvation of Electrolytes and Solution Equilibria, Elton Price, Ch. 2, Vol. I 10. Solvation and Complex Formation in Protic and Aprotic Solvents, Sten Ahrland, Ch. 1, Vol. VA 11. Solvent Basicity, Robert L. Benoit and Christen Louis, Ch. 2, Vol. VA 12. Electrode Potentials in Non aqueous Solvents, H. Strehlow, Ch. 4, Vol. I 13. Redox Systems in Nonaqueous Solvents, Michel Rumeau, Ch. 3, Vol. IV 14. Acidity Functions for Amphiprotic Media, Roger G. Bates, Ch. 3, Vol. I 15. Hydrogen Bonding Phenomena, Ann T. Lemley, Ch. 2, Vol. IV Part III. Acidic Solvents 16. Liquid Hydrogen Chloride, Hydrogen Bromide, and Hydro- gen Iodide, Frank Klanberg, Ch. 1, Vol. II 17. Anhydrous Hydrogen Fluoride as a Solvent and a Medium for Chemical Reactions, Martin Kilpatrick and John G. Jones, Ch. 2, Vol. II 18. Liquid Hydrogen Sulfide, F. Fehér, Ch. 4, Vol. Ill 19. Sulfuric Acid, Witt Lee, Ch. 3, Vol. II 20. Halosulfuric Acids, S. Natarajan and A. W. Jache, Ch. 2, Vol. VB 21. Nitric Acid, W. H. Lee, Ch. 4, Vol. II 22. Anhydrous Acetic Acid as Nonaqueous Solvent, Alexander I. Popov, Ch. 5, Vol. Ill 23. Other Carboxylic Acids, Alexander I. Popov, Ch. 6, Vol. Ill 24. Trifluoroacetic Acid, John B. Milne, Ch. 1, Vol. VB Part IV. Basic Solvents 25. Liquid Ammonia, J. J. Lagowski and G. A. Moczygemba, Ch. 7, Vol. II 26. The Physical Properties of Metal Solutions in Nonaqueous Solvents, J. C. Thompson, Ch. 6, Vol. II 27. Hydrazine, D. Bauer and Ph. Gaillochet, Ch. 6, Vol. VA 28. Pyridine, J.-M. Nigretto and M. Jozefowicz, Ch. 5, Vol. VA 29. Tetramethylurea, Barbara J. Barker and Joseph A. Caruso, Ch. 4, Vol. IV 30. Amides, Joe W. Vaughn, Ch. 5, Vol. II PREFACE Xlll Part V. Aprotic Solvents 31. Liquid Sulfur Dioxide, D. F. Burow, Ch. 2, Vol. HI 32. Sulfolane, Jukka Martinmaa, Ch. 2, Vol. IV 33. Inorganic Acid Chlorides of High Dielectric Constant (with Special Reference to Antimony Trichloride), E. C. Baughan, Ch. 5, Vol. IV 34. Inorganic Halides and Oxyhalides, R. C. Paul and G. Singh, Ch. 4, Vol. VB 35. Acyl Halides as Nonaqueous Solvents, Ram Chand Paul and Sarjit Singh Sandhu, Ch. 3, Vol. Ill 36. Cyclic Carbonates, W. H. Lee, Ch. 6, Vol. IV 37. The Interhalogens, D. Martin, R. Rousson, and J.-M. Weulersee, Ch. 3, Vol. VB 38. Molten Salts as Nonaqueous Solvents, D. H. Kerridge, Ch. 5, Vol. VB The division of some chapters between Parts I and II in the outline is somewhat arbitrary since many chapters in Part I are organized about well- established or evolving principles. I should like to acknowledge the help of Ms. R. Schall who assisted in numerous ways during the preparation of Volume V. The cooperation of the staff of Academic Press in many ways since the inception of this treatise has been outstanding. Finally, the contributions of the numerous authors, both in terms of the manuscripts they produced and their numerous sug- gestions are gratefully appreciated. It is apparent that a very large number of persons contributed materially to the success of this effort since its inception in 1965. J. J. LAGOWSKI Contents of Other Volumes VOLUME I PRINCIPLES AND TECHNIQUES Lewis Acid-Base Interactions in Polar Nonaqueous Solvents DEVON W. MEEK Solvation of Electrolytes and Solution Equilibria ELTON PRICE Acidity Function for Amphiprotic Media ROGER G. BATES Electrode Potentials in Nonaqueous Solvents H. STREHLOW Solvent Extraction of Inorganic Species LEONARD I. KATZIN Experimental Techniques for Low-Boiling Solvents JINDRICH NASSLER Experimental Techniques in the Study of Fused Salts R. A. BAILEY AND G. J. JANZ Author Index—Subject Index VOLUME II ACIDIC AND BASIC SOLVENTS Liquid Hydrogen Chloride, Hydrogen Bromide, and Hydrogen Iodide FRANK KLANBERG Anhydrous Hydrogen Fluoride as a Solvent and a Medium for Chemical Reactions MARTIN KILPARTICK AND JOHN G. JONES Sulfuric Acid W. H. LEE XV xvi CONTENTS OF OTHER VOLUMES Nitric Acid W. H. LEE Amides JOE W. VAUGHN The Physical Properties of Metal Solutions in Nonaqueous Solvents J. C. THOMPSON Liquid Ammonia J. J. LAGOWSKI AND G. A. MOCZYGEMBA Author Index—Subject Index VOLUME III INERT, APROTIC, AND ACIDIC SOLVENTS Bronsted Acid-Base Behavior in "Inert" Organic Solvents MARION MACLEAN DAVIS Liquid Sulfur Dioxide D. F. BUROW Acyl Halides as Nonaqueous Solvents RAM CHAND PAUL AND SARJIT SINGH SANDHU Liquid Hydrogen Sulfide F. FEHÉR Anhydrous Acetic Acid as Nonaqueous Solvent ALEXANDER I. POPOV Other Carboxylic Acids ALEXANDER I. POPOV Author Index—Subject Index CONTENTS OF OTHER VOLUMES xvii VOLUME IV SOLUTION PHENOMENA AND APROTIC SOLVENTS Conductivity in Nonaqueous Solvents JOHN H. ROBERTS Hydrogen Bonding Phenomena ANN T. LEMLEY Redox Systems in Nonaqueous Solvents MICHEL RUMEAU Tetramethylurea BARBARA J. BARKER AND JOSEPH A. CARUSO Inorganic Acid Chlorides of High Dielectric Constant E. C. BAUGHAN Cyclic Carbonates W. H. LEE Sulfolane JUKKA MARTINMAA Author Index—Subject Index VOLUME VB ACIDIC AND APROTIC SOLVENTS Trifluoroacetic Acid JOHN B. MILNE Halosulfuric Acids SARASWATHI NATARAJAN AND ALBERT W. JACHE The Interhalogens DOMINIQUE MARTIN, ROGER ROUSSON, AND JEAN-MARC WEULERSSE Inorganic Halides and Oxyhalides as Solvents RAM CHAND PAUL AND GURDEV SINGH Molten Salts as Nonaqueous Solvents D. H. KERRIDGE Author Index—Subject Index
The list of books you might like
