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The Chemistry of Metal Enolates (Chemistry of Functional Groups) PDF

1249 Pages·2009·13.7 MB·English
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The chemistry of Metal Enolates Part 1 Editedby JACOB ZABICKY Ben-GurionUniversityoftheNegev 2009 A John Wiley and Sons, Ltd., Publication  AnInterscience Publication The chemistry of Metal Enolates PataiSeries:TheChemistryofFunctionalGroups AseriesofadvancedtreatisesfoundedbyProfessorSaulPataiandunderthegeneral editorshipofProfessorZviRappoport ThePataiSeriespublishescomprehensivereviewsonallaspectsofspecific functionalgroups.Eachvolumecontainsoutstandingsurveysontheoreticaland computationalaspects,NMR,MS,otherspectroscopicmethodsandanalytical chemistry,structuralaspects,thermochemistry,photochemistry,syntheticapproaches andstrategies,syntheticusesandapplicationsinchemicalandpharmaceutical industries,biological,biochemicalandenvironmentalaspects. Todate,over120volumeshavebeenpublishedintheseries. RecentlyPublishedTitles ThechemistryoftheCyclopropylGroup(Volume2) ThechemistryoftheHydrazo,AzoandAzoxyGroups(Volume2,2parts) ThechemistryofDouble-BondedFunctionalGroups(Volume3,2parts) ThechemistryofOrganophosphorusCompounds(Volume4) ThechemistryofHalides,Pseudo-HalidesandAzides(Volume2,2parts) ThechemistryoftheAmino,NitroandNitrosoGroups(2volumes,2parts) ThechemistryofDienesandPolyenes(2volumes) ThechemistryofOrganicDerivativesofGoldandSilver ThechemistryofOrganicSiliconCompounds(2volumes,4parts) ThechemistryofOrganicGermanium,TinandLeadCompounds(Volume2,2parts) ThechemistryofPhenols(2parts) ThechemistryofOrganolithiumCompounds(2volumes,3parts) ThechemistryofCyclobutanes(2parts) ThechemistryofPeroxides(Volume2,2parts) ThechemistryofOrganozincCompounds(2parts) ThechemistryofAnilines(2parts) ThechemistryofOrganomagnesiumCompounds(2parts) ThechemistryofHydroxylamines,OximesandHydroxamicAcids(2parts) ForthcomingTitles ThechemistryofOrganocopperCompounds ThePataiSeriesOnline Since2003thePataiSeriesisavailableinelectronicformatonWiley InterScience.Allnewtitleswillbepublishedasonlinebooksandagrowinglistofoldertitles willbeaddedeveryyear.ItistheultimategoalthatalltitlespublishedinthePatai Serieswillbeavailableinelectronicformat. FormoreinformationseeunderOnlineBookson: www.interscience.wiley.com C [M] O C The chemistry of Metal Enolates Part 1 Editedby JACOB ZABICKY Ben-GurionUniversityoftheNegev 2009 A John Wiley and Sons, Ltd., Publication  AnInterscience Publication Copyright2009 JohnWiley&SonsLtd,TheAtrium,SouthernGate,Chichester, WestSussexPO198SQ,England Telephone(+44)1243779777 Email(forordersandcustomerserviceenquiries):[email protected] VisitourHomePageonwww.wiley.com AllRightsReserved.Nopartofthispublicationmaybereproduced,storedinaretrievalsystemortransmitted inanyformorbyanymeans,electronic,mechanical,photocopying,recording,scanningorotherwise,except underthetermsoftheCopyright,DesignsandPatentsAct1988orunderthetermsofalicenceissuedbythe CopyrightLicensingAgencyLtd,90TottenhamCourtRoad,LondonW1T4LP,UK,withoutthepermissionin writingofthePublisher.RequeststothePublishershouldbeaddressedtothePermissionsDepartment,John Wiley&SonsLtd,TheAtrium,SouthernGate,Chichester,WestSussexPO198SQ,England,oremailedto [email protected],orfaxedto(+44)1243770620. Designationsusedbycompaniestodistinguishtheirproductsareoftenclaimedastrademarks.Allbrandnames andproductnamesusedinthisbookaretradenames,servicemarks,trademarksorregisteredtrademarksoftheir respectiveowners.ThePublisherisnotassociatedwithanyproductorvendormentionedinthisbook.This publicationisdesignedtoprovideaccurateandauthoritativeinformationinregardtothesubjectmattercovered. ItissoldontheunderstandingthatthePublisherisnotengagedinrenderingprofessionalservices.Ifprofessional adviceorotherexpertassistanceisrequired,theservicesofacompetentprofessionalshouldbesought. OtherWileyEditorialOffices JohnWiley&SonsInc.,111RiverStreet,Hoboken,NJ07030,USA Jossey-Bass,989MarketStreet,SanFrancisco,CA94103-1741,USA Wiley-VCHVerlagGmbH,Boschstr.12,D-69469Weinheim,Germany JohnWiley&SonsAustraliaLtd,42McDougallStreet,Milton,Queensland4064,Australia JohnWiley&Sons(Asia)PteLtd,2ClementiLoop#02-01,JinXingDistripark,Singapore129809 JohnWiley&SonsCanadaLtd,6045FreemontBlvd,Mississauga,Ontario,L5R4J3,Canada Wileyalsopublishesitsbooksinavarietyofelectronicformats.Somecontentthatappears inprintmaynotbeavailableinelectronicbooks. LibraryofCongressCataloging-in-PublicationData: Thechemistryofmetalenolates/editedbyJacobZabicky. p.cm.—(Pataiseries:thechemistryoffunctionalgroups) “AvailableinelectronicformatonWileyInterScience.” Includesbibliographicalreferencesandindex. ISBN978-0-470-06168-8(cloth:alk.paper)1.Organometalliccompounds.2.Enols.I.Zabicky,Jacob. QD411.C462009 547(cid:1).05–dc22 2009001886 BritishLibraryCataloguinginPublicationData AcataloguerecordforthisbookisavailablefromtheBritishLibrary ISBN978-0-470-06168-8 Typesetin9/10ptTimesbyLaserwordsPrivateLimited,Chennai,India PrintedandboundinGreatBritainbyMPGBiddlesLimited,KingsLynn,Norfolk Thisbookisprintedonacid-freepaperresponsiblymanufacturedfromsustainableforestry inwhichatleasttwotreesareplantedforeachoneusedforpaperproduction. Dedicated to Judith for the best things life can give Tali and David for the realizations of the present Yael, Noa, Danielle and Jehonathan for the promise of the future Contributing authors JuanAndre´s Departament de Qu´ımica F´ısica y Anal´ıtica, Universitat Jaume I, 12071 Castello´, Spain Fax: +34-96-4728066;e-mail: [email protected] Ksenija Chemistry Department, Rice University,6100 Main St., Babic´-Samardzˇija Houston,TX 77005, USA Present address: Baker Hughes Incorporated, 12645 West Airport Blvd., Sugar Land, TX 77478, USA Fax: +1-281-276-5491;e-mail: [email protected] ShmuelBittner Department of Chemistry, Ben-Gurion University of the Negev, P.O. Box 653, Beer-Sheva 84105,Israel Fax: +972-77-7575886;e-mail: [email protected] HermiFelintoBrito Department of Fundamental Chemistry, Universityof Sa˜o Paulo, Sa˜o Paulo-SP, 05508-000,Brazil Fax: +55-11-3815-5579;e-mail: [email protected] RoyBuschbeck Technische Universita¨t Chemnitz, Fakulta¨t fu¨r Naturwissenschaften,Institut fu¨r Chemie, Lehrstuhl fu¨r Anorganische Chemie, Strasse der Nationen 62, 09111 Chemnitz, Germany Fax: +49-371/531-21219;e-mail: [email protected] PaolaDeplano Universita` di Cagliari, Dipartimento di Chimica Inorganica e Analitica, S.S. 554-Bivio per Sestu, I09042 Monserrato-Cagliari, Italy Fax: +39-706754456;e-mail: [email protected] LuisR.Domingo Departament de Qu´ımica Orga´nica, Universitat de Valencia, Dr. Moliner50, 46100 Burjassot, Valencia, Spain Fax: +34-96-3544328;e-mail: [email protected] JasonEames Department of Chemistry, University of Hull, Cottingham Road, Kingston upon Hull, HU6 7RX, England Fax: +44-1482-464610;e-mail: [email protected] MariaClaudiaFranc¸a Instituteof Nuclear Energy and Research, Av. Prof Lineu CunhaFelinto Prestes 2242 Cidade Universita´ria, Sa˜o Paulo-SP. 05508-000,Brazil Fax: +55-11-3133-9249;e-mail: [email protected] vii

Description:
Metal Enolates form a class of compounds that have recently received much study because of their part in the important C-C-bond forming aldol reaction. Focusing on this important class of compounds in organic synthesis, The Chemistry of Metal Enolates features contributions on all aspects of Metal E
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