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Geophysical Monograph Series Including IUGG Volumes Maurice Ewing Volumes Mineral Physics Volumes Geophysical Monograph Series 101 Properties of Earth and Planetary Materials at High 118 Magnetospheric Current Systems Shin-ichi Ohtani, Pressure and Temperature Murli Manghnani and Ryoichi Fujii, Michael Hesse, and Robert L. Lysak (Eds.) Takehiki Yagi (Eds.) 119 Radio Astronomy at Long Wavelengths Robert G 102 Measurement Techniques in Space Plasmas: Particles Stone, Kurt W. Weiler, Melvyn L. Goldstein, and Jean- Robert F. Pfaff, Joseph E. Borovsky, and David T. Young Louis Bougeret (Eds.) (Eds.) 120 GeoComplexity and the Physics of Earthquakes John 103 Measurement Techniques in Space Plasmas: Fields B. Rundle, Donald L. Turcotte, and William Klein Robert F. Pfaff, Joseph E. Borovsky, and David T. Young (Eds.) (Eds.) 121 The History and Dynamics of Global Plate Motions 104 Geospace Mass and Energy Flow: Results From the Mark A. Richards, Richard G. Gordon, and Rob D. International Solar-Terrestrial Physics Program James van der Hilst (Eds.) L. Horwitz, Dennis L. Gallagher, and William K. 122 Dynamics of Fluids in Fractured Rock Boris Peterson (Eds.) Faybishenko, Paul A. Witherspoon, and Sally M. 105 New Perspectives on the Earth's Magnetotail A. Benson (Eds.) Nishida, D. N. Baker, and S. W. H. Cowley (Eds.) 123 Atmospheric Science Across the Stratopause David 106 Faulting and Magmatism at Mid-Ocean Ridges W. E. Siskind, Stephen D. Eckerman, and Michael E. Roger Buck, PaulT. Delaney, Jeffrey A. Karson, and Summers (Eds.) Yves Lagabrielle (Eds.) 124 Natural Gas Hydrates: Occurrence, Distribution, and 107 Rivers Over Rock: Fluvial Processes in Bedrock Detection Charles K. Paull and Willam P. Dillon (Eds.) Channels Keith J. Tinkler and Ellen E. Wohl (Eds.) 125 Space Weather Paul Song, Howard J. Singer, and 108 Assessment of Non-Point Source Pollution in the George L. Siscoe (Eds.) Vadose Zone Dennis L. Corwin, Keith Loague, and Timothy R. Ellsworth (Eds.) 126 The Oceans and Rapid Climate Change: Past, Present, 109 Sun-Earth Plasma Interactions J. L. Burch, R. L. and Future Dan Seidov, Bernd J. Haupt, and Mark Maslin (Eds.) Carovillano, and S. K. Antiochos (Eds.) 110 The Controlled Flood in Grand Canyon Robert H. 127 Gas Transfer at Water Surfaces M. A. Donelan, W. Webb, John C. Schmidt, G. Richard Marzolf, and M. Drennan, E. S. Saltzman, and R. Wanninkhof Richard A. Valdez (Eds.) (Eds.) 111 Magnetic Helicity in Space and Laboratory Plasmas 128 Hawaiian Volcanoes: Deep Underwater Perspectives Michael R. Brown, Richard C. Canfield, and Alexei A. Eiichi Takahashi, Peter W Lipman, Michael O. Garcia, Pevtsov (Eds.) Jiro Naka, and Shigeo Aramaki (Eds.) 112 Mechanisms of Global Climate Change at Millennial 129 Environmental Mechanics: Water, Mass and Energy Time Scales Peter U. Clark, Robert S. Webb, and Transfer in the Biosphere Peter AC. Raats, David Lloyd D. Keigwin (Eds.) Smiles, and Arthur W. Warrick (Eds.) 113 Faults and Subsurface Fluid Flow in the Shallow Crust 130 Atmospheres in the Solar System: Comparative William C. Haneberg, Peter S. Mozley, J. Casey Aeronomy Michael Mendillo, Andrew Nagy, and J. Moore, and Laurel B. Goodwin (Eds.) H. Waite(Eds.) 114 Inverse Methods in Global Biogeochemical Cycles 131 The Ostracoda: Applications in Quaternary Research Prasad Kasibhatla, Martin Heimann, Peter Rayner, Jonathan A. Holmes and Allan R. Chivas (Eds.) Natalie Mahowald, Ronald G Prion, and Dana E. 132 Mountain Building in the Uralides Pangea to the Hartley (Eds.) Present Dennis Brown, Christopher Juhlin, and Victor 115 Atlantic Rifts and Continental Margins Webster Puchkov (Eds.) Mohriak and Manik Taiwan! (Eds.) 133 Earth's Low-Latitude Boundary Layer Patrick T. Newell 116 Remote Sensing of Active Volcanism Peter J. and Terry Onsager (Eds.) Mouginis-Mark, Joy A. Crisp, and Jonathan H. Fink 134 The North Atlantic Oscillation: Climatic (Eds.) Significance and Environmental Impact James W. 117 Earth's Deep Interior: Mineral Physics and Hurrell, Yochanan Kushnir, Geir Ottersen, and Martin Tomography From the Atomic to the Global Scale Visbeck (Eds.) Shun-ichiro Karato, Alessandro Forte, Robert 135 Prediction in Geomorphology Peter Wilcock and Liebermann, Guy Masters, and Lars Stixrude (Eds.) Richard Iverson (Eds.) Geophysical Monograph 136 The Central Atlantic Magmatic Province Insights from Fragments of Pangea W. Hames J. G. McHone P. Renne C. Ruppel Editors 88 American Geophysical Union Washington, DC Published under the aegis of the AGU Books Board Jean-Louis Bougeret, Chair, Gray E. Bebout, Carl T. Friedrichs, James L. Horwitz, Lisa A. Levin, W. Berry Lyons, Kenneth R. Minschwaner, Darrell Strobel, and William R. Young, members. Library of Congress Cataloging-in-Publication Data The Central Atlantic magmatic province : insights from fragments of Pangea / W. Hames ... [et al.], editors. p. cm. -- (Geophysical monograph ; 136) Includes bibliographical references. ISBN 0-87590-995-7 1. Rifts (Geology)--North Atlantic Ocean. 2. Continental margins-North Atlantic Ocean. 3. Magmatism—North Atlantic Ocean. 4. Geology, Stratigraphic-Triassic. 5. Geology, Stratigraphic--Jurassic. I. Hames, W. (Willis) 1960- II. Series QE606.5.N724 C46 2003 551.872-dc21 2002038310 ISSN 0065-8448 ISBN 0-87590-995-7 Copyright 2003 by the American Geophysical Union 2000 Florida Avenue, N. W. Washington, DC 20009 Cover photos depict volcanic and intrusive rocks of the Central Atlantic Magmatic Province. From left to right: Cliffs of the Palisades sill basalts dominate the western shore of the Hudson River near New York City (photo by Anthony G Taranto Jr.); Volcano-sedimentary sequence in CAMP lavas from central Algarve (Portugal), where red clay sediments alternate with green pyro- clastic layers (photo by Nasrrddine Youbi); Volcanic pile of CAMP basalt pahoehoe lava flows overlying red clay sediments in Argana Basin, Morocco (photo by Nasrrddine Youbi). Figures, tables, and short excerpts may be reprinted in scientific books and journals if the source is properly cited. Authorization to photocopy items for internal or personal use, or the internal or personal use of specific clients, is granted by the American Geophysical Union for libraries and other users reg­ istered with the Copyright Clearance Center (CCC) Transactional Reporting Service, provided that the base fee of $1.50 per copy plus $0.35 per page is paid directly to CCC, 222 Rosewood Dr., Danvers, MA 01923. 0065-8448/03/$01.50+0.35. This consent does not extend to other kinds of copying, such as copying for creating new collec­ tive works or for resale. The reproduction of multiple copies and the use of full articles or the use of extracts, including figures and tables, for commercial purposes requires permission from the American Geophysical Union. Printed in the United States of America. CONTENTS Preface Willis E. Hames, J. Gregory McHone, Paul R. Renne, and Carolyn Ruppel vii Introduction W. Hames, J. G. McHone, P. Renne, and C. Ruppel 1 Cyclo-, Magneto-, and Bio-Stratigraphic Constraints on the Duration of the CAMP Event and its Relationship to the Triassic-Jurassic Boundary Paul E. Olsen, Dennis V. Kent, Mohammed Et-Touhami, and John Puffer 7 Relative Timing of CAMP, Rifting, Continental Breakup, and Basin Inversion: Tectonic Significance Roy W. Schlische, Martha Oliver With jack, and Paul E. Olsen 33 Age Estimates of the Seaward-Dipping Volcanic Wedge, Earliest Oceanic Crust, and Earliest Drift-Stage Sediments Along the North American Atlantic Continental Margin Richard N. Benson 61 Critical Evaluation of 40Ar/39Ar Ages for the Central Atlantic Magmatic Province: Timing, Duration and Possible Migration of Magmatic Centers Ajoy K. Baksi . 77 The Central Atlantic Magmatic Province (CAMP) in Brazil: Petrology, Geochemistry, 40Ar/39Ar Ages, Paleomagnetism, and Geodynamic Implications Angelo De Min, Enzo M. Piccirillo, Andrea Marzoli, Giuliano Bellieni, Paul R. Renne, Marcia Ernesto, and Leila S. Marques 91 Paleomagnetic and Geochemical Constraints on the Timing and Duration of the CAMP Activity in Northeastern Brazil M. Ernesto, G. Bellieni, E. M. Piccirillo, I. S. Marques, A. De Min, I. G Pacca, G. Martins, and). W. P. Macedo 129 A Reactivated Back-arc Source for CAMP Magma John H. Puffer 151 Temporal Chemical Variations Within Lowermost Jurassic Tholeiitic Magmas of the Central Atlantic Magmatic Province Vincent J. M. Salters, P. C. Ragland, W. E. Hames, K. Milla, and C. Ruppel 163 The Late Triassic-Early Jurassic Volcanism of Morocco and Portugal in the Framework of the Central Atlantic Magmatic Province: An Overview Nasrrddine Youbi, Lfnia Tavares Martins, Jose Manuel Munha, Hassan Ibouh, Jose Madeira, El Houssaine Ait Chayeb, and Abdelmajid El Boukhari 179 The Northernmost CAMP: 40Ar/39Ar Age, Petrology and Sr-Nd-Pb Isotope Geochemistry of the Kerforne Dike, Brittany, France Fred Jourdan, Andrea Marzoli, Herve Bertrand, Michael Cosca, and Denis Fontignie 209 CONTENTS Magma Flow Pattern in the North Mountain Basalts of the 200 Ma CAMP Event: Evidence From the Magnetic Fabric Richard E. Ernst, Jelle Zeilinga de Boer, Peter Ludwig, and Taras Gapotchenko 227 Volatile Emissions From Central Atlantic Magmatic Province Basalts: Mass Assumptions and Environmental Consequences J. Gregory McHone 241 Volcanism of the Central Atlantic Magmatic Province as a Potential Driving Force in the End-Triassic Mass Extinction JozsefPalfy 255 PREFACE A singular event in Earth's history occurred roughly 200 Some authors present syntheses of earlier work, and dis­ million years ago, as rifting of the largest and most recent cussions of models proposed for the CAMP, in combination supercontinent was joined by basaltic volcanism that with new data and in a format that is more detailed than formed the most extensive large igneous province (LIP) previously available. Stratigraphic relationships that define known. A profound and widespread mass extinction of ter­ the relative timing of CAMP magmatism, and correlations restrial and marine genera occurred at about the same time, to important biostratigraphic units are a major theme for suggesting a causal link between the biological transitions some papers. Other papers draw inferences and correlations of the Triassic-Jurassic boundary and massive volcanism. A to basaltic sub-provinces that may be members of the series of stratigraphic, geochronologic, petrologic, tectonic, CAMP, such as the buried continental flood basalts and the and geophysical studies have led to the identification of the seaward dipping reflector sequences (SDRs) of eastern dispersed remnants of this Central Atlantic Magmatic North America. Detailed reviews and analysis of radioiso­ Province (CAMP) on the rifted margins of four continents. topic data for CAMP igneous rocks are an important com­ Current discoveries are generally interpreted to indicate ponent of some papers in this volume, with conclusions that CAMP magmatism occurred in a relative and absolute that bear on the timing and duration of CAMP magmatic interval of geologic time that was brief, and point to mech­ activity. Although consistent themes with respect to timing anisms of origin and global environmental effects. Because and duration of magmatism emerge from these papers, vari­ many of these discoveries have occurred within the past ances in opinion are also evident, with some authors pre­ several years, in this monograph we summarize new obser­ ferring to view CAMP basalts as a temporal benchmark, vations and provide an up-to-date review of the province. whereas others interpret the available age data to represent Certainly several previous works support the current a measurable range of duration for CAMP magmatism. monograph, and contain matter that is closely related and The basaltic remnants of the CAMP have been identified relevant to the topic. However, while these volumes pro­ in North and South America, West Africa and Europe, over vide important syntheses that emphasize stratigraphic and regions with a reconstructed total area of about 10 million petrologic data of the North American portion of the square kilometers. Thus, reviews that report and synthesize CAMP, more recent research in several areas has promoted observations for each of these regions constitute critical recognition and definition of the CAMP in a circum- aspects of this volume. Papers here also provide new data Atlantic context, including: (1) precise absolute and tectonic interpretations for the CAMP in South geochronology of CAMP igneous rocks; (2) high-resolu­ America, where CAMP basalts have been identified rough­ tion stratigraphic studies that also may combine detailed ly 2000 km within the continent's interior. The deeply erod­ paleontology with magneto-stratigraphy and cyclo-stratig- ed plexus of basaltic dikes exposed in eastern North raphy; (3) petrologic and paleomagnetic studies that char­ America, with their related sills and flows of Newark acterize and relate distal portions of the CAMP; (4) geo- Supergroup basins, are a source for much of the petrologic chemical and paleontologic studies that suggest global cli­ and geochemical data of the CAMP. New data and synthe­ mate change at the Triassic-Jurassic boundary; and (5) ses of previous studies of the North American CAMP pre­ recognition of the important role for LIPs in crustal devel­ sented in this volume suggest extensive involvement of the opment and as a record of modes for mass and energy trans­ subcontinental lithosphere, and passive mechanisms for fer throughout Earth's history. generation of CAMP magmas, as compared to models that In this light, we conceived the present monograph to pro­ invoke deep mantle plumes. CAMP basaltic rocks in West vide insights unique to a circum-Atlantic perspective of the Africa and Portugal constitute an eastern boundary of the CAMP and its possible effects on Earth's climate and bio­ province. New data for this eastern part of the CAMP are logical systems from an international group of authors. presented within the context of a regional synthesis. vii Identification of CAMP basalts in the Brittany region of This volume arose from discussions following a theme France also emphasizes the northern extent of the province, session in the Fall 1999 meeting of the American as reported with new data. Geophysical Union (The Earliest Magmatism of the The results of other studies examine differing characteris­ Circum-Atlantic Large Igneous Province) and a workshop tics of the CAMP that point to underlying causes and prob­ in the summer of 2000 (International Workshop for a able effects of the province. The anisotropy of magnetic sus­ Climatic, Biotic, and Tectonic, Pole-to-Pole Coring ceptibility in basaltic dikes and flows has proven very use­ Transect of Triassic-Jurassic Pangea). We gratefully ful in analysis of magma transport directions and the loca­ acknowledge the inspiration and support from many col­ tion of magma sources, as reported in an analysis of dike leagues who participated in those meetings. We are partic­ and flow patterns from the Fundy basin. It is clear that the ularly grateful to the many reviewers of papers in this vol­ volatile emissions of the CAMP province were sufficient to ume (as indicated in the individual acknowledgements), induce major, global environmental changes, as also who provided an exceptionally high level of professional reviewed and considered here. The role of CAMP magma- peer review. We also acknowledge the editorial assistance tism as a driving force behind global Triassic-Jurassic envi­ and oversight of the American Geophysical Union book ronmental changes and mass extinctions is discussed and department staff. carefully considered, with comparisons of terrestrial and marine paleontologic records to the evolution of the CAMP and other possible causative mechanisms. The present volume provides definite advances in our Willis E. Hames understanding of the CAMP that will be useful to scholars Auburn University and researchers with interests in the magmatism of this province, events associated with the Triassic-Jurassic J. Gregory McHone boundary, the nature of mass extinctions, and large igneous University of Connecticut and Wesley an University provinces in general. Although the availability of literature for the CAMP has surged in the past few years, as this vol­ ume attests, we are still in a reconnaissance stage for under­ Paul R. Renne standing the CAMP with new discoveries emerging on Berkeley Geochronology Center and multiple research fronts. Thus, papers in this volume also University of California, Berkeley direct the reader to areas for further research with a rich potential for understanding one of Earth's most significant Carolyn Ruppel magmatic episodes. Georgia Institute of Technology viii Introduction W. Hames Department of Geology and Geography, Auburn University, Auburn, Alabama J. G. McHone University of Connecticut, Department of Geology and Geophysics, Storrs, Connecticut Wesleyan University, Department of Earth and Environmental Sciences, Middletown, Connecticut P. Renne Berkeley Geochronology Center, Berkeley, California University of California, Department of Earth and Planetary Science, Berkeley, California C. Ruppel School of Earth and Atmospheric Sciences, Georgia Institute of Technology, Atlanta, Georgia OVERVIEW OF RESEARCH ON THE CENTRAL and buried flood basalts that once covered large areas of ATLANTIC MAGMATIC PROVINCE the land, and in the sedimentary strata that host the vol­ canic remnants. Scientists collect forensic evidence in Large igneous provinces represent catastrophic out­ rock exposures from coastal Brittany to Brazilian rainfor­ pourings of immense quantities of basaltic lava, the origin ests, in strata buried deeply beneath Texas and on plateaus of processes that are hidden deep within Earth's interior in sub-Saharan Mali in the effort to describe this province and obscured by the movements of tectonic plates. Scien­ and determine its origin. Indeed, over the past several tists from many different fields are combining their efforts years we have learned through research that much of the to understand the underlying mechanisms by which large magmatism in this province was very sudden, although it igneous provinces' form, the distribution and timing of may have spread diachronously. The absolute age and such provinces, and the effects and consequences of the stratigraphic juxtaposition of this province seems coinci­ associated volcanism. This book presents a collection of dent with the transition from the Triassic to the Jurassic thirteen papers that delve into such fundamental questions period. Many scientists are now studying this magmatic for one of Earth's most calamitous events - the profound province in an effort to understand how its effects may and extensive magmatism that accompanied the breakup relate to the global climate changes and profound mass of Pangea. extinction at the end of the Triassic (when perhaps 80% of Dramatic relics of the magmatism that accompanied Earth's terrestrial and marine faunas perished). And yet breakup of Pangea are preserved on every continent of the such a catastrophic distress for some may provide oppor­ circum-Atlantic region, in exposures of igneous intrusions tunity to others, as the Jurassic rise of dinosaurs to domi­ that once provided magma conduits, as partially eroded nate Earth may have begun with global climate changes The Central Atlantic Magmatic Province: wrought by this large igneous province. Thus, the re­ Insights from Fragments of Pangea search on this individual magmatic province is part of a Geophysical Monograph 136 broader and contentious scientific trial to determine Copyright 2003 by the American Geophysical Union whether massive volcanic events, meteorite impact 10.1029/136GM01 events, or combinations of both are responsible for the 1 2 INTRODUCTION major mass extinction events that have modulated the Relationships of the CAMP to the Seaward Dipping course of life on Earth for the past 300 million years. Reflector Sequences of the Central Atlantic Basin Recognition of the Central Atlantic Magmatic Province A seam that runs near the central axis of the CAMP, along the plate boundary that would become the Atlantic Although geologists first recognized the extent and sig­ basin, is defined by the seaward-dipping reflector se­ nificance of Triassic-Jurassic basalts around the Atlantic quences (SDRS, Figure 1). The SDRS are considered region in the late nineteenth century (Russell, 1880), it is from seismic studies to represent thick, wedge-shaped ac­ only within the past few years that the timing and extent cumulations of basalt flows [Holbrook and Kelemen, of magmatism was sufficiently constrained to define what 1993; Oh et al., 1995] that are deeply buried within the we now refer to as the Central Atlantic Magmatic Prov­ continental margin. Extrusion of basalts in the SDRS ince [CAMP; Marzoli et al., 1999]. The known distribu­ marks an end to CAMP magmatism in the continental tion of CAMP dikes, sills and flows is represented in Fig­ realm and the birth of the central Atlantic basin. However, ure 1 (adapted from McHone, 2000). Rifting of Pangea the timing of formation for SDRS in the central Atlantic, and deposition of clastic sediments in intermontane basins and whether they should be considered as part of the began by about 230 million years ago, reactivating more CAMP, is unclear. For comparison, the SDRS of the ancient crustal boundaries and leading to a configuration North Atlantic Igneous Province seem to have formed of incipient continental fragments as shown in Figure 1 by several years after the continent-based magmatism [Saun­ roughly 200 million years ago. CAMP basalts and associ­ ders et al., 1999]. Considering the CAMP, Benson [this ated intrusions developed near the center of this evolving volume] reviews stratigraphic interpretations of the oldest rift setting and close to an equatorial latitude [Olsen, drift-stage rocks of the North American margin and of 1997]. Much of the perimeter for the CAMP coincides early Atlantic sea-floor spreading rates suggestive of with orogenic belts and deep boundaries in the continental much younger ages for the SDRS and earliest Atlantic sea lithosphere, such as the western limit of the CAMP and floor. In contrast, Schlische et al. [this volume] present a the Blue Ridge to Piedmont province boundary of the model for diachronous rift-drift CAMP magmatism, in southeastern Appalachians. which the SDRS form in an earlier magmatic pulse with the CAMP to the south and after the CAMP through a Characteristics of the CAMP separate magmatic pulse to the north. Olsen et al. [this volume] review and test earlier evidence for the age of the The CAMP is dominated by tholeiitic basalts, with an CAMP and drilled units correlated with the SDRS, and extent and major geochemical relationships that continue suggest they could be of the same age. Both Benson and to be defined by new discoveries. CAMP dikes have been Olsen et al. [this volume] present discussions to highlight identified in northwestern France [Jordan et al., this vol­ the need for drilling of basalts correlated with the SDRS ume], that are similar in age and overall chemistry to in order to evaluate the alternate models for timing of the CAMP basalts that are 2000 km within continental South SDRS in the Central Atlantic and their relationship to America [De Min et al., this volume], although regional CAMP magmatism. heterogeneities in basalt composition exist and seem re­ lated to differences in regional lithospheric composition. The CAMP as an Agent of Planetary Catastrophe CAMP basalts in eastern Brazil are also more extensive than previously recognized, where paleomagnetic data Through recorded human history we have come to un­ also suggest local basaltic magmatism significantly before derstand that volcanic events can cause catastrophes, but and after a main stage at 200-190 Ma [Ernesto et al., this that the effects are generally local. The violent and explo­ volume]. The CAMP volcanics in Morocco and Portugal sive eruption of Mount Vesuvius was a catastrophe for the comprise a significant proportion of subaerial lavas and citizens of Pompeii as recorded by Pliny the Younger pyroclastics interbeded with shallow-water clastic se­ (and experienced by Pliny the Elder!), although this event quences, and the geochemistry of dikes and flows in the was inconsequential for the climate and life of Earth be­ region is also compatible with a lithospheric mantle yond a small region of western Italy. It is difficult, there­ source [Youbi et al., this volume]. The broadly uniform fore, to imagine volcanic events, even the massive out­ composition of many CAMP basalts, the extent of CAMP pourings of basalt in large igneous provinces, as consti­ magmatism, the relationship to thickened lithosphere and tuting "planetary catastrophes" as posed by Courtillot crustal boundaries of Pangea, and geochemical trends are [1999]. If we consider the scale of large igneous prov­ collectively most compatible with "passive" models in­ inces (Figure 2), however, the magnitude of their potential volving upper mantle geodynamics [De Min et al., this effects is more readily understood. volume; Jourdan et al., this volume; Puffer, this volume; The Columbia River Flood Basalt Province (Figure 2) Salters et al., this volume]. is approximately one tenth the size of the other large ig-

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