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Technical Proceedings of the 2007 Cleantech Conference and Trade Show PDF

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2007 Cleantech Conference and Trade Show Cleantech 2007 ^C^eantech 2007 The Cleantech Conference, Venture Forum and Trade Show Boca Raton London New York TechConnecf CRC Press is an imprint of the Taylor & Francis Group, an informa business Artwork provided by Prof. Eric J. Heller, http:// www.ericjhellergallery.com Transport IV (cover): Transport IV renders electron flow paths in a ’’two dimensional electron gas”. The research leading to the Transport series was inspired by the experiments of Mark Topinka, Brian Leroy, and Prof. Robert Westervelt at Harvard, which actually measured the paths taken by the electrons. The theory was performed with the help of Scot Shaw, a member of my research group at the time. Transport IV is based on flow patterns for electrons riding over bumpy landscape, which is what electrons experience in the two-dimensional electron gas (2DEG) that they dwell in. A 2DEG is a sea of electrons confined to a sheet, i.e. two dimensions. The bumps they encounter are due to charged atoms lying above the sheet. The electrons have more than enough energy to ride over any bump, and the concentrations of electron flow into the branches seen here are recently discovered indirect effects of that bumpy ride. The channeling or branching was unexpected and has implications for small electronic devices of the future. This image was made in a computer simulation by launching 100,000 electrons from the lower middle of the image, and following their tracks. Each electron had a slightly different launch angle. A color map was applied to turn the density of electron paths into color. Code written in Fortran computed the trajectories, and wrote information about them to a very large raster image. The algorithm used to write to pixels, which had already been accessed by previous electron paths gives the peculiar shading and form to this image. The electron tracks in Transport IV are an excellent example of the wonderful way nature emulates herself in different contexts. The branching pattern is reminiscent of familiar natural forms. 2007 Cleantech Conference and Trade Show Cleantech 2007 Cleantech 2007 The Cleantech Conference, Venture Forum and Trade Show May 23-24, 2007 Santa Clara, California, U.S.A. www.nsti.org NSTI- TechConnect 2007Joint Meeting 2007 Cleantech Conference, Venture Forum and Trade Show, Cleantech 2007 The 2007 NSTI Nanotechnology Conference and Trade Show, Nanotech 2007 2007 NSTI Bio Nano Conference and Trade Show, Bio Nano 2007 10th International Conference on Modeling and Simulation of Microsystems, MSM 2007 7th International Conference on Computational Nanoscience and Technology, ICCN 2007 6th Workshop on Compact Modeling, WCM 2007 NSTI Nanotech Ventures 2007 Nanotech for Investors 4th Bi-Annual Summit 2007 TechConnect Summit Cleantech 2007Proceedings Editors: Matthew Laudon Bart Romanowicz mlaudon @ [email protected] TechConnect Boston · Geneva · San Francisco TTeecchh CCoonnnnecetc™t TU CRC Press Taylor & Francis Group 6000 Broken Sound Parkway NW, Suite 300 Boca Raton, FL 33487-2742 First issued in hardback 2019 © 2007 by TechConnect. Copyright and reprint permissions: Abstracting is permitted with credit to the source. CRC Press is an imprint of Taylor & Francis Group, an Informa business No claim to original U.S. Government works ISBN 13: 978-1-4200-6382-0(pbk) ISBN 13: 978-1-138-47437-6(hbk) This book contains information obtained from authentic and highly regarded sources. Reasonable efforts have been made to publish reliable data and information, but the author and publisher cannot assume responsibility for the validity of all materials or the consequences of their use. The authors and publishers have attempted to trace the copyright holders of all material reproduced in this publication and apologize to copyright holders if permission to publish in this form has not been obtained. If any copyright material has not been acknowledged please write and let us know so we may rectify in any future reprint. Except as permitted under U.S. Copyright Law, no part of this book may be reprinted, reproduced, transmitted, or utilized in any form by any electronic, mechanical, or other means, now known or hereafter invented, including photocopying, microfilming, and recording, or in any information storage or retrieval system, without written permission from the publishers. For permission to photocopy or use material electronically from this work, please access www.copyright.com (http://www.copyright.com/) or contact the Copyright Clearance Center, Inc. (CCC), 222 Rosewood Drive, Danvers, MA 01923,978-750-8400. CCC is a not-for-profit organization that provides licenses and registration for a variety of users. For organizations that have been granted a photocopy license by the CCC, a separate system of payment has been arranged. Trademark Notice: Product or corporate names may be trademarks or registered trademarks, and are used only for identification and explanation without intent to infringe. Visit the Taylor & Francis Web site at http://www.taylorandfrancis.com and the eRe Press Web site at http://www.crcpress.com Cleantech 2007 Proceeding Editors VOLUME EDITORS Wade Adams Matthew Laudon Rice University TechConnect Daniel L. Laird Bart Romanowicz Sandia National Laboratories Nano Science and Technology Institute Producing Sponsor TechConnect Co-Producing Sponsors MITStanfordTJC Berkeley Nanotechnology Forum Nano Science and Technology Institute Press Sponsor Business Wire Commercialization Partner BusinessWeek Sponsors Buchanan Ingersoll & Rooney, PC Institute of Biophysics, Chinese Academy of Clean Technology International Corp. Sciences Controlled Contamination Services, LLC Lawrence Berkeley National Laboratory Economic and Workforce Development through the NanoDynamics, Inc. California Community Colleges Omron Advanced Systems, Inc Full Circle Solar SOPOGY, Inc. NanoSelect Tesla Motors Media Sponsors Nature R&D Magazine Science Magazine Sustainable Industries Journal Red Herring, Inc. Inside Greentech Fuel Cell Magazine CLEAN — Soil, Air, Water Battery Power Products & Technology i Table of Contents Program Committee........................................................................................................................................................vii Energy and Fuels Extracting unbumt coal from black coal fly ash............................................................................................................5 M. Kusnierova, P. Fecko Bacterial desulphurization of brown coals......................................................................................................................9 P. Fecko, M. Kusnierova, M. Safarova, V. Cablik Amorphous Diamond Solar Cells..................................................................................................................................13 J.C. Sung, M-C. Kan, T-J. Hsiao and M. Sung Integrated Multistage Supercritical Technology to Produce High Quality Vegetable Oil and Biofuels................17 G. Anitescu, A. Deshpande, P.A. Rice and L.L. Tavlarides 8nm cerium oxide as a fuel additive for fuel consumption and emissions reduction..............................................21 G. Wakefield and M. Gardener Effect of Surface Hydration and Interfusion of Suspended Silica Nanoparticles on Heat Transfer.......................25 D. Milanova, X. Wu and R. Kumar Energy Applications of Nanotechnology Evaluation of Nanostructured Polymeric Coatings for Corrosion Protection...........................................................29 A. Aglan, A. Ludwick and M. Reeves Preparation and Characterization of Nafion/Microporous Titanosilicate Composite Membranes as Ion- Conducting Materials....................................................... 33 S -Y. Ryu, J.-D. Jeon and S.-Y. Kwak Amorphous Diamond as a Thermionic Material..........................................................................................................37 J.C. Sung, M-C Kan, T-J Hsiao, Y-T Chen and M. Sung Ultra-short pulsed laser for nano-texturation associated to plasma immersion implantation for 3D shallow doping : Application to silicon photovoltaic......................................................................................................41 M. Halbwax, T. Samet, Ph. Delaporte, M. Sentis, H. Etienne, F. Torregrosa, V. Vervisch and S. Martinuzzi Dye-sensitized solar cell using a Ti02 nanocrystalline film electrode prepared by solution combustion synthesis.................................................................................................................................................................45 CM. Wang and S.L. Chungb Synthesis and characterization of a highly cross linked PEGME and PEG for solid electrolyte and its application in dye-sensitized solar cells...............................................................................................................49 M. Shaheer Akhtar, J-M Chun, H-C Lee, K-J Kim and O-B Yang Nano-Hetero Structure for direct energy conversion..................................................................................................53 L. Popa-Simil Nanotechnology - Disruptive Technologies for Electric Utility Systems. Challenges and Opportunities.............57 J. Stringer and R.H. Richman Catching Mr. Big with the Small - To Infinitesimal and Beyond'............................................................................60 I. Eastwood TiN/GaN- Metal/Semiconductor Multilayers for Thermionic Energy Conversion Devices...................................63 V. Rawat and T.D. Sands Pt and Pt-Ru/Carbon Nanotube Nanocomposites Synthesized in Supercritical Fluid as Electrocatalysts for Low-Temperature Fuel Cells.........................................................................................................................67 Y. Lin, X. Cui, J. Wang, C.H. Yen and C.M. Wai Nanoporous Silicon Membrane Based Micro Fuel Cells for Portable Power Sources Applications......................71 K-L Chu, M.A. Shannon and R.I. Masel Novel Electrolyte Membrane for Fuel Cell Utilizing Nano Composite....................................................................75 K. C. Nguyen, H.V. Nguyen, S.T. Do, T.T. Doan, A.T. Nguyen, T.V. Le and T.N.T. Nguyen Heat Transfer Cost-Effectiveness of Nanofluids........................................................................................................79 D. Xu, L. Pan and Q. Yao ii Emissions, and Environmental Influence of His-195 on the nitrogenase FeMo-cofactor activity..............................................................................83 C. Cavallotti, D. Moscatelli and S. Carra Development of Functionally Graded SiC-Based.......................................................................................................87 T. Gerdes and M. Willert-Porada Study on non-Freon air cooling system using water refrigerant................................................................................91 A. Sugawara, S. Nakamikawa, M. Kageyama, S. Yamazaki, N. Abe, T. Itou, A. Tsurumaki and K. Kawasaki Conjugates of Enzyme-Magnetic Nanoparticles for Bioremediation*......................................................................95 Y. Qiang, A. Sharma, A. Paszczynski and D. Meyer Recovery of Caustic Soda in Textile Mercerization by Combined Membrane Filtration.......................................99 J. Yang, C. Park, D. Lee and S. Kim Study of model contaminants desorption from recycled PET in dry air and nitrogen atmosphere by thermogravimetric analysis..............................................................................................................................103 A.S.F. Santos, J.A.M. Agnelli, E.S. Medeiros, E. Corradini, S. Manrich Development of a Mobile Asbestos Decontamination Process..............................................................................106 T. Gerdes, A. Rosin, M. Willert-Porada Serpentine Fluidic Structures for Particle Separation.............................................................................................110 A.S. Kole, M.H. Lean, J. Seo Sorption of Ethylbenzene, Toluene and Xylene onto Crumb Rubber from Aqueous Solutions..........................114 L. A. Alamo-Nole, F. Roman and O. Perales-Perez Growth and Some Enzymatic Responses of E. coli to Photocatalytic Ti02..........................................................118 A. Erdem, D. Metzler, H.W. Chou, H.Y. Lin and C.P. Huang Novel FD SOI Devices Structure for Low Standby Power Applications...............................................................122 M-W Ma, T-S Chao, K-S Kao, J-S Huang and T-F Lei Solar-Blind Dual-Band UV/IR Photodetectors Integrated on a Single Chip.........................................................126 D. Starikov, C Boney, R. Pillai and A. Bensaoula Enviroment, Health and Society Characterization on Dioxin Emission of Ti02 Nanoparticle-Encapsulating Poly(vinyl chloride) (TEPVC) compared to conventional PVC.......................................................................................................................130 H. Yoo, S.H. Kim, A.R. Lee and S.-Y. Kwak Theoretical Study of the Reaction between OH Radicals and Formaldehyde adsorbed on Small Silica Clusters....................................................................................................................................................134 C. Iuga and A. Vivier-Bunge An investigation of natural nanoparticles for cleaning applications.......................................................................140 M. Nero and B. Tran Aided Transport of Nano-Iron in Clay Soils Using Direct Electric Field..............................................................144 L. Hannum and S. Pamukcu Nano-Catalysts and Colloidal Suspensions of Carbo-Iron for Environmental Application.................................148 K. Mackenzie, H. Hildebrand and F.-D. Kopinke An integrated NMR/nanosensor system for sensitive detection of environmental toxins and harmful microbes................................................................................................................................................152 J.M. Perez, D.P. Fries and J.J. Hickman Nanotechnology and the Global Poor: United States Policy and International Collaborations...........................155 R. Rodrigues, R. Sandler, W.D. Kay and T. Lodwick Nanotechnology and the Water Market: Applications and Health Effects............................................................159 F. S. Mowat and J. Tsuji Novel Technologies Nano-structures materials for Energy Direct Conversion and Fuel Breeding........................................................163 L. Popa-Simil Building Green with Nanotechnology........................................................................................................................167 G. Elvin Heat is the Enemy of Energy Efficiency....................................................................................................................171 D. Forder and P. Fox iii Self-Assembled Soft Nanomaterials from Renewable Resources..........................................................................175 G. John Industry and Policy Designing Today’s CleanTech Research Facility: Sustainable, Highly Technical Architectural and Engineering Design Applied to the New York State Alternative Fuel Vehicle Research Laboratory (AFVRL)............................................................................................................................................................. 178 J. Ostafi and D. Sereno Good Policy Makes Good Business.............................................................................................................................181 B. Cinnamon Clean Tech: New Paradigms and Communications Challenges..............................................................................183 M. Allison, A. Pray, H. Drage and P. Missimore Photovoltaics Innovation and Commercialization in Ohio........................................................................................187 D.M. Giolando, R. Collins, R.J. Davis Photovoltaics and Fuel Cells Bulk Heterojunction Organic-Inorganic Photovoltaic Cell Based on Doped Silicon Nanowires........................191 G. Goncher, L. Noice and R. Solanki Molecular Building Blocks for Efficient Solid State Lighting................................................................................195 P.E. Burrows and L.S. Sapochak Dynamics of Water in Nafion Fuel Cell Membranes: the Effects of......................................................................199 D. E. Moilanen, I.R. Piletic and M.D. Fayer Determination of Pore Size Distribution of Nafion/Sulfated beta-Cyclodextrin...................................................203 J. -D. Jeon, B.H. Lee and S.-Y. Kwak Hydroxyapatite-imidazole-polymer composite films as a proton conductor under no humidified condition....207 H. Tsutsumi and Y. Hisha Block Copolymer Directed Nanocomposites for Fuel Cell Applications..............................................................211 T. Dermis, S. Mayavan, N.K. Dutta, N.R. Choudhury and S. Holdcroft Microbial fuel cell........................................................................................................................................................215 M. Willert-Porada, K. Lorenz, R. Freitag, V. Jerome, S. Peiffer Synthesis of visible light active nanocrystalline bismuth oxide based photocatalysts.........................................219 K. K. Akurati, A. Vital, F. Reifler, A. Ritter and T. Graule Nanoparticle Processes & Applications Nanoparticles Formed by Complexation of Poly-gamma-glutamic Acid with Lead Ions...................................223 M. Bodnar, A-L Kjoniksen, J.F. Hartmann, L. Daroczi, B. Nystrom and J. Borbely Nano hetero nuclear fuel structure.............................................................................................................................227 L. Popa-Simil Development of a novel material for reversible hydrogen storage.........................................................................231 E. Titus, M.C. Coelho, G. Cabral, J.C. Madaleno, T. Shokuhfar and J. Gracio Active Coatings Technologies for Customized Military Coating Systems............................................................234 J.L. Zunino III Design and Manufacturing Concepts of Nanoparticle-reinforced Aerospace Materials......................................238 M. V. Kireitseu, G.R. Tomlinson and V. Basenuk Titanium Dioxide Nanostructured Coatings: Application in Photocatalysis and Sensors....................................242 J.A. Byrne, J.W.J. Hamilton, T.A. McMurray, P.S.M. Dunlop, V.J.A. Donaldson, J. Rankin, G. Dale and D. A1 Rousan CNT Composites for Aerospace Applications.........................................................................................................246 S. Bellucci, C. Balasubramanian, P. Borin, F. Micciulla and G. Rinaldi Advancements in the Supercritical Water Hydrothermal Synthesis (scWHS) of Metal Oxide Nanoparticles ... 251 E. Lester, P. Blood, J. Li and M. Poliakoff Monometallic nano-catalysts for the reduction of perchlorate in water.................................................................255 D.M. Wang, H.Y. Lin and C.P. Huang Functionalized Nanoporous Ceramic Sorbents for Removal of Mercury and Other Contaminants....................259 S.V. Mattigod, G.E. Fryxell, R. Skaggs and K.E. Parker Thermostability of Ti02 nanoparticle and its Photocatalytic Reactivity at Different Anatase/Rutile Ratio......262 Y-H Tseng, H-Y Lin, C-S Kuo, Y-Y Li and C-P Huang IV Destruction of Organophosphate Agents by Recyclable Catalytic Magnetic Nanoparticles...............................266 L. Bromberg and T.A. Hatton Enhancement of Oxygen Transfer in Fermentation by Use of Functionalized Magnetic Nanoparticles.............270 B. Olle, L. Bromberg, T.A. Hatton and D.I.C. Wang Nanostructured perovskite-based oxidation catalysts for improved environmental emission control.................274 P. Seegopaul, M. Bassir, H. Alamdari and A. Van Neste Nano-Engineering Of Magnetic Particles For Biocatalysis And Bioseparation...................................................278 C. H. Yu, C.C.H. Lo, C.M.Y. Yeung, K. Tam and S.C. Tsang Gas Sensor Arrays by Supersonic Cluster Beam Deposition.................................................................................282 E. Barborini, M. Leccardi, G. Bertolini, O. Rorato, M. Franchi, D. Bandiera, M. Gatelli, K. Wegner, A. Raso, A. Garibbo, C. Ducati, P. Piseri and P. Milani Preparation and Characterization of Various Nanofluids.......................................................................................285 W.C. Williams, I.C. Bang, E. Forrest, L.W. Hu and J. Buongiomo High performance iPP based nanocomposite for food packaging application......................................................289 M. Avella, M.E. Errico and G. Gentile Enlarge the distance of water molecules to incise microorganism cell-the development and application of nano-grade microorganism cell crushing machine.........................................................................................293 Y. Hongwen and G. Suge Systematic Approach on Modeling and Identification for Nanobattery Prototyping...........................................297 P. Bhattacharya, Z. Ye, E. Walker, F. Lacy and M. Banerjee Sensors Biosensor for heavy metals using hydrothermally grown ZnO nanorod/nanotube and metal-binding peptides...............................................................................................................................................................301 W. Jia, E.T. Reitz and Y. Lei Multiplexed immunoassays by flow cytometry for detection of Clenbuterol, Chloramphenicol and sulfadimidine with high sensitivity and selectivity........................................................................................304 Y. Zhao, M. Zou, H. Gao, Q. Xue and P. Zhou Chemical Nano-Sensor Development and Characterization...................................................................................308 A. J. Jin Composite Carbon Nanostructures as Promising Carriers for Gaz Analysis........................................................312 L. Majoli, A. Evstratov, J.-M. Guillot, A. Rouviere and P. Baussand Molecular Simulation Studies on Adsorption of Mercuric Chloride.......................................................................316 R. R. Kotdawala, N. Kazantzis and R.W. Thompson Layer by Layer Fabrication of an Amperometric Nanocomposite Biosensor for Sulfite.....................................320 S. B. Adeloju and A. Ohanessian Electrochemical ‘Lab-on-a-Chip’ for Toxicity Detection in Water........................................................................322 R. Popovtzer, T. Neufeld, E.Z. Ron, J. Rishpon and Y. Shacham-Diamand Investigating the Benefit-Cost of MEMS Application for Structural Health Monitoring of Transportation Infrastructure.......................................................................................................................................................326 M. K. Jha and A.B. Davy Wireless Micro and Nano Sensors for Physiological and Environmental Monitoring.........................................330 B. Kaminska Electrospun Ti02 nanofibers for gas sensing applications......................................................................................334 I-D Kim, A. Rothschild, H.L. Tuller, D.Y. Kim and S.M. Jo Index of Authors........................................................................................................................................................339 Index of Keywords.....................................................................................................................................................343 v

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