T112313 sub[Aitted Cor 2kh DIPLaLA 211E 14e4RIAL COLLY74- by AJ MR=2 Dept. of Cho-ilionl

495 Pages·2013·62.04 MB·English

T112313
sub[Aitted Cor
2kh DIPLaLA 211E 14e4RIAL COLLY74-
by
A. J. MR=2
Dept. of Cho-ilionl .riginocrint7
and Applied Che,aistry.
lobruary, 1953.
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approOis ons
introduction
Cha9tor Ona. Lisorionl
(n) AOC 4nw of the li;droon-Olcyppn Reaction 6
(b) micobaniaA of the aiLethane-Oxylw Reaction 8
hoica1 Acthodo for ttlo Ini,astition of
into:alelintos in Flatlos 13.
elysloal utet'aods t'or the Invesui,ation of
Intermediates in flames 15
Gilftotar raVerientO,
Part AI
ri ,sti.tion If li.vdromn Vcro%tide usi
ectanzium loiide 151
(b) The Colourigietrio 1;stiaati)a of i'croxi)ers LUiflf
Axitoniu.i 2hiwanate •and tarrous Sulphate 26
(o) Analjsis of Peracidn in tho Presume of Carboxylic
Acid by a lotontiowetrio asthod 20
(d) ehe 41timati'm or tOrzlialdehydo
(e) Tests fox Alcohol 30
Cl or Ii o n ioxide
(4) Tests for Ozone 32
.ktei,on 2.
(u) General 11T tQ-iar1ng the Auelysio
of Peroxide Aixtures 34
(b) Tho ,stialation of kmeth$1 aydroperoxide in tho
41rontloe IV ii,vdroea 37
(c) Zzta ora4ato-raliale ...-ephrtwtin or Poroxirl 47
9.-luroaont ,axAtion Coofficients
of Peroxides 49
Puroxida Joparation by tiL e Low 2eaorsture
Distillation a-id tho Infra-Rad jpectrum
of to Concentrated 3olution 51
2e- foot Of Catalysts on the ibortion of
-• iodine fro Acidified i?ota7;siuM IOdide. by
Hydroporelcide 57
2:10 ,-.ction of ;21atinul Black on the 4?ro6uot of
the &xplosion of'alethsne uxy'on 65
Volaro7raphic hinalysis of the Nonotion Produot
froal the Low Pressure 4xplosion of i.act4ane ,
and Oxygen 67
3.
joction
(a) Doscription of the Apparatus for Carrying out
3in7,10 f!;:4plosions of othane and Oxygen 70
(b) alethod of Calculating Gas Analysis exults 72
(o) Infra-Hed GS8 Analysis of te Product of t he
;Lxpiolion of &ethane and Oxygen 78
jummary of Part A 82
Part B. .110tatic :i;xcerimcznts in Unc. d
'Pyrex Vqsseis.
oction 1,
(a) 1;xperialents with ikAhane • 86
(i) ,,ethod 86
(ii) Calculation of i4mults 89
(iii)R esults - 8)
(b) 2c)losion of -gixttires of rbon 'ide 2ydrogen
and Oxymn 97
(e) a:xplosion of miixtures of Hydrogen and Oxygen 101.
(i) extent or Reaction in the i.bcplosion of
Hydrop:en-Uxygen 4ixtures 101
(ii) Aiethod of Calculating Percontape Combustion 103
(iii) e fifeet of Initial Pressure on the Yield
of Hydrogen Peroxide 116
irreproduoibility kiAoolatad wit uneoatee
4''yrox les3o13 1„:3
ii) .4tCoote due to ,angas of ,ianation
7es3o1 furtacto 1..—!,
(ii) Th-votrAa n'id leo eila trect.4 146
jiaation,20
(a) On •r( Zonlideration* Conoeriw, ,'1A4 AIet40,d3 132
(b) itriloriptrion of ikpperatus 133
(o) Resulti frldi Multi,03tatie Apparatus; Ry'roo,wit.
Oxyr:en 4xplonions 130
(d) trall iu1tt ttic Ati,Aparetue; eMiai
Ox77en ?.:Rplosione 145
Aramarj af *dart 2 147
.7Antl f.44 Ilyrer
:Joe i)n L.
(n) Stabilinatin It Uyidrolen ier1lo by Joria mad 154
;)419ticn 2. (Xxparimonts wit4 ilydrooa arkj oxyr,!ani
(a) i.nii1 erm.erture 150
(b) i ,tfoot of Refri7orant 2elperature 166
(0) :ha Iteot .dlturo Goaposition 167
(3) :le If.not or 4del lasee 171
: gti:-011 3* ( c.ai;aents wit!-k aothaae and Owen)
(a) 271g1 Mot rInitiol ?res-mre 181
(b) 2h•o Zroot tAxtura C.,oalpealtion 183
(c) ;ffootct;oCri'ernnt :e0aparnture 182
C1) ,rroot •rir 7osle1 Aamater 184
(e) .:;"tiuntion :ioittting Initial Oroalura or the
41xp1osire ?,,ixture anJ the Yield of l!jdrolen
eeromide 18
;lootion 4.
(a) :he Aplosion or Aixturea or Cnrbln Aonoxide
Hydrolon and Oxylon 1 i4
3utomary of Psrt G
Psrt D. L.e Ul io , a trum
liwdro;.!oh
Ap)aratue 401
(b) Results 'r ,e ,xporimonts with tly..lrorw a4
0OXX3Y7 gen 206
(o) Results Cr oa the 'ilxperiAants with et4ano and
0Vgian 210
Liait of oeteotion or aydr .1,e Perrooxxiiddee by the
3pootrosoopio Aethod 413
(,) leneral Considerations Gonoeraiw, the YJetootion of
. Hydrotin Peroxide by the 40otrosoopio Method 217
,rodu.4'LW 4° ir? ilroxide fr
the ;;:xelosi3P ot I1jdroo11 snd you
el_gr 3rDerimntp.
(a) :)onoript.oi or gohotion Vonsela 222
(b) :ho Aireot of Vessel Dimensilns an ant
.Zaiapersturo 222
e lemoval of the Heat of losotiln by the
lefripwant 225
xlar*c ZDoed 2h0te7Tqlohg of the iiiethsne-
PWW1
231
•( a) Apparntua
(b) Results °32
ChlaPter 2hroo.
Ju4tory ofporL-ntal crk
"'ritt0P ot 41244-421 1411401" 40
o idatin 11114za.
r4,4% .:e1.11pertr,:y 4rfcatai
Coanidoretin 41
(he :,!'"0 -lee Oxidatiln of Ito 4n4 tAe 04 ' $s iit
24 3
(e) .orbienoo rIr t Simeleoular tiln
+ 02 s u:A300
Mien
)4 :04per4t4r0 4roota)
(vi) ;101.0 4)eridso in the iV000nnon kc4tn7
Lane:king 253
APt0-#
Ineon?late Lixidatitn in ::Jew 2reasure A;Aoaiona 266
(b) Instability or a,w1r0Aul Vorexido fl'o ow
Orvours 27Q
(i) il7iropen-Ox7men loion3 270
(ii) AtethenewOrynen E:pioA3n8 g73
(Zlo faotora Atroatin' t6 'or.LAti)n of
Usiroran Peroxii4 'ow 2*.easure ,441tpl

(n) flenura7 ..!onsiderations 278
(b) Xroot, r);: tLo Rorrigoroll, 1rZour TJ*
ioita 27')
(a) .rfeeta ;onne tad withFla egation 284
(j) :41 ,Amo ',gator in Relation to
lead to t:40 Pros tmee 3r A7drGm eeroxide i vA0
lattetin troJuet 281
:ho -14;tiolpotion of '74o- Ph.4414zn.irraca q:-.:-.ottons •
tho 'Fortiatlon of liyar7en •sitide • 201 •
(r) e asibIe :daftatizm L.koonimatii tor Vilo :01.4ati3n or
4proon iberoxi4o in 4,v r AIL 08i,31.13 298
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