Synergy in supramolecular chemistry PDF
Preview Synergy in supramolecular chemistry
CHEMISTRY SYNERGY IN SYNERGY IN SUPRAMOLECULAR SUPRAMOLECULAR S CHEMISTRY Y N CHEMISTRY Supramolecular chemistry provides very different insights into chemical E events, particularly at nano- and meso-scale levels. In addition, application R of supramolecular chemistry to materials science has recently developed G significantly to give a variety of highly functionalized sensors, molecular Y devices, and polymeric materials. An up-to-date survey of recent progress in this field, Synergy in Supramolecular Chemistry introduces basic concepts I N and examples of supramolecular chemistry in terms of cooperativity and synergy. S U The book draws on an interdisciplinary panel of experts at the frontiers of research to explore non-linear regulation mechanisms useful for controlling P the functions of artificial supramolecules. It begins with a discussion of R the synergistic and cooperative events in the formation of supramolecular A architectures. It then tackles the synergistic and cooperative control of their t M properties and functions in supramolecular sensors and devices, supramo- O lecular catalysts, and supramolecular functional assemblies and polymers. L FEATURES E • Presents information relevant to researchers and students working in a C wide range of nano- and materials science and technology-related fields U • Describes strategies and methods to create functional supramolecules L • Provides examples of supramolecular functions in practical application A • Shares knowledge and presents concepts in supramolecular chemistry R from an interdisciplinary team of experts C These cooperative and synergistic chemical events especially in supra- H molecular chemistry have attracted significant attention from researchers E engaged in organic chemistry, inorganic chemistry, biological chemistry, M polymer chemistry, medicinal chemistry, and other related materials sciences. An interdisciplinary resource, this book draws on experts at the frontiers I S of research to supply examples of supramolecular functions in practical T application and strategies for creating the functional next-generation R supramolecules. Y TAT S U YA N A B E S H I M A K20703 EDITED BY ISBN: 978-1-4665-9502-6 90000 9 781466 595026 K20703_Cover_PubGr.indd All Pages 11/11/14 10:44 AM SYNERGY IN SUPRAMOLECULAR CHEMISTRY SYNERGY IN SUPRAMOLECULAR CHEMISTRY TAT S U YA N A B E S H I M A EDITED BY CRC Press Taylor & Francis Group 6000 Broken Sound Parkway NW, Suite 300 Boca Raton, FL 33487-2742 © 2015 by Taylor & Francis Group, LLC CRC Press is an imprint of Taylor & Francis Group, an Informa business No claim to original U.S. Government works Version Date: 20141008 International Standard Book Number-13: 978-1-4665-9504-0 (eBook - PDF) This book contains information obtained from authentic and highly regarded sources. Reasonable efforts have been made to publish reliable data and information, but the author and publisher cannot assume responsibility for the validity of all materials or the consequences of their use. The authors and publishers have attempted to trace the copyright holders of all material reproduced in this publication and apologize to copyright holders if permission to publish in this form has not been obtained. If any copyright material has not been acknowledged please write and let us know so we may rectify in any future reprint. Except as permitted under U.S. Copyright Law, no part of this book may be reprinted, reproduced, transmit- ted, or utilized in any form by any electronic, mechanical, or other means, now known or hereafter invented, including photocopying, microfilming, and recording, or in any information storage or retrieval system, without written permission from the publishers. 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Visit the Taylor & Francis Web site at http://www.taylorandfrancis.com and the CRC Press Web site at http://www.crcpress.com Contents Contributors .............................................................................................................vii Preface.......................................................................................................................ix Chapter 1 Cooperativity and Synergy in Multi-Metal Supramolecular Systems ...1 Tatsuya Nabeshima Chapter 2 Hierarchically Assembled Titanium(IV) Helicates ...........................19 Markus Albrecht Chapter 3 Supramolecular Hosts and Catalysts Formed by Synergistic Molecular Assemblies of Multinuclear Zinc(II) Complexes in Aqueous Solutions ..............................................................................33 Shin Aoki, Mohd Zulkefeli, Masanori Kitamura, and Yosuke Hisamatsu Chapter 4 Supramolecular Assemblies Based on Interionic Interactions ...........57 Hiromitsu Maeda Chapter 5 Chemosensitive Soft Materials Based on Thermosensitive Polymers ....75 Shogo Amemori, Kazuya Iseda, Kenta Kokado, and Kazuki Sada Chapter 6 Synergistic Effect on Superlattice Formation in Self-Assembled Monolayers at Liquid–Solid Interfaces ..............................................91 Kazukuni Tahara, Steven De Feyter, and Yoshito Tobe Chapter 7 Polymeric Architectures Formed by Supramolecular Interactions .....111 Takeharu Haino Chapter 8 Self-Assembled Molecular Capsule .................................................133 Dariush Ajami Chapter 9 Synergistic Effects in Double Helical Foldamers ............................149 Yun Liu and Amar H. Flood v vi Contents Chapter 10 Ion Pair Templation Strategies for Synthesis of Interlocked Molecules .........................................................................................173 Graeme T. Spence and Bradley D. Smith Chapter 11 Synergy of Reactivity and Stability in Nanoscale Molecular Architectures ....................................................................................191 Kei Goto Chapter 12 Supramolecular Catalyst with Substrate Binding Sites ....................219 Yoshinori Takashima and Akira Harada Chapter 13 Supramolecular Functions of Cyclodextrin Complex Sensors for Sugar Recognition in Water .............................................................235 Hiroyuki Kobayashi, Takashi Hashimoto, and Takashi Hayashita Chapter 14 Design of Chirality-Sensing Systems Based on Supramolecular Transmission of Chirality .................................................................247 Ryo Katoono Chapter 15 Fundamental Aspects of Host–Guest Complexation Synergistic Binding .............................................................................................261 Keiji Hirose Chapter 16 Supramolecular Chemistry Strategies for Naked-Eye Detection and Sensing ......................................................................................301 Kamaljit Singh, Paramjit Kaur, Hiroyuki Miyake, and Hiroshi Tsukube Chapter 17 Self-Assembled Catenanes, Knots, and Links and Synergistic Effects of Weak Interactions ............................................................321 Loïc J. Charbonnière and Ali Trabolsi Contributors Dariush Ajami Takashi Hashimoto Scripps Research Institute Sophia University La Jolla, California Tokyo, Japan Markus Albrecht Takashi Hayashita RWTH Aachen University Sophia University Aachen, Germany Tokyo, Japan Shogo Amemori Keiji Hirose Hokkaido University Osaka University Sapporo, Japan Osaka, Japan Shin Aoki Yosuke Hisamatsu Tokyo University of Science Tokyo University of Science Tokyo, Japan Tokyo, Japan Loïc J. Charbonnière Kazuya Iseda Laboratoire d’Ingénierie Moléculaire Hokkaido University Appliquée à l’Analyse Sapporo, Japan Strasbourg, France Ryo Katoono Steven De Feyter Hokkaido University Katholieke Universiteit Leuven Sapporo, Japan Leuven, Belgium Paramjit Kaur Amar H. Flood Guru Nanak Dev University Indiana University Amritsar, India Bloomington, Indiana Masanori Kitamura Kei Goto Kanazawa University Tokyo Institute of Technology Kanazawa, Japan Tokyo, Japan Hiroyuki Kobayashi Takeharu Haino Sophia University Hiroshima University Tokyo, Japan Hiroshima, Japan Kenta Kokado Akira Harada Hokkaido University Osaka University Sapporo, Japan Osaka, Japan vii viii Contributors Yun Liu Graeme T. Spence Indiana University University of Notre Dame Bloomington, Indiana Notre Dame, Indiana Hiromitsu Maeda Kazukuni Tahara Ritsumeikan University Osaka University Kusatsu, Japan Osaka, Japan Hiroyuki Miyake Yoshinori Takashima Osaka City University Osaka University Osaka, Japan Osaka, Japan Tatsuya Nabeshima Yoshito Tobe University of Tsukuba Osaka University Tsukuba, Japan Osaka, Japan Kazuki Sada Ali Trabolsi Hokkaido University Centre for Science and Engineering Sapporo, Japan New York University Abu Dhabi Abu Dhabi, United Arab Emirates Kamaljit Singh Hiroshi Tsukube Guru Nanak Dev University Osaka City University Amritsar, India Osaka, Japan Bradley D. Smith University of Notre Dame Mohd Zulkefeli Notre Dame, Indiana University Teknologi MARA Selangor, Malaysia
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