240 x 159 /Pantone 2935C & 2735C 27.8mm Wear is a major factor in reducing the safety, reliability and service life of any S u machine with moving parts. This important book reviews the use of coatings to r protect machine components against wear. f a c e The first group of chapters introduces the subject by looking at mechanisms of c surface wear, the mechanical testing of coatings and the range of surface coatings o methods. The bulk of the book reviews the principles, applications, strengths and a t weaknesses of particular coating techniques. There are chapters on chemical and i n physical vapour deposition methods, electroless plating, electroplating, thermal g spraying, welding and laser surface treatments. The book concludes with an s assessment of future trends. f o r With its distinguished editor and international team of contributors, Surface p r coatings for protection against wear will be a standard text for materials and o Surface coatings mechanical engineers with an interest in wear prevention. t e c t Dr Brian Mellor works within the Engineering School of the University of i o for protection Southampton. He is also Technical Manager of the University’s Engineering n Materials Consultancy Service. a g a against wear i n s t w e a r Woodhead Publishing and Maney Publishing on behalf of M The Institute of Materials, Minerals & Mining e l l o r Woodhead Publishing Ltd CRC Press LLC B. G. Mellor Abington Hall 6000 Broken Sound Parkway, NW Abington Suite 300 Cambridge CB1 6AH Boca Raton England FL 33487 www.woodheadpublishing.com USA ISBN-13: 978-1-85573-767-9 CRC order number WP2579 ISBN-10: 1-85573-767-1 ISBN-10: 0-8493-2579-X m3 I The Institute of Materials, Minerals & Mining Surface coatings for protection against wear Related titles: Laser shock peening: Performance and process simulation (ISBN-13: 978-1-85573-929-1; ISBN-10: 1-85573-929-1) Laser shock peening (LSP) is a relatively new surface treatment for metallic materials. LSP is a process to induce compressive residual stresses using shock waves generated by laser pulses. LSP can greatly improve the resistance of a material to crack initiation and propagation brought on by cyclic loading and fatigue. This book is the fi rst to consolidate scattered knowledge into one comprehensive volume. It describes the mechanisms of LSP and its substantial role in improving fatigue performance in terms of modifi cation of microstructure, surface morphology, hardness and strength. In particular it describes numerical simulation techniques and procedures which can be adopted by engineers and research scientists to design, evaluate and optimise LSP processes in practical applications. Solving tribology problems in rotating machines (ISBN-13: 978-1-84569-110-3; ISBN-10: 1-84569-110-5) Bearings are widely used in rotating machines. Understanding the factors affecting their reliability and service life is essential in ensuring good machine design and performance. Solving tribology problems in rotating machines reviews these factors and their implications for improved machine performance. The fi rst two chapters review ways of assessing the performance and reliability of rolling- element bearings. The author then goes on to discuss key performance problems and the factors affecting bearing reliability. There are chapters on cage and roller slip, and particular types of failure in equipment such as alternators, condensers and pumps. The author also reviews the effects of such factors as localised electrical currents, seating, clearance, grades of lubricant, axial forces, vibration on performance and service life. The book concludes by reviewing ways of improving bearing design. Processes and mechanisms of welding residual stress and distortion (ISBN-13: 978-1-85573-771-6; ISBN-10: 1-85573-771-X) Measurement techniques for characterisation of residual stress and distortion have improved signifi cantly. More importantly the development and application of computational welding mechanics have been phenomenal. Through the collaboration of experts, this book provides a comprehensive treatment of the subject. It develops suffi cient theoretical treatments on heat transfer, solid mechanics and materials behaviour that are essential for understanding and determining welding residual stress and distortion. It outlines the approach for computational analysis that engineers with suffi cient background can follow and apply. The book will be useful for advanced analysis of the subject and provides examples and practical solutions for welding engineers. Details of these and other Woodhead Publishing materials books and journals, as well as materials books from Maney Publishing, can be obtained by: • visiting our web site at www.woodheadpublishing.com • contacting Customer Services (e-mail: [email protected]; fax: +44 (0) 1223 893694; tel: +44 (0) 1223 891358 ext. 30; address: Woodhead Publishing Limited, Abington Hall, Abington, Cambridge CB1 6AH, England) If you would like to receive information on forthcoming titles, please send your address details to: Francis Dodds (address, tel and fax: as above; email: francisd@ woodhead-publishing.com). Please confi rm which subject areas you are interested in. Maney currently publishes 16 peer-reviewed materials science and engineering journals. For further information visit www.maney.co.uk/journals. Surface coatings for protection against wear Edited by B.G. Mellor Woodhead Publishing and Maney Publishing on behalf of The Institute of Materials, Minerals & Mining CRC Press Boca Raton Boston New York Washington, DC Woodhead publishing limited Cambridge England Woodhead Publishing Limited and Maney Publishing Limited on behalf of The Institute of Materials, Minerals & Mining Woodhead Publishing Limited, Abington Hall, Abington, Cambridge CB1 6AH, England www.woodheadpublishing.com Published in North America by CRC Press LLC, 6000 Broken Sound Parkway, NW, Suite 300, Boca Raton, FL 33487, USA First published 2006, Woodhead Publishing Limited and CRC Press LLC © 2006, Woodhead Publishing Limited, except Chapter 2 which is © Crown Copyright The authors have asserted their moral rights. This book contains information obtained from authentic and highly regarded sources. Reprinted material is quoted with permission, and sources are indicated. Reasonable efforts have been made to publish reliable data and information, but the authors and the publishers cannot assume responsibility for the validity of all materials. Neither the authors nor the publishers, nor anyone else associated with this publication, shall be liable for any loss, damage or liability directly or indirectly caused or alleged to be caused by this book. Neither this book nor any part may be reproduced or transmitted in any form or by any means, electronic or mechanical, including photocopying, microfi lming and recording, or by any information storage or retrieval system, without permission in writing from Woodhead Publishing Limited. The consent of Woodhead Publishing Limited does not extend to copying for general distribution, for promotion, for creating new works, or for resale. Specifi c permission must be obtained in writing from Woodhead Publishing Limited for such copying. Trademark notice: Product or corporate names may be trademarks or registered trademarks, and are used only for identifi cation and explanation, without intent to infringe. British Library Cataloguing in Publication Data A catalogue record for this book is available from the British Library. Library of Congress Cataloging in Publication Data A catalog record for this book is available from the Library of Congress. Woodhead Publishing ISBN-13: 978-1-85573-767-9 (book) Woodhead Publishing ISBN-10: 1-85573-767-1 (book) Woodhead Publishing ISBN-13: 978-1-84569-156-1 (e-book) Woodhead Publishing ISBN-10: 1-84569-156-3 (e-book) CRC Press ISBN-10: 0-8493-2579-X CRC Press order number: WP2579 The publishers’ policy is to use permanent paper from mills that operate a sustainable forestry policy, and which has been manufactured from pulp which is processed using acid-free and elementary chlorine-free practices. Furthermore, the publishers ensure that the text paper and cover board used have met acceptable environmental accreditation standards. Typeset by SNP Best-set Typesetter Ltd., Hong Kong Printed by TJ International Limited, Padstow, Cornwall, England Contents Contributor contact details ix Preface xi 1 Understanding surface wear in engineering materials 1 R.J.K. Wood, University of Southampton, UK 1.1 Introduction 1 1.2 Role of stress distributions in wear 2 1.3 Wear in tribocontacts 6 1.4 Stress fi elds for coated systems 40 1.5 Conclusions 48 1.6 References 48 1.7 Appendix: Nomenclature 55 2 Mechanical testing of coatings 58 N.M. Jennett and M.G. Gee, National Physical Laboratory, UK 2.1 Introduction 58 2.2 Thickness 59 2.3 Fracture and adhesion testing 62 2.4 Scratch testing 66 2.5 Instrumented indentation testing 68 2.6 Impact excitation 73 2.7 Surface acoustic wave spectroscopy 73 2.8 Residual stress measurement 76 2.9 Conclusions 77 2.10 References 77 3 The range of surface coating methods 79 P.H. Shipway, University of Nottingham, UK 3.1 Introduction 79 v vi Contents 3.2 Basic classifi cation of processes employed for coating 80 3.3 Processes: coatings deposited on to the substrate 81 3.4 Processes: coatings formed by reactions involving the substrate 91 3.5 Comparison of the methods 94 3.6 Future trends 97 3.7 References 98 3.8 Further reading 98 4 Chemical vapour deposition methods for protection against wear 101 D.W. Wheeler, Atomic Weapons Establishment, UK 4.1 Introduction 101 4.2 The chemical vapour deposition process 102 4.3 Factors affecting the coating characteristics 108 4.4 Advantages and disadvantages of chemical vapour deposition 110 4.5 Plasma-assisted chemical vapour deposition 111 4.6 Hard coatings produced by chemical vapour deposition 112 4.7 Conclusions 132 4.8 Future trends 135 4.9 Sources of further information 136 4.10 Acknowledgements 137 4.11 References 137 5 Physical vapour deposition methods for protection against wear 146 S.J. Bull, University of Newcastle, UK 5.1 Introduction 146 5.2 Fundamentals of physical vapour deposition 147 5.3 Commercial physical vapour deposition processes 156 5.4 Coatings for wear resistance 164 5.5 Applications 171 5.6 Future trends 178 5.7 References 179 6 Electroless plating for protection against wear 184 C. Ponce de León, University of Southampton, UK, C. Kerr, Tin Technology Ltd, UK, and F.C. Walsh, University of Southampton, UK 6.1 Introduction 184 6.2 Electrolyte composition and operating conditions 192 Contents vii 6.3 Characteristics of electroless deposits 195 6.4 Conclusions 217 6.5 References 219 6.6 Appendix: Professional associations 224 7 Electroplating for protection against wear 226 R.G.A. Wills and F.C. Walsh, University of Southampton, UK 7.1 Introduction 226 7.2 Electrodeposited metallic coatings 232 7.3 Electrodeposited composite coatings 240 7.4 Anodised coatings on light metals 241 7.5 Conclusions and further reading 241 7.6 References 245 7.7 Appendix: Professional associations 247 8 Thermal spraying methods for protection against wear 249 J.M. Guilemany and J. Nin, Universitat de Barcelona, Spain 8.1 Introduction 249 8.2 Thermal spray process fundamentals 256 8.3 Coating structures 266 8.4 Post-spray treatments 272 8.5 Structure–property relationships 272 8.6 Industrial applications 283 8.7 Unsuccessful coatings and applications 288 8.8 Future trends 290 8.9 References 293 9 Welding surface treatment methods for protection against wear 302 B.G. Mellor, University of Southampton, UK 9.1 Introduction 302 9.2 Welding processes suitable for hardfacing 303 9.3 Nature of the deposit 310 9.4 Hardfacing materials 315 9.5 Hardfacing alloy selection 360 9.6 Hardfacing process selection 361 9.7 Distortion and residual stresses 366 9.8 Successful and unsuccessful applications 369 9.9 Conclusions 370 9.10 References 370 viii Contents 10 Laser surface treatment methods for protection against wear 377 H.C. Man, Hong Kong Polytechnic University, Hong Kong, PR China 10.1 Introduction 377 10.2 Operation principles 377 10.3 Lasers for laser surface engineering 380 10.4 Advantages and limitations of laser surface engineering 381 10.5 Applications on ferrous alloys 382 10.6 Applications on aluminium alloys 383 10.7 Applications on titanium alloys 386 10.8 Conclusions 388 10.9 References 390 11 Future trends in surface coatings for protection against wear 392 A.O. Kunrath, D. Zhong, B. Mishra and J.J. Moore, Colorado School of Mines, USA 11.1 Introduction 392 11.2 Coating materials 392 11.3 Coating architectures 394 11.4 Smart systems 399 11.5 New processes 401 11.6 Conclusions 408 11.7 References 408 Index 415 Contributor contact details Chapter 1 NG7 2RD UK Professor R.J.K. Wood School of Engineering Sciences Email: philip.shipway@nottingham. University of Southampton ac.uk Highfi eld Southampton Chapter 4 SO17 1BJ UK Dr D.W. Wheeler Atomic Weapons Establishment Email: [email protected] Aldermaston Reading Chapter 2 Berkshire RG7 4PR Dr N.M. Jennett and Dr M.G. Gee UK National Physical Laboratory Hampton Road Email: [email protected] Teddington Middlesex Chapter 5 TW11 0LW UK Professor S.J. Bull Chemical Engineering and Email: [email protected] Advanced Materials Email: [email protected] University of Newcastle NE1 7RU Chapter 3 UK Professor P.H. Shipway Email: [email protected] School of Mechanical, Materials and Manufacturing Engineering Chapter 6 University of Nottingham University Park Dr C. Ponce de León and Nottingham Professor F.C. Walsh ix
Description: