Surface and Interfacial Organometallic Chemistry and Catalysis PDF
Preview Surface and Interfacial Organometallic Chemistry and Catalysis
16 Topics in Organometallic Chemistry Editorial Board: J. M. Brown · P. H. Dixneuf · A. Fürstner · L. S. Hegedus P. Hofmann · P. Knochel · G. van Koten · S. Murai · M. Reetz Topics in Organometallic Chemistry Recently Published and Forthcoming Volumes Surface and Interfacial Organometallic Metallocenes in Stereoselective Synthesis Chemistry and Catalysis Volume Editor: T. Takahashi Volume Editors: C. Copéret, B. Chaudret Vol. 8, 2004 Vol. 16, 2005 Transition Metal Arene π-Complexes in Organic Chiral Diazaligands for Asymmetric Synthesis Synthesis and Catalysis Volume Editors: M. Lemaire, P. Mangeney Volume Editor: E. P. Kündig Vol. 15, 2005 Vol. 7, 2004 Palladium in Organic Synthesis Organometallics in Process Chemistry Volume Editor: J. Tsuji Volume Editor: R. D. Larsen Vol. 14, 2005 Vol. 6, 2004 Metal Carbenes in Organic Synthesis Organolithiums in Enantioselective Synthesis Volume Editor: K. H. Dötz Volume Editor: D. M. Hodgson Vol. 13, 2004 Vol. 5, 2003 Theoretical Aspects of Transition Metal Catalysis Organometallic Bonding and Reactivity: Volume Editor: G. Frenking Fundamental Studies Vol. 12, 2005 Volume Editor: J. M. Brown, P. Hofmann Vol. 4, 1999 Ruthenium Catalysts and Fine Chemistry Volume Editors: C. Bruneau, P. H. Dixneuf Activation of Unreactive Bonds and Organic Vol. 11, 2004 Synthesis Volume Editor: S. Murai New Aspects of Zirconium Containing Organic Vol. 3, 1999 Compounds Volume Editor: I. Marek Lanthanides: Chemistry and Use in Organic Vol. 10, 2004 Synthesis Volume Editor: S. Kobayashi Precursor Chemistry of Advanced Materials Vol. 2, 1999 CVD, ALD and Nanoparticles Volume Editor: R. Fischer Alkene Metathesis in Organic Synthesis Vol. 9, 2005 Volume Editor: A. Fürstner Vol. 1, 1998 Surface and Interfacial Organometallic Chemistry and Catalysis Volume Editors: Christophe Copéret · Bruno Chaudret With contributions by J.-M. Basset · F. Bonino · S. Bordiga · R. L. Brutchey · J.-P. Candy B. Chaudret · C. Copéret · A. Damin · H.-J. Freund · K. L. Fujdala B. C. Gates · E. Groppo · C. Lamberti · C. Prestipino · T. Risse A. Roucoux · T. D. Tilley · A. Zecchina 123 The series Topics in Organometallic Chemistry presents critical reviews of the present and future trends in polymer and biopolymer science including chemistry, physical chemistry, physics and material science. It is adressed to all scientists at universities and in industry who wish to keep abreast of advances in the topics covered. As a rule, contributions are specially commissioned. The editors and publishers will, however, always be pleased to receive suggestions and supplementary information. Papers are accepted for Topics in Organometallic Chemistry in English. In references Topics in Organometallic Chemistry is abbreviated Top Organomet Chem and is cited as a journal. Springer WWW home page: http://www.springeronline.com Visit the TOMC content at http://www.springerlink.com/ Library of Congress Control Number: 2005928333 ISSN 1436-6002 ISBN-10 3-540-26496-5 Springer Berlin Heidelberg New York ISBN-13 978-3-540-26496-5 Springer Berlin Heidelberg New York DOI 10.1007/b105251 This work is subject to copyright. All rights are reserved, whether the whole or part of the material is concerned, specifically the rights of translation, reprinting, reuse of illustrations, recitation, broad- casting, reproduction on microfilm or in any other way, and storage in data banks. Duplication of this publication or parts thereof is permitted only under the provisions of the German Copyright Law of September 9, 1965, in its current version, and permission for use must always be obtained from Springer. Violations are liable for prosecution under the German Copyright Law. Springer is a part of Springer Science+Business Media springeronline.com ⃝c Springer-Verlag Berlin Heidelberg 2005 Printed in Germany The use of registered names, trademarks, etc. in this publication does not imply, even in the absence of a specific statement, that such names are exempt from the relevant protective laws and regulations and therefore free for general use. Cover design: Design & Production GmbH, Heidelberg Typesetting and Production: LE-TEX Jelonek, Schmidt & Vöckler GbR, Leipzig Printed on acid-free paper 02/3141 YL – 5 4 3 2 1 0 Volume Editors Christophe Copéret Bruno Chaudret Laboratoire de Chimie Organometallique Laboratoire de Chimie de Coordination de Surface du CNRS 43 Bd du 11 Novembre 1918 route de Narbonne 69616 Villeurbanne, France 31077 Toulouse Cédex 04, France Topics in Organometallic Chemistry Also Available Electronically For all customers who have a standing order to The Handbook of Environmen- tal Chemistry, we offer the electronic version via SpringerLink free of charge. Please contact your librarian who can receive a password or free access to the full articles by registering at: springerlink.com If you do not have a subscription, you can still view the tables of contents of the volumes and the abstract of each article by going to the SpringerLink Home- page, clicking on “Browse by Online Libraries”, then “Chemical Sciences”, and finally choose The Handbook of Environmental Chemistry. You will find information about the – Editorial Board – Aims and Scope – Instructions for Authors – Sample Contribution at springeronline.com using the search function. Preface Molecular chemistry has laid down the rules for understanding and prepar- ing well-defined organometallic and metallo-organic complexes that have been central to the development of homogeneous catalysts. The goal of this book is to show that molecular chemistry is also a tool for studying much larger systems, such as those involved in heterogeneous catalysis. Heterogeneous catalysts are typically made of oxide materials, metallic particles, or organometallic com- ponents. While the main part of the catalyst is constituted by the bulk of the material, the catalytic events take place at the interface between the reactant phase and the surface of the material, and more specifically at the active sites. Thus, these systems correspond to large ensembles of atoms (metal particles or oxides), which are composed of organometallic and metallo-organic build- ing blocks, and active sites, which can be described as organometallic and metallo-organic centres. It is therefore obvious that molecular organometallic (and inorganic) chemistry must play an essential role in the field of hetero- geneous catalysis whether discussing the method of preparation of catalysts, the understanding of catalytic phenomena on surfaces, or the rational devel- opment of better catalysts. In this book, we have therefore addressed these various questions through selected examples. The first two chapters focus on the molecular understanding of known industrial heterogeneous catalysts. The third contribution discusses the synthesis and the properties of tailored oxide materials. The next paper addresses the use of surface science as a tool for un- derstanding the active sites of heterogeneous catalysts. The fifth chapter tack- les the preparation of well-defined active sites through surface organometallic chemistry and their relation to the understanding of industrial processes. The sixth contribution discusses the use of metal clusters as a model of metallic particles. Finally, the remaining two chapters focus on the use of well-defined organometallic complexes for the synthesis of nanoparticles and their use in catalysis. Villeurbanne, Toulouse, Bruno Chaudret September 2005 and Christophe Copéret Contents Anatomy of Catalytic Centers in Phillips Ethylene Polymerization Catalyst A. Zecchina · E. Groppo · A. Damin · C. Prestipino . . . . . . . . . . . . 1 Single Site Catalyst for Partial Oxidation Reaction: TS-1 Case Study S. Bordiga · A. Damin · F. Bonino · C. Lamberti . . . . . . . . . . . . . . 37 Tailored Oxide Materials via Thermolytic Molecular Precursor (TMP) Methods K. L. Fujdala · R. L. Brutchey · T. D. Tilley . . . . . . . . . . . . . . . . . 69 Spectroscopic Characterization of Organometallic Centers on Insulator Single Crystal Surfaces: From Metal Carbonyls to Ziegler–Natta Catalysts T. Risse · H.-J. Freund . . . . . . . . . . . . . . . . . . . . . . . . . . . . 117 Analogy between Surface and Molecular Organometallic Chemistry J.-P. Candy · C. Copéret · J.-M. Basset . . . . . . . . . . . . . . . . . . . 151 Oxide- and Zeolite-supported “Molecular” Metal Clusters: Synthesis, Structure, Bonding, and Catalytic Properties B. C. Gates . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 211 Synthesis and Surface Reactivity of Organometallic Nanoparticles B. Chaudret . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 233 Stabilized Noble Metal Nanoparticles: An Unavoidable Family of Catalysts for Arene Derivative Hydrogenation A. Roucoux . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 261 Author Index Volumes 1–16 . . . . . . . . . . . . . . . . . . . . . . . . 281 Subject Index . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 289
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