Supplements / Erganzungen

545 Pages·2011·14.666 MB·English

by  Rolf K. Freier

Rolf Κ. Freier
Aqueous Solutions
Wäßrige Lösungen
2

Rolf K.Freier
Aqueous Solutions
Data for
Inorganic
and Organic
Compounds
Vol. 2 Supplements
Wäßrige Lösungen
Daten für
Anorganische
und Organische
Verbindungen
Bd. 2 Ergänzungen
w
GDE _
Walter de Gruyter · Berlin · New York 1978
Editor/Herausgeber Publisher/Verlag
Dr.-Ing. Rolf K. Freier Walter de Gruyter & Co
Diplom-Ingenieur, Diplom-Chemiker Genthiner Straße 13
Handlungsbevollmächtigter im Hause D-1000 Berlin 30
Hamburgische Electricitäts-Werke AG
Andreas-Meyer-Straße 8 Walter de Gruyter Inc.
D-2000 Hamburg 74 3 Westchester Plaza
Elmsford, N.Y. 10523, USA
Private address/Privatanschrift
Ilsenweg 28
D-2000 Hamburg 65
Library of Congress Cataloging in Publication Data
Freier, Rolf Kurt.
Aqueous solutions.
Bibliography: v. 2, p.
Includes index.
1. Solution (Chemistry)-Tables. I. Title.
II. Title: Wäßrige Lösungen.
QD541.F73 54Γ.3422Ό212 75-34201
ISBN 3-11-001627-3 (v. 1)
CIP-Kurztitelaufnahme der Deutschen Bibliothek
Freier, Rolf K.
Aqueous solutions: data for inorganic and organic compounds =
Wäßrige Lösungen. - Berlin, New York: de Gruyter.
Vol. 2. Supplements. - 1. Aufl. - 1977.
ISBN 3-11-006537-1
© Copyright 1977 by Walter de Gruyter & Co., Berlin. - All rights reserved, including those of
translation into foreign languages. No part of this book may be reproduced in any form - by
photoprint, microfilm, or any other means - nor transmitted nor translated into a machine
language without written permission from the publisher.
Typesetting: Fotosatz Tutte, Salzweg-Passau. - Printing: Grafik + Druck, München. - Binding:
Lüderitz & Bauer, Berlin. - Cover design: T. Bonnie, Hamburg. Printed in Germany.
© Copyright 1977 by Walter de Gruyter & Co., vormals G.J. Göschen'sehe Verlagshandlung,
J. Guttentag, Verlagsbuchhandlung, Georg Reimer, Karl J. Trübner, Veit & Comp., Berlin30.
Alle Rechte, insbesondere das Recht der Vervielfältigung und Verbreitung sowie der Über-
setzung, vorbehalten. Kein Teil des Werkes darf in irgendeiner Form (durch Photokopie, Mikro-
film oder ein anderes Verfahren) ohne schriftliche Genehmigung des Verlages reproduziert oder
unter Verwendung elektronischer Systeme verarbeitet, vervielfältigt oder verbreitet werden.
Printed in Germany.
Satz: Fotosatz Tutte, Salzweg-Passau. - Druck: Grafik + Druck, München. - Bindearbeiten:
Lüderitz & Bauer, Berlin. - Einbandentwurf: T. Bonnie, Hamburg.
Preface
The two volumes aim to bring together into a single work all data, at present
scattered through numerous literary works, on the physical and chemical quali-
ties of water - especially its great significance as a solvent.
Volume 1 contains primarily the solubilities and redox potentials of important
inorganic and organic compounds. The compounds marked by an asterisk (*)
refer to volume 2 (supplement). There the user will find further information.
Volume 2 contains mainly excerpts from important texts, tables, illustrations,
equations of reaction etc. from original papers - besides other extensive information.
Therefore the two volumes represent a compact collection of data on the physical
and in particular the chemical values of water.
It is not possible for a collection of this kind to be complete. The editor and
publisher therefore invite the user to send them any relevant data which would
serve to supplement the present edition. Any other critical comments will also be
gratefully received.
The editor wishes to express his thanks to
the officers of the Hamburgische Electricitäts-Werke AG, Hamburg, for their
understanding support of this collection, the Verlag Walter de Gruyter, Ber-
lin, New York, for editorial support,
Messrs. Richard Fröschel and Hans Adolf Heß for researching the often
very disparate literature sources,
and all authors listed and not listed.
Hamburg, Autumn 1977 Rolf K. Freier
Vorwort
Das Tabellenwerk hat zum Ziel, die in der Literatur verstreut liegenden Daten
über die physikalisch-chemischen Eigenschaften des Wassers - vor allem in seiner
überragenden Bedeutung und Rolle als Lösungsmittel - an einer Stelle zu kon-
zentrieren.
Band 1 enthält im wesentlichen die Löslichkeiten wichtiger anorganischer und
organischer Verbindungen sowie deren Redoxpotentiale. Die mit einem Stern (*)
gekennzeichneten Stellen verweisen auf den Band 2 (Ergänzungsband) dieses Ta-
bellenwerkes. Der Benutzer findet dort weitere Informationen.
Band 2 enthält im wesentlichen wichtige Textauszüge, Tabellen, Abbildungen,
Reaktionsgleichungen usw. aus Originalbeiträgen der Literatur - neben einer Viel-
zahl anderer Informationen.
Das zweibändige Werk stellt somit eine geschlossene Sammlung von Daten physi-
kalischer und insbesondere chemischer Größen des Wassers dar.
Eine Sammlung dieser Art kann natürlich nicht vollständig sein. Herausgeber und
Verlag bitten daher um Zuschriften, die geeignet sind, die Datensammlung sinn-
voll zu ergänzen. Auch für jeden sonst kritischen Hinweis sind Herausgeber und
Verlag dankbar.
Der Herausgeber ist sehr zu Dank verpflichtet
dem Vorstand der Hamburgischen Electricitäts-Werke AG, Hamburg, für die
verständnisvolle Förderung des Tabellenwerkes
dem Verlag Walter de Gruyter, Berlin, New York, für seine Unterstützung
bei der redaktionellen Bearbeitung und Gestaltung, den Herren Dipl.-Ing.
Richard Fröschel und Chemotechniker Hans Adolf Heß für die Verarbei-
tung der vielfach unterschiedlichen Literaturquellen
und allen genannten und ungenannten Autoren.
Hamburg, Herbst 1977 Rolf K. Freier
Table of Contents
Inorganic Compounds
Ag Solubility of Ag20. Hydrolysis of Ag+ ions
Oligodynamic Ag Effect
AgF Hydrates of AgF. Anhydrous AgF
AgF Density of AgF and AgN03 solutions
AgN0
3
Ag20 Hydrolysis of Ag+ ions
AgOH Reaction of Ag20 and AgOH with water
(AgO ")
Ag2S Thiocomplexes of silver
Ag2S03 Formation of complex salts
.3AI Solubility of aluminum oxide and its hydrates (effect of pH)
Oxidation of Al
ALCL, Densities of A1C13 solutions
A1K(S04)2 Density of alum solutions
CrK(S0)
42
A1(N03)3 Density of A1(N03)3 solutions
A1NH4(S04)2 Density of A1NH4(S04)2 solutions
AI2(SO4)3 Density of A12(S04)3 solutions
18 Ar Solubility of the noble gases in water
AS203 Reaction of As203 with water
Dissociation constant of As(OH)3
Densities of As203 solutions
H3AS03 Dissociation constants of H3As03
H3AS04 Reaction of As205 with water
Densities of H3As04 solutions
79AU Reactions of Au3+, Au203 and Au(OH)3 with water
AUC13 Densities of AUC13 solutions
AU203 s. 79AU, page 6
BCI3 Boiling point of BCI3
HBF4 Formation and boiling point of HBF4
VIII
HB0 Properties of HB0: spec, conductivity, dissociation constants, hydrolysis of its salts, solubility of B0,
3 3 3 3 2 3
chemical reactions 7
Distribution of species in boric acid solutions 8
Equilibrium quotients of boric acid. Dependence on temperature and ionic strength 9
Dependence of the pH of boric acid solutions on the temperature 9
Densities of boric acid solutions 10
Boric acid equilibria. Ionization constants as a function of temperature 10
BNH Properties of BNH 11
3 3 6 3 3 6
B0 Properties of B0 11
2 3 2 3
Ba Oxidation of Ba 11
56
BaBr Densities of barium halide solutions 12
2
BaCI
2
Bal
2
Ba(CHC0) Various hydrates of Ba(CHC0) 12
3 22 3 22
Ba(N0) Densities of Ba(N0) solutions 12
32 32
BaO Hydrolysis of Ba2 + ions to BaO 12
Ba(OH) Densities of Ba(OH) solutions 13
2 2
Ba(OH) · 8H0 Hydrolysis of Ba2+ ions 13
2 2
<Be Reactions of Be0~ ions 13
2 3
BeCl Densities of Be salt solutions 13
2
Be(N0) s. BeCl, page 13
32 2
BeO Reaction of BeO with water 14
BeS0 s. BeCl, page 13
4 2
3jBr Solubility of bromine in water. Bromine hydrates 14
Solubility of gasous bromine in water 14
Densities of bromine solutions 15
HBr Solubility of HBr in water (effect of pH) 15
HBr Densities of HBr and HC10 solutions 16
3
HCIO3
HBrO Dissociation of HBrO at various temperatures 16
C Oxidation potential of C to CO and to C0 16
6 2
CO Properties of CO at low temperatures 16
Solubility of CO in water, pressure 760 Torr 17
IX
CO, Solubility of C02 in water when the gas and saturation pressure of the water is 760 Torr 17
Solubility of C02 in water under pressure 18
pH values of C02 solutions 18
Dissociation constants of H2C03 19
Solubility of C02 and redox potential 19
Analysis of carbonic acid in water 19
Method I (total ion concentration < 100 mg/'l) 19
Method II (total ion concentration > 100 mg/1) 20
Ionic strength 20
Description of the mass action equilibria 21
pH functions of carbonic acid solutions 23
Lime-carbonic acid equilibrium 24
Tillman's Law constants: C02—CaO equilibrium (mval2), [(C02 mg/1) CaO d], 24, 25
Table for determination of free carbonic acid and equilibrium pH from the concentrations of bicarbonate
(hydrogencarbonate) and calcium oxide 26
Electrical conductivity of carbonic acid in chemically pure water (20 =C) 27
Reactions of C02 with water 27
Partition coefficients of C02 as a function of temperature or pH 28
C02 content of water drops 29
pH values of pure solutions of C02 and NaOH at 25=C 29
The equivalence factor of carbonic acid at 25 °C 29
Melting and boiling points of C02 29
Dependence of pH on carbonate hardness (hydrogencarbonate concentration) of water 30
CO 2 partial pressure over carbonate and bicarbonate (hydrogencarbonate) solutions 30
Solubility of water in liquid C02 31
Carbonated water for soft drinks 31
Carbonic acid for impregnating 31
Conductivity of C02 in water 32
The system H20—CaO— C02 33
Parameters of C02 in water 34
Absorption of C02 from the air by pure water 35
Relation of the HC03 and COf" concentrations to the C02 pressure 35
COS Melting and boiling points of COS 35
Ca3(As04)2 Reaction of Ca3(As04)2 with C02 35
CaBr2 Melting and boiling points of CaBr2 35
CaCl
Cal 2 Densities of CaBr2, CaCl2 and Cal2 solutions 36
2
CaCN2 Reactions of CaCN2 in water 36
CaCOs Solubility of CaC03 under various conditions 36
Solubility of CaC03 at various partial pressures of C02 37
Water hardness
Conversion factors for various hardness scales 37
Drinking water hardness 37
Hardness of drinking water in various countries: % of population affected 37