Supercapacitors and Their Applications: Fundamentals, Current Trends, and Future Perspectives PDF
Preview Supercapacitors and Their Applications: Fundamentals, Current Trends, and Future Perspectives
Supercapacitors and Their Applications Owing to their high power density, long life, and environmental compatibility, super- capacitors are emerging as one of the promising storage technologies, but with chal- lenges around energy and power requirements for specific applications. This book focuses on supercapacitors including details on classification, charge storage mecha- nisms, related kinetics, and thermodynamics. Materials used as electrodes, electro- lytes, and separators, procedures followed, characterization methods, and modeling are covered, along with emphasis on related applications. Features: • Provides an in-depth look at supercapacitors, including their working con- cepts and design • Reviews detailed explanation of various characterization and modeling techniques • Gives special focus to the application of supercapacitors in major areas of environmental as well as social importance • Covers cyclic voltammetry, charging–discharging curves, and electrochem- ical impedance spectroscopy as characterization techniques • Includes a detailed chapter on historical perspectives on the evolution of supercapacitors This book is aimed at researchers and graduate students in materials science and engineering, nanotechnology, chemistry in batteries, and physics. Supercapacitors and Their Applications Fundamentals, Current Trends, and Future Perspectives Edited by Anjali Paravannoor and Baiju K. V. First edition published 2023 by CRC Press 6000 Broken Sound Parkway NW, Suite 300, Boca Raton, FL 33487-2742 and by CRC Press 4 Park Square, Milton Park, Abingdon, Oxon, OX14 4RN CRC Press is an imprint of Taylor & Francis Group, LLC © 2023 selection and editorial matter, Anjali Paravannoor and Baiju K.V.; individual chapters, the contributors Reasonable efforts have been made to publish reliable data and information, but the author and publisher cannot assume responsibility for the validity of all materials or the consequences of their use. The authors and publish- ers have attempted to trace the copyright holders of all material reproduced in this publication and apologize to copyright holders if permission to publish in this form has not been obtained. If any copyright material has not been acknowledged please write and let us know so we may rectify in any future reprint. 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ISBN: 9781032192604 (hbk) ISBN: 9781032192628 (pbk) ISBN: 9781003258384 (ebk) DOI: 10.1201/9781003258384 Typeset in Times by Deanta Global Publishing Services, Chennai, India Contents Editor Biographies ...................................................................................................vii Contributors ..............................................................................................................ix Preface.......................................................................................................................xi Chapter 1 Historical Perspectives .........................................................................1 Vijila Kalarivalappil and Baiju Kizhakkekilikoodayil Vijayan Chapter 2 Electric Double-Layer Capacitors ......................................................17 Shyamli Ashok, Deepu Joseph, Jasmine Thomas, Nygil Thomas and Anjali Paravannoor Chapter 3 Fundamentals of Pseudocapacitors ....................................................33 Shyamli Ashok, Deepu Joseph, Jasmine Thomas and Nygil Thomas Chapter 4 Looking Deeper into Electrode Processes .........................................49 Sindhu Thalappan Manikkoth, Fabeena Jahan, Deepthi Panoth, Anjali Paravannoor, and Baiju Kizhakkekilikoodayil Vijayan Chapter 5 Design Considerations ........................................................................71 Mijun Chandran, Asha Raveendran, Mari Vinoba, and Margandan Bhagiyalakshmi Chapter 6 Characterization Techniques ..............................................................87 Deepthi Panoth, Kunnambeth M. Thulasi, Fabeena Jahan, Sindhu Thalappan Manikkoth, Divya Puthussery, Baiju Kizhakkekilikoodayil Vijayan, and Anjali Paravannoor Chapter 7 Design, Fabrication, and Operation .................................................105 Sudhakar Y. N., Shilpa M. P., Shivakumar Shetty, Sreejesh M., Shridhar Mundinamani, Margandan Bhagiyalakshmi, and Gurumurthy S. C. v vi Contents Chapter 8 Conventional Applications of Supercapacitors ................................119 Gopakumar G. and S. Anas Chapter 9 Portable Electronics and Microsupercapacitors ...............................137 Gopakumar G., Sujith K. V., Sarayu Jayadevan, and S. Anas Chapter 10 Electric and Hybrid Electric Vehicle ................................................147 Sruthi Maruthiyottu Veettil, Sindhu Thalappan Manikkoth, Anjali Paravannoor, and Baiju Kizhakkekilikoodayil Vijayan Chapter 11 Power Harvesting and Storage System: Supercapacitors Aiding New and Renewable Energy Generation ..........................................161 Nijisha P. and Shidhin M. Chapter 12 Market Trends, Innovations and Challenges ....................................181 Anjali Paravannoor Index ......................................................................................................................201 Editor Biographies Dr Anjali Paravannoor is currently working as a DST-INSPIRE faculty at Kannur University, Kerala, India. She earned her PhD degree (2015) in Nanomaterials from Amrita Viswavidyapeetham University, Ettimadai, India. She received her master’s degree in Nanoscience and Technology from Bharathiar University, Coimbatore, India. Over the last ten years, she has been actively involved in research in the field of supercapacitor systems. She has more than 30 publications in peer-reviewed inter- national journals and several book chapters in the area of energy generation and storage. Currently, she is working on 2D nanostructures for pseudocapacitor applica- tions. Her research interests also include the development of novel anode materials for lithium-ion and sodium-ion battery applications. Dr Baiju Kizhakkekilikoodayil Vijayan is currently working as an Assistant Professor at Kannur University, Kerala, India. He has worked as a Scientist at the Centre for Materials for Electronics Technology, Thrissur, India, which is a research and development laboratory under the Ministry of Electronics and Information Technology, Government of India, from 2011 to 2016. He also worked as a Post- Doctoral Associate in North-Western University, Evanston, Illinois, USA, from October 2008 to April 2011, in the area of photocatalytic reduction of carbon dioxide to fuel. He earned his PhD from the National Institute of Interdisciplinary Science and Technology, formerly known as RRL Trivandrum, India, on the topic of sol-gel synthesis of nanomaterials in 2008. To his credit he has more than 60 published papers (>3500 citations) in peer-reviewed international journals and 7 patents. He is currently working in the area of nanostructured materials for catalyst, photocatalyst, supercapacitor, and solar cell applications. vii Contributors Shyamili Ashok Kunnambeth M. Thulasi Department of Chemistry School of Chemical Sciences Nirmalagiri College Kannur University Kannur, India Payyanur, India Margandan Bhagiyalakshmi Shidhin M. Department of Chemistry Central European Institute of Central University of Kerala Technology Kerala, India Brno University of Technology Brno, Czech Republic Mijun Chandran Department of Chemistry Sreejesh M. Central University of Tamil Nadu Centre for Nano and Soft Matter Thiruvarur, India Sciences (CeNS) Bangalore, India Gopakumar G. Department of Chemistry Sindhu Thalappan Manikkoth University of Kerala School of Chemical Sciences Kollam, India Kannur University Payyanur, India Fabeena Jahan School of Chemical Sciences Sruthi Maruthiyottu Veettil Kannur University Central NMR Facility Payyanur, India CSIR – National Chemical Laboratory Pune, India Sarayu Jayadevan Department of Chemistry Shridhar Mundinamani Sir Syed College Department of Physics Taliparamba, India Siddaganga Institute of Technology Tumakuru, India Deepu Joseph Department of Physics Shilpa M. P. Nirmalagiri College Department of Physics, Kannur, India Manipal Institute of Technology Manipal, India Vijila Kalarivalappil Basic Science and Humanities Nijisha P. Division School of Chemical Sciences Indian Naval Academy Kannur University Kannur, India. Payyanur, India ix
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