GEOLOGICA ULTRAIECTINA Mededelingen van de Faculteit Aardwetenschappen Universiteit Utrecht No. 199 Thermal evolution of high-pressure metamorphic rocks in the Alps Fraukje M. Brouwer Cover illustration: Spinel-corundum-plagioclase symplectite surrounding kyanite in a metabasic rock from the Lepontine gneisses near Bellinzona, Switzerland. SEM backscatter electron image. Thermal evolution of high-pressure metamorphic rocks in the Alps Thermische evolutie van hoge druk metamorfe gesteenten in de Alpen (met een samenvatting in het Nederlands) PROEFSCHRIFT ter verkrijging van de graad van Doctor aan de Universiteit Utrecht op gezag van de Rector Magnificus Prof. Dr. H.O. Voorma ingevolge het besluit van het College voor Promoties in het openbaar te verdedigen op 20 november 2000, des namiddags te 16.15 uur door Fraukje Myriam Brouwer Geboren op 24 mei 1973, te Uden Supervisors: Prof Dr. R.L.M. Vissers Prof Dr. MJR. Wortel Members ofthe dissertation committee: Prof Dr. R. Compagnoni Dipartimento di Scienze Mineralogiche e Petrologiche Universita degli Studi di Torino, Italy Prof Dr. M. Engi Mineralogisch-Petrographisches Institut Universitat Bern, Switzerland Prof Dr. S.M. Schmid Geologisch-Palaontologisches Institut Universitat Basel, Switzerland Prof Dr. ].L.R. Touret Faculteit Aardwetenschappen Vrije Universiteit Amsterdam, The Netherlands ISBN 90-5744-°56-3 Voor mijn ouders -----. NWO The research described in this thesis was conducted at the Faculty of Earth Sciences, Utrecht University, under the programme of the Vening Meinesz Research School of Geodynamics (VMSG). The author acknowledges financial support from the Geosciences Foundation (GOA, currently ALW) of the Netherland~ Organi~ation for Scientific Research (NWO), project number 750-196-15. Contents Samenvatting (Abstract in Dutch) II Riassunto (Abstract n Italian) IS Abstract 19 Chapter I Introduction 21 1.1 Scope of this study 21 1.2 Approach 22 1.3 Outline of this thesis 22 Chapter 2 Introduction to Alpine geology 25 2. I Plate tectonic setting 25 2.2 Geometry of the Alps 25 2·3 Structure of the central and western Alps 28 2.3.1 The central Alps 28 2.3.2 The western Alps 29 2.3.3 The Ligurian Alps 31 Chapter 3 Metamorphic history of the Lepontine gneisses around Alpe Arami, southern Switzerland 33 3· I Abstract 33 3·2 Introduction 33 3.2.1 Geology of the Lepontine Alps 33 3.2.2 The origin and history of the Alpe Arami peridotite 36 3.2.3 The study area 37 3.3 Structural history of the Lepontine gneisses 38 3.3. I Structures of the gneisses 38 3.3.2 Comparison with regional studies 44 3.4 Lithologies and mineral chemistry 45 3·4· I Petrography 45 3.4.2 Eclogites and eclogite-amphibolites 46 3.4.2. I Petrography of eclogites and eclogite-amphibolites 46 3.4.2.2 Symplectitic transformations 47 3·4· 2. 3 Mineral chemistry of eclogites and eclogite amphibolites 49 3.4.3 Cima Lunga metapelitic lens 52 3.4.3.1 Petrography of metapelites 53 3.4.3.2 Mineral chemistry of metapelites 56 3.4.4 Thermobarometry 56 3.4.5 CompllatlOn of the PTt trajectory 63 7 Contents 3.5 Geodynamic implications 66 3.5. J Juxtaposition ofthe Cima Lunga nappe and the Arbedo zone 66 3.5.2 Three possible scenarios for Alpe Arami and the Lepontine gneisses 67 3.5.3 Implications for orogenic processes 68 3.6 Conclusions 70 Chapter 4 Structure and metamorphism of the Gran Paradiso massif, western Alps, Italy 73 4· I Abstract 73 4.2 Introduction 73 4.2. I Geology of the western Alps 73 4.2.2 Gran Paradiso massif 75 4.3 Structure of the Gran Paradiso basement 77 4· 3· J Pre-Alpine deformation 77 4.3.2 Alpine deformation 77 4.4 Metamorphism of the Gran Paradiso basement 80 4.4. I Petrography 80 4.4.2 Mineral chemistry 85 4.4.3 Thermobarometry 89 4.4.4 Compilation of the PTt trajectory 94 4.5 Geodynamic implications 98 4.6 Conclusions 99 Chapter 5 Metamorphic history of ec10gitic metagabbro blocks from a tectonic melange in the Voltri massif, Ligurian Alps, Italy JOJ 5. I Abstract IO I 5.2 Introduction 101 5.2. I Geology of the Voltri massif J 0 J 5.2.2 Tectonic melange in the northern Voltri massif I02 5.3 Metagabbros of the Voltri melange 105 5.3.1 Petrography 105 5.3.2 Mineral chemistry 107 5.4 Metamorphic history 109 5·4· I Thermobarometry 109 5.4.2 Compilation of the PTt trajectory II3 5.5 Discussion I 16 5.5. I Comparison with previous studies I 16 5.5.2 Tectonic implications II6 5.6 Conclusions 118 8 Contents Chapter 6 The thermal evolution of convergent margins: a numerical modelling study applied to the Alps 119 6. I Abstract II9 6.2 [ntroduction I 19 6.3 Possible causes for heating 122 6.3. I Processes in the upper mantle 122 6.3.2 Radiogenic heating within the deformed crust 124 6.3.3 Selection of possibly viable hypotheses 126 6.4 Numerical investigations 126 6.4. I Slab detachment 126 6.4.2 Tectonically Accreted Radiogenic Material (TARM) 129 6.4.3 Comparison of model results for the two hypotheses 131 6.5 Comparison of model results with observations: a test of the hypotheses 133 6.5. I Geodynamic setting and PTt trajectories of se1ected areas 133 6.5.2 Comparison of model results with observations 136 6.6 Exhumation of high-pressure rocks in the Alps ] 38 6.7 Conclusions 141 Chapter 7 Conclusions and future research 143 References Appendix I Thermobarometry ]57 AI.I Introduction 157 AI.2 Garnet-omphacite thermobarometry 157 AI.2.I Krogh (1988) 157 AI.2.2 Holland (1983) 157 AI.2.3 Powell (1985) 159 AI.3 Garnet-phengite thermometry 160 AI.4 Phengite barometry 161 AI.5 Garnet-clinopyroxene-phengite barometry 162 AI.6 Garnet-amphibole thermometry 163 AI.7 Garnet-amphibole barometry 164 AI.8 Amphibole-plagioclase thermometry 167 Al.9 GASP barometry [69 AI.IO Garnet-biotite thermometry 17° AI.IO.I Ferry and Spear (1978) 17° AI.IO.2 Hodges and Spear (1982) [70 AI.IO.3 Kleemann and Reinhardt (1994) 171 AI. I I Simultaneous solution of GASP and garnet-biotite 171 ALlL1 GASP and Ferry and Spear (1978) 172 ALlL2 GASP and Kleemann and Reinhardt (1994) 172 9
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