Stress corrosion cracking © Woodhead Publishing Limited, 2011 SSttrreessss--RRaajjaa--PPrree..iinndddd ii 88//2233//1111 22::5533::5599 PPMM Related titles: Gaseous hydrogen embrittlement of high performance metals in energy technologies (ISBN 978-1-84569-677-1) Hydrogen embrittlement is the process whereby various metals, particularly high strength steels, become brittle and crack following exposure to hydrogen at high temperatures. The process has increasingly been recognised as a key factor in fatigue and failure of components in the energy sector, including developing technologies using hydrogen as an alternative fuel source. This comprehensive reference summarises the wealth of recent research on how hydrogen embrittlement affects particular industries, its mechanisms and how it can be predicted to prevent component failure. Thermal barrier coatings (ISBN 978-1-84569-658-0) Thermal barrier coatings are used to counteract the effects of high temperature corrosion and degradation of materials exposed to environments with high operating temperatures. The book covers both ceramic and metallic thermal barrier coatings as well as the latest advances in physical vapour deposition and plasma spraying techniques. Advances in nanostructured thermal barrier coatings are also discussed. The book reviews potential failure mechanisms in thermal barrier coatings as well as ways of testing performance and predicting service life. A fi nal chapter reviews emerging materials, processes and technologies in the fi eld. Nanostructured metals and alloys (ISBN 978-1-84569-670-2) Nanostructured metals and alloys have enhanced tensile strength, fatigue strength and ductility and are suitable for use in applications where strength or strength-to-weight ratios are important. 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Please confi rm which subject areas you are interested in. © Woodhead Publishing Limited, 2011 SSttrreessss--RRaajjaa--PPrree..iinndddd iiii 88//2233//1111 22::5533::5599 PPMM Stress corrosion cracking Theory and practice Edited by V. S. Raja and Tetsuo Shoji Oxford Cambridge Philadelphia New Delhi © Woodhead Publishing Limited, 2011 SSttrreessss--RRaajjaa--PPrree..iinndddd iiiiii 88//2233//1111 22::5533::5599 PPMM Published by Woodhead Publishing Limited, 80 High Street, Sawston, Cambridge CB22 3HJ, UK www.woodheadpublishing.com Woodhead Publishing, 1518 Walnut Street, Suite 1100, Philadelphia, PA 19102-3406, USA Woodhead Publishing India Private Limited, G-2, Vardaan House, 7/28 Ansari Road, Daryaganj, New Delhi – 110002, India www.woodheadpublishingindia.com First published 2011, Woodhead Publishing Limited © Woodhead Publishing Limited, 2011; Chapters 1, 2 and 18 © The Commonwealth of Australia; Chapter 19 © Her Majesty the Queen in right of Canada, as represented by the Minister of Natural Resources The authors have asserted their moral rights. This book contains information obtained from authentic and highly regarded sources. Reprinted material is quoted with permission, and sources are indicated. 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Trademark notice: Product or corporate names may be trademarks or registered trademarks, and are used only for identifi cation and explanation, without intent to infringe. British Library Cataloguing in Publication Data A catalogue record for this book is available from the British Library. Library of Congress Control Number: 2011934934 ISBN 978-1-84569-673-3 (print) ISBN 978-0-85709-376-9 (online) The publisher’s policy is to use permanent paper from mills that operate a sustainable forestry policy, and which has been manufactured from pulp which is processed using acid-free and elemental chlorine-free practices. Furthermore, the publisher ensures that the text paper and cover board used have met acceptable environmental accreditation standards. Typeset by Replika Press Pvt Ltd, India Printed by TJI Digital, Padstow, Cornwall, UK © Woodhead Publishing Limited, 2011 SSttrreessss--RRaajjaa--PPrree..iinndddd iivv 88//2233//1111 22::5533::5599 PPMM Contents Contributor contact details xiii List of reviewers xix Foreword xxi Preface xxiii Part I Fundamental aspects of stress corrosion cracking (SCC) and hydrogen embrittlement 1 1 Mechanistic and fractographic aspects of stress-corrosion cracking (SCC) 3 S. P. Lynch, Defence Science and Technology Organisation (DSTO), Australia 1.1 Introduction 3 1.2 Quantitative measures of stress-corrosion cracking (SCC) 5 1.3 Basic phenomenology of stress-corrosion cracking (SCC) 6 1.4 Metallurgical variables affecting stress-corrosion cracking (SCC) 11 1.5 Environmental variables affecting stress-corrosion cracking (SCC) 14 1.6 Surface-science observations 14 1.7 Proposed mechanisms of stress-corrosion cracking (SCC) 18 1.8 Determining the viability and applicability of stress- corrosion cracking (SCC) mechanisms 28 1.9 Transgranular stress-corrosion cracking (T-SCC) in model systems 29 1.10 Intergranular stress-corrosion cracking (I-SCC) in model systems 54 1.11 Stress-corrosion cracking (SCC) in some commercial alloys 58 1.12 General discussion of stress-corrosion cracking (SCC) mechanisms 66 1.13 Conclusions 76 © Woodhead Publishing Limited, 2011 SSttrreessss--RRaajjaa--PPrree..iinndddd vv 88//2233//1111 22::5533::5599 PPMM vi Contents 1.14 Acknowledgements 78 1.15 References 78 2 Hydrogen embrittlement (HE) phenomena and mechanisms 90 S. P. Lynch, Defence Science and Technology Organisation (DSTO), Australia 2.1 Introduction 90 2.2 Proposed mechanisms of hydrogen embrittlement (HE) and supporting evidence 100 2.3 Relative contributions of various mechanisms for different fracture modes 113 2.4 General comments 123 2.5 Conclusions 125 2.6 References 126 Part II Test methods for determining stress corrosion cracking (SCC) susceptibilities 131 3 Testing and evaluation methods for stress corrosion cracking (SCC) in metals 133 W. Dietzel and P. Bala Srinivasan, Helmholtz-Zentrum Geesthacht, Germany and A. Atrens, The University of Queensland, Australia 3.1 Introduction 133 3.2 General aspects of stress corrosion cracking (SCC) testing 134 3.3 Smooth specimens 136 3.4 Pre-cracked specimens – the fracture mechanics approach to stress corrosion cracking (SCC) 143 3.5 The elastic-plastic fracture mechanics approach to stress corrosion cracking (SCC) 155 3.6 The use of stress corrosion cracking (SCC) data 158 3.7 Standards and procedures for stress corrosion cracking (SCC) testing 159 3.8 Future trends 163 3.9 References 164 Part III Stress corrosion cracking (SCC) in specifi c materials 167 4 Stress corrosion cracking (SCC) in low and medium strength carbon steels 169 U. K. Chatterjee, Indian Institute of Technology Kharagpur, India and R. K. Singh Raman, Monash University, Australia 4.1 Introduction 169 © Woodhead Publishing Limited, 2011 SSttrreessss--RRaajjaa--PPrree..iinndddd vvii 88//2233//1111 22::5544::0000 PPMM Contents vii 4.2 Dissolution-dominated stress corrosion cracking (SCC) 170 4.3 Hydrogen embrittlement-dominated stress corrosion cracking (SCC) 187 4.4 Conclusions 191 4.5 References 192 5 Stress corrosion cracking (SCC) in stainless steels 199 V. Kain, Bhabha Atomic Research Centre, India 5.1 Introduction to stainless steels 199 5.2 Introduction to stress corrosion cracking (SCC) of stainless steels 202 5.3 Environments causing stress corrosion cracking (SCC) 203 5.4 Effect of chemical composition on stress corrosion cracking (SCC) 215 5.5 Microstructure and stress corrosion cracking (SCC) 218 5.6 Nature of the grain boundary and stress corrosion cracking (SCC) 221 5.7 Residual stress and stress corrosion cracking (SCC) 223 5.8 Surface fi nishing and stress corrosion cracking (SCC) 225 5.9 Other fabrication techniques and stress corrosion cracking (SCC) 229 5.10 Controlling stress corrosion cracking (SCC) 231 5.11 Sources of further information 233 5.12 Conclusions 233 5.13 References 234 6 Factors affecting stress corrosion cracking (SCC) and fundamental mechanistic understanding of stainless steels 245 T. Shoji, Z. Lu and Q. Peng, Tohoku University, Japan 6.1 Introduction 245 6.2 Metallurgical/material factors 245 6.3 Environmental factors 254 6.4 Mechanical factors 261 6.5 Elemental mechanism and synergistic effects for complex stress corrosion cracking (SCC) systems 263 6.6 Typical components and materials used in pressurized water reactors (PWR) and boiling water reactors (BWR) 265 6.7 References 269 7 Stress corrosion cracking (SCC) of nickel-based alloys 273 R. B. Rebak, GE Global Research, USA 7.1 Introduction 273 © Woodhead Publishing Limited, 2011 SSttrreessss--RRaajjaa--PPrree..iinndddd vviiii 88//2233//1111 22::5544::0000 PPMM viii Contents 7.2 The family of nickel alloys 274 7.3 Environmental cracking behavior of nickel alloys 279 7.4 Resistance to stress corrosion cracking (SCC) by application 285 7.5 Conclusions 301 7.6 References 301 8 Stress corrosion cracking (SCC) of aluminium alloys 307 M. Bobby Kannan, James Cook University, Australia, P. Bala Srinivasan, Helmholtz-Zentrum Geesthacht, Germany and V. S. Raja, Indian Institute of Technology Mumbai, India 8.1 Introduction 307 8.2 Stress corrosion cracking (SCC) mechanisms 308 8.3 Factors affecting stress corrosion cracking (SCC) 313 8.4 Stress corrosion cracking (SCC) of weldments 325 8.5 Stress corrosion cracking (SCC) of aluminium composites 331 8.6 Conclusions 334 8.7 References 334 9 Stress corrosion cracking (SCC) of magnesium alloys 341 A. Atrens, The University of Queensland, Australia, W. Dietzel and P. Bala Srinivasan, Helmholtz-Zentrum Geesthacht, Germany, N. Winzer, Fraunhofer Institute for Mechanics of Materials IWM, Germany and M. Bobby Kannan, James Cook University, Australia 9.1 Introduction 341 9.2 Alloy infl uences 345 9.3 Infl uence of loading 354 9.4 Environmental infl uences 360 9.5 Mechanisms 363 9.6 Recommendations to avoid stress corrosion cracking (SCC) 370 9.7 Conclusions 371 9.8 Acknowledgements 373 9.9 References 373 10 Stress corrosion cracking (SCC) and hydrogen- assisted cracking in titanium alloys 381 I. Chattoraj, Council of Scientifi c and Industrial Research (CSIR), India 10.1 Introduction 381 10.2 Corrosion resistance of titanium alloys 385 © Woodhead Publishing Limited, 2011 SSttrreessss--RRaajjaa--PPrree..iinndddd vviiiiii 88//2233//1111 22::5544::0000 PPMM Contents ix 10.3 Stress corrosion cracking (SCC) of titanium alloys 386 10.4 Hydrogen degradation of titanium alloys 388 10.5 Conclusions 404 10.6 Acknowledgements 405 10.7 References 405 11 Stress corrosion cracking (SCC) of copper and copper-based alloys 409 M. Bobby Kannan, James Cook University, Australia and P. K. Shukla, Southwest Research Institute, USA 11.1 Introduction 409 11.2 Stress corrosion cracking (SCC) mechanisms 410 11.3 Stress corrosion cracking (SCC) of copper and copper-based alloys 411 11.4 Role of secondary phase particles 419 11.5 Stress corrosion cracking (SCC) mitigation strategies 419 11.6 Conclusions 422 11.7 References 424 12 Stress corrosion cracking (SCC) of austenitic stainless and ferritic steel weldments 427 H. Shaikh, T. Anita, A. Poonguzhali, R. K. Dayal and B. Raj, Indira Gandhi Centre for Atomic Research, India 12.1 Introduction 427 12.2 Effect of welding defects on weld metal corrosion 429 12.3 Stress corrosion cracking (SCC) of austentic stainless steel weld metal 431 12.4 Welding issues in ferritic steels 462 12.5 Conclusions 478 12.6 References 478 13 Stress corrosion cracking (SCC) in polymer composites 485 J. K. Lim, Chonbuk National University, South Korea 13.1 Introduction 485 13.2 Stress corrosion cracking (SCC) of short fi ber reinforced polymer injection moldings 487 13.3 Stress corrosion cracking (SCC) evaluation of glass fi ber reinforced plastics (GFRPs) in synthetic sea water 505 13.4 Fatigue crack propagation mechanism of glass fi ber reinforced plastics (GFRP) in synthetic sea water 511 13.5 Aging crack propagation mechanisms of natural fi ber reinforced polymer composites 519 © Woodhead Publishing Limited, 2011 SSttrreessss--RRaajjaa--PPrree..iinndddd iixx 88//2233//1111 22::5544::0000 PPMM x Contents 13.6 Aging of biodegradable composites based on natural fi ber and polylactic acid (PLA) 526 13.7 References 535 Part IV Environmentally assisted cracking problems in various industries 537 14 Stress corrosion cracking (SCC) in boilers and cooling water systems 539 M. J. Esmacher, GE Water & Process Technologies, USA 14.1 Overview of stress corrosion cracking (SCC) in water systems 539 14.2 Stress corrosion cracking (SCC) in boiler water systems 540 14.3 Stress corrosion cracking (SCC) in cooling water systems 552 14.4 Stress corrosion cracking (SCC) monitoring strategies 566 14.5 References 567 15 Environmentally assisted cracking (EAC) in oil and gas production 570 M. Iannuzzi, Det Norske Veritas, Norway 15.1 Introduction 570 15.2 Overview of oil and gas production 571 15.3 Environmentally assisted cracking (EAC) mechanisms common to oil and gas production 580 15.4 Materials for casing, tubing and other well components 584 15.5 Corrosivity of sour high pressure/high temperature (HPHT) reservoirs 592 15.6 Environmentally assisted cracking (EAC) performance of typical alloys for tubing and casing 594 15.7 Qualifi cation of materials for oil- and gas-fi eld applications 599 15.8 The future of materials selection for oil and gas production 603 15.9 References 604 16 Stress corrosion cracking (SCC) in aerospace vehicles 608 R. J. H. Wanhill, National Aerospace Laboratory NLR, The Netherlands and R. T. Byrnes and C. L. Smith, Defence Science and Technology Organisation (DSTO), Australia 16.1 Introduction 608 16.2 Structures, materials and environments 610 16.3 Material–environment compatibility guidelines 615 © Woodhead Publishing Limited, 2011 SSttrreessss--RRaajjaa--PPrree..iinndddd xx 88//2233//1111 22::5544::0000 PPMM
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