Standard Reference Materials: A REFERENCE METHOD FOR THE DETERMINATION OF LITHIUM IN SERUM PDF
Preview Standard Reference Materials: A REFERENCE METHOD FOR THE DETERMINATION OF LITHIUM IN SERUM
Standard Reference Materials; A REFERENCE METHOD FOR THE DETERMINATION OF (OTBIUM IN SERUM Runue 4. Velynoldi, Robert C. Paul, Roberr Sehatteg, Jolay Mande Lawreuce A. Machin, Ernest L. Garnes, and Theodore C, Rains National Memaenent Laboratory Wathingten, DO. 2284 Wi the operation of @ Commits of Lert George N. Bowers, Jt! Bradley Th, Copeland Foenis 0, Rodpusenis and James Bt, White “ain nt Hoes, 2k Tinga Dereon Hepa, Hoa, 318 Fearn of Ftolgs ator Cori, Lox Anse, CA, ‘Cntr in Duroe Conch lon GA oO oe \ee/ rcay os US. DEPARTMENT OF COMMERCE, Phiip M. Klutznick, Secretary Lute. Hodges. Jr, Daputy Seeetary Jordan 4. Baruch, Assistant Secretory for Productivity, Technology aiid Innovation NNnTIQhAL BUREAU OF SLAREALDS, Ernest Ambler. Director Issued July 1980 Libsary of Congress Catalog Card Number; 80400101 National Bureau of Standards Specia] Publication 260-62 "ot Bae San. (USS 26 peas 5) (4a a peat in. PREPACE Stundard Reference Materials (SWI's] as defined by the National Bureau of Standards are wall-characterized materials, produced in quantity and certified Cor one or mave physical or chomicnl propertles. They are used to assure the accuracy and coupatibitity of measurcwouts throughout the Nation. SRM’: are widely weed as primary standards in many diverse fie Dndted States and throughout the werld, They are alsa used extensively in the ficlds of envivonmenta] and clinical anal- in science, industry, and technology, both vithin the ysis, In many applications, traceability of quality controt and meseuronent processus te (he mulional weasureuent system are carried out through the mechanism and use of SWM's. For ueny of the Kation's scientists and technologists it is there- fore of nore than passing interest to knew the details of the SRY certification neasureconts mide at NUS or of recommended nathods for use vith SRM's lv assure accurate avusurcmeats ip the fictd. an NBS series of papers, of which this publica- tion is a meabor, called tha NBS Special Publication - 260 Series, is reserved lor this purpose. This 260 Serios ix dedicated to the dissenination of information on different phases of the preparation, measure- vent, certification and use of NBS-SRM's, In ganeval, much nore dotuil «ill be found in those papers than is generally atiowed, ov ad vable, in eciontific journal articles. Tale enables the user to assess the validity and accuracy of the neusuremont provosses omployed, to judge the statisticul analysis, and to tourn details of techniques and netheds utilized for work entailing the greatest care and accuracy. ‘hese papers alse should provide sufficient additional Information not found gn the certificate so that mew applica tions in diverse fields not foreseen at the tine the SRM war priginatly fssued wi]1 he sought ané found. Inquiries concerning the tachnical content of th paper should be directed to the author(s), they questio concerned with the availability, delivery, pricey ote., 0 specific SRWs cited ju this document will receive proupt attention Mont Office of Standard Reference Materials Nationa) Burcan of Standards Washington, 0.¢, 20234 George A. Uriane, ied Office of Standard Reference Materials OK A Fumdamenta1 reynirewent fur assoring adequate patient 5 of constitveats in pedy Gluids. Tho usjor functions of the Sational Jureau of Standards (BS) Gutorisls fer the celikeation of measureavat systems and to cove is the need Tor the accurate anazy: are to wrovide certified Standard ReLerence develop new or improved analytical wéthods, The results prue- seated in this MBS Social PubLicstion provide a wothodvloyy of known seewrecy for the detorsinatioa of 1itndaw in serum The evelvation of a refecence method by compurisun ta a definitive method, used cor the First time at NBS in the development of reference methods Tor calcim, sium, and chloride in serus, alse vas apeliod te this werk. This hierercty 0° onalytical procedures bos heen accepted as a valid Zormal ior developing reference methods by the clinical comMunLy aL a recent Conference va au Understanding for a cium, potas Wationel Recerence System :n Clinical csemistry. In an undertaking of this cagnitude, extensive collaho- ration vith a committow of exporls, Lhe Cvotex for Disease Goutrod, the Fuel aud Deuy Administration, and a wide spectrum vf participsting aualylical laboratories that Stato, hospital, industrial, and acalecie lablish a xidely secentea includeé. Fodor: laboruturies way evsential Le yeference mathoc, Tt is hoped that this wark will provide an additional basis for the Geveloyment of future clinicat efevence nattods through coutinued ceilaoration and the concerted efforts ef the individual parcictpancs. Gort #. Beimaaa, Director Ueotex Zor fmalytical Chemistry nore Hecansa of concern fov the useability of this Lithium reterence mothod, Canter tor Disease Control ganayonont has Jeelinad to endorse the method described in tis report. However, the wuthors believe the proseat nethed should Iunction as the relerence method uasil the efficacy of a subsequent improved method has heen demonstrated, sincy this procedure 25 been shorn te satisfy the generally accepted criteria of « xeferonce method. 41S supports the evelution of aualytical methods und belioves it important that the principles of emslytical practice delineated in, Ube present roport be circulated ina timely wamer HS «iJ continue to participate in intoriaboratory exercises that are alged toxand establishing the transfer ability of proposed reference proceduyge sud wili maintain its primury role in supplying SMMt's und defizitive wethods. stalog of SI Stalin Ielerence Mera {1999 80 edition), RW. Seward ey US Spor, unl AU (Apa 19/4) Ss" SAU aan Miolaoka, RE, aid Mpa $< fog Satin Uelerr: Mitra Preparation of ite Cast ton Sestveiarnl Sundants, RRS Mig, ub. 21 Clune 3968). CONS. Ot" Micali Rf Wyman, Be ta and Fly By ‘Muni Reerence: Matric Preparation of RWS Copperttee Spectaeheiel Stsdacts INS Mie PB 60 Octaber 968) COMP Miclaole. RE, Yalow, Hand Mowe Slandact Reiotenso Matera: Metalograhic ‘Eharaeteiaation of an NBS Spence oe Alloy Steel Sueded, BAS Mix J'ubl. 280.1 ‘Ovtoter Ine) COMe- £1060" Hage. ha. Mears, T, Wo sod Mishel, Kb ‘Stisdlerd Relereace Material: Sours: of Infoatien, NBS Mee, Publ, 2604 Pebrtny 1955, O0M24-110S tier: Aociray of Soltion 3-Ray Specto~ meme Aaulgss of CeppreRere Adoys. NBS ist, Poth 2008 (Marea IMS). PBIGRDGRE™ Shultz, Joy Standard Reterence Matera: Methods fer tbe Chenical Antti of Wite Ceram Sind, NUS Miss Po, 26 (Guy ors Contre dae Nett, 1 Ky Slandard Reference Marerials IMshads forthe Chemical Azalsis of NBS Miso. Pail, 280? (Qetaber (905), COTS ae" Richewa, M.S, Standard Reereves Manes ‘analyais nf iranian Crncemfertes atthe Netw Horou of Stidandy, NBS Me Pa 2H December 1965) COMA TAR Anh, §: Cy Chsay, b. ML. Gaeinkl 8, By Hetchinny 1 We Rad Sandy Re Ste sd Welrence Mater Hal? Lives of Sates Macctale of Snotcen Radiasetiee Muclides Toad by the Natinal Gurces of Studs, WHS Mise, Publ. 260-9 (November IBS) ‘Yakowi, HL, Vieh, DB. lebih K.P Jase DMichaci, RE, Standard Releenes Materia orengenly Characeration MHS Spee: etic Somande I Canelge Bras a eR ‘log Stee, HS Mig, Pahl AU Cece TAS ODEETeL1063" Nepultiady Ay abd Homing. FG, Samdard TReforeace Sarerilet Wiaeosity of Standard Lead Sloe Glass, NUS Wise. Publ. 260-17 ‘®ovenbse 196, NS Mi, Pu, 260416 akon, H, Vid, D.L., and Mice 1. ‘Standaed Relsronte Materials: Homcgeneity Chametereition of NES Spectnanctie Stand tude fF White Coat fron and Stvneoe Sts Powder Compuch, NUS Mike, Pohl. 260-12 (September 1968) NS Mi. Pot. 260-12 Spake, fT Smetiher, DA, Runge. nod Devoe, 2. R Suadand okwee Mate Tac Moabasee Sposccoopy Standard fe the Cheseia! Shift of Hon Compooads, NAS “ss bt. 260-35 (Saly 1967}. NBS Mise, Publ patie Nistiie Deesndoaciou o€ Oxegen Vers Matala ~ SRA 480,109). 8 1092, RIS Mis. Pu 260-40 (Sepoctber 19), AS Nie a l= Inmagine Baud Shoe, FJ. Standan! els Tact Macale Recommended Met af Uae ‘Gf Standard Lighter Paper 1 CDSE Ing Carbon Aro Teed im Vesting Tess for Coane t Ligh, BAS Mie Pu. 26015 lun 10E,. (Replaced by BBS Spee, PabL past) Yobowit, thy Michaelis RB. and Wie, B,J ‘Standerd Relerence Matevals: Homogensity Chancteatien of MS Spwctnnactie Sand tude TV Preemion and. Miupiute, Charac- ‘eebation of MeDVE 140 Alloy Fabseatod by Pender Metsiargical Methods, KES Spee abl 36016 (Jimmy 16H) COMTELIOEI* caubzire, £1, Champion, Cf, Garba. EL, W. ie Sagara Retorooce Rlateris: Hovie Ail, Inge and Away Standard Relerense taernby SS. Spec abl 26047 Febery 1910, Ow al Print ater, 5. By Munich) Paty and Cesled, N, Gastundara Reteronce Mattils: Calibre fon af NES Sosoadnry Sandars Magar Tape {Couper ior Reeroae lng he Spesasn A, "Rif Spo, Publ 20-6 (November Jot5), (oe SRS Spee Pu 36029) raul Ry te and Mandal, J, Stara Meferenoe incr Ania of Trershorsny Meviure Tees on the Vane Psesae of Geld Ceci ‘Romo Samied Reference Matai 75). NDS ‘Spee Pant 20:19 Gnuiry (970, PBYBOUEI™ Paks i. Cand Mandel, Standard Referenot Matias Anas of bselabrator) Vs ‘Bonn a Voque Fess of Cada Sioer, NBS Spee Pom slat aary 1. bacrarestig ‘vakovion H. Tori ©. By amd Wicks RE ‘Standard Resoince Matariate Heaangeneity Cheractsuation Fe) St Aly, NBS Spe Pot ta Gebruns 1971). COMET supaliane, Aa a08 Hlawtie, £6, Sandan Roewce diner Vivsy of a Stadoed MovoaThzate Gls, NBS Spee FOR. 260-23 esrmber 8). CONTAMTSTe* sipmufelt KS, Marnske, god Fagus, Te Sianand Refrenas Matas: Companion’ (Rodan, Sharda NRE Spee Putt 2E024 Fesunes 197, CORTE ann GFE akowita We Raster, 8. Day 608 Miceli RR, taeda ¥efgooe Wana A Steodord Reference Matis! Costing emioaly Toor Povere Antente, NHS 3) Pabr Sae2s (brary 1971). COMMS EEE Marcin. 2, Fu Standard Reference Matias: etna Haro of Stndards 6 Stel Comer ivroute iu Sect, SBS Spee. Bobb. 26-18 ietray 1971). 88 exact SNORT GGrrer E,,atlan, 1 and Ses, WR, ‘Stnsdaed Weference Macatiae: Cranium fhotopit Stmnderd Reference stevia, NBS Spee, Publ 260-22 (Ape S71), COMTS- tiie amwch SFB peu, Be fo Rabe 8 ihe and Micha, Rey Sandan Relerence Mterih: Preparation and Fvatsation ul SRM ab ane 402 Geldsiver and Gold Epps lls fot Mieworayan, NBS Spee Pub aes tanga (990, COMTI SDI lay 8. 8, Standard Renee Marie CAR ‘ton of NBS Sceuntury Senofard Magra “Tape (Ceapetee amplnde Refereuo) Ua, a hake Taps Ample Menuet one 1D. CoMeE sa ~ Goevahinime, Re 8. Freeda, A. Yond Shrievch, A.B. (sated hy WC, Seb, Slandaed Reterence Materia: StuadaTd Semples awed ia te USSR (A Tmt ‘oat hs Rubia HBS Spe, Publ 2009 me Tat. cowme aang Ms 1G. and Spark a, Saar Refrnce ‘Mave: Thermal Conducisity of Eka fron SRA 714 fom dt 209K, NBS Spo PB beat [towemner 1920), CON sms Mavtodinena, Rey 1d. Laven). Wy Soulard elena Biter Saban Guar: Cet, foc High Accurany Spectcopbotouctes, NBS Specs Publ 24032 (Dasober 173). 8 cent? Shiapgr3tst Wagner, HL. Standord Refweoce Medes Gompareion al Orginal and Supplemeresl SRM M5, Sinow Moller Wot Die tasion Poietizene, NHS Spec, Pvbl, 20031 (iar usmy Conne sistem Specks LL ant Mut J, Satan Retecce ‘Materinte Therlectic Vaogs, NOS Sper uel 24034, (po 1972), CONT Spacbe Mey and Mam Gy Stn ‘oot Nutsriale:"Ihesaoal Coudueuity of ‘280, NBS Spee Publ 20038 (Apa 1972) (635, Mandel J, Moos, LJ, and Young D. 4) Sehr ene Bi 4 Ree Scrum MUS SH 95, NBS Spm PON O36 (May WD, ConrasisaT™ Stole, JT Ball, RK. Rains, TC end Mes, ‘On Mua Reermnce Mita” Method ob ‘arms of NBS Che Standnrd, NTS Spec, Fr 2605 ns 124 CORED 02 fast Matalin! Pregaation and Caltaton of Stindarde a! Spectral Spectr etietance, [NBS Spee, Publ 20-38 (ay 1972). COM sisseet Car AL Ke Damn, YA ist. Je Gant Fovell RL, StindrdRetence Metis The Bid Curent Due Metied for Ret Chacisernaion of High-Porty Net, NES Spee Pub 26039 (ney 197, COM2-S0250" Menta, 6, Garo. P-D., and Meni, 0 Stunt an Kelseace Mater Selestiom tral nna Toayprtare Staniande Ther Euogeratve Study (SRM 734,758, 70), NAS Sper Publ. 26- (Agor 1972) COM 72 sine Wood, L.A. and Shouse, PL 3., Standard Referens Matera Ue of Santard Lig ‘Stone. Paper for Callrating Carbon Aves Used in Testing, Teter for Colifaess Light RBS Spee Publ 2647 (Auge 1972) ‘ooMirsamee ‘Wagner HL. and Veo, P ede, Standard Referens haere The Charatervaion of Liner Potsettstne, SRM 147s, NS Spee Publ. 260-42 (Septeraher 1973). COMT2: Pores ‘Yaka Roh 00 Mich Ry ‘Standard Relereree Mater Preparation aod omogrorce Charateritun ofan AusoiiGe Io Chroms-Nike) Alloy, NBS Spec Pub Beha} (Movember 972, COMA Sehooies, J. Suton, (3 e-xod B05. A, “eq Sone) Reference Mate Poegattion nd. Use af Superconductive Fixed Point Doce, SRM Jet NAS Spec. Pobl. 20445 (ener 1972, CONS So Greif, By Maint, Eins, 7. C. and Rashosey, 8. D., Standard Refeeate uteri Powdered tad Based Pat, SEM 1573, MBS Spee, Publ. 26043 (Mirch 1973). COMP soe st J.C and Giseaano,P. 3. Stata Refers (nce Mitel herbal Condstesy and Hroeiaa? Reb Standard Refeotae Mato fia Auuonie Snake Stee, SEM 73S 8, ron to 1200 K, BES Spe, PobL 2-45 ‘Msech 1925), SRUCRLUTTOIZTS ast JG, Standard Reference Miteriste Pha ‘oa! Redlity of Eketrlye Irom, SRD 797, sod umes Soil Ser SESC¥4 > {o 280K, NES Sper Publ 20047 (Rebrusry Iya). COMDesaITE* ‘Mangan B.Wevand Wins Jo Slade Refer ret Matyi: Deseipeionand Uae of reson ‘Thermometer for the Clinical Lanoratoy SRM 935 andSRE034 NBSSpee Pub 26 (din 199g ects? SNOOSDOE OTITIS ‘Carpenter; B.S, vr lckoer, GM. Standard ‘Referens Merial Cate Clase Stand- fo fn Fon Teac Ut, MES Spex PUBL Seta vunerches 1924). SNOORODE OIA Hus, (end Ciarestan. PJ. Sten ars ce Materite These ondacty ond Hc ‘rin! Rect Stand efoonce Mariage Flaroltie ton, SIEM 784 and 197 fom 40 1009 K, NBS Spee. Publ. 26050 Tune 1975) Love SNooMrraTaaseF Miodivens, sed Solin, JR, Standard rere Material: Glas Piters Az Sten elerence Material for Speetroghorometry; Seki, Peyton: Catenion Uve- Si ot HG, RES Symes PUBL, 26051 (eovembee 95), SIS SNIE403-014018 nue 1.G sand Giateaann ,f, Stantand Re foc: Material "Toran Corot el El {ikea Resianty Standard Releence Balcila 1 nd 79, rom 403000, NUS Spee PUBL 2a 52 (Septouber 197M, SLDS6 SADIE. Durst, Standued Reference Materiati ‘Sesnlcdinaion of pH Messorements, NBS Spc, Path 36253 (Deoerber 15, erica), $105 Sn00}03.015812 barks, Re Wand Mavradionyna, R Standard ‘Reciese Steet Coriteation and Uae of ‘Asis Poasan Disha Solum att uation Abeorbeaer Star, NES Spee abl 29054 gost 1877). BUM SOUS. o1s2i-? iar, DA, Ceninisan, A, bina, Sand Tuga, TB Standard Reference Matis ottalpy and Meat Capacity, Molybdenum SRM 81, From 27310 200K, AWS. PUD, DHSS (Sepromber 1977, $220" SND. ise Powell 1, Spo, he Tay and Hot 3. . ‘Standard Reference Materials: Standard “Thensocouple Maer, Presi 967, BS ‘Spee, Publ 2656 CFebrvary 197), 320° saiaannoitsea Cab, 3. Pad Plebanatd, 1, Guide to Daed Stam Ueference Material” NES Spec, Pu, 2a (Behram 19) SLAP SHOR ona ures, J, and Marco. GM. Standood Wefer= Tranuoiion Mexeurements, SRC 1250, NES Spe. Pb. 20-5 fn pes) (Chang, T. and Kako, AHL, Standard Reference Muti Eleetroa Parmigmetc Resobanee Iejensty Standard. SEM 2501, NIS Spee bl 240-59 (Angus 197K S230" NB. mW. Ww. TABLE OF CoMrENTS PAGE INTRODUCTION: ©. see . 2 DAVELOPWUNT OF THR SHRM LITHIOC REFERENCE MEU. ee cee Ay Organization. soe ee 4 4B. Participating laboratories, Standards, Serna Samples, and Definitive Method... 2 + + C. Functions of the Various Groups =)... 10 Pian for Testing the Candidate Reference Method. sees : wee 10 REPERENC METHOD PROTOCOL FOR TH vETDRUENSTION OF SERUM LITHO ee ee ee OB Ae Gonerad ee eS B. Protocol Synopsis... ee ee ee BS G. Detailed Protocol. 22. ee ee RESULTS AND STATISTICAL ANALYSIS. 6.) 2 2) 0 A. Interlavoratory Hxercase Results.» 2... 30 DISGBBSION. Se OF A. Candidate Protocol. 2... ee ee 8F CONCLUSIONS ee ee TB RFRBRENCES. oe ee 16 APPENDIE AL ee 6 APPUMDTL B.S ee TF APPENDIX. . 3 APPRENDI. D. . we
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