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Springer Series in Light Scattering Alexander Kokhanovsky Editor Springer Series in Light Scattering Volume 3: Radiative Transfer and Light Scattering Springer Series in Light Scattering Series editor Alexander Kokhanovsky, Vitrociset Belgium, Darmstadt, Germany Editorial Advisory Board Thomas Henning, Max Planck Institute for Astronomy, Heidelberg, Germany George Kattawar, Texas A&M University, College Station, USA Oleg Kopelevich, Shirshov Institute of Oceanology, Moscow, Russia Kuo-Nan Liou, University of California, Los Angeles, USA Michael Mishchenko, NASA Goddard Institute for Space Studies, New York, USA Lev Perelman, Harvard University, Cambridge, USA Knut Stamnes, Stevens Institute of Technology, Hoboken, USA Graeme Stephens, Jet Propulsion Laboratory, Los Angeles, USA Bart van Tiggelen, J. Fourier University, Grenoble, France Claudio Tomasi, Institute of Atmospheric Sciences and Climate, Bologna, Italy The main purpose of new SPRINGER Series in Light Scattering is to present recent advances and progress in light scattering media optics. The topic is very broad and incorporates such diverse areas as atmospheric optics, ocean optics, optics of close-packed media, radiative transfer, light scattering, absorption, and scattering by single scatterers and also by systems of particles, biomedical optics, optical properties of cosmic dust, remote sensing of atmosphere and ocean, etc. The topic is of importance for material science, environmental science, climate change, and also for optical engineering. Although main developments in the solutions of radiative transfer and light scattering problems have been achieved in the 20th century by efforts of many scientists including V. Ambartsumian, S. Chandrasekhar, P. Debye, H. C. van de Hulst, G. Mie, and V. Sobolev, the light scattering media optics still have many puzzles to be solved such as radiative transfer in closely packed media, 3D radiative transfer as applied to the solution of inverse problems, optics of terrestrial and planetary surfaces, etc. Also it has a broad range of applications in many brunches of modern science and technology such as biomedical optics, atmospheric and oceanic optics, and astrophysics, to name a few. It is planned that the Series will raise novel scientific questions, integrate data analysis, and offer new insights in optics of light scattering media. More information about this series at http://www.springer.com/series/15365 Alexander Kokhanovsky Editor Springer Series in Light Scattering Volume 3: Radiative Transfer and Light Scattering 123 Editor Alexander Kokhanovsky Vitrociset Belgium Darmstadt, Hessen Germany ISSN 2509-2790 ISSN 2509-2804 (electronic) Springer Series in Light Scattering ISBN 978-3-030-03444-3 ISBN 978-3-030-03445-0 (eBook) https://doi.org/10.1007/978-3-030-03445-0 Library of Congress Control Number: 2018960351 © Springer Nature Switzerland AG 2019 This work is subject to copyright. All rights are reserved by the Publisher, whether the whole or part of the material is concerned, specifically the rights of translation, reprinting, reuse of illustrations, recitation, broadcasting, reproduction on microfilms or in any other physical way, and transmission or information storage and retrieval, electronic adaptation, computer software, or by similar or dissimilar methodology now known or hereafter developed. The use of general descriptive names, registered names, trademarks, service marks, etc. in this publication does not imply, even in the absence of a specific statement, that such names are exempt from the relevant protective laws and regulations and therefore free for general use. The publisher, the authors and the editors are safe to assume that the advice and information in this book are believed to be true and accurate at the date of publication. Neither the publisher nor the authors or the editors give a warranty, express or implied, with respect to the material contained herein or for any errors or omissions that may have been made. The publisher remains neutral with regard to jurisdictional claims in published maps and institutional affiliations. This Springer imprint is published by the registered company Springer Nature Switzerland AG The registered company address is: Gewerbestrasse 11, 6330 Cham, Switzerland Contents The LIDORT and VLIDORT Linearized Scalar and Vector Discrete Ordinate Radiative Transfer Models: Updates in the Last 10 Years . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1 Robert Spurr and Matt Christi Radiative Transfer of Light in Strongly Scattering Media . . . . . . . . . . . 63 Boaz Ilan and Arnold D. Kim Polarized Radiation Transport Equation in Anisotropic Media . . . . . . . 105 Margarita G. Kuzmina Aerosol Layer Height over Water via Oxygen A-Band Observations from Space: A Tutorial . . . . . . . . . . . . . . . . . . . . . . . . . . . 133 Anthony B. Davis and Olga V. Kalashnikova Optical Properties of Black Carbon Aggregates . . . . . . . . . . . . . . . . . . . 167 Chao Liu Index . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 219 v Contributors Matt Christi Fort Collins, Colorado, CO, USA Anthony B. Davis Jet Propulsion Laboratory, California Institute of Technology, Pasadena, CA, USA Boaz Ilan Applied Mathematics Department, University of California, Merced, Merced, CA, USA Olga V. Kalashnikova Jet Propulsion Laboratory, California Institute of Technology, Pasadena, CA, USA Arnold D. Kim Applied Mathematics Department, University of California, Merced, Merced, CA, USA Margarita G. Kuzmina Keldysh Institute of Applied Mathematics, Russian Academy of Sciences, Moscow, Russia Chao Liu School of Atmospheric Physics, Nanjing University of Information Science and Technology, Nanjing, China Robert Spurr RT Solutions, Inc., Cambridge, MA, USA vii The LIDORT and VLIDORT Linearized Scalar and Vector Discrete Ordinate Radiative Transfer Models: Updates in the Last 10 Years Robert Spurr and Matt Christi 1 Introduction 1.1 General Background It has been 10 years since the last major review paper on the LIDORT and VLIDORT radiative transfer models; this paper appeared in Light Scattering Reviews, Volume 3 (Spurr (2008), hereinafter referenced as [R1]). The present work will review the current status of the two models in the light of new developments and upgrades in the intervening period. LIDORT stands for “LInearized Discrete Ordinate Radiative Transfer”, and the LIDORTmodel is a comprehensive linearized scalar (no polariza- tion) RT package based on the discrete-ordinate method for solution of the radiative transfer equation (RTE). VLIDORT is the corresponding vector version of LIDORT, dealing with polarized light fields. Radiative Transfer (RT) models have been around for more than a century, from early investigations in stellar atmospheres, through the pioneering work by Chan- drasekhar in the 1940s on the Rayleigh-atmosphere planetary problem, to the wealth of numerical code packages available today. Interestingly, it is only in recent years (see for exampleMishchenko 2014 and references therein), that a rigorous derivation of the radiative transfer equation (RTE) has been established for randomly-oriented particles and particle groups, starting from a set of fundamental assumptions in clas- sical electromagnetic scattering theory. In his famous book on radiative transfer, Chandrasekhar laid out his analytic solution to the Stokes-vector polarized RTE for a single-layer Rayleigh scattering R. Spurr (B) RT Solutions, Inc., 9 Channing Street, Cambridge, MA 02138, USA e-mail: 2 R. Spurr and M. Christi medium (Chandrasekhar 1960). Part of the heritage for LIDORT comes from the older DISORT model (Stamnes et al. 1988), which was made available in the late 1980s. DISORT is the first multiple-scattering multi-layer discrete ordinate scalar RT numerical model able to deal with both solar and thermal sources. The LIDORT model development was started in 1999 in response to a need for a multiple-scattering RT model that would not only calculate radiance fields, but also generate analytically-derived accurate fields of radiance partial derivatives (Jaco- bians, also known as weighting functions or sensitivity functions) with respect to any atmospheric and/or surface parameters that characterize the optical property inputs to the model. Simultaneous output of calculated intensities and Jacobians is essential for the forward-model component of remote-sensing retrievals based on inverse techniques using functional minimization (with and without regularization) (Rodgers 2000). Jacobians are also important for linear error analyses and sensitivity studies. RT models having this capability are said to be “linearized”. Indeed, the use of linearized RTmodels is obviously superior to the older technique of finite-difference (FD) Jacobian computation,whereby two separate calls to theRTmodel are needed to develop a radiance difference to be divided by a perturbation of the desired Jacobian parameter. For applications requiring multi-layer profile Jacobians, FD estimates are slow and cumbersome, requiring many RT model calls; there are also questions of accuracy, since it is a matter of trial and error choosing the degree of perturbation. With LIDORT, a single call to the model will deliver any number of Jacobians of all kinds, and there are no issues of perturbation accuracy. The LIDORT linearization method is based on end-to-end analytic differentia- tion of the entire discrete ordinate radiation field in a multi-layer atmosphere, start- ing with individual layer solutions of the RTE, and moving through the solutions to the boundary-value problem and the post-processing of the solutions using the source-function integration technique (Spurr et al. 2001; Spurr 2002). Other lin- earized RT models have used the “forward-adjoint” RT solution method to obtain accurate derivatives (Hasekamp and Landgraf 2002; Ustinov 2005; Rozanov and Rozanov 2007; Doicu and Trautmann 2009). 1.2 Historical Overview of the (V)LIDORT Models There have been a number of versions of LIDORT since its inception in 1999, and similarly for VLIDORT (original version, 2004). Table 1 gives an overview of the model features and associated version numbers. The first LSR paper [R1] covered versions of LIDORTup to and including 3.3, andVLIDORTup toVersion 2.4 (orange shading); up to that point, codes were written in Fortran 77. Thereafter, codes were translated to Fortran 90. More details on the historical development of these models may be found in the product User Guides. The LIDORT and VLIDORT Linearized Scalar and Vector Discrete … 3 Table 1 Major capabilities of LIDORT and VLIDORT Feature LIDORT VLIDORT version version Pseudo-spherical (solar beam attenuation) 2.1 1.0 Generalized output of Jacobians 2.1 2.0 Green’s function treatment 2.3 n/a 3-kernel BRDF system+ linearizations 2.4 2.2 Performance (multiple SZA, BVP telescoping) 3.0 2.2 Outgoing sphericity correction 3.2 2.3 Total column Jacobian facility 3.3 2.4 Transmittance-only thermal mode 3.3 2.4 Fortran 90 releases, use of I/O type structures 3.5 2.5 Development of BRDF supplement 3.5 2.5 Development of new surface-leaving supplement 3.6 2.6 Atmospheric and surface Planck-function Jacobians 3.7 2.7 Codes made thread-safe for OpenMP parallel computing 3.7 2.7 Introduction of Taylor series expansions 3.7 2.7 Use of phase functions (matrices) in FO code 3.8 2.8 Do-loop optimizations; bookkeeping improvements 3.8 2.8 BRDF and surface-leaving supplement upgrades 3.8 2.8 Fortran 77 Versions. The first version of LIDORT was developed in 1999 with the profile-Jacobian linearization in a plane-parallel atmosphere (Spurr et al. 2001). Out- put of weighting functions was limited to the TOA (top-of-atmosphere) upwelling radiation field, with surface property Jacobians only for the Lambertian albedo. Second versions of LIDORT included development of the pseudo-spherical treat- ment of the solar beam attenuation in a curved atmosphere, and extensions for both upwelling and downwelling Jacobian output at any layer boundary or intermediate level. Green’s function methods were introduced for solving the radiative trans- fer equation (RTE) for solar beam source terms (Spurr 2002; Van Oss and Spurr 2002), and a fully-linearized 3-kernel BRDF (bidirectional reflection distribution function) was developed for the surface boundary condition (Spurr 2004). For the third LIDORT versions, the generation of total column (as opposed to profile) Jaco- bians was integrated into the code, along with an exact treatment of single scattering for curved line-of-sight paths. Developments for VLIDORT have followed a similar path, starting in 2004 with the first version (no linearization), with second versions developed subsequently following their counterparts with the scalar code (Spurr 2006). All these developments were summed up in the previous review article [R1]. Fortran 90 Versions. In 2010, the LIDORT code was translated to Fortran 90 (Ver- sion 3.5), followed byVLIDORT (Version 2.5). Themodels’ organization and coding were overhauled in order to bring the codes in linewithmodern computing standards.

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