Spectroscopic Properties of Inorganic and Organometallic Compounds: Volume 35

376 Pages·2002·3.259 MB·English

by  G Davidson, Brian E Mann, Keith B Dillon, David W H Rankin, Heather E Robertson

Spectroscopic Properties of Inorganic and
Organometallic Compounds
Volume35

ASpecialistPeriodicalReport
Spectroscopic Properties
of Inorganic and
Organometallic
Compounds
Volume 35
AReviewoftheLiteraturePublisheduptolate2001
SeniorReporter
G.Davidson,DepartmentofChemistry,UniversityofNottingham,
UK
Reporters
K.B.Dillon,UniversityofDurham,UK
B.E.Mann,UniversityofSheffield,UK
D.W.H.Rankin,UniversityofEdinburgh,UK
H.E.Robertson,UniversityofEdinburgh,UK
NEWFROM2003
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toarrangeaccesstobesetup.
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ISBN0-85404-436-1
ISSN0584-8555
©TheRoyalSocietyofChemistry2002
Allrightsreserved
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Preface
I am delighted to be able to introduce the thirty-fifth volume in the series of
SpecialistPeriodicalReportsonthe‘SpectroscopicPropertiesofInorganicand
Organometallic Compounds’. The series represents an unrivalled source of
accessible information about an area of chemical research which continues to
growinextentandimportance.
TheReportersaretobecongratulatedonproducingaccountsoftheirchosen
fieldswhichcoverthemostsignificantpublishedworkinamannerwhichisboth
timely,readableandaccessible.
Both theReportersandtheeditorial staffat theRoyalSociety of Chemistry
havemademyjobveryeasy!
GeorgeDavidson
September2002
v
MMMM
Contents
Chapter1 NMRSpectroscopyintheLiquidandGasPhase 1
ByB.E.Mann
1 Introduction 1
2 Stereochemistry 2
2.1 ComplexesofGroups1and2 3
2.2 ComplexesofGroup3,theLanthanidesandActinides 6
2.3 ComplexesofGroup4 7
2.4 ComplexesofGroup5 8
2.5 ComplexesofGroup6 9
2.6 ComplexesofGroup7 12
2.7 ComplexesofGroup8 13
2.8 ComplexesofGroup9 17
2.9 ComplexesofGroup10 20
2.10 ComplexesofGroup11 25
2.11 ComplexesofGroup12 26
3 DynamicSystems 27
3.1 FluxionalMolecules 28
3.1.1 Group1 28
3.1.2 Magnesium 29
3.1.3 Strontium 29
3.1.4 Group3andtheLanthanides 29
3.1.5 Uranium 30
3.1.6 Group4 30
3.1.7 NiobiumandTantalum 32
3.1.8 Chromium,MolybdenumandTungsten 32
3.1.9 Manganese 34
3.1.10 Rhenium 34
3.1.11 Iron 35
3.1.12 Ruthenium 35
3.1.13 Osmium 37
3.1.14 Cobalt 37
3.1.15 Rhodium 38
3.1.16 Iridium 38
SpectroscopicPropertiesofInorganicandOrganometallicCompounds,Volume35
©TheRoyalSocietyofChemistry,2002
vii
viii Contents
3.1.17 Nickel 39
3.1.18 Palladium 39
3.1.19 Platinum 41
3.1.20 Copper 42
3.1.21 Silver 42
3.1.22 Gold 42
3.1.23 Zinc 42
3.1.24 Boron 42
3.1.25 Aluminium 42
3.1.26 Gallium 43
3.1.27 Indium 43
3.1.28 Silicon 43
3.1.29 Germanium 44
3.1.30 Tin 44
3.1.31 Nitrogen 44
3.1.32 Phosphorus 45
3.1.33 Arsenic 45
3.1.34 Oxygen 45
3.1.35 Tellurium 45
3.1.36 Xenon 45
3.2 Equilibria 45
3.2.1 IonicEquilibria 45
Group1 46
Beryllium 47
Magnesium,Calcium,StrontiumandBarium 48
Yttrium,LanthanumandtheLanthanides 48
Uranium 49
Titanium 50
Zirconium 50
Hafnium 50
Vanadium 50
Tantalum 50
MolybdenumandTungsten 50
Rhenium 51
Iron 51
Ruthenium 52
Osmium 52
Cobalt 52
Rhodium 53
Nickel 53
PalladiumandPlatinum 53
Copper 55
Silver 55
Gold 55
Zinc 56
Cadmium 56
Contents ix
Mercury 56
Boron 57
Aluminium 57
Gallium 58
Thallium 58
Silicon 58
Tin 58
Lead 59
Selenium 59
Chlorine 59
Bromine 59
3.2.2 EquilibriaAmongUnchargedSpecies 59
Lithium 59
Magnesium 60
StrontiumandBarium 60
Ytterbium 60
Lanthanum 60
Titanium 60
Zirconium 61
Vanadium 61
Niobium 61
Molybdenum 61
Tungsten 61
Rhenium 61
Iron 62
Ruthenium 62
Osmium 63
Cobalt 63
Rhodium 63
Nickel 64
PalladiumandPlatinum 64
Copper 65
Silver 65
Gold 65
Zinc 65
Cadmium 65
Boron 66
AluminiumandGallium 66
Indium 66
Silicon 66
Tin 67
Arsenic 67
Antimony 67
Tellurium 68
Helium 68
Xenon 68
x Contents
3.3 CourseofReactions 68
3.3.1 Lithium 68
3.3.2 Beryllium 68
3.3.3 Yttrium 68
3.3.4 ThoriumandUranium 68
3.3.5 TitaniumandZirconium 68
3.3.6 Vanadium 69
3.3.7 Niobium 69
3.3.8 Tantalum 70
3.3.9 ChromiumandMolybdenum 70
3.3.10 Tungsten 70
3.3.11 Rhenium 71
3.3.12 Iron 72
3.3.13 Ruthenium 72
3.3.14 Osmium 73
3.3.15 Cobalt 74
3.3.16 Rhodium 74
3.3.17 Iridium 75
3.3.18 Nickel 76
3.3.19 PalladiumandPlatinum 76
3.3.20 Copper 78
3.3.21 Zinc 78
3.3.22 Cadmium 79
3.3.23 Mercury 79
3.3.24 Boron 79
3.3.25 AluminiumandGallium 79
3.3.26 Indium 80
3.3.27 Silicon 80
3.3.28 Germanium 80
4 ParamagneticComplexes 81
4.1 TheTransitionMetals 81
4.1.1 Vanadium 81
4.1.2 Chromium 81
4.1.3 Tungsten 81
4.1.4 Manganese 82
4.1.5 Rhenium 82
4.1.6 Iron 82
4.1.7 Ruthenium 83
4.1.8 Osmium 83
4.1.9 Cobalt 83
4.1.10 RhodiumandIridium 84
4.1.11 Nickel 84
4.1.12 Copper 84