Solid State Ionics: Ionics for Sustainable World PDF
Preview Solid State Ionics: Ionics for Sustainable World
IonIcs for sustaInable World TThhiiss ppaaggee iinntteennttiioonnaallllyy lleefftt bbllaannkk Proceedings of the 13th Asian Conference on IonIcs for sustaInable World Sendai, Japan 17 – 20 July 2012 Editors B V R Chowdari National University of Singapore, Singapore J Kawamura J Mizusaki K Amezawa Tohoku University, Japan World Scientific NEW JERSEY • LONDON • SINGAPORE • BEIJING • SHANGHAI • HONG KONG • TAIPEI • CHENNAI Published by World Scientific Publishing Co. Pte. Ltd. 5 Toh Tuck Link, Singapore 596224 USA office: 27 Warren Street, Suite 401-402, Hackensack, NJ 07601 UK office: 57 Shelton Street, Covent Garden, London WC2H 9HE British Library Cataloguing-in-Publication Data A catalogue record for this book is available from the British Library. SOLID STATE IONICS Ionics for Sustainable World Proceedings of the 13th Asian Conference Copyright © 2013 by World Scientific Publishing Co. Pte. Ltd. All rights reserved. This book, or parts thereof, may not be reproduced in any form or by any means, electronic or mechanical, including photocopying, recording or any information storage and retrieval system now known or to be invented, without written permission from the Publisher. For photocopying of material in this volume, please pay a copying fee through the Copyright Clearance Center, Inc., 222 Rosewood Drive, Danvers, MA 01923, USA. In this case permission to photocopy is not required from the publisher. ISBN 978-981-4439-90-9 Printed in Singapore. Rhaimie - Solid State Ionics (Procs---Book).pmd1 9/3/2012, 10:56 AM iii PREFACE Solid state ionics is a multidisciplinary scientific field to deal with ionic transport in a variety of solids including ceramics, glasses, polymers, composites, nano-scale materials, and biomaterials. In a couple of decades, solid state ionics grew up to one of the most attractive scientific fields because of its useful technological applications such as batteries, fuel cells, sensors, solar cells, capacitors, and electrochromic displays. So far, a large number of scientists and engineers in all over the world are engaged in the research in solid state ionics. Their missions will become increasingly important in future to satisfy social needs solving energy issue and achieving environmental sustainability. Historically, Asia has taken an indispensable role for the developments of solid state ionics. The term of “solid state ionics” was originally established by a Japanese professor, Takehiko Takahashi, in 1970s. The Asian Society for Solid State Ionics was founded in 1986. A series of the academic conference has been biennially held since 1988, in order to enhance the scientific level and to promote friendship and collaboration between the researchers in the Asian society. The present conference is the 13th conference in the series, and held in Japan for the first time. The conference venue Sendai is known as the city where was seriously damaged by the large earthquake and the subsequent Tsunami on 11 March 2011. The city is still under reconstruction even one year after the horrible disasters. Our cordial thanks are devoted to all the participants in the conference for their kind participations in spite of such a situation. The 13th Asian Conference on Solid State Ionics covers all the practical, fundamental, conventional, and groundbreaking aspects of solid state ionics for establishing a sustainable world. We hope the conference will be a milestone toward achieving reconstruction of our mother earth from environmental destruction as well as of Sendai city from earthquake damages. This proceedings book contains research papers on the latest developments and findings in solid state ionics, which are presented at the conference. We express gratitude to the authors for submitting the manuscripts before the deadline and to the publishers for supplying this proceedings book in time for the conference. We are also thankful to the sponsors for their interests in the conference. Last, but not least, we are grateful to the members of the International, the Domestic and the Local Organizing Committees for their untiring efforts in making the conference successful. 7 May 2012 Editors iv ORGANIZATION Organizers Asian Society for Solid State Ionics IMRAM, Tohoku University The Solid State Ionics Society of Japan Conference Chairs Prof. Junichi Kawamura IMRAM, Tohoku University Prof. Junichiro Mizusaki IMRAM, Tohoku University International Organizing Committee Prof. Stefan Adams National University of Singapore, Singapore Prof. B.V.R. Chowdari National University of Singapore, Singapore Prof. M.A.K.L. Dissanayake University of Peradeniya, Sri Lanka Prof. Liu Hanxing Wuhan University & Technology, China Prof. Xuejie Huang Center for Clean Energy, Institute of Physics, CAS, China Prof. Evvy Kartini National Nuclear Energy Agency, Indonesia Prof. Ajit Kulkarni Indian Institute of Technology Bombay, India Prof. Jong-Sook Lee Chonnam National University, Korea Prof. S.R.S. Prabaharan Manipal International University, Malaysia Prof. S. Selvasekarapandian Kalasaringam University, India Prof. V.A. Seneviratne University of Peradeniya, Sri Lanka Prof. Zhaoyin Wen Shanghai Institute of Ceramics, CAS, China Prof. Han-Ill Yoo Seoul National University, Korea Domestic Organizing Committee Prof. Masaru Aniya Grad. Sch. of Sci. and Tech., Kumamoto University Prof. Ryoji Kanno Grad. Sch. of Eng., Tokyo Institute of Technology Prof. Junichi Kawamura IMRAM, Tohoku University Dr. Tetsuro Kobayashi Toyota Central R&D Labs. Inc. Prof. Junichiro Mizusaki IMRAM, Tohoku University Prof. Takashi Sakuma Grad. Sch. of Sci. and Eng., Ibaraki University v Dr. Kazunori Takada National Institute for Materials Science (NIMS) Prof. Masahiro Tatsumisago Grad. Sch. of Eng., Osaka Prefecture University Prof. Masayoshi Watanabe Grad. Sch. of Eng., Yokohama National University Prof. Shu Yamaguchi Grad. Sch. of Eng., The University of Tokyo Local Organizing Committee Prof. Koji Amezawa IMRAM, Tohoku University Prof. Masatoshi Arai Japan Proton Accelerator Research Complex (JPARC) Prof. Shinichi Hashimoto Grad. Sch. of Envi. Stud., Tohoku University Prof. Itaru Honma IMRAM, Tohoku University Prof. Fumitada Iguchi Grad. Sch. of Eng., Tohoku University Prof. Tamio Ikeshoji IMR, Tohoku University Dr. Yoshiki Iwai IMRAM, Tohoku University Prof. Tatsuya Kawada Grad. Sch. of Envi. Stud., Tohoku University Prof. Naoaki Kuwata IMRAM, Tohoku University Prof. Hideki Maekawa Grad. Sch. of Eng., Tohoku University Prof. Shinichi Orimo IMR, Tohoku University Prof. Noriko Sata Grad. Sch. of Eng., Tohoku University Prof. Kazuhisa Sato Grad. Sch. of Eng., Tohoku University Prof. Hitoshi Takamura Grad. Sch. of Eng., Tohoku University Dr. Reiji Takekawa IMRAM, Tohoku University Prof. Atsushi Unemoto IMRAM, Tohoku University Prof. Takeshi Usuki Grad. Sch. of Sci. and Eng., Yamagata University Prof. Keiji Yashiro IMRAM, Tohoku University Prof. Hiroo Yugami Grad. Sch. of Eng., Tohoku University Local staff Katsuko Abe IMRAM, Tohoku University Yoko Arai IMRAM, Tohoku University Yuki Chiba IMRAM, Tohoku University Emi Hashimoto IMRAM, Tohoku University Sayuri Hayasaka IMRAM, Tohoku University Dr. Hellar Nithya IMRAM, Tohoku University Dr. Jeyapandian Malathi IMRAM, Tohoku University Yasutaka Matsuda IMRAM, Tohoku University Hiroe Shoji IMRAM, Tohoku University vi Sponsored By Asian Society for Solid State Ionics The Solid State Ionics Society of Japan IMRAM, Tohoku University Sendai Tourism & Convention Bureau (STCB) Aoba Foundation for The Promotion of Engineering Res. Cen. for Sustainable Sci. & Eng., IMRAM, Tohoku University Nano-Macro Materials, Devices and System Research Alliance The SOFC Society of Japan The Committee of Battery Technology, The Electrochemical Society of Japan vii Wednesday, 18 July Plenary Talk 9:00- 9:30 Opening Session 9:30-10:20 SOLID STATE IONIC MATERIALS: PAST, PRESENT & FUTURE PL-1 B. V. R. Chowdari 10:20-10:35 Coffee break 10:35-11:25 EXCHANGE AND INTERCALATION REACTION FROM SODIUM BASED AxMO2 LAYERED OXIDES PL-2 C. Delmas, R. Berthelot, D. Carlier, M. Pollet, C. Didier, M. Guignard, J. Darriet and F. Weill 11:25-12:15 HIGH POWER DENSITY SOLID OXIDE FUEL CELLS USING LaGaO3 PEROSKITE OXIDE THIN PL-3 FILM PREPARED BY PLD METHOD Tatsumi Ishihara 21 12:15-13:45 Lunch Session A Solid Electrolytes 13:45-14:10 WATER STABLE LITHIUM ION CONDUCTING SOLID ELECTROLYTE FOR LITHIUM-AIR Inv-A1 RECHARGEABEL BATTERY O. Yamamoto, N. Imanishi, Y. Takeda, K. Ishiguro, Y. Nakata, Y. Takahashi, and M. Zhang 14:10-14:25 CORRELATION BETWEEN ELECTRICAL CONDUCTIVITY AND GLASS TRANSITION Oral-A1 TEMPERATURE OF Li2O:B2O3:SiO2:TiO2:Li2SO4 GLASSES A. V. Deshpande, N. S. Satpute 33 14:25-14:40 INTERFACE RESISTANCE AT THE SINGLE GRAIN BOUNDARY OF LiCoO2 EPITAXIAL THIN Oral-A2 FILMS A. Kumatani, T. Ohsawa, T. Suzuki, Y. Takagi, S. Shiraki, H. Oki, H. Moriwake, Y. Ikuhara, T. Hitosugi 14:40-14:55 STRUCTURE AND ELECTROCHEMICAL PROPERTIES OF LAYERED STRUCTURE Oral-A3 La2Li2x(CO)1-xO4 Muhammad Iqbal, Genki Kobayashi, Masaaki Hirayama, Ryoji Kanno 41 14:55-15:10 GEL MEMBRANE AS A KEY CHOICE TO ENSURE THE SAFETY PROBLEM OF LITHIUM ION Oral-A4 BATTERIES FOR ELECTRIC VEHICLES Y. S. Zhu, Y. Y. Hou, X. J. Hou, Y. P. Wu 15:10-15:30 Coffee break SE calculations 15:30-15:55 STRUCTURE – CONDUCTIVITY CORRELATIONS IN BATTERY MATERIALS Inv-A2 S. Adams 76 15:55-16:10 FIRST PRINCIPLES CALCULATION OF ELECTRONIC STRUCTURES AND THEORETICAL Oral-A5 POTENTIALS OF SPINEL LiNi0.5Mn1.5O4 A. Kuwabara, C. A. J. Fisher, Y. H. Ikuhara, H. Moriwake, Y. Ikuhara, H. Oki 16:10-16:25 VARIATION OF IONIC CODUCTIVITY WITH ANNEALING TEMPERATURE IN ARGYRODITE Oral-A6 SOLID ELECTROLYTES R. Prasada Rao, Chen Maohua, S. Adams 3 16:25-16:40 THEORETICAL AND EXPERIMENTAL STUDIES OF CONDUCTION PATHWAYS IN IONIC Oral-A7 CONDUCTORS Max Avdeev, Matthew Sale 16:40-16:55 FAST Li-ION CONDUCTOR: HOW THE IONS MOVE IN SOLID ELECTROLYTE LiBH4 Oral-A8 Tamio Ikeshoji, Eiji Tsuchida, Tetsuya Morishita, Kazutaka Ikeda, Motoaki Matsuo, Yoshiyuki Kawazoe, and Shin-ichi Orimo 17:00-19:00 Poster session Poster
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