Solid State Ionics 1993: Vol 63-65 Table of Contents

9 Pages·1993·1.5 MB·English

CONTENTS
Preface
Organizing and Advisory Committees
Invited lecture
M. Senna, Incipient chemical interaction between fine particles under mechanical stress —-
a feasibility of producing advanced materials via mechanochemical routes
A. SYNTHESIS AND CHARACTERIZATION
F. Lindner and A. Feltz, Electrophoretic deposition - a method for preparation of
semiconducting oxide ceramic layers
M. Schultz, St. Grimm and W. Burckhardt, The isoelectric point of pure and doped zirconia in
relation to the preparation route
C. Ducamp-Sanguesa, R. Herrera-Urbina and M. Figlarz, Fine palladium powders of uniform
particle size and shape produced in ethylene glycol
I. Voigt and A. Feltz, Reactivity of manganese oxide-doped Y,O,-stabilized ZrO,
H.W. Brinkman, G.Z. Cao, J. Meijerink, K.J. de Vries and A.J. Burggraaf, Modelling and
analysis of CVD processes for ceramic membrane preparation
E.L. Sham, E.M. Farfan-Torres, $. Bruque-Gamez and J.J. Rodriguez-Jiménez, Synthesis of
ZrC/ZrO, by pyrolysis of modified zirconium alkoxide precursors
J. Garcia, A. Gonzalez, M.J. Sanchis, M.D. Marcos, E. Martinez, F. Sapifia, D. Beltran and
A. Beltran, Precursor-based synthetic pathways to nanometer NdNiO,_., particles
M. Vallet-Regi, C.V. Ragel, J. Ramirez and J.M. Gonzalez-Calbet, Synthesis of mixed oxides by
decomposition of polymeric acids
A. Galdén and M.C. Guillem, Preparation of mixed oxides MNdO,, with M=Cr, Fe.
Comparison of several methods
J.L. Pizarro, M.I. Arriortua, L. Lezama, T. Rojo and G. Villeneuve, Synthetic pathways to
obtain phosphates and arsenates of Co(II) and Ni(II) related to minerals: magnetic
properties
P. Barret, L. Ben Allal and D. Bertrandie, Elucidation of reaction process between solid
tricalcium silicate and a lanthanum salt solution in connection with the precipitation pH.
Extension to other elements
M.D. Marcos, P. Amords, A. Beltran and D. Beltran, New tubular transition metal oxoanionic
derivatives: a systematic approach to condensed phases of the dumortierite family
M.D. Marcos, P. Amordés, A. Beltran and D. Beltran, Transition metal derivatives of low
oxidation state phosphorus oxoacids: synthetic pathways and structural studies
J. Subrt and J. Tlaskal, Mechanically activated reaction of barium carbonate with iron(III)
oxide-hydroxides
x Contents
E. Ponthieu, L. Rao, L. Gengembre, J. Grimblot and R.B. Kaner, Solid-state synthesis of
aluminum nitride through a metathetical route
S. Colque, P. Grange and B. Delmon, Preparation of tungsten carbides on silica — evidence of
coupling effects during reduction/carburization of tungsten oxide
L. Perier-Camby and G. Thomas, Solid way synthesis of barium aluminate. Kinetic study of the
formation of intermediate compounds
M. Valigi, A. Cimino, D. Cordischi, S. De Rossi, C. Ferrari, G. Ferraris, D. Gazzoli, V. Indovina
and M. Occhiuzzi, Molybdenum (VI) interaction with zirconia surface and its influence on
the crystallization and sintering
L. Aymard and M. Figlarz, Production of Ag-Pd alloys by mechanical alloying
T. Yamamoto, S. Kikkawa and F. Kanamaru, Preparation of new ternary nitrides CaMN
(M=Co, Ni)
M. Ueda, S. Shimada and M. Inagaki, Preparation of a-Fe,O0, balloons and reaction with ZnO
powder
M. Labeau, B. Gautheron, J. Pefia, M. Vallet-Regi and J.M. Gonzalez-Calbet, Synthesis of pure
and Pd-doped SnO, particles
M. Vallet-Regi, V. Ragel, J. Roman, J. Martinez, M. Labeau, A. Varela and J.M. Gonzalez-
Calbet, Synthesis of cassiterite by pyrolysis of an aerosol
M. Ocafia, C.J. Serna, J.V. Garcia-Ramos and E. Matijevi¢, A vibrational study of uniform SnO,
powders of various morphologies
M. Amberg and J.R. Giinter, Oxides of tetravalent metals, prepared from their sulfides and
selenides
M. Itoh, A. Matsumoto, O. Sakurada, M. Hashiba and Y. Nurishi, Diversity of MgAl,O,
formation associated with changes in physical nature of powders
M. Hashiba, C. Matsuda, Y. Katayama, O. Sakurada and Y. Nurishi, Promotion of ZnAl,O,
formation in the presence of Li,AIF,
R. Furuichi, S. Nakano, S. Shimada and T. Ishii, Effect of preparation temperature and grinding
time of a-Fe,O, on its reactivity for MgFe,O, formation
M. Vallet-Regi, J. Pefia, A. Martinez and J.M. Gonzalez-Calbet, Influence of the synthetic
method on the TiO, texture
M.V. Cabaiias, J.M. Gonzalez-Calbet and M. Vallet-Regi, Influence of the synthetic route on the
BaFe,,0;9 properties
M.J. Saavedra, C. Parada, M.O. Figueiredo and A. Correa dos Santos, Ca—Zr-O system:
synthesis and characterization of compounds using several routes of preparation
G. Monrés, J. Carda, M.A. Tena, P. Escribano, F. Ribot and C. Sanchez, Vanadium clusters in
doped ZrO,-SiO, toughened ceramic composites obtained from alkoxides
Contents
Invited lectures
S. Bordére, A. Floreancig, F. Rouquérol and J. Rouquérol, Obtaining a divided uranium oxide
from the thermolysis of UO,(NO;) 2°6H,0: outstanding role of the residual pressure
A. Rousset, Reactivity of solids and new metastable phases: examples of mixed valence defect
spinel ferrites and manganites
Plenary lecture
J. Sestak and J. Malek, Diagnostic limits of phenomenological models of heterogeneous
reactions and thermal analysis kinetics
B. THERMAL DECOMPOSITION
P. Porta, G. Moretti, M. Musicanti and A. Nardella, Copper-manganese mixed oxides:
formation, characterization and reactivity under different conditions
M.T. Clavaguera-Mora, S. Surifiach, M.D. Baré and N. Clavaguera, Study of phase
transformation kinetics: application to non-crystalline solids
M. Sturzenegger, H.R. Oswald and A. Reller, Thermochemical reactivity of delafossite-type
AgNio.sTig 502 and CuNi sTig 502 in O, and H,
M.C. Annesini, R. Lavecchia, L. Marrelli, M.L. Jacono, M.C. Campa, G. Fierro, G. Moretti and
P. Porta, Reduction kinetics of CuO-ZnO
D. Stirling and F.S. Stone, UV-visible-NIR reflectance spectroscopy applied to Cu-Zn
hydroxycarbonates and their decomposition products
P. Balaz and J. Brianéin, Reactivity of mechanically activated pyrite
A.R. Landa-Canovas, L.C. Otero-Diaz, L. Botto and I.B. Schalamuk, Electron microscopy study
of the decomposition products at 1300°C from jamesonite mineral FePb,Sb,S,,4
M. Epple and H.K. Cammenga, The dehydration of lithium sulphate monohydrate investigated
with DSC, TG and temperature-resolved X-ray diffractometry - a comparison between three
methods
S. Shimada and M. Inagaki, A kinetic study on oxidation of niobium carbide
L.C. Otero-Diaz, M.J. Torralvo and R.M. Rojas, Thermal behaviour and microstructural
characterization of y-Dy,S,
F. Gémez-Garcia, J.P. Gomez, J.M. Jiménez-Mateos, S. Vic, J.L.G. Fierro, M.A. Pefia and
P. Terreros, Mg-Ni—O based OCM catalyst obtained by carbonate precursor method
M.G. Salvetti, M. Pijolat, M. Soustelle and E. Chassagneux, Pyrolysis of a polysilazane precursor
to SiCN ceramics
M. Touboul and E. Bétourné, LiB,O,(OH )-H,0 as precursor of lithium boron oxide LiB,O,; :
Synthesis and dehydration process
M. Maciejewski, A. Baiker, H. Viebrock, U. Sazama, P.-M. Wilde and A. Reller, Structure and
thermochemical reactivity of Cu(NH;),CO,
xii Contents
M. Insausti, R. Cortes, M.I. Arriortua, T. Rojo and E.H. Bocanegra, Alkaline-earth Cu(II)
oxalate compounds as precursors of MCuO, (M = Ca, Sr, Ba) oxides: thermal and
spectroscopic study
A. Marini, V. Berbenni, V. Massarotti, P. Mustarelli, R. Riccardi, A. Gazzaniga, F. Giordano,
G..Bruni and M. Villa, Thermal study of water/B-cyclodextrin interactions
F. Rouquérol, Y. Laureiro and J. Rouquérol, Influence of water vapour pressure on the thermal
dehydration of lithium sulphate monohydrate
Invited lectures
M.J. McKelvy, R. Sharma and W.S. Glaunsinger, Atomic-level imaging of intercalation reactions
by DHRTEM
A.R. Landa-Canovas and L.C. Otero-Diaz, Transformation of Mn(Mn, Er),S, spinel-type by
electron radiation damage at 400 kV
C. INTERCALATION AND SOFT CHEMISTRY
Y.J. Li and M.S. Whittingham, Hydrothermal synthesis of new metastable phases: preparation
and intercalation of a new layered titanium phosphate
G. Dhalenne, F. D’Yvoire, P. Berthet and A. Revcolevschi, Electrochemical oxidation of CO-
ZrO,(CaO) lamellar eutectic structures to form aligned Co,;0,-ZrO,(CaO) material:
Mechanism and crystallography of the reaction
F. Garcia-Alvarado and J.M. Tarascon, New vanadium bronzes M,V,O; (M=Cu or Ag;
0<y<0.85): Structure and lithium intercalation
M.A.G. Aranda, S. Bruque, J.R. Ramos-Barrado and J.P. Attfield, Relation between structure
and ionic conductivity in the lithium derivatives, LiMnXO,(OH) (X=P, As)
R. Dronskowski, A quantum mechanical study on the reactivity and acidity of the LiAlO,-
benzoic acid soft chemical reaction
P.G. Dickens, G.P. Stuttard, R.E. Dueber, M.J. Woodall and S. Patat, Intercalation compounds
of some mixed oxides of uranium
P. Gémez-Romero, M.R. Palacin, N. Casafi and A. Fuertes, Synthesis of a reduced niobium
“blue” with a layered perovskite structure
M.C. Blesa, U. Amador, E. Moran, N. Menéndez, J.D. Tornero and J. Rodriguez-Carvajal,
Synthesis and characterization of nickel and magnesium ferrites obtained from a-NaFeO,
L. Seguin, M. Figlarz and J. Pannetier, A novel supermetastable WO, phase
O. Garcia-Martinez, R.M. Rojas, E. Vila and J.L. Martin de Vidales, Microstructural
characterization of nanocrystals of ZnO and CuO obtained from basic salts
C. Barriga, P. Lavela, J. Morales and J.L. Tirado, Chemical and electrochemical intercalation of
lithium into SnTiS, and BiTi,S, misfit layer compounds
J.M. Trillo, M.D. Alba, R. Alvero, M.A. Castro, A. Mujfioz, J. Poyato, M.M. Tobias and
G. Lagaly, Montmorillonites intercalated with Al(III), La(III) and alumina pillars: structural
aspects and reactivity
Contents
T. Tsuchida, Preparation and reactivity of acicular a-Al,O, from synthetic diaspore, B-
Al,O;'H,0
N. Soga and M. Senna, Intercalation of cetyl trimethyl ammonium bromide into mechanically
activated V,O, xerogel
A. Shimizu, T. Tsumura and M. Inagaki, Electrochemical intercalation of lithium into V,O.:
Effect of host materials
A. Boireau, J.L. Soubeyroux, R. Olazcuaga, C. Delmas and G. le Flem, Li intercalation in
Cu}! ;Ti,(PO,)3: A neutron diffraction study of Li; ,<Cup sTi,(PO,);
M.L. Rodriguez, M. Suarez, J.R. Garcia and J. Rodriguez, Intercalation of n-alkylamines in
a-hafnium phosphate
B. Chauvel, P. Bondot, M. de Roy and J.P. Besse, Local environment in mixed valence
VOPO,:2H,0 intercalated compounds
M. Cantero, M. Martinez-Lara, S. Bruque and L. Moreno-Real, Reaction of niobium phosphate
with hydrazine: structural modification
E.M. Farfan-Torres, J. Maza-Rodriguez, M. Martinez-Lara and A. Jimenez-Lopez, Formation of
silica interlayers in a-zirconium-titanium mixed phosphate and phosphonate
J.M. Saniger and N.A. Sanchez, Zeolite 4A reactivity with gaseous fluorine
U. Amador, A. Varez, E. Moran and M.A. Alario-Franco, On the motion of lithium in
YBa,Cu,O, lithiated materials
Y. Soneda and M. Inagaki, Formation and stability of new FeCl,-graphite intercalation
compounds
O. Kalogirou, G. Haack, B.R. R6hl and W. GunBer, Méssbauer study of a modified M-type
Ba(Sr)-ferrite prepared by ion exchange
Plenary lecture
V.V. Boldyrev, Mechanochemistry and mechanical activation of solids
Invited lecture
J. Alamo, Chemistry and properties of solids with the [NZP] skeleton
D. STRUCTURE, DEFECTS AND PROPERTIES
H.R. Oswald, S. Felder-Casagrande and A. Reller, Structure and properties of perovskite-related
Sr—Ru-Ti-O phases
J.M. Salazar and F. Tzschichholz, Defect self-organization in two-dimensional lattices under an
external loading
M. Millares, B. Pieraggi and E. Lelievre, Reaction/diffusion in the Au-In system
P. Melnikov, I. Bueno, C. Parada, E. Moran, C. Leén, J. Santamaria and F. Sanchez-Quesada, A
study of ionic conductivity in double rare-earth chromates
xiv Contents
J. Blasco, J. Garcia, M.G. Proietti and J. Chaboy, Structural and physical characterization of
NdNiO, synthesized by a sol-gel method
J. Blasco and J. Garcia, Structure, magnetic and electrical properties in Nd, _,La,NiO,; system
M.L. Lépez, I. Alvarez, M. Gaitan, A. Jerez, C. Pico and M.L. Veiga, Structural study and
magnetic measurements of some perovskites MLnLiTeO,
P. Gémez-Romero, M.R. Palacin, N. Casafi, A. Fuertes and B. Martinez, Towards the synthesis
of layered perovskites. Synthesis, structure and magnetic properties of La,CuTiO,
I. Alvarez, M.L. Lépez, C. Génzalez, A. Jerez, M.L. Veiga and C. Pico, Synthesis, structural
characterization and properties of perovskite-type mixed oxides: BaLnBNiO, (Ln=La,Nd;
B=Sb,Nb,Ta)
M. Parras , J. Alonso, J.M. Gonzalez-Calbet and M. Vallet-Regi, Compositional variations and
structural disorder in the BaMnO,_, system
B. Gillot, B. Domenichini, Ph. Tailhades, L. Bouet and A. Rousset, Reactivity of the submicron
molybdenum ferrites towards oxygen and formation of new cation deficient spinels
W. Wolski, E. Wolska, J. Kaczmarek and U. Politafiska, Nonstoichiometric solid solutions
during formation of Cd/Ni ferrites
J. Kaczmarek and E. Wolska, The defect structure and vacancy distribution in the low-
temperature hausmanite
C. Alonso, M. Acha and C. Andrade, Reactivity of metallic glass fibres in simulated concrete
pore solutions
J.P. Rino and G.A. Antonio, Amorphous ZrF, - a molecular dynamics study
J. Quifiones, A. Urefia, J.M. Gomez de Salazar, H. Blanco and S. Merino, Mathematical models
of diffusion processes
L. Lezama, J.M. Rojo, J.L. Pizarro, M.I. Arriortua and T. Rojo, Reduced molybdenum
phosphates: synthesis, characterization and magnetic properties
W. Gunsser, W.J. Girnus and K. Matzen, Preparation and structural properties of amorphous
and polycrystalline Gd,Cr,Gas,O_, . (x=0, 1, 2)
C.L. Zeng, Y. Niu, W.T. Wu, J.Q. Zhang, F. Gesmundo and J.T. Guo, Rapid oxidation and
sulfidation of FeAl intermetallics in NaCl-(Na, K.)SO, melts at 800-850°C
J. Alamo and J.L. Rodrigo, High temperature neutron diffraction study of CaZr,(PO,)<
M.P. Carrasco, M.C. Guillem and J. Alamo, Preparation, structural characterization and study
of the properties of the system NaGe,(PO,),—NaTi,(PO,);
M.P. Carrasco, M.C. Guillem and J. Alamo, Structural study, thermal expansion and electrical
conductivity of the composition NaSnZr(PO,),
B.A. Menegazzo, D. Garcia and J.A. Eiras, Structural analysis of PLZT powders prepared by
conventional and precipitation methods
Contents
N. Cho, S. Kikkawa, F. Kanamaru, Y. Takeda, O. Yamamoto, H. Kido and T. Hoshikawa,
Crystal structural, electric and magnetic studies on the misfit layer compounds “LnMS,”
(Ln=rare-earth metal; M=Ti,V,Cr)
C. Real, M.D. Alcala and J.M. Criado, Correlation between the structural defects induced by
ball-milling of Pb,O, and the structure of PbO yielded from its thermal decomposition
I. Bueno, C. Parada, R. Saez Puche and E.J. Baran, Thermal decomposition, vibrational study
and magnetic properties of Ln,(CrO,),;-7H,O(Ln=La-Eu)
M. Parras, J.M. Gonzdlez-Calbet, M. Vallet-Regi and J.C. Grenier, A high temperature study of
the BaFeO,_, system
Invited lecture
A.V. Chadwick, EXAFS studies of dopant sites in metal oxides
E. SURFACE AND CATALYSIS
C. Mazzocchia, A. Kaddouri, R. Anouchinsky, M. Sautel and G. Thomas, On the NiO, MoO,
mixed oxide correlation between preparative procedures thermal activation and catalytic
properties
M. de Boer, E.P.F.M. Koch, R.J. Blaauw, E.R. Stobbe, A.N.J.M. Hoffmann, L.A. Boot, A.J. Van
Dillen and J.W. Geus, The cobalt-molybdenum interaction in CoMo/SiO, catalysts: A CO-
oxidation study
L.E. Cadus, F.J. Gotor, D. Acosta, J. Naud, P. Ruiz and B. Delmon, Solid state reaction in the
iron—molybdenum-antimony oxide system
J.P. Espinés, A.R. Gonzalez-Elipe and G. Munuera, Diffusion of nickel and surface
reconstruction in Ni/TiO, catalysts promoted by H, and O, treatments
J. Soria, J.C. Conesa, A. Martinez-Arias and J.M. Coronado, ESR study of the clustering of Cu
ions on the ceria surface in impregnated CuO/CeO,
J. Herreros, A. Garcia Arribas and J.M. Barandiaran, Working electrode polarization in
galvanostatic deposition of amorphous Co-P ferromagnetic alloys
Y. Niu, F. Gesmundo and F. Viani, The corrosion of Fe, Co and Ni alloys containing 15 and 30
wt% Nb in H,-H,S mixtures under 10~* atm S, at 600°C
J.J. Pis, J.A. Menéndez, C. Barriocanal, R. Alvarez, J.B. Parra and M.A. Diez, Relation between
reactivity and textural properties in cokes from wet and preheated coals
M. Fernandez-Garcia, J.C. Conesa and F. Illas, Quantum chemical study of the bond activation
for NO adsorbed on a Cu surface
M. Pijolat, M. Prin, M. Soustelle, O. Touret and P. Nortier, Surface area stability of lanthanum-
doped ceria
S. Gotti, L. Sobrados and M.S. Hernandez, Increase of acid-surface reactivity through water
molecules adsorption process: V,O;—CaCO, behaviour
J. Callejas-Fernandez, R. Martinez-Garcia, J. de las Nieves Lopez and R. Hidalgo-Alvarez,
Electrosuperficial properties of calcium oxalate hydrates: Crystal growth and ionic reactivity
xvi Contents
M.T. Gaztafiaga, S. Gofii and J.L. Sagrera, Reactivity of high-alumina cement in water: pore-
solution and solid phase characterization
T.F. Otero and E. Angulo, Oxidation-reduction of polypyrrole films. Kinetics, structural model
and applications
T.F. Otero and C. Santamaria, Redox behaviour of thin polypyrrole films. Optimization of
response times
H. Kruidhof, H.J.M. Bouwmeester, R.H.E.v. Doorn and A.J. Burggraaf, Influence of order-
disorder transitions on oxygen permeability through selected nonstoichiometric perovskite-
type oxides
Invited lecture
J.-C. Grenier, A. Wattiaux, A.D emourgues, M. Pouchard and P. Hagenmuller, Electrochemical
oxidation: a new way for preparing high oxidation states of transition metals
Plenary lecture
C.N.R. Rao, Fascinating chemistry of metal clusters and carbon clusters (fullerenes)
F. SUPERCONDUCTING MATERIALS AND RELATED SOLIDS
V.A. Self, M.R. Soames, P.A. Sermon, M.S.W. Vong and M.A.S.L. Thoo, Reactivity of
YBa,Cu,0, superconductors towards NO
I. Sargankova, P. Diko, M. Timko, M. Cernik and J. Mihalik, Synthesis of YBa,Cu,O,_, via
sol-gel
U. Amador, E. Moran, M.A. Alario-Franco, J. Ibafiez, J. Martin and T.S. Rey, On the oxidation-
reduction of Ba,PrCu,O, single crystals
E. Garcia, M. Vallet-Regi, A. Reller and J.M. Gonzdlez-Calbet, Thermogravimetric and
microstructural studies on YBa,Cu,;_ ,Fe,O,
V. Primo, F. Sapifia, M.J. Sanchis, R. Ibafiez, A. Beltran and D. Beltran, Fast synthesis of single-
phased 110 K bismuth superconductor by freeze-drying of acetic precursors. Kinetic role of
calcium and copper oxides
A. Sotelo, L.A. Angurel, M.T. Ruiz, A. Larrea, F. Lera and G.F. de la Fuente, Stoichiometry
variation effect on the superconducting properties of polymer-processed
(Bi, _.Pb,)Sr,Ca,Cu,0;9 ceramics
Y.-B. Huang, G.F. de La Fuente, A. Sotelo, M.T. Ruiz, A. Larrea, L.A. Angurel, R. Navarro,
F. Lera, R. Ibafiez, H. Miao, V. Primo and D. Beltran, Ag/ (Bi, Pb)—Sr-Ca—Cu-O
superconducting tape processing: Solid state chemistry aspects
A. Castro, P. Millan, M.J. Martinez-Lope and J.B. Torrance, Substitutions for Bi?* into
(Bi,O,)?* layers of the Aurivillius (Bi,O,)(A,_,B,O3,4;) oxides
M.T. Fernandez-Diaz, J.L. Martinez and J. Rodriguez-Carvajal, High-temperature phase
transformation of oxidized R,NiO,,,; (R=La, Pr and Nd) under vacuum
Contents
C. Rial, U. Amador, A. Varez, E. Moran, M.A. Alario-Franco, A. Gonzalez and J.M. Pingarrén,
Room temperature lithium reduction of LagMO,,5 (M=Cu, Ni)
E. Garcia-Matres, J. Rodriguez-Carvajal, J.L. Martinez, J.A. Alonso, A. Salinas-Sanchez and
R. Saez-Puche, Polymorphism in the oxides R,BaNiO,; (R=Tm, Yb, Lu)
R. Sdez-Puche, J. Hernandez-Velasco and F. Fernandez, Synthesis, characterization and
polymorphism of new R,BaCoO, oxides (R=Dy-Lu)
A. Salinas-Sanchez and R. Saez-Puche, Structural characterization and magnetic properties of
LaRBaCuO, oxides (R=rare earth)
M.J. Ruiz Aragon, C. Rial, E. Moran, J.B. Torrance, N. Menéndez and J.B. Tornero, Synthesis
and characterization of LaMCuFeO,,,; (Ln=Y, La, Pr; M=Ca, Sr, Ba)
N. Casafi-Pastor, P. Gomez-Romero, A. Fuertes and J.M. Navarro, Electrochemical oxidation of
La,CuO,. Influence of thermal treatment on superconductivity
M.A. Sefiaris-Rodriguez, M.A. Alario-Franco, S.L. Stoll and A. Stacy, The microstructure of
superconducting La,_,K,CuO,_, (x=0.22)