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SOIL CONTAMINATION MAPPING FOR AN ABANDONED COAL MINE SITE BY USING WORLDVIEW 2 AND ASTER IMAGERY A THESIS SUBMITTED TO THE GRADUATE SCHOOL OF APPLIED AND NATURAL SCIENCES OF MIDDLE EAST TECHNICAL UNIVERSITY BY HİLAL SOYDAN IN PARTIAL FULFILLMENT OF THE REQUIREMENTS FOR THE DEGREE OF MASTER OF SCIENCE OF PHILOSOPHY IN MINING ENGINEERING AUGUST 2013 iv Approval of the thesis: SOIL CONTAMINATION MAPPING FOR AN ABANDONED COAL MINE SITE BY USING WORLDVIEW 2 AND ASTER IMAGERY submitted by HİLAL SOYDAN in partial fulfillment of the requirements for the degree of Master of Science of Philosophy in Mining Engineering Department, Middle East Technical University by, Prof. Dr. Canan Özgen _____________________ Dean, Graduate School of Natural and Applied Sciences Prof. Dr. Ali İhsan Arol _____________________ Head of Department, Mining Engineering Prof. Dr. H. Şebnem Düzgün Supervisor, Mining Engineering Dept., METU _____________________ Examining Committee Members: Prof. Dr. Bahtiyar Ünver _____________________ Mining Engineering Dept., Hacettepe Uni. Prof. Dr. H. Şebnem Düzgün _____________________ Mining Engineering Dept., METU Prof. Dr. Ali İhsan Arol _____________________ Mining Engineering Dept., METU Assoc. Prof. Dr. Nuray Demirel _____________________ Mining Engineering Dept., METU Dr. İ. Hakkı Güçdemir _____________________ Department of Soil and Water Resources Research, Republic of Turkey Ministry of Food, Agriculture and Livestock Date: ______ v I hereby declare that all information in this document has been obtained and presented in accordance with academic rules and ethical conduct. I also declare that, as required by these rules and conduct, I have fully cited and referenced all material and results that are not original to this work. Name, Last Name: Hilal SOYDAN Signature : iv ABSTRACT SOIL CONTAMINATION MAPPING FOR AN ABANDONED COAL MINE SITE BY USING WORLDVIEW 2 AND ASTER IMAGERY Soydan, Hilal M.Sc., Department of Mining Engineering Supervisor: Prof. Dr. H. Şebnem Düzgün August 2013, 183 pages Being an indispensable economic and energy source, coal mining may be the cause of long term environmental damages like serious water and soil contamination due to inappropriate mining operations. In order to detect and avoid it, mapping the contamination levels related to mining industry has been a challenge for soil scientists to find the most appropriate and time and cost effective method for constructing soil contamination maps. So far, Remote Sensing (RS) and Geographical Information Systems (GIS) have been utilized as auxiliary data for producing more accurate Digital Soil Maps (DSM), especially by methods based on supervised classification techniques. In this study, Worldview 2 stereo imagery and ASTER imagery of an abandoned mining area were utilized for data analyses by forming statistical relationships between reflectance spectra of both imageries, and results of chemical analyses of soil. Similar statistical relationships are examined between the laboratory reflectance spectra and the chemical properties of the soil samples from study area. After employing necessary pre-processing techniques, Worldview 2 and ASTER data spectra were utilized for Multiple Linear Regression (MLR) analysis. Furthermore, after the fieldwork, ASD Inc. Agrispec spectrometer measurements were performed in order to collect laboratory spectra of soil samples as an input of spectral library of the area and the acquired spectra data were used as the input for Partial Least Square Regression (PLSR) analyses for demonstrating the relationship between the constituents of soil and laboratory spectra. The PLSR coefficients were plotted for identifying important wavelengths related to the properties and a comparison between PLSR and MLR analysis results was performed to see the consistency and differences of predictive wavelengths for each soil property. The comparison showed that the results were internally consistent as well as with the published results in the literature to predict specified soil properties. In addition, MLR equations defining the soil properties were applied to the bareland areas of the study area to produce contamination maps whose accuracy assessments were implemented with an independent data set. ASTER, whose bands up to shortwave infrared region were utilized, ended up providing higher accuracies than Worldview-2 for producing soil contamination maps. Keywords: Abandoned Coal Mines, Digital Soil Mapping, Soil Contamination, Aster, Worldview 2 v ÖZ WORLDVIEW 2 VE ASTER GÖRÜNTÜLERİ KULLANILARAK TERKEDİLMİŞ BİR KÖMÜR MADEN SAHASININ TOPRAK KİRLİLİK HARİTALARININ OLUŞTURULMASI Soydan, Hilal Yüksek Lisans, Maden Mühendisliği Bölümü Tez Yöneticisi: Prof. Dr. H. Şebnem Düzgün Ağustos 2013, 183 sayfa Kömür madenciliği vazgeçilmesi güç bir ekonomik kaynak olarak özellikle enerji üretimi açısından önemini korumakta, ancak düzgün uygulanmayan madencilik aktiviteleri su ve toprak kirliliği gibi çevresel problemlere ve uzun süreli zararlara sebep olmaktadır. Bu kirliliğin tespiti ve engellenmesi için zaman ve maliyet açısından etkin yöntemlerle toprak kirlilik seviyelerinin haritalanması toprak bilimciler için önemli bir çalışma alanı olmuştur. Şu ana kadar Coğrafi Bilgi Sistemleri (CBS) ve Uzaktan Algılama (UA) metotları yardımıyla denetimli sınıflandırma kullanarak doğruluğu yükseltilmiş dijital toprak haritaları üretimi ile ilgi birçok çalışma yapılmıştır. Bu çalışmada ise, CBS ve UA yöntemleri kapsamında, ASTER ve Worldview 2 uydu görüntülerinin yansıma değerleri ve üzerinde çalışılan terk edilmiş maden alanından toplanmış toprak numunelerinin laboratuar yansıma değerleri ile kimyasal analiz sonuçları arasında istatistiksel ilişkiler kurulmuştur. Gerekli veri ön-işleme teknikleri uygulandıktan sonra, Worldview 2 ve ASTER görüntülerinden alınan yansıma profilleri çoklu lineer regresyon analizlerine tabi tutulmuştur. Araziden alınan toprak numunelerinin laboratuar spektraları ASD Inc. Agrispec spektrometresi ile toplanarak arazinin spektral kütüphanesine eklenmiş ve bu spektral veri, kısmi en küçük kareler regresyon analizi için girdi olarak kullanılarak, toprak bileşenlerinin laboratuar spektrası ile ilişkisi değerlendirilmiştir. Buna ek olarak, kısmi en küçük kareler regresyon katsayı grafikleri çizilerek, toprak bileşenlerinin tahmini için önemli dalga boyları belirlenmiş ve toprak özelliklerini tahmin eden bu dalga boylarının birbiriyle ve literatürdeki sonuçlarla uygunluğunu görmek amacıyla, en küçük kareler regresyon analizi sonuçları ve çoklu lineer regresyon sonuçları birbiriyle karşılaştırılmıştır. Yapılan karşılaştırmalarda sonuçların birbiriyle olduğu kadar literatürle de uyumlu olduğu görülmüştür. Bu işlemden sonra, çoklu lineer regresyon denklemleri, çalışma alanı içerisindeki boş arazilere uygulanarak, doğruluğu bağımsız bir veri seti ile değerlendirilen toprak kirliliği haritaları oluşturulmuştur. Ayrıca, kısa dalga kızıl ötesine (SWIR) kadar olan bantları kullanılan Aster uydu görüntüsünün toprak kirliliği haritaları tahmininde daha iyi sonuçlar verdiği saptanmıştır. Anahtar Kelimeler: Terk edilmiş Kömür Madenleri, Dijital Toprak Haritalama, Toprak Kirliliği, Aster, Worldview 2 vi To my family vii ACKNOWLEDGEMENTS First of all, I would like to express my deepest gratitude to my supervisor Prof. Dr. H. Şebnem Düzgün for her guidance, advice, criticism, encouragements and patience throughout the research. I also offer my special thanks to the examining committee members for serving on the master thesis committee and their valuable contributions and comments. I would like to thank to my friends and colleagues Esra Nur Tanrıseven, Mustafa Çırak, Ahnet Güneş Yardımcı, Özlem Erdaş and Onur Gölbaşı for their precious supports and encouragements. I would also like to express my sincere gratitude to my surgeon Dr. Ömer Erçetin. This study would not exist if he didn‘t accept to operate on me. I cannot thank him enough for being there. I also want to thank to my dear Murat not only for his support and patience for this study but also for standing beside me throughout all the staff I have gone through. Finally, I feel grateful to my mother Emel Soydan, my father Ahmet Yahya Soydan and my sister Gülay Menekşe Soydan for their endless support, unconditional love and encouragement. viii TABLE OF CONTENTS ABSTRACT ................................................................................................................................. v ÖZ ............................................................................................................................................... vi ACKNOWLEDGEMENTS ...................................................................................................... viii LIST OF TABLES ....................................................................................................................... x LIST OF FIGURES .................................................................................................................. xiii LIST OF ABBREVIATIONS ................................................................................................... xvi CHAPTERS 1. INTRODUCTION .................................................................................................................. 1 2. LITERATURE SURVEY ....................................................................................................... 7 2.1 Hyperspectral Analysis of Soil .......................................................................................... 7 2.2 Soil Mapping Using Remote Sensing .............................................................................. 12 2.2.1 Image Processing Analysis ...................................................................................... 16 2.2.2 Spectroscopic Analysis ............................................................................................ 19 3. RESEARCH METHODOLOGY ......................................................................................... 25 4. IMPLEMENTATION OF METHODOLOGY: CASE STUDY .......................................... 29 4.1 General Information about the Study Area ...................................................................... 29 4.2 Environmental Problems Related to Study Area ............................................................. 30 4.3 Data Collection ................................................................................................................ 33 4.3.1 Soil Sample Collection ............................................................................................ 36 4.4 Image Processing Analysis .............................................................................................. 37 4.4.1 Digital Elevation Model Generation ........................................................................ 37 4.4.2 Orthorectification of Worldview 2 Imagery ............................................................ 41 4.4.3 Preprocessing of ASTER Data ................................................................................. 43 4.4.4 Radiance Calibration of ASTER and Worldview 2 Imageries ................................ 45 4.4.5 Support Vector Machine (SVM) Classification ....................................................... 45 4.5 Spectroscopic Analysis .................................................................................................... 48 4.5.1 Multiple Linear Regression ...................................................................................... 49 4.5.2 Partial Least Square Regression Analysis ................................................................ 69 5. RESULTS AND DISSCUSSION ....................................................................................... 101 6. CONCLUSIONS AND RECOMMENDATIONS ............................................................. 117 REFERENCES ........................................................................................................................ 119 APPENDICES A. SPECTRAL PROFILES ............................................................................................. 131 B. RESIDUAL PLOTS ................................................................................................... 149 C. ACCURACY ASSESSMENT TABLES .................................................................... 155 D. PREDICTED MAPS ................................................................................................... 168 ix LIST OF TABLES TABLES Table 1.1 Environmental impacts and monitoring levels of mining activities (Düzgün and Demirel, 2011) ....................................................................................................................... 1 Table 2.1 Analysis models to evaluate spectroscopic data (Schwartz et al., 2011) ............. 15 Table 2.2 Conversion coefficients (W / .sr. μm) (Group 4, 2013) .................................. 19 Table 4.1 Data utilized in study ............................................................................................ 33 Table 4.2 Properties of utilized satellite imagery ................................................................. 35 Table 4.3 Flow diagram of digital elevation model generation ............................................ 38 Table 4.4 GCPs used for DEM generation ........................................................................... 39 Table 4.5 Multispectral Wv-2 orthorectification GCPs ....................................................... 42 Table 4.6 Panchromatic Wv-2 orthorectification GCPs ....................................................... 43 Table 4.7 ASTER co-registration GCPs ............................................................................... 44 Table 4.8 Ground truth (pixels) for Wv-2 imagery .............................................................. 46 Table 4.9 Ground truth (percent) for Wv-2 imagery ............................................................ 46 Table 4.10 Ground truth (pixels) for ASTER imagery ......................................................... 47 Table 4.11 Ground truth (percent) for ASTER imagery ...................................................... 47 Table 4.12 Descriptive statistics of soil chemical analysis results ...................................... 48 Table 4.13 Correlation coefficients of soil chemical analysis results .................................. 49 Table 4.14 Multiple linear regression model of moisture (ASTER) .................................... 50 Table 4.15 Analysis of variance of moisture model (ASTER) ............................................ 50 Table 4.16 Multiple linear regression model of CEC (ASTER) .......................................... 51 Table 4.17 Analysis of variance of CEC model (ASTER) ................................................... 51 Table 4.18 Multiple linear regression model of calcium (ASTER) ..................................... 51 Table 4.19Analysis of variance of calcium model (ASTER) ............................................... 52 Table 4.20 Multiple linear regression model of clay (ASTER) ........................................... 52 Table 4.21 Analysis of variance of clay model (ASTER) .................................................... 52 Table 4.22 Multiple linear regression model of sand (ASTER) ........................................... 53 Table 4.23 Analysis of variance of sand model (ASTER) ................................................... 53 Table 4.24 Multiple linear regression model of copper (ASTER) ....................................... 54 Table 4.25 Analysis of variance of copper model (ASTER) ................................................ 54 Table 4.26 Multiple linear regression model of iron (ASTER) ............................................ 54 Table 4.27 Analysis of variance of iron model (ASTER) .................................................... 54 Table 4.28 Multiple linear regression model of potassium (ASTER) .................................. 55 Table 4.29 Analysis of variance of potassium model (ASTER) .......................................... 55 Table 4.30 Multiple linear regression model of nickel (ASTER) ........................................ 55 Table 4.31 Analysis of variance of nickel model (ASTER) ................................................. 56 Table 4.32 Multiple linear regression model of sulphur (ASTER) ...................................... 56 Table 4.33 Analysis of variance of sulphur model (ASTER) .............................................. 56 x

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(2011) stated that vis-NIR spectra depicted the information about soil's color, iron oxides, organic matter content (ENVI Classic Tutorial, 2013). Retrieved from http://www.exelisvis.com/portals/0/pdfs/envi/Flaash_Module.pdf. ENVI. (2009). Agricultural Engineers, 44(6), 1445-1453. Thornton
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