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Significance of the scientific research of Nicolae Vasilescu Karpen PDF

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Andrei Nicolaide Significance of the scientific research of · - NICOLAE VASILESCU KARPEN AGIR Publishing House ~ Arhiva digitala SaDAng SIGNIFICANCE OF THE SCIENTIFIC RESEARCH OF NICOLAE VASILESCU KARPEN HISTORI.CAL LANDMARKS SERIES Prof. dr.şt. Andrei NICOLAIDE SEMNIFICAŢIA CERCETĂRILOR ŞTIINŢIFICE ALE LUI NICOLAE VASILESCU KARPEN Seria REPERE ISTORICE Editura AGIR Bucureşti, 2006 Lucrare editată cu sprijinul AUTORITĂŢII NAŢIONALE PENTRU CERCETARE ŞTIINŢIFICĂ Arhiva digitala SaDAng ANDREI NICOLAIDE, Prof. D.Sc. Member ofthe Academy ofTechnical Sciences in Remania SIGNIFICANCE OF THE SCIENTIFIC RESEARCH of NICOLAE VASILESCU KARPEN ( 1870-1964) AGIR Publishing House Bucharest, 2006 THE GENERAL ASSOCIATION OF ENGfNEERS fN ROMAN[A © Editura AGIR, 2006 Editura AGIR (AGIR Publishing House) Calea Victoriei, nr.118, sector I, 010093 Bucureşti, România Tel./Fax: 4021-316 89 92, 4021-316 89 93 E-mail: [email protected] Descrierea ClP a Bibliotecii Naţionale a României NlCOLAIDE, A. Significancc of thc scicntific rcscarch of Vasilescu Karpcn: (1870-1964) / A. Nicolaide. -Bucureşti: Editura A.G.J.R. 53(498) Vasilescu Karpen,N. 929 Vasilescu Karpen,N. Editorial Assistant: eng. Dan BOGDAN Cover: eng. Ion MARIN Arhiva digitala SaDAng PREFACE The present book is devoted to the life and achievements of an important Romanian scientist Nicolae VASILESCU KARPEN. A short biography highlighting the most important stages of bis life is followed by a thorough analysis of his scientific contribution. The aim is not only a remembrance of his activity, but also an analysis attempting to emphasize the relation between his contribution and the actual state of science in the concemed domains. N. Vasilescu Karpen had a multifarious activity, however his major contributions concern two domains, namely Electrodynamics and Electrochernistry. Conceming Electrodynamics, he studied convection electric currents. The experimental verification of the magnetic effect of convection currents is the resuit of studies and experimental research of many remarkable scientists, but N. Vasilescu Karpen bas the merit of having established the final results with high precision, superior to the former experiments, and of having removed the doubts which existed at that time. Conceming Electrochemistry, he studied the operation of electric cells, and developed a new theory of their operation. This study Ied him to establish a new type of cells, which he named K cells. The K cells produce electric energy without any traceable chemical reactions, except oxidation-reduction reactions, but the delivered power is small. In order to realize the importance of his contributions, we shall present bis research including bis derivations, as concisely and clearly as possible, and then, we shall analyse anew the problems using the methods used at present. In this manner, some interesting situations could be highlighted. We shall give only the following example. In order to explain the operation of electric cells, the theory proposed by N. Vasilescu Karpen offers a suggestive description of the phenomena, which lead to the appearance of the electromotive force. In this theory, he proposed to consider in the electrolyte solution of the cells, not only the presence of positive and negative ions, but also, that of free electrons, especially in the neighbourhood of the electrodes. At that time, no theory considered the presence of electrons in the solution. The theory ofN. Vasilescu Karpen was published between the years 1923 and 1944, as he progressed in his research. The presence of electrons in solution was experimentally proved much latcr, in 1958. Fmther, the theory of solvation was developed, hence bringing an argument in favour of bis theory. 6 Preface The theory of N. Vasilescu Karpen allows explaining the operation of various types of cells including alsa the K cells, operation that could not be satisfactorily explained by the theories known previously. It is wo11h noting that his experiments conceming the operation of cells with unalterable electrodes led Vasilescu Karpen to the experimental development of the world-wide first cell with dissolved liquid fuel. According to the reasons above, the present book has faur parts. The first one contains the biographic data; the second one, his conh·ibution to the Electrodynamics of electrified bodies in motion; the third one, his contribution to Electrochemistry; and the fourth one, some other contributions in various domains. For an easy understanding of the content of the present book, the Intemational System of units of measure, SI, and the symbols accepted at present have been used. We remade the original involved calculations, and we have carried out their treatment with improved precision using the contemporary methods. The author wishes to thank Professor Florin Teodor Tănăsescu, Secretary general of the Academy of Technical Sciences in Romania, for his recornmendation to write this book and for his support. At the same time, the author wishes to thank professors: Toma Dordea and Alexandru Timotin, members of the Romanian Academy; Augustin Moraru, from the Polytechnica University of Bucharest; Ovidiu Gh. Drăgănescu, from the University of Craiova, for their support. Several photographs illustrating this book have been kindly provided by: Gabriel Braru, from. Craiova; Vasile C. Diaconescu, director of the Museum of the Polytechnica University of Bucharest; Nicolae Diaconescu, director ofthe National Technical Museum Dimitrie Leonida from Bucharest; The Nobel Foundation; Pierre -Edouard Bour, from the Laboratoires de Philosophie et d'Histoire des Sciences - Archives Henri Poincare, CNRS Nancy - Universite, whom the author expresses his thanks. Finally, the author should like to gratefully thank Professor Michel Poloujadoff, from the University Pierre et Marie Curie (Paris VI), for having carefully read the manuscript and written the Foreword of this book. The book is addressed to all readers interested in the History of science, Electrodynamics, and Electrochemistry. Andrei Nicolaide Arhiva digitala SaDAng FOREWORD by Michel POLOUJADOFF Professor emeritus at the University Pierre et Marie CURIE (Paris VI), Doctor honoris causa ofthe Polytechnic University ofBucharest, Honorary Member oftl'le Academy ofTechnical Sciences in Romania. Indeed, Nicolae Vasilescu Karpen was a great servant of bis country, Romania, and a great servant of Science. That is why Professor Nicolaide wished to devote to him this truly beautiful book. Such homage is quite necessary, since, if the scientists do not honour their most eminent representatives, they leave the opportunity open to mediocrities to push themselves forward and occupy the whole scene. The book is conceived as a didactic work of physics, revisiting the ideas of a master, giving them a more modern form, and enlightening their reason. This expose, written from a great distance in time, appears to me as being quite faithful. But let me allow seeing in it especially one fact: an important document for understanding the history of our science and of our technology. The remarkable achievements of N. Vasilescu Karpen concern especially two domains: Electrodynamics and Electrochemistry. At first, I shall refer to the former domain. I have been very astonished indeed, as many readers will be, to learn that in 1904, it was yet possible to defend a thesis on the experiment ofthe Rowland disc, although it was twenty-eight years old at the time. Anyway, we can irnmediately realize that the panel was perfectly entitled to judge of the actuality and the pertinence of the subject; indeed, that panel included two members on the eve of being awarded the Nobel Prize (Moissan was awarded it in 1906, and Lippmann in 1908), and one member over any prize: Henri Poincare. I am therefore very grateful to Professor Nicolaide for explaining completely and clearly how the subject evolved over twenty-five years, which were the difficulties that remained to be solved, and why, consequently, the thesis was quite opportune. In the mean time, however, the quantum mechanics had already been conceived by Planck, and was to be developed in the spirit of Einstein. We derive from this chronology a splendid example of the history of science and technology, where we often see a page being written, while the preceding page has not been finished yet. Now, let us proceed to the latter of the domains mentioned above, namely, Electrochemistry. N. Vasilescu Karpen carried out thorough research on the 8 Foreword electrolyse phenomenon and electric cells. He established a new theory of electric cells, permitting the explanation of phenomena, which the previous theories could not explain. At the same time, he achieved a new type of cells that he called K cells. These cells with unalterable electrodes have presented the interesting property of delivering electric cun-ent, without any detectable chernical reaction, except the oxidation-reduction reactions on the electrodes. But much more important than the study of these cells, is the fact, that while trying to improve their properties, N. Vasilescu Karpen invented, achieved aud experimentally tested the first combustion cell with dissolved liquid fuel, which, as is known, has since had a wide development. Another element to which we have to assign a great importance in assessing N. Vasilescu Karpen is that attending advanced studies, and even more, writing a thesis, were extremely rare steps at the beginning of the 20th century. The exarnination of the thesis of N. Vasilescu Karpen reveals to us the list of professors of the Faculty of Science of Paris, at the moment of the approval of the defence of the thesis: they were thirty ! ! By way of example, there were just one hundred in 1955, and there are more than one thousand at present in all Paris Universities. N. Vasilescu Karpen belongs to a group of men that had the immense privilege of witnessing to an unbelievable explosion of the initial knowledge of our actual civilisation. Born in 1870, in a wealthy farnily, between the invention of the Gramme commutator (1869), and the drum winding (1871), we can imagine the life that he could have led in his youth, thanks to the memories of childhood of his contemporary Marcel Proust, and that he devoted to his instruction. We know also the life of the poor people of the same time, through the works of Emile Zola, Victor Hugo, and others. Born just before the apparition of « White Coal », N. Vasilescu Karpen lived to observe the building of the first nuclear plants. Now, a question has to be posed : what have we done by the example set by N. Vasilescu Karpen? Despite the perfidious insinuations of many politicians, our contemporaries make every year, revolutionary progress, in the knowledge of matter, living or inert, as the list of Nobel Prizes winners attests. We do not realize it, because we are now accustomed to miracles. And we realize even less the impact of fundamental discoveries on industrial production. May the outstanding history of this great scientist take us to a wiser, more rational thinking. And thanks to the author of this work, for having given us the opportunity of such considerations. Paris, on the 2 J5' ofF ebruary 2006. Mic/iei Poloujadoff. Arhiva digitala SaDAng

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