Resonant and non-dissipative tunneling in independently contacted graphene structures F. T. Vasko∗ QK Applications, 3707 El Camino Real, San Francisco, CA 94033, USA (Dated: January 24, 2013) The tunneling current between independently contacted graphene sheets separated by boron ni- tride insulator is calculated. Both dissipative tunneling transitions, with momentum transfer due 3 to disorder scattering, and non-dissipative regime of tunneling, which appears due to intersection 1 ofelectronandholebranchesofenergyspectrum,aredescribed. Dependenciesoftunnelingcurrent 0 on concentrations in top and bottom graphene layers, which are governed by the voltages applied 2 through independent contacts and gates, are considered for the back- and double-gated structures. The current-voltage characteristics of the back-gated structure are in agreement with the recent n experiment[Science335,947(2012)]. Forthedouble-gatedstructures,theresonantdissipativetun- a neling causes a ten times enhancement of response which is important for transistor applications. J 2 PACSnumbers: 72.80.Vp,73.40.Gk,85.30.Mn 2 ] l I. INTRODUCTION l a h In contrast to the tunneling processes between bulk - s materials,[1]thetunnelingbetweenlow-dimensionalsys- e temsmustbeassistedbyscatteringinordertosatisfythe m momentumandenergyconservationlaws,seeresultsand t. discussions for double quantum wells or wires in Refs. 2 a or3,respectively. Whenthesplittingenergybetween2D m states(thisenergy∆isdeterminedbytransversevoltages - appliedacrossstructure)exceedsthecollisionbroadening d energyΓ(h¯/Γisthedeparturetime),thetunnelingprob- n o abilityappearstobeproportionalΓ. Inconditionsoftun- c nelingresonanse,when∆≪Γ,thisprobabilityispropor- [ tional to ¯h/Γ, [4] i.e. the tunnel current depends on the scatteringtimeinthesamewayasthecurrentinmetallic 2 v conductor. The breakdown of the dissipative tunneling 7 regime is possible if the energy spectrum branches are 4 intersectedandthe energy-momentumconservationlaws 8 are satisfied without scattering. For example, the in- FIG. 1: (Color online) (a) Gt/BN/Gb structure under volt- 1 ages Vtb and Vbg applied to top (t-) and bottom (b-) layers tersection of the parabolic electron branches in double . through independent contacts; back gate (blue) is separated 2 quantumwellstakesplaceifthemagneticfieldisapplied by substrate of thickness ds and top gate under voltage Vtg 1 perpendicular to the tunneling direction, see [5] and [6] is shown by blue dashed lines. (b) Dispersion laws of t- and 2 1 for the experimental data and theory. Similar intersec- b-layers(blackandgraycrossedlines)withFermienergiesεFt tionbetweenthelinearbranchesofgaplessenergyspectra and ε for the electron-electron tunneling regime. (c) The : Fb v should take place in graphene/boron nitride/graphene same as in (b) for theelectron-hole tunneling regime. i (G/BN/G) heterostructure. Such a structure was re- X ported recently [7] and the tunneling transistor, which r a is based on the independently-contacted G-sheets con- acteristics were not analyzed) and a problem is timely nected through a few monolayer BN, was demonstrated. now. [8]Incontrasttothesemiconductorheterostructurecase, In the paper, we calculate the tunneling current I be- the independently-contacted G/BN/G structures can be tweenthe independently-contactedtop (Gt) and bottom easily realized with the use of the single-layer-transfer (Gb) graphene layers separated by BN. We analyze the technology. [9] But a complete theoretical investigation dependenciesofI onthe sheetconcentrations(Fermien- oftunneling currentinsucha structure is notperformed ergies)andon∆, whicharedeterminedbythegatevolt- yet(somenumericalresultsonthetunnelingconductance ages applied to the contacts, see Fig. 1a. Depending on were reportedrecently [10] but the current-voltagechar- voltagesapplied,onecanrealizedeitherelectron-electron (hole-hole) or electron-hole regimes of tunneling, as it is shown in Figs. 1b and 1c, respectively. In the latter case the cross-point E =0 is located between the Fermi ∗Electronicaddress: [email protected] energies (εFt > 0 > εFb or vise versa) and the non- 2 dissipative regime of tunneling takes place in addition Similarly to Ref. 6, one express {ρ} through the carrier to the resonant dissipative tunneling transitions. The distributionsdeterminedby[ρ]andthetunnelingcurrent current-voltagecharacteristicsappearstobedifferentfor density takes form these regimes. For the back-gated structure, the results are in agreement with the experimental data. [8] For 0 double-gatedstructures, the resonantdissipative tunnel- I ≈ 4i dtSp [ρˆ] Tˆ,e−iHˆGt/h¯IˆeiHˆGt/h¯ . (4) L2¯h ingregimecanberealized,withatentimesenhancement −Z∞ (cid:16) h i(cid:17) of response. The paper is organized as follows. In Sec. II, Here Sp(...) means both summations over states of car- we present the basic equations which describe the two riers in G - and G -layers and averaging over lateral t b regimes of interlayer tunneling. In Sec. III we analyze disorder which should be included in the Hamiltonians the current-voltage characteristics and compare the re- hˆ . Calculations of Sp(...) are performed below with Gt,b sultsforthe back-gatedstructurewiththe ofexperimen- the use of the basis formed by 2-row wave functions in tal data. [8] The last section includes the discussion ap- kth layer Ψ(kα) determined by the eigenvalue problem x proximationsused,andtheconclusions. InAppendix,we hˆ Ψ(kα) = ε Ψ(kα). We introduce the spectral density evaluatetheeffectivetunnelingHamiltonianforG/BN/G Gk x α x matrix, labeled by l,l′ =1 and 2, as structure. A(k) (x−x′)= δ(E−ε )Ψ(kα)Ψ(kα)∗ , (5) II. BASIC EQUATIONS E,ll′ * kα lx l′x′ + Xα k Under consideration of G /BN/G structure, we use where the averaging over random disorder in kth layer t b the tunneling Hamiltonian which connects Gt and Gb h...ik is performed. Using the Fermi distribution for layersdescribedby 2×2matriceshˆ , i.e. we introduce heavily-doped layers, when [ρ] is replaced by the θ- Gt,b 4×4 matrix [11] function θ(εFk − εkα) with the Fermi energies εFk in Eq.(4), we transform I into hˆ τˆ HˆGBNG =(cid:12) τˆGt hˆGb (cid:12)≡HˆG+Tˆ. (1) I = 8π|e| εFtdE dx dx′ (6) Hlaeyreersw, eHˆha,vaendsepthareatt(cid:12)(cid:12)(cid:12)uednntehliengHacmo(cid:12)(cid:12)(cid:12)nitltroibnuiatniono,fTuˆ,ncworuipttleedn ¯hL2 εZFb Z Z through tGhe 2×2 matrix τˆ= τˆ+ which is determined by ×tr τˆ+AˆE(b)(x′−x)τˆAˆ(Et)(x−x′) . a stackinggeometryofthe structure,seeAppendix. The h i chargedensityinG andG layers,Q(k) (hereandbelow wheretr(...)meanssummationoverthematrixvariable. t b t k = t,b), and the tunnel current density, I , are deter- Below, we express Aˆ(k) in the momentum representa- t E mine throughthe 4×4density matrix ρˆt by the formulas tion as Aˆ(k) = i GˆR(k)−GˆR(k) + /2π, where GˆR(k) [12] E,p E,p E,p E,p is the retarded Gr(cid:16)een’s function of(cid:17)kth layer with the QI(tk) = L42Sp ePIˆˆk ρˆt . (2) csproliststinpgoinenteregnye.rgiWesit±hi∆n/t2hewmritotdeenl othfrsohuogrht-rtahnegeledveisl-- (cid:12) t (cid:12) (cid:18)(cid:12) (cid:12) (cid:19) order with the same statistically independent character- (cid:12) (cid:12) (cid:12) (cid:12) Here L2 is th(cid:12)(cid:12)e norm(cid:12)(cid:12)alization ar(cid:12)(cid:12)ea, Pˆ(cid:12)(cid:12)k is the projection istics for k = t and b, the Green’s function in the Born approximationtakes form [13] operator on the k-states, and the interlayer current op- erator Iˆis determined from the charge conservation re- quirement I =dQ(t)/dt=−dQ(b)/dt (see similar calcu- GˆR(k) =Pˆ(+)G(k) +Pˆ(−)G(k) ≡G(k)+ σˆ ·pG(k), t t t E,p p E,p p E,−p Ep p Ep lations in Refs. 6), so that G(k) ≈ (E∓∆/2)(1+Λ +ig)−υp −1, (7) E,p E∓∆/2 e 0 −iτˆ Iˆ= . (3) ¯h iτˆ 0 where −∆/(cid:2)2 and +∆/2 are correspondent to(cid:3)t- and b- (cid:12) (cid:12) (cid:12) (cid:12) layers and υ ≃ 108 cm/s is the carrier velocity. The As a result, tunneling pr(cid:12)ocesses a(cid:12)re described by the (cid:12) (cid:12) projection operators on the conduction (+) and valence above-introducedmatricesTˆandIˆ,aswellasthedensity (−) band states, Pˆ(±) = [1±(σˆ ·p)/p]/2, are writ- matrixgovernedbythestandardequation: i¯h(∂ρˆ/∂t)= p t ten through the 2×2 isospin Pauli matrix σˆ. The self- [Hˆ ,ρˆ]. [12] GBNG t energy contributions (E ∓∆/2)(Λ +ig) are writ- Further, we separate the diagonal and non-diagonal E∓∆/2 tenthroughthe logarithmically-divergentrealcorrection partsofthedensitymatrixρˆ ≡[ρˆ]+{ρˆ}whichdescribe t t t which is proportional to Λ = (gπ)ln(E /|E|) and the the distribution of carriers in G - and G -layers and the E c t b coupling constant g. This approach corresponds to the tunneling current, It = (4/L2)Sp Iˆ{ρˆt} , respectively. short-range scattering with the cut-off energy Ec. [14] (cid:16) (cid:17) 3 The interlayer tunneling is described by the parameters 1 T2 =tr(τˆ+τˆ), T2 = tr(τˆ+σˆ τˆσˆ ), (8) s 2 µ µ µ X whichappearundercalculationofthematrixtraceinEq. (6). Using Eqs. (7) and (8) we transform the tunneling current density (6) into the form εFt 2e dE I = T2ImG(t)ImG(b) π¯h L2 Ep Ep εZFb Xp (cid:16) +T2ImG(t)ImG(b) , (9) s Ep Ep (cid:17) where the explicit expressions for G(k) and G(k) are de- Ep Ep termined by Eq. (7). Due to the in-plane symmetry of FIG.2: (Coloronline)(a)TunnelingcurrentdensityI versus the problem, I is written as the double-integral over the p-plane and the energy interval (ε ,ε ). levelsplitting∆fortheresonanttunnelingregimeatεF =200 Ft Fb meV and δε=50 meV (1) or 100 meV (2) for g =0.3. Solid Integrations in (9) are performed analytically for the and dashed curves are plotted for χ =1 and χ =0, respec- collisionless case, g →0, and the tunneling current den- tively. Curve (3) is plotted for parameters (1) at g = 0.15. sityisgivenbythesumofthedissipativecurrent,whichis Dottedcurvefitsdependencies(2)withtheuseEq. (10). (b) ∝δΓ(∆), and the non-dissipative contribution (∝χ|∆|): The same as in panel (a) for the non-dissipative regime, if εF =0 and δε=200 meV (1) or 100 meV (3). Curve (2) cor- ε2Ft−ε2Fb δΓ(∆) , εFtεFb >0 responds εF =200 meV, δε =100 meV and dotted line gives I ≃J sign(ε ) ε2 +ε2 , (10) ∝∆ contribution in Eq. (10). T (cid:0) Ft (cid:1)Ft Fb ×δ (∆)+χ|∆|/2 , ε ε <0 Γ Ft Fb (cid:0) (cid:1) J = |e| T2+Ts2 , χ= T2−Ts2. Fermi energies determined by εF = (εFt +εFb)/2 and T 2h¯3υ2 T2+T2 δε = ε −ε at χ =1 or 0. The resonant dissipa- (cid:0) (cid:1) s F Ft Fb tive regime of tunneling is realizedat |ε |>|δε /2|and F F Here the resonant dissipative contribution (at ε ε > Ft Fb peak value I(∆ = 0) increases both with doping levels 0) is written through the δ-like function δ (∆) = Γ and with g, as it is shown in Fig. 2a. If |ε | < |δε /2|, F F Γ/[π(∆2 + Γ2)] with the phenomenological broadening the electron-hole tunneling regime takes place and the Γ ≃ g(ε +ε ). At ε ε < 0, the non-dissipative Ft Fb Ft Fb non-dissipative contribution becomes dominant with in- contribution is written through the factor χ (0 < χ < 1 creasing of ∆, where I ∝ χ|∆|. At small ∆ the de- because T2 ≥ T2) determined by the tunneling energies s pendency I(∆) is transformed into narrow peak due to T and T . These parameters depend on the stacking s the dissipative contribution with weak broadening, see order of the G /BN/G structure and rough estimate t b Eq. (10) and Fig. 2b. The numerical results given by for the case of N-layer BN barrier [15] is determined Eq. (9)areinagoodagreementwiththeapproximations by Eq. (A.4), see Appendix. As a result, we obtain (10), shown by the dotted asymptotics, because of weak T,T ∼ γ(γ/ε )N, where γ ∼0.4 eV is the interlayer s BN (≤10%)contributionsfromtherenormalizationofenergy overlap integral and ε ≤2.5 eV is of the order of the BN spectra. c- and v-band energies in BN. We use below T,T ∼13 e s Neglectingthequantumcapacitancecontributionsand µeV for N = 4 and ∼6 µeV for 6-layer BN barrier, e the near-contactdrops of potentials, we use εFt−εFb ≃ which are in agreement with the experimental data of eV andtheGausstheoremconnectedthecarrierconcen- tb Ref. 8. The scattering parameters used in Eqs. (9, 10) trations in graphene with interlayer electric fields, V /d tb are taken from the conductivity measurements, see sim- and V /d (here d and d are thicknesses of BN layer bg s s ilar considerations in Refs. 16. We choose the cut-off andSiO substrate). As a result, the Fermienergiesand 2 energy E ∼0.2 eV and the coupling constants g ≃0.3 or c ∆ are connected with drops of voltages as follows: 0.15correspondedtothe maximalsheetresistance∼4or 2 kΩ per square. 2εFt,b ≃±eVtb−F(eVtbεd)−F(eVbgεds −eVtbεd), ThecurrentdensityI isdependentonεFt, εFb and∆, ∆≃eVtb+F(eVtbεd)−F(eVbgεds −eVtbεd), whicharedeterminedbythedropsofvoltagesappliedto ǫ(h¯v)2 three- or four-terminal structures, see Fig. 1a. Before F(x)=sign(x) |x|, ε = . (11) d 4e2d study of the current-voltage characteristics, we consider p the dependencies of the total current I on these three Here”+”and”−”standforG -andG -layers,ε >0 t b Ft,b energies. In Fig. 2 we plot the tunneling current, which or < 0 correspond to electron or hole doping, and the is determined by Eqs. (9) and (7), versus ∆ for different dielectric permittivity ǫ≃4 is the same for BN and SiO 2 4 FIG. 3: (Color online) Tunneling current I versus V at tb V =0 for structures with 4- and 6-layer BN barriers (black bg andred curves,respectively;squaresand triangles areexper- imental points [8]). Solid, dotted, and dashed curves corre- spondtoχ=1. 0.5,and0. Insetsshow∆andconcentrations nt or nb (solid or dashed lines) versus Vtb. FIG. 4: (Color online) (a) Current density I versus V for tb layers, see Refs. 7 and 8. For the double-gated struc- 4-layer BN barrier at V =0 (red), -25 V (blue), and -50 V bg turewithtopgateseparatedbyBNinsulatorofthickness (black). ExperimentalpointsareshownforV =0(triangles) bg d , one obtains similar expressions for ε and ∆ after and-50V(hexagons). Insetshows∆versusV . (b)Thesame t Ft,b tb the replacement eV ε → eV ε −eV ε , see voltages as in panel(a) for 6-layerBN barrier. tb d tb d tg dt shown in Fig. 1a. The approach (11) is valid for the heavily-doped graphene layers, so that the fields V /d, tb V /d , and V /d should be strong enough. On the bg s tg t in Fig. 4 for N =4, 6 and χ = 1, 0. Once again, there other hand, these fields are restricted by the breakdown is a reasonable agreement of I(V ,V ) with the avail- tb bg condition for BN layer, when these fields should be ≪7 able experimental data for N =4 at V < 0. A visible tb MV/cm. [17] asymmetry of I takes place if V →−V but deviations tb tb from experimental data increase. The dependencies for N =6 are similar but I is ∼2-times weaker and the res- III. CURRENT-VOLTAGE CHARACTERISTICS onant dissipative contribution is absent for Vbg =−25 V because ∆6=0, see inset. In this section we analyze the current-voltage charac- An enhancement of the resonant dissipative tunnel- teristics for the back- and double-gated structures. Be- ing contributions takes place in the double-gated (four- low, the tunneling current density is determined by Eqs. terminal)structure,whenI dependsonVtb,Vtg,andVbg. (7) and (9) with the Fermi energies and the level split- These dependencies are shown in Fig. 5 for the struc- ting written through the voltages applied according to ture with 10-layer BN cover layer (dt =3.4 nm; with a Eqs. (11). The parameters described both the elastic negligible tunneling, if dt ≫2 nm [19]) at different top- scattering processes and the interlayer tunnel coupling andback-gatevoltages(Vtg =0correspondstothethree- are chosen the same as for the above calculations shown terminalstructure). Sincethecondition∆=0isrealized in Fig. 2. now at higher energies, the resonant dissipative tunnel- Fortheback-gatedstructurewithN-layerBNbarriers ingpeaksare>10timesgreaterthanthebackgroundcur- (N =4 and 6) and g =0.3 the dependencies of I versus rent. Thisisthecentralresultwhichshouldbeimportant V at fixed V are shown in Fig. 3 at V = 0, when for the transistor applications. Note, that for ∆ ∼0 at tb bg bg Ia−reVt∝b =V−IaVntbd. ∆[18is] Tthheeseulmectorofnlin(heaorle)ancdonscqeunatrrae-trioonost pVetbak∼0is(stuhpepcruersvseed3. inBeFyiogn.d5ao)f tthheisrnesaornroawntrdeigsisoipna,ttihvee tb functions, see insets. The current-voltage characteristics resonant condition ∆(Vtb)≈0 should not be suppressed I(V ) are in reasonable agreement with the experimen- by lateral inhomogeneities and the peaks caused by the tb tal data of Ref. 8 if we used the scale factor J with the resonant dissipative tunneling should not be smeared. T above-estimated T and T . The dependencies on χ are Overall, the consideration presented here gives an ad- s weak enough (≤25% for N =4 and ≤10% for N =6, not equate theoreticaldescriptionofthe tunneling transistor shown). If ∆ ∼0, when V ≃-0.55 V for 6-layer barrier, effect which is in reasonable agreement with the exper- tb a negative resonant contribution due to dissipative tun- imental data. [8] The analysis performed opens a way neling gives ∼30% variations of the I-V characteristic. for the verificationofscattering mechanismsand tunnel- SuchapeculiaritywasnotfoundinRef. 8;probably,itis ing parameters in G/BN/G structures. In addition, the duetoalateralredistributionsofchargesoralarge-scale double-gated (four-terminal) structure was not consid- inhomogeneities of the samples used. The I-V charac- ered before and this structure show a great (ten times) teristics of back-gated structures at V 6= 0 are plotted enhancement of tunneling current tunability. bg 5 andthe results obtainedcan be applied for characteriza- tion of scattering mechanisms and tunneling parameters in the tunnel-coupled graphene structures. More impor- tantly, that these results open a way for improvement of tunneling transistor, a new type of graphene-based de- vice. We believe that our study will stimulate a further investigation of these device applications. Appendix: Tunneling Hamiltonian Below we describe the tunnel-coupled states in G/BN/G structure using the 6-column wave function [ψ ,φ,ψ ] which is written through the spinors ψ cor- t b t,b respond to the G and G graphene layers. These layers t b are connected through the spinor φ described the sin- gle BN-layer. Within the tight-binding approach, [15] FIG. 5: (Color online) (a) Dependencies I(Vtb) for double- the eigenstate of energy E is determined by the problem gatedstructurewith4-layerBNbarrierand10-layerBNcover written through the 6×6 Hamiltonian layer under Vbg = −50 V and Vtg = 1.5 V (1), 0.75 V (2), - 0a.n7d5dVas(h3e)d, acnudrv-e1s.5coVrr(e4sp).onIdnsetot sχho=w0s ∆andve1r,sursesVptebc.tiSvoelliyd. hˆGt −E hˆGBN 0 ψt hˆ+ hˆ −E ˆh φ =0, (A.1) (b) The same as in upperpanel for Vbg =0 V. (cid:12)(cid:12)(cid:12) G0BN BhˆN+BNG hˆGBbN−GE (cid:12)(cid:12)(cid:12)(cid:12)(cid:12)(cid:12)ψb (cid:12)(cid:12)(cid:12) (cid:12) (cid:12)(cid:12) (cid:12) (cid:12) (cid:12)(cid:12) (cid:12) wher(cid:12)e hˆ and hˆ are the 2 × 2(cid:12)H(cid:12)ami(cid:12)ltonians of G , IV. CONCLUSION Gt Gb t G ,andBN-layers,whilehˆ andhˆ describeweak b GBN BNG interlayer coupling of G and G sheets with BN layer. t b We have adopted the theory of low-dimensional tun- Under a transverse voltage applied, hˆ = ˆh ±∆/2, neling [4, 6] to the case of the tunneling charge trans- wherehˆ istheHamiltonianofsinglegGrat,pbheneGlayerand fer in independently contacted graphene structures with G ∆ is a splitting energy between the cross-points in G - multi-layer BN barrier taking into account the two ba- t and G -layers. For the low-energy (|E| <1 eV) states, if sic mechanisms of charge transfer: resonant dissipative b |E| ≪ |ε | where ε ∼3.4 eV and ε ∼-1.4 eV are the tunneling and non-dissipative tunneling. Both the non- c,v c v c- and v-band extrema energies in BN, we can eliminate dissipative tunneling currentand the non-resonantdissi- the spinor φ from the system (A.1). As a result, the pativetunnelingprocessesareresponsibleforthecurrent- eigenstate problem is determined by the 4×4 effective voltage characteristics of back-gated structures. [8] The tunneling Hamiltonian resonant dissipative tunneling regime is achieved for the double-gated structures and these devices demonstrate hˆ +τˆ −E τˆ ψ aimtpeonrttaimntesfoernthraanncseismtoerntapopflIic-Vaticohnasr.acteristics which is (cid:12) G τˆ+t hˆG+τˆb−E (cid:12)(cid:12)ψbt (cid:12)=0. (A.2) (cid:12) (cid:12)(cid:12) (cid:12) Further, we discuss the assumptions used. Because of Here t(cid:12)(cid:12)he 2×2 matrix τˆ describes(cid:12)(cid:12)tu(cid:12)(cid:12)nne(cid:12)(cid:12)ling through BN a luck of data on stacking order in G/BN/G structures insulator, while τˆ and τˆ correspond to the tunneling t b the tunneling energiesT andT wereestimatedfromthe renormalizationof t- and b-states: s current-voltage characteristics of Ref. 8 and this result τˆ≈−hˆ hˆ−1 hˆ , (A.3) is in agreement with the tight-binding model. [15] More GBN BN BNG accurate estimates for T and Ts should be based on ad- τˆt ≈−hˆGBNhˆ−B1Nhˆ+GBN, τˆb ≈−hˆ+BNGhˆ−B1NhˆBNG. ditional structural measurements. The simplified elec- trostatics description, given by Eq. (11), fails for the Thus, we arrive to the Hamiltonian (1) with the renor- low-doped G - or G -layers, under weak interlayer fields malizationcontributionsτ includedtohˆ ;these cor- t b t,b Gt,b applied. Inthesenarrowregions,amorecomplicatedde- rections are negligible for the weak tunneling regime. scription, which involves the quantum capacitance effect For the case of N-layer BN insulator, we consider andthe contactphenomena,shouldbe applied. The rest the 2(N + 2)-column wave function with N-spinors ofassumptions(themodelofelasticscattering,[16]iden- φ ,...,φ described the BN layers. These states are 1 N ticalscatteringinGt,b-layers,weaknessoflong-rangedis- coupled by the interlayer hopping matrices hˆBNBN and order, and the single-particle approach) are rather stan- hˆ+ which are placed to upper and lower sub- BNBN dard. diagonals of 2(N +2)×2(N +2) Hamiltonian. [15] Af- Toconclude,webelievethatthe descriptionoftunnel- tereliminationsofthe spinorsφ ,...,φ fromthetight- 1 N ing processes is an essential part of physics of graphene bindingeigenstateproblem,wearrivetoEq. (A.3)where 6 the non-diagonal matrix τˆ is replaced by orderofε−1 where ε is determinedbyε . 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