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Relationships of density, microfibril angle, and sound velocity with stiffness and strength in mature wood of Douglas-fir PDF

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Handbook of Wood Chemistry and Wood Composites S E C O N D E D I T I O N Roger M. Rowell Edited by Boca Raton London New York CRC Press is an imprint of the Taylor & Francis Group, an informa business CRC Press Taylor & Francis Group 6000 Broken Sound Parkway NW, Suite 300 Boca Raton, FL 33487-2742 © 2013 by Taylor & Francis Group, LLC CRC Press is an imprint of Taylor & Francis Group, an Informa business No claim to original U.S. Government works Version Date: 20120725 International Standard Book Number-13: 978-1-4398-5381-8 (eBook - PDF) This book contains information obtained from authentic and highly regarded sources. Reasonable efforts have been made to publish reliable data and information, but the author and publisher cannot assume responsibility for the valid- ity of all materials or the consequences of their use. The authors and publishers have attempted to trace the copyright holders of all material reproduced in this publication and apologize to copyright holders if permission to publish in this form has not been obtained. If any copyright material has not been acknowledged please write and let us know so we may rectify in any future reprint. Except as permitted under U.S. Copyright Law, no part of this book may be reprinted, reproduced, transmitted, or uti- lized in any form by any electronic, mechanical, or other means, now known or hereafter invented, including photocopy- ing, microfilming, and recording, or in any information storage or retrieval system, without written permission from the publishers. For permission to photocopy or use material electronically from this work, please access www.copyright.com (http:// www.copyright.com/) or contact the Copyright Clearance Center, Inc. (CCC), 222 Rosewood Drive, Danvers, MA 01923, 978-750-8400. CCC is a not-for-profit organization that provides licenses and registration for a variety of users. For organizations that have been granted a photocopy license by the CCC, a separate system of payment has been arranged. Trademark Notice: Product or corporate names may be trademarks or registered trademarks, and are used only for identification and explanation without intent to infringe. Visit the Taylor & Francis Web site at http://www.taylorandfrancis.com and the CRC Press Web site at http://www.crcpress.com For a teacher, success is not measured in the number of students who conform to your way of thinking; it is measured in the number of students in whom you have confirmed the excitement of the learning process. Roger M. Rowell Contents Preface...............................................................................................................................................ix Acknowledgments..............................................................................................................................xi Editor..............................................................................................................................................xiii Contributors......................................................................................................................................xv Chapter 1 Wood.and.Society.........................................................................................................1 Christopher D. Risbrudt Part I Structure and Chemistry Chapter 2 Structure.and.Function.of Wood...................................................................................9 Alex C. Wiedenhoeft Chapter 3 Cell.Wall.Chemistry....................................................................................................33 Roger M. Rowell, Roger Pettersen, and Mandla A. Tshabalala Part II Properties Chapter 4 Moisture.Properties.....................................................................................................75 Roger M. Rowell Chapter 5 Biological.Properties.of.Wood....................................................................................99 Rebecca E. Ibach Chapter 6 Thermal.Properties,.Combustion,.and.Fire.Retardancy.of.Wood............................127 Roger M. Rowell and Mark A. Dietenberger Chapter 7 Weathering.of.Wood.and.Wood.Composites............................................................151 Philip D. Evans v vi Contents Chapter 8 Surface.Characterization...........................................................................................217 Mandla A. Tshabalala, Joseph Jakes, Mark R. VanLandingham, Shaoxia Wang, and Jouko Peltonen Part III Wood Composites Chapter 9 Wood.Adhesion.and.Adhesives.................................................................................255 Charles R. Frihart Chapter 10 Wood.Composites......................................................................................................321 Mark A. Irle, Marius Catalin Barbu, Roman Reh, Lars Bergland, and Roger M. Rowell Chapter 11 Chemistry.of.Wood.Strength....................................................................................413 Jerrold E. Winandy and Roger M. Rowell Chapter 12 Fiber.Webs.................................................................................................................457 Roger M. Rowell Chapter 13 Wood/Nonwood.Thermoplastic.Composites............................................................473 Craig M. Clemons, Roger M. Rowell, David Plackett, and B. Kristoffer Segerholm Part IV Property Improvements Chapter 14 Heat.Treatment..........................................................................................................511 Roger M. Rowell, Ingeborga Andersone, and Bruno Andersons Chapter 15 Chemical.Modification.of Wood...............................................................................537 Roger M. Rowell Chapter 16 Lumen.Modifications................................................................................................599 Rebecca E. Ibach and Roger M. Rowell Contents vii Chapter 17 Plasma.Treatment.of.Wood.......................................................................................627 Wolfgang Viöl, Georg Avramidis, and Holger Militz Chapter 18 Sustainability.of.Wood.and.Other.Biomass..............................................................659 Roger M. Rowell Index ..................................................................................................................................................................669 Ho¯ryu¯.Temple.in.Nara,.Japan.is.over.1300.years.old.and.is.one.of.the.oldest.remaining.wooden.structures.in. the.world. Preface Wood.has.played.a.major.role.throughout.human.history..The.earliest.humans.used.wood.to.make. shelters,.cook.food,.construct.tools,.build.boats,.and.make.weapons..There.are.human.marks.on.a. climbing.pole.that.were.made.over.300,000.years.ago..We.have.found.wood.in.the.Egyptian.pyra- mids,.Chinese.temples.and.tombs,.and.ancient.ships.that.attest.to.the.use.of.wood.by.earlier.societ- ies..Collectively,.society.learnt.very.early.about.the.great.advantages.of.using.a.resource.that.was. widely.distributed,.multifunctional,.strong,.easy.to.work,.aesthetic,.sustainable,.and.renewable.. Wood.has.been.used.by.people.for.centuries.as.a.building.material.and.we.have.accepted.its.limita- tions.in.use,.such.as.instability.toward.moisture,.and.degradations.due.to.microorganisms,.termites,. fire,.and.ultraviolet.radiation..We.must.accept.that.wood.was.designed.by.nature.to.perform.in.a.wet. environment,.and.nature.is.programmed.to.recycle.wood.to.carbon.dioxide.and.water.using.the. chemistries.of.decay,.thermal,.ultraviolet,.and.moisture.degradations..By.accepting.these.limita- tions,.however,.we.also.limit.our.expectations.of.performance,.which,.ultimately,.limits.our.ability. to.accept.new.concepts.for.improved.biomaterials. We.are.concerned.about.issues.dealing.with.the.environment,.sustainability,.recycling,.energy,. sequestering.carbon,.and.the.depletion.of.our.natural.resources.with.a.growing.world.population.. Wood.is.receiving.a.fresh.look.by.scientists,.politicians,.and.economists.because.of.its.unique.prop- erties,.aesthetics,.availability,.abundance,.and.perhaps.most.important.of.all,.its.renewability..We. will.not,.however,.be.able.to.realize.the.full.potential.that.wood.and.wood.products.can.play.in.our. “modern.society”.as.a.material.and.chemical.feed.stock.until.we.understand.its.chemistry.and.mate- rials.properties.and.performance..That.understanding.holds.the.key.to.its.utilization..Wood.will.not. reach.its.highest.use.potential.until.we.fully.describe.it,.understand.the.mechanisms.that.control.its. performance.properties,.and.finally,.are.able.to.manipulate.those.properties.to.give.us.the.desired. performance.we.seek. The.purpose.of.this.book.is.to.present.the.latest.concepts.in.wood.chemistry.and.wood.compos- ites.as.understood.by.the.various.authors.who.have.written.the.chapters..I.thank.them.for.their.time. and.effort.in.the.preparation.of.this.book..The.book.is.an.update.of.two.earlier.books,.Chemistry of Solid Wood,.Advances in Chemistry Series,.207,.American.Chemical.Society,.Washington,.DC,. 1984,.which.is.long.out.of.print.and.the.first.edition.of.this.CRC.handbook.published.in.2005. ix

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