Re Organorhenium Compounds: Part 1

627 Pages·1988·17.19 MB·English

by  Manfred Winter (auth.), Dr. Adolf Slawisch (eds.)

2 He I 10 Ne I 18 Ar I 36 Kr I 54 Xe I 86 Rn I H/31
~
2 5 6 7 8 I
I H 9 F 17 Cl 35 Br 53 I 85 At
8 0 3 16 s 9 34 Se 10 52 Te II 84 Po 12 71 Lu 03 Lr 71
1
4 16 17 18 19 71
7 N 15 p 33 As 51 Sb 83 Bi 70 Yb 102 No
6 c 14 14 Si 15 32 Ge45 50 Sn 46 82 Pb 47 69 Tm 101 Md 71
mbers I 5 B 13 13 Al35 31 Ga 36 49 ln 37 81 Tl 38 68 Er 100 Fm 71
Nu 32 33 34 71
melin System I I ' I I . I ! I 29 30 so 57 Cu Zn 47 48 65 Ag 61 Cd 79 80 68 Au 62 Hg 66 67 Dy Ho 98 99 1 Cf 71 Es
e G 28 Ni 46 Pd 78 Pt 65 Tb 97 Bk7
thwith 27 Co 58 45 Rh64 77 Ir 67 64 Gd 96 cm71
Table of Elements the I I ! I I ' I ! I 24 25 26 Cr 52 Mn 56 Fe 59 42 43 44 Mo 53 Tc 69 Ru 63 74 75 76 w 54 Os 66 Re 70 61 62 63 Pm Sm Eu 93 94 95 Np 71 Pu 71 Am71
Periodic . l i I I I . i I ' I ! i I i i ' i I 22 23 21 V 48 Sc 39 Ti 41 40 41 39 y 39 Zr 42 Nb49 72 73 57** La 39 Hf 43 Ta 50 104 105 89*** 71 71 Ac 40 60 59 58 Nd Pr Ca 91 92 i~ u 55 44 Pa 51
4 Be 26 12 Mg 27 20 Ca 28 38 Sr 29 56 Ba 30 88 Ra 31 ides n 39 des
2 20 21 * 22 24 25 ntha ctini
I H 3 LI II Na 19 K 37 Rb 55 Cs 87 Fr *La **A
~ *
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Gmelin Handbook of lnorganic Chemistry
8th Edition
Gmelin Handbook
of lnorganic Chemistry
8th Edition
Gmelin Handbuch der Anorganischen Chemie
Achte, völlig neu bearbeitete Auflage
Prepared Gmelin-lnstitut für Anorganische Chemie
and issued by der Max-Planck-Gesellschaft
zur Förderung der Wissenschaften
Director: Ekkehard Fluck
Founded by Leopold Gmelin
8th Edition 8th Edition begun under the auspices of the
Deutsche Chemische Gesellschaft by R. J. Meyer
Continued by E. H. E. Pietsch and A. Kotowski, and by
Margot Becke-Goehring
Springer-Verlag Berlin Heidelberg GmbH 1989
Gmelin-lnstitut für Anorganische Chemie
der Max-Planck-Gesellschaft zur Förderung der Wissenschaften
ADVISORY BOARD
Dr. G. Breit, Chairman (Ruhrchemie AG, Oberhausen-Holten), Prof. Dr. K. Dehnicke (Philipps
Universität, Marburg), Prof. Dr. N. N. Greenwood (University of Leeds), Prof. Dr. H. Grünewald
(Bayer AG, Leverkusen), Prof. Dr. H. Harnisch (Hoechst AG, Frankfurt/Main-Höchst), Prof. Dr.
H. Nöth (Universität München), Prof. Dr. H. Ottermanns (Degussa AG, Frankfurt/Main), Prof.
Dr. G. zu Putlitz (Universität Heidelberg), Prof. Dr. A. Rabenau (Max-Planck-lnstitut für Fest
körperforschung, Stuttgart), Prof. Dr. A. Sirnon (Max-Planck-lnstitut für Festkörperforschung,
Stuttgart), Prof. Dr. Dr. A. H. Staab (Präsident der Max-Planck-Gesellschaft, München), Prof.
Dr. Dr. h.c. mult. G. Wilke (Max-Planck-lnstitut für Kohlenforschung, Mülheim/Ruhr)
DIRECTOR DEPUTY DIRECTOR
Prof. Dr. Dr. h.c. Ekkehard Fluck Dr. W. Lippert
CHIEF EDITORS
Dr. K.-C. Buschbeck - Dr. H. Bergmann, J. Füssel, H. Hartwig, Dr. H. Katscher, Dr. R. Keim,
Dr. E. Koch, Dipl.-Phys. D. Koschel, Dr. U. Krüerke, Dr. P. Merlet, Dr. E. Schleitzer-Rust,
Dr. F. Schröder, Dr. A. Slawisch, Dr. W. Töpper
CORRESPONDENT MEMBERS OF THE SCIENTIFIC STAFF Dr. B. Baker, Dr. P. L. Bayless,
Dr. V. Haase, Dr. E. F. Hockings,
Dipl.-lng. G. Kirschstein,
Dr. W. F. McNamara, Dr. K. Rumpf
EMERITUS MEMBER OF THE INSTITUTE Prof. Dr. Dr. E.h. Margot Becke
CORRESPONDENT MEMBERS OF THE INSTITUTE Prof. Dr. Hans Bock
Prof. Dr. Dr. Alois Haas, Sc. D. (Cantab.)
STAFF GMELIN HANDBOCK
Dr. G. Bär, D. Barthel, Dr. N. Baumann, Dr. B. Becker, Dr. W. Behrendt, D. Benzaid, Dr. L.
Berg, Dipl.-Chem. E. Best, Dr. R. Bohrer, K. D. Bonn, P. Born-Heck, Dipl.-Phys. R. Bost, Dr. R.
Braun, Dipl.-lng. V. A. Chavizon, E. Cloos, Dipl.-Phys. G. Czack, I. Deim, Dipl.-Chem. H.
Demmer, U. Dietz, Dipl.-Geol. R. Ditz, R. Dowideit, Dipl.-Chem. M. Drößmar, U. Duggen, Dipl.
Chem. R. Durban, M. Engels, Dr. H.-J. Fachmann, Dr. J. Faust, B. Fischer, G. Funk, Dipl.-lng.
N. Gagel, Dr. D. Germeshausen, Dr. U. W. Gerwarth, Dipl.-Phys. D. Gras, Dipl.-Bibl. W. Grieser,
Dr. I. Haas, Dr. R. Haubold, B. Heibel, Dipl.-Min. H. Hein, A. Heise-Schuster, H.-P. Hente, H.
W. Herold, U. Hettwer, Dr. R. Heumüller, Dr. G. Hönes, Dr. W. Hoffmann, Dr. W. Huisl, B. Jaeger,
R. Jonuschat, Dr. R. Jotter, Dr. J. von Jouanne, Dr. B. Kalbskopf, Dipl.-Chem. W. Karl, H.-G.
Karrenberg, Dipl.-Phys. H. Keller-Rudek, B. Kirchner, P. Klauck, A. Klusch, Dipl.-Chem. C.
Koeppel, Dipl.-Chem. H. Köttelwesch, R. Kolb, E. Kranz, Dipl.-Chem. I. Kreuzbichler, Dr. A.
Kubny, Dr. M. Kunz, Dr. W. Kurtz, M. Langer, Dr. U. Lanzendörfer, Dr. B. Ledüc, Dr. A. Leonard,
H. Mathis, E. Meinhard, C. Metz, K. Meyer, Dr. M. Mirbach, Dipl.-Chem. B. Mohsin, Dr. U. Neu
Becker, K. Nöring, Dipl.-Chem. R. Nohl, Dipl.-Min. U. Nohl, Dr. U. Ohms-Bredemann, Dr. W.
Petz, I. Rangnow, Dr. B. Rempter, Dipl.-Phys. H.-J. Richter-Ditten, Dipl.-Chem. H. Rieger, E.
Rieth, A. Rosenberger, E. Rudolph, G. Rudolph, Dipl.-Chem. S. Ruprecht, Dr. B. Sarbas, Dr.
H. Schäfer, Dr. D. Schiöberg, V. Schlicht, Dipl.-Chem. D. Schneider, Dipl.-Min. P. Schubert, Dr.
K. Schücke, A. Schwärzet, Dr. B. Schwager, Dipl.-lng. H. M. Somer, G. Strauss, Dr. G. Swoboda,
Dr. U. Taubald, M. Teichmann, Dr. D. Tille, Dipl.-lng. H. Vanecek, Dipl.-Chem. P. Velic, Dipl.
lng. U. Vetter, H.-M. Wagner, Dipl.-Phys. J. Wagner, R. Wagner, Dr. E. Warkentin, Dr. C. Weber,
Dr. A. Wietelmann, Dr. M. Winter, Dr. B. Wöbke, K. Wolff
STAFF GMELIN ON LI NE DATA SYSTEM
Dr. R. Deplanque, Dr. P. Kuhn, Dr. G. Olbrich
Organometallic Compounds in the Gmelin Handbook
The following listing indicates in which volumes these compounds are discussed or are
referred to:
Ag Silber B 5 (1975)
Au Organagold Garnpounds (1980)
Be Organaberyllium Garnpounds 1 (1987)
Bi Bismut-Organische Verbindungen (1977)
Co Kobalt-Organische Verbindungen 1 (1973), 2 (1973), Kobalt Erg.-Bd. A (1961), B 1
(1963), B 2 (1964)
Cr Chrom-Organische Verbindungen (1971)
Cu Organacopper Garnpounds 1 (1985), 2 (1983), 3 (1986), 4 (1987), Index (1987)
Fe Eisen-Organische Verbindungen A 1 (1974), A 2 (1977), A 3 (1978), A 4 (1980), A 5
(1981), A6 (1977), A 7 (1980), AB (1985), B 1 (partly in English; 1976), Organairan
Garnpounds B 2 (1978), Eisen-Organische Verbindungen B 3 (partly in English; 1979),
B 4 (1978), B 5 (1978), Organairan Garnpounds B 6 (1981), B 7 (1981), B 8 to B 10
(1985), B 11 (1983), B 12 (1984), B 13 (1988), B 14 (1989), B 15 (1989), Eisen-Organische
Verbindungen C 1 (1979), C 2 (1979), Organairan Garnpounds C 3 (1980), C 4 (1981),
C5 (1981), C7 (1985), and Eisen B (1929-1932)
Ga Organagallium Garnpounds 1 (1986)
Ge Organagermanium Garnpounds 1 (1988), 2 (1989)
Hf Organahafnium Garnpounds (1973)
Nb Niob B 4 (1973)
Ni Nickel-Organische Verbindungen 1 (1975), 2 (1974), Register (1975), Nickel B 3 (1966),
and C 1 (1968), C 2 (1969)
Np, Pu Transurane C (partly in English; 1972)
Pb Organalead Garnpounds 1 (1987)
Pt Platin C (1939) and D (1957)
Re Organarhenium 1 (1989) present volume
Ru Ruthenium Erg.-Bd. (1970)
Sb Organoantimony Garnpounds 1 (1981), 2 (1981), 3 (1982), 4 (1986)
Sc, Y, D 6 (1983)
La to Lu
Sn Zinn-Organische Verbindungen 1 (1975), 2 (1975), 3 (1976), 4 (1976), 5 (1978), 6 (1979),
Organatin Garnpounds 7 (1980), 8 (1981), 9 (1982), 10 (1983), 11 (1984), 12 (1985), 13
(1986), 14 (1987), 15 (1988), 16 (1988)
Ta Tantal B 2 (1971)
Ti Titan-Organische Verbindungen 1 (1977), 2 (1980), Organotitanium Garnpounds 3
(1984), 4 and Register (1984)
u Uranium Suppt. Vol. E 2 (1980)
V Vanadium-Organische Verbindungen (1971), Vanadium B (1967)
Zr Organozirconium Garnpounds (1973)
Gmelin Handbook
of lnorganic Chemistry
8th Edition
Re
Organarhenium
Compounds
Part 1
With 89 illustrations
AUTHOR Manfred Winter
FORMULA INDEX Edgar Rudolph
EDITOR Adolf Slawisch
CHIEF EDITOR Adolf Slawisch
Springer-Verlag Berlin Heidelberg GmbH 1989
L1TERATURE CLOSING DATE: 1987
Library 01 Congress CataLog Card Number: Agr 25-1383
ISBN 978-3-662-08846-3 ISBN 978-3-662-08844-9 (eBook)
DOI 10.1007/978-3-662-08844-9
This work is subject to copyright. AU rights are reserved, whether the whoLe or pari 01 the materiaL is concerned, specilicaUy those
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"VerwertungsgeseUschaft Wort", Munich.
© by Springer-VerLag Berlin HeideLberg 1988
Originally published by Springer-Verlag, Berlin· HeideLberg . New York· London . Paris· Tokyo in 1988
Softcover reprin! of !he hardcover 8th ed~ion 1988
The use 01 registered names, trademarks, etc., in this pubLication does not impLy, even in the absence 01 a specilic statement, that
such names are exempt from the relevant protective laws and regulations and therefore free for general use.
Preface
The present volume is the first of a series of volumes dealing with organorhenium com
pounds. lt covers the Literature completely up to the end of 1987. An empirical formula index
and a Ligand formula index provide ready access to the compounds covered.
ln accordance with the previous arrangement adopted for organemetallic compounds (cf.
volumes covering organocobalt, organonickel, or organotitanium compounds), this volume
starts with the mononuclear organorhenium compounds. lt contains compounds in which the
organic Ligand is bonded to the Re atom by one C atom CL Ligand) and up to four CO groups.
Other mononuclear compounds will be covered in the next volume of this series.
A formula like (C0)2Re(2D)s 1L beloenog s to a type of mononuclear rhenium compounds
containing three monodentate ligands two-electron donor) such as P(CH3)s and one Ligand
bonded by one C atom CL) such as C5H7 (trans-pentadienyl) or C(O)R with R = CH3.
Much of the data, particularly in tables, is given in abbreviated form without dimensions;
for explanation see p. X. Additional remarks, if necessary, are given in the headings of tl'le
tables.
Frankfurt am Main Adolf Slawisch
November 1988
X
Remarks on Abbreviation& and Dimensions
Many compounds in this volume are presented in tables in which numerous abbreviations
are used, the dimensions are omitted for the sake of conciseness. This necessitates the
following clarification.
Abbreviations used with temperatures are m.p. for melting point, dec. for decomposition,
and b.p. for boiling point.
NMR represents nuclear magnetic resonance. Chemical shifts are given as 8 values in ppm
and to low field from the following reference substances: Si(CH3)4 for 1H and 13C, BF3 · O(C2H5h
for 118, CFCl3 for 19F, H3P04 for 31P, and Sn(CH3)4 for 119Sn. Otherwise, the reference substances
and signs are given. Multiplicities of the signals are abbreviated as s, d, t, q, qui, sext, sept
(singlet to septet), m (multiplet), and br (broad); terms like d of d (doublet of doublet) arealso
used. Assignments referring to labeled structural formulas are given in the form C-4, H-3,5.
Coupling constants J in Hz usually appear in parentheses after the 8 value, along with
the multiplicity and the assignment, and refer to the respective nucleus. lf a more precise
designation is necessary, they are given as, e.g., "J(C,H) or J(H-1 ,3) referring to Labeted
formulas.
ESR represents electron spin resonance; the hyperfine interactions are given as a(Re) or
a(P).
Optical spectra are labeled as IR (infrared) and UV (electronic spectrum including the
visible region). IR bands and Raman absorptions are given in cm-1. The assigned bands are
usually labeled with the symbols v for stretching, 8 for deformation, and Q for rocking vibration
with the indexes sym and asym for symmetrical and asymmetrical. The stretching force and
interaction constants are denoted k1, k2, and k;, respectively. The UV absorption maxima, "-max•
are given in nm followed by the extinction coefficient E (in L · cm-1 · mol-1) or log E in
parentheses.
Solvents or the physical state of the sample and the temperature (none is given if room
temperature applies) are given in parentheses immediately after the spectral symbol, e.g.,
IR (solid), 1H NMR (C6D6, 50°C}, or at the end of the data if their formula (C6H6 = benzene) or
name (acetone-d6) except THF, which represents tetrahydrofuran.
Molecular weights are given in the entire volume in g/mol; the abbreviation calc. is used
for calculated.