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AAss aa ccoonnsseeqquueennccee ooff tthhee rreessttrruuccttuurriinngg ooff tthhee NNAATTOO SScciieennccee PPrrooggrraammmmee iinn 11999999,, tthhee NNAATTOO SScciieennccee SSeerriieess wwaass rree--oorrggaanniizzeedd ttoo tthhee ffoouurr ssuubb--sseerriieess nnootteedd aabboovvee.. PPlleeaassee ccoonnssuulltt tthhee ffoolllloowwiinngg wweebb ssiitteess ffoorr iinnffoorrmmaattiioonn oonn pprreevviioouuss vvoolluummeess ppuubblliisshheedd iinn tthhee SSeerriieess.. hhttttpp::////wwwwww..nnaattoo..iinnVVsscciieennccee hhttttpp::////wwwwww..wwkkaapp..nnll hhttttpp::////wwwwww..iioosspprreessss..nnll hhttttpp::////wwwwww..wwttvv--bbooookkss..ddee//nnaattoo__ppccoo..hhttmm SSeerriieess IIVV:: EEaarrtthh aanndd EEnnvviirroonnmmeennttaall SSeerriieess -- VVooll.. 55 Radionuclides and Heavy Metals in Environment edited by Marina V. Frontasyeva Frank Laboratory of Neutron Physics, Joint Institute for Nuclear Research, Dubna, Russia Vladimir P. Perelygin Flerov Laboratory of Nuclear Reactions, Joint Institute for Nuclear Research, Dubna, Russia and PeterVater Kernchemie FB 15, Philipps-Universităt, Marburg, Germany 111.... " Springer-Science+Business Media, B.V. Proceedings of the NATO Advanced Research Workshop on Monitoring and Man-Made Radionuclides and Heavy Metals Waste in Environment Dubna, Russia 3-6 October 2000 A C.1. P. Catalogue record for this book is available from the Library of Congress. ISBN 978-1-4020-0059-1 ISBN 978-94-010-0993-5 (eBook) DOI 10.1007/978-94-010-0993-5 Printed on acid-free paper AII Rights Reserved © 2001 Springer Science+Business Media Dordrecht Originally published by Kluwer Academic Publishers in 2001 Softcover reprint of the hardcover 1s t edition 2001 No part of the material protected by this copyright notice may be reproduced or utilized in any form or by any means, electronic or mechanical, including photocopying, recording or by any information storage and retrieval system, without written permission from the copyright owner. TABLE OF CONTENTS Preface xi List of Participants xv 1. Man - Made Radionuclides in Environment and Living Species Tracking the Behaviour of Plutouium iu Man D. Newton and S.N. Dmitriev 1 Accelerator Mass Spectrometry for Plutonium Isotopes: Methods and Procedures N.D. Priest, G. Merlo Pich,. L Vintro and L. K. Fifield 9 Man-Made Plutonium in Enviroument - Possible Hazard for Human Health VP. Perelygin, Yu.T. Chuburkov, T.P. Drobina and G.P. Knjazeva 19 90Sr and 137Cs Activity in Surface Soil Samples from Some Areas Affected by the (<MAY AK» Plutonium Production Association M. V Frontasyeva, L.I. Smirnov, S.A Romanov, V.D. Cherchintsevand E. Steinnes 29 Actinide Determination in Environment (Liquids, Soils, Aerosols) VN. Kosyakov 37 Chernobyl "Hot Particles": Radionuclide Composition and Contribution in the Total Soil Radioactivity L.L. Kashkarov, YO. Tcherkezian, G.V. Kalinina, AI. Ivliev, T.Y. Shalaeva and P.A Korovaikov 43 Dating of Radioactive Contamination of a Locality in the Southern Regions ofthe Western Kazakhstan ASh. Gaitinov, N.P. Andreeva and I.Ya. Chasnikov 49 Destruction of Fuel Particles from the Chernobyl Fall-Out on the Territory of Belarus V Mironov, 1. Matusevitch and Y. Kudryashov 55 Determination of Actinides in Biological Samples in Belarus AF. Malenchenko, N.N. Bazhanova, S.F. Boulyga, N. Y. Kanash, M.K. Kievets, E.M. Lomonosova, LV. Zhuk and 0.1. Yaroshevich 61 Determination of Diffusion Coefficients of In, Cd, Hf and Po Hydrated Ions in Aqueous Solutions Using the Method of Horizontal Zone Electrophoresis in Free Electrolyte G.A Bojikov, P.I. Ivanov, AN. Priemyshev, G.D. Bontchev, M.V. Milanov, O.D. Maslov and S.N. Dmitriev 67 High - Sensitive Determinations of Po and Am Content in Human Tissues Yu.T. Chuburkov, V.P. Perelygin, 1.M. Mietelski and Z. Szeglowski 71 vi Isotopic Composition of Uranium in the Products of Accidental Ejection from the Chernobyl NPP E. Y. Sobotovich and G.N. Bondarenko 77 Methods of High -Sensitive Analysis of Actinides in Liquid Radioactive Waste AA Dyakov, T.N. Perekhozheva and E.I. Zlokazova 85 Non-Destructive Method of Pu and U Isotope Determination in Specimens V.P. Perelygin, Yu.T. Chubwkov, 1.V. Bondar, L.I. Kravets, LG. Abdullaev and G.S. Abdullaeva 87 Radioecological Analysis of Vietnam Soil Samples Dinh Thi Lien, Z. Szeglowski, H. Gondunova, Dang Duc Nhan, Le Khanh Phon, Luu Tam Bat and Lam Vinh Anh 93 Radioecological Researches in INP NNC RK (Almaty) KK Kadyrzhanov, AZh. Tuleushev, S.N. Lukashenko, Y.P. Solodukhin, L Y. Kazachevskiy and S. Khazhekber 10 1 Radioisotopes in Life Sciences. The Production of High-Pure Radionuclide Sources at FLNR, JINR S.N. Dmitriev, N.G. Zaitseva, O.D. Maslov, G.Ya. Starodub, AV. Sabelnikov, S.V .Shishkin and T.Y. Shishkina 107 Radionuclides in Bones of Wild, Herbivorous Animals from North-Eastern Poland 1. W. Mietelski, P. Gaca., M. Tomczak, M. Zalewski, E.M. Dutkiewicz, Z. Szeglowski, M. Jasinska., P. Zagrodzki and K Kozak 113 Some Man-Made and Natural Radionuclide Profiles in the Bottom Sediments of the Black Sea Yu.A Sapozhnikov, St.N. Kaimykov, R.A A1iev and KM. Shimkus 121 The Contamination of Belarus Territory by Transuranium Elements Y. Kudryashov, V. Mironov and E. Konoplya 127 Trace Element Analysis of Actinides in Natural Waters and Soils Using (y,1) Reaction O.D. Maslov, S.N. Dmitriev, L.G. Molokanova, M.Y. Gustova and A Y. Sabelnikov 13 5 Treatment of.Radioactive Waste Solutions Using Local Clay Minerals M.R. Ezz EI-Din, H. Molukhia and A Ramadan 143 2. Heavy Metals in Environment Use of Mosses to Monitor Trace Element Deposition from the Atmosphere: Why and How E. Steinnes 149 Biomonitoring Trace Element Atmospheric Deposition: An Internationally Harmonised Approach B. Smodis and A Bleise 157 Vll Study of Trace Elements in Annual Segments of Moss Biomonitors Using Epithermal Neutron Activation Analysis: Link with Atmospheric Aerosol M. V. Frontasyeva, Yeo V. Yermakova, E. Steinnes and K.A Rahn 165 The Use of Lichens and Mosses to Monitor Trace Element Pollution in Slovenia Z. Jeran and R. Jacimovic 171 New Results from Air Pollution Studies in Romania O.A Stan, A Lucaciu, M. V. Frontasyeva and E. Steinnes 179 Neutron Activation Analysis of Surficial Sediments from the South-West Part of the Black Sea D.S. Khamrayeva (Gafitullina), N. Mukhamedshina, T. Akyuz, S. Akyuz, A Oya Algan, A Bassari, R. Petrova and V.P. Perelygin 191 Nuclear and Related Analytical Techniques Used to Study the Anthropogenic Impact on the Sister River in the Vicinity of the town of Klin (Moscow Region, Russia) S.v. Morzbukhina, V.V. Uspenskaya, L.P. Chermnykh, I.L. Khodakovsky, M.V. Frontasyeva and S.F. Gundorina 195 Enzymatic Method for Heavy Metals Determination in Waters and Soils T.N. Shekhovtsova, N.A. Bagirova, LA Veselova and S.v. Muginova 201 Heavy Metals in Food Products and Biological Samples from the Gdarlsk District M. Biziuk, 1. Namiesnik and L. Zaslawska 209 Human Hair Composition in Environment Monitoring and Mapping L.I. Zhuk, E.A Danilova, T.Yu. Yashina and AA Kist 217 Environmental Sampling and Analysis of Coal Fly Ash Intended for Use in Roads: Potential Impacts on Environmental Health Decision-Making D.A Belluck and S.L. Benjamin 227 The Pollution of the Environment Caused by Lead Dumping After the Chornobyl NPP Accident - Myth or Reality? O.B. Blum 237 Development of the Method of Bacterial Leaching of Metals Out of Low- Grade Ores, Rocks and Industrial Wastes Using Neutron Activation Analysis L.A Tsertsvadze, T.D. Dzadzamia, Sh.G. Petriashvili, D.G. Shutkerashvili, E.I. Kirkesali, M.v. Frontasyeva, S.S. Pavlov and S.F. Gundorina 245 Vlll 3. Radioactivity and Heavy Metals in Environment; Natural Radioactivity; Earthquakes About a Complex Method to Predict Earthquakes Based on Observations of Rn, Hz, He, Ne , Organic Gases and Heavy Elements from Aerosols M. Kaviladze, N. Gubadze, M. Sikharulidze, G. Natsvlishvili and E. Gamtsemlidze 259 Chemical Nature of Seismic Phenomena Yu.T. Chuburlcov 263 Determination of Radionuclides, Toxic Heavy Metals and Trace Elements in Environmental Samples S. Gerbish, G. Ganchimeg, 1. Bayannaa, B. Dalkhsuren and G. Ganbold 273 Development of Simultaneously Radon and Gamma Measurements to Carry out Monitoring into the Environment -Applications to Survey of Nuclear Waste Storage D. Klein, M. Voytchev, M. Kostova and S. Lamy 283 Dynamics of Subsoil Radon within the Geodynamically Active Regions of Turkmenistan J. Ishankuliev, B.N. Gaipov, S.P. Tretyakova, V.P. Perelygin, B.A. Muradov and B. Kerimov 291 Low Activity Beta-Alpha Radiometer (LABAR) T. Ruskov, L. Dimitrov, B. Kunov, E. Moravska, D. Lefterov and D. Petkov 297 Monitoring and Management of Mountain Environment J.N. Stamenov, B.I. Vachev and 1.P. Carbonnel 305 Radionuclide and Heavy Metal Pollution in Romania E. Pincovschi and 1.1. Georgescu 313 Radon Over Volcanic and Seismic Areas M.M. Monnin 319 Rapid Changes of Some Geophysical Parameters in the Nature V.1. Nevinsky, 1.0. Nevinsky and T.V. Tsvetkova 331 Some Global Environmental Issues of the 21st Century R. Wilson 335 Track Methods of Measurements in the Environment Developed in Khlopin Radium Institute V.A. Nikolaev 349 An Accelerator Based Nuclear Analytical Method for the Analysis of Environmental Samples M.A. Chaudhri 361 IX 4. Transmutation of Man-Made Radionuclides ADS (Accelerator-Driven Systems) -A New Technology to Destroy Completely Long-Lived Radwaste R Brandt 367 Electronnclear Technology for the Incineration of Plutonium V.S. Barashenkov 379 Fission of Pb Nuclei Induced by 0.5, 1.0, 1.5, 3.7 and 7.4 GeV Protons in the Volume of Massive UlPb and Pb Targets v.P. Perelygin, O.S. Zaveriukha, B.N. Kulakov, M.I. Krivopustov, I.G. Abdullaev, G.P. Knjazeva, RI. Petrova, R Brandt, M. Ochs, J.S. Wan and P. Vater 385 Author Index 387 Subject Index 389 PREFACE This volume entitled "Radionuclides and Heavy Metals in Environment" contains the Proceedings of the NATO Advanced Research Workshop (ARW) "Monitoring of Natural and Man-Made Radionuclides and Heavy Metal Waste in Environment" that was held at the Joint Institute for Nuclear Research (JlNR), Dubna, Russia from 3 October to 6 October, 2000. Originally, it was planned to held the ARW in 1999, the year when NATO was celebrating its 50th anniversary. Few days before opening it had to be postponed because of problems in issuing visa for all the colleagues who intended to participate. The ARW was organized and conducted by the co-directors Prof. Vladimir P. Perelygin, Joint Institute for Nuclear Research, Dubna, Russia and Dr. Peter Vater, Philipps Universitat, Marburg, Germany. The JlNR was chosen as the host institute of ARW because of the lack of contact and real co-operation between the former Soviet Union (FSU) countries specialists in ecology and their Western well experienced colleagues. The selection of this location and supplementary funds provided by Russian Foundation on Basic Research, Moscow, Russia, and the JINR, Dubna., Russia made it possible to attain a rather large number of participants and observers from FSU countries. The JlNR provided to all the participants of the workshop an effective car/minibus transportation Moscow-Dubna-Moscow and a rather good accommodation in Dubna. In total 43 official ARW participants and about 40 observers had submitted 80 contributions, including 47 oral and 33 poster presentations at 12 plenary and two posters sessions. Two round-table discussions were conducted, too. The NATO ARW was addressed to the critical problems of abundance and accumulation of man-made radionuclides (in particular, plutonium) and heavy metals in the environment and their inevitable negative influence on human health. It ftrstly brought together specialists who use different methods and different approaches to these urgent environmental problems which are of great international importance. The program of the NATO ARW covered four main topics, the papers in this volume are arranged, accordingly. First. About 20 communications dealt with the problem of growing abundance of man-made radionuclides in environment, in particular weapon and reactor Pu and also Am. The contributions include diverse methods of high-sensitive analysis of artiftcial radionuclides (in particular Pu and Am), such as accelerator mass spectrometry, combined neutron-ganuna activation and luminescence analysis. The results on high-sensitive determinations of Pu, Np and Am content in samples taken from the Chernobyl, Chelyabinsk, Semipalatinsk hot spots and also from more quiet regions of Poland, Russia and North Belarus were presented, too. xi