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Quantum Orders and Symmetric Spin Liquids (the original version) Xiao-Gang Wen∗ Department of Physics, Massachusetts Institute of Technology, Cambridge, Massachusetts 02139 (Dated: June3, 2001) A concept – quantum order – is introduced to describe a new kind of orders that generally 2 appear in quantum states at zero temperature. Quantum orders that characterize universality 0 classes of quantum states (described by complex ground state wave-functions) is much richer then 0 classicalordersthatcharacterizeuniversalityclassesoffinitetemperatureclassicalstates(described 2 bypositiveprobabilitydistributionfunctions). TheLandau’stheoryforordersandphasetransitions does not apply to quantum orders since they cannot be described by broken symmetries and the n associated orderparameters. Weintroduced amathematical object – projective symmetry group – a tocharacterizequantumorders. Withthehelpofquantumordersandprojectivesymmetrygroups, J we construct hundreds of symmetric spin liquids, which have SU(2), U(1) or Z2 gauge structures 2 at low energies. We found that various spin liquids can be divided into four classes: (a) Rigid spin liquid – spinons (and all other excitations) are fully gaped and may have bosonic, fermionic, ] l or fractional statistics. (b) Fermi spin liquid – spinons are gapless and are described by a Fermi e liquid theory. (c) Algebraic spin liquid – spinons are gapless, but they are not described by free - r fermionic/bosonic quasiparticles. (d) Bose spin liquid – low lying gapless excitations are described t byafreebosontheory. Thestabilityofthosespinliquidsarediscussedindetails. Wefindthatstable s . 2Dspinliquidsexistin thefirstthreeclasses (a–c). Those stablespinliquidsoccupyafiniteregion t a in phase space and represent quantum phases. Remarkably, some of the stable quantum phases m support gapless excitations even without any spontaneous symmetry breaking. In particular, the gapless excitations in algebraic spin liquids interact down to zero energy and the interaction does - d not open any energy gap. We propose that it is the quantum orders (instead of symmetries) that n protect thegapless excitationsand makealgebraic spin liquidsand Fermispin liquidsstable. Since o highTc superconductorsarelikelytobedescribedbyagaplessspinliquid,thequantumordersand c theirprojectivesymmetrygroupdescriptionslaythefoundationforspinliquidapproachtohighTc [ superconductors. 2 PACSnumbers: 73.43.Nq,74.25.-q,11.15.Ex v 1 7 Contents C. Classification of symmetric U(1) and SU(2) 0 7 spin liquids 15 0 I. Introduction 2 1 V. Continuous transitions and spinon A. Topological orders and quantum orders 2 0 spectra in symmetric spin liquids 17 t/ B. Spin-liquid approach to high Tc A. Continuous phase transitions without a superconductors 3 symmetry breaking 17 m C. Spin-charge separation in (doped) spin B. Symmetric spin liquids around the - liquids 5 U(1)-linear spin liquid U1Cn01n 17 d D. Organization 6 C. Symmetric spin liquids around the n o SU(2)-gapless spin liquid SU2An0 20 c II. Projective construction of 2D spin liquids D. Symmetric spin liquids around the v: – a review of SU(2) slave-boson approach6 SU(2)-linear spin liquid SU2Bn0 22 i X VI. Mean-field phase diagram of J -J model 23 III. Spin liquids from translationally invariant 1 2 r a ansatz 9 VII. Physical measurements of quantum orders 23 IV. Quantum orders in symmetric spin liquids 12 VIII. Four classes of spin liquids and their A. Quantum orders and projective symmetry stability 26 groups 12 A. Rigid spin liquid 26 B. Classification of symmetric Z spin liquids 14 B. Bose spin liquid 26 2 C. Fermi spin liquid 26 D. Algebraic spin liquid 27 E. Quantum order and the stability of spin ∗URL:http://dao.mit.edu/~wen liquids 29 2 IX. Relation to previously constructed spin A. Topological orders and quantum orders liquids 30 Matter can have many different states, such as gas, X. Summary of the main results 30 liquid, and solid. Understanding states of matter is the firststepinunderstandingmatter. Physicistsfindmatter canhavemuchmoredifferentstatesthanjustgas,liquid, A. Classification of projective symmetry and solid. Even solids and liquids can appear in many groups 33 differentformsandstates. Withsomanydifferentstates 1. General conditions on projective symmetry of matter, a general theory is needed to gain a deeper groups 33 understanding of states of matter. 2. Classification of Z2 projective symmetry All the states of matter are distinguished by their in- groups 34 ternal structures or orders. The key step in developing 3. Classification of U(1) projective symmetry the general theory for states of matter is the realization groups 36 that all the orders are associated with symmetries (or rather, the breaking of symmetries). Based on the rela- 4. Classification of SU(2) projective symmetry tionbetweenordersandsymmetries,Landaudevelopeda groups 43 generaltheory of orders and the transitions between dif- ferent orders.[1, 2] Landau’s theory is so successful and B. Symmetric perturbations around one starts to have a feeling that we understand, at in symmetric spin liquids 44 principle, all kinds of orders that matter can have. 1. Construction of symmetric perturbations 44 However, nature never stops to surprise us. In 1982, Tsui, Stormer, and Gossard[3] discovered a new kind of 2. Symmetric perturbations around the state – FractionalQuantum Hall(FQH) liquid.[4] Quan- Z -linear state Z2A003z 45 2 tumHallliquidshavemanyamazingproperties. Aquan- 3. Symmetric perturbations around the tum Hall liquid is more “rigid” than a solid (a crystal), U(1)-linear state U1Cn01n 45 in the sense that a quantum Hall liquid cannot be com- 4. Symmetric perturbations around the pressed. ThusaquantumHallliquidhasafixedandwell- SU(2)-gapless state SU2An0 47 defined density. When we measure the electron density 5. Symmetric perturbations around the in terms of filling factor ν, we found that all discovered SU(2)-linear state SU2Bn0 52 quantum Hall states have such densities that the filling factorsareexactlygivenby some rationalnumbers, such as ν = 1,1/3,2/3,2/5,.... Knowing that FQH liquids References 57 exist only at certain magical filling factors, one cannot help to guess that FQH liquids should have some inter- nal orders or “patterns”. Different magical filling fac- torsshouldbe due to those different internal“patterns”. I. INTRODUCTION However, the hypothesis of internal “patterns” appears to have one difficulty – FQH states are liquids, and how Due to its long length, we would like to first outline can liquids have any internal “patterns”? the structure of the paper so readers can choose to read In 1989, it was realized that the internal orders in thepartsofinterests. ThesectionXsummarizethemain FQH liquids (as well as the internal orders in chiral spin results of the paper, which also serves as a guide of the liquids[5, 6]) are different from any other known orders wholepaper. Theconceptofquantumorderisintroduced and cannot be observed and characterized in any con- in section IA. A concrete mathematical description of ventional ways.[7, 8] What is really new (and strange) quantum order is described in section IVA and section about the orders in chiral spin liquids and FQH liquids IVB. Readers who are interestedin the backgroundand is that they are not associated with any symmetries (or motivation of quantum orders may choose to read sec- thebreakingofsymmetries),andcannotbe describedby tion IA. Readers who are familiar with the slave-boson Landau’stheoryusingphysicalorderparameters.[9]This approachandjustwantaquickintroductiontoquantum kindoforderiscalledtopologicalorder. Topologicalorder ordersmaychoosetoreadsectionsIVAandIVB. Read- is a new concept and a whole new theory was developed ers who are not familiar with the slave-boson approach to describe it.[9, 10] may find the review sections II and III useful. Read- Knowing FQH liquids contain a new kind of order – ers who do not care about the slave-bosonapproach but topologicalorder, we would like to ask why FQH liquids are interested in application to high T superconductors are so special. What is missed in Landau’s theory for c and experimental measurements of quantum orders may states of matter so that the theory fails to capture the choosetoreadsectionsIA, IB,VII andFig. 1-Fig. 15, topological order in FQH liquids? to gain some intuitive picture of spinon dispersion and When we talk about orders in FQH liquids, we are neutron scattering behavior of various spin liquids. really talking about the internal structure of FQH liq- 3 uids at zero temperature. In other words, we are talking also appear in spin liquids at zero temperature. In fact, abouttheinternalstructureofthequantumgroundstate the conceptoftopologicalorderwasfirstintroducedin a of FQH systems. So the topological order is a property study of spin liquids.[9] FQH liquid is not even the first of ground state wave-function. The Landau’s theory is experimentally observed state with non trivial topolog- developed for system at finite temperatures where quan- ical orders. That honor goes to superconducting state tum effects can be ignored. Thus one should not be sur- discovered in 1911.[12] In contrast to a common point prisedthat the Landau’stheory does not apply to states ofview,asuperconductingstatecannotbecharacterized at zero temperature where quantum effects are impor- bybrokensymmetries. Itcontainsnontrivialtopological tant. The very existence of topological orders suggests orders,[13] and is fundamentally different from a super- that finite-temperature orders and zero-temperature or- fluid state. ders are different, and zero-temperature orders contain After a long introduction, now we can state the main richerstructures. WeseethatwhatismissedbyLandau’s subject of this paper. In this paper, we will study a new theory is simply the quantum effect. Thus FQH liquids class of quantum orders where the excitations above the arenotthatspecial. TheLandau’stheoryandsymmetry ground state are gapless. We believe that the gapless characterization can fail for any quantum states at zero quantum orders are important in understanding high T c temperature. As a consequence, new kind of orders with superconductors. To connect to high T superconduc- c no broken symmetries and local order parameters (such tors, we will study quantum orders in quantum spin liq- astopologicalorders)canexistforanyquantumstatesat uids on a 2D square lattice. We will concentrate on how zero temperature. Because the orders in quantum states to characterize and classify quantum spin liquids with at zero temperature and the orders in classical states at different quantum orders. We introduce projective sym- finite temperatures arevery different, here we wouldlike metrygroupstohelpustoachievethisgoal. Theprojec- to introduce two concepts to stress their differences:[11] tive symmetry group can be viewed as a generalization (A) Quantum orders:[92] which describe the universal- of symmetry group that characterize different classical ity classes of quantum ground states (ie the universality orders. classes of complex ground state wave-functions with in- finity variables); (B)Classical orders: which describe the universality B. Spin-liquid approach to high Tc superconductors classes of classical statistical states (ie the universality classes ofpositive probability distribution functions with There are many different approaches to the high T infinity variables). c superconductors. Different people have different points From the above definition, it is clear that the quantum of view on what are the key experimental facts for the ordersassociatedwith complex functions are richerthan high T superconductors. The different choice of the key the classical orders associated with positive functions. c experimentalfactsleadtomanydifferentapproachesand The Landau’s theory is a theory for classical orders, theories. The spinliquid approachis basedona pointof whichsuggeststhatclassicalordersmaybecharacterized view that the high T superconductors are doped Mott by broken symmetries and local order parameters.[93] c insulators.[14,15,16](HerebyMottinsulatorwemeana The existence of topological order indicates that quan- insulator with an odd number of electron per unit cell.) tum orders cannot be completely characterized by bro- We believe that the most important properties of the ken symmetries and order parameters. Thus we need to high T superconductors is that the materials are in- develop a new theory to describe quantum orders. c sulators when the conduction band is half filled. The In a sense, the classical world described by positive charge gap obtained by the optical conductance experi- probabilitiesisaworldwithonly“blackandwhite”. The ments is about 2eV, which is much larger than the anti- Landau’stheoryandthesymmetryprincipleforclassical ferromagnetic(AF) transitiontemperatureT 250K, AF orders are color blind which can only describe different ∼ the superconducting transition temperature T 100K, c “shades of grey” in the classical world. The quantum ∼ and the spin pseudo-gap scale ∆ 40meV.[17, 18, 19] worlddescribedbycomplexwavefunctionsisa“colorful” ∼ The insulating property is completely due to the strong world. Weneedtousenewtheories,suchasthetheoryof correlations present in the high T materials. Thus the c topologicalorderandthetheorydevelopedinthispaper, strongcorrelationsareexpecttoplayveryimportantrole to describe the rich “color” of quantum world. inunderstandinghighT superconductors. Manyimpor- c The quantum orders in FQH liquids have a special tantpropertiesofhighT superconductorscanbedirectly c property that all excitations above ground state have fi- linkedtotheMottinsulatorathalffilling,suchas(a)the nite energygaps. Thiskindofquantumordersarecalled low charge density[20] and superfluid density,[21] (b) T c topological orders. In general, a topological order is de- being proportional to doping T x,[22, 23, 24] (c) the c finedas aquantumorderwhereallthe excitations above positive charge carried by the cha∝rge carrier,[20] etc . ground state have finite energy gapes. In the spin liquid approach, the strategy is to try to Topological orders and quantum orders are general understand the properties of the high T superconduc- c properties ofany states atzero temperature. Nontrivial tors from the low doping limit. We first study the spin topological orders not only appear in FQH liquids, they liquid state at half filling and try to understand the par- 4 ent Mott insulator. (In this paper, by spin liquid, we The algebraic spin liquids and Fermi spin liquids are in- mean a spin state with translation and spin rotation teresting since they can be stable despite their gapless symmetry.) At half filling, the charge excitations can excitations. Those gapless excitations are not protected be ignored due to the huge charge gap. Thus we can bysymmetries. Thisis particularlystrikingforalgebraic use a pure spin model to describe the half filled system. spin liquids since their gapless excitations interact down After understand the spin liquid, we try to understand tozeroenergyandthestatesarestillstable. Wepropose the dynamics of a few doped holes in the spin liquid that it is the quantum orders that protect the gapless states and to obtain the properties of the high T su- excitations and ensure the stability of the algebraic spin c perconductors at low doping. One advantage of the spin liquids and Fermi spin liquids. liquid approach is that experiments (such as angle re- Wewouldliketopointoutthatbothstableandunsta- solvedphoto-emission,[17, 18,25, 26]NMR,[27], neutron blespinliquidsmaybeimportantforunderstandinghigh scattering,[28, 29, 30] etc ) suggest that underdoped cu- T superconductors. Although at zero temperature high perates have many striking and qualitatively new prop- c T superconductorsarealwaysdescribedstablequantum ertieswhichareverydifferentfromthewellknownFermi c states,someimportantstatesofhighT superconductors, liquids. It is thus easier to approve or disapprove a new c such as the pseudo-gap metallic state for underdoped theoryintheunderdopedregimebystudyingthosequal- samples, are observed only at finite temperatures. Such itatively new properties. finite temperature states may correspondto (doped) un- Since the properties of the doped holes (such as their stable spin liquids, such as staggered flux state. Thus statistics, spin, effective mass, etc ) are completely de- even unstable spin liquids can be useful in understand- termined by the spin correlation in the parent spin liq- ing finite temperature metallic states. uids, thus in the spin liquid approach,eachpossible spin liquid leads to a possible theory for high T supercon- There are many different approach to spin liquids. In c ductors. Using the concept of quantum orders, we can addition to the slave-boson approach,[6, 15, 16, 31, 32, say that possible theories for high T superconductors in 33, 35, 36, 37, 38, 39, 40] spin liquids has been stud- c the low doping limits are classified by possible quantum iedusingslave-fermion/σ-modelapproach,[41,42,43,44, orders in spin liquids on 2D square lattice. Thus one 45, 46] quantum dimer model,[47, 48, 49, 50, 51] and way to study high T superconductors is to construct all various numerical methods.[52, 53, 54, 55] In particular, c the possible spin liquids that have the same symmetries the numericalresults andrecentexperimentalresults[56] as those observed in high T superconductors. Then an- stronglysupporttheexistenceofquantumspinliquidsin c alyze the physical properties of those spin liquids with some frustrated systems. A 3D quantum orbital liquid dopings to see which one actually describes the high Tc was also proposed to exist in LaTiO3.[57] superconductor. Although we cannot say that we have However, I must point out that there is no generally constructed all the symmetric spin liquids, in this paper accepted numerical results yet that prove the existence wehavefoundawaytoconstructalargeclassofsymmet- of spin liquids with odd number of electron per unit cell ricspinliquids. (Herebysymmetricspinliquidswemean for spin-1/2 systems, despite intensive search in last ten spin liquids with all the lattice symmetries: translation, years. But it is my faith that spin liquids (with odd rotation, parity, and the time reversal symmetries.) We number of electron per unit cell) exist in spin-1/2 sys- also find a way to characterize the quantum orders in tems. For more general systems, spin liquids do ex- those spin liquids via projective symmetry groups. This ist. Read and Sachdev[43] found stable spin liquids in gives us a global picture of possible high T theories. c a Sp(N) model in large N limit. The spin-1/2 model We would like to mention that a particular spin liquid studiedinthis papercanbe easilygeneralizedtoSU(N) – the staggered-flux/d-wave state[31, 32] – may be im- model with N/2 fermions per site.[31, 58] In the large portant for high T superconductors. Such a state can c N limit, one can easily construct various Hamiltonians explain[33, 34] the highly unusual pseudo-gap metallic whose ground states realize various U(1) and Z spin 2 state found in underdoped cuperates,[17, 18, 25, 26] as liquids constructed in this paper.[59] The quantum or- well as the d-wave superconducting state[32]. ders in those large-N spin liquids can be described by The spin liquids constructed in this paper can be di- the methods introduced in this paper. Thus, despite the vided into four class: (a) Rigid spin liquid – spinons are uncertainty about the existence of spin-1/2 spin liquids, fully gaped and may have bosonic, fermionic, or frac- the methods and the results presented in this paper are tional statistics, (b) Fermi spin liquid – spinons are gap- not about (possibly) non-existing “ghost states”. Those lessandaredescribedby aFermiliquidtheory,(c)Alge- methods and results apply, at least, to certain large-N braic spin liquid – spinons are gapless, but they are not systems. In short, non-trivial quantum orders exist in described by free fermionic/bosonic quasiparticles. (d) theory. We just need to find them in nature. (In fact, Bose spin liquid – low lying gapless excitations are de- ourvacuumislikelytobeastatewithanon-trivialquan- scribed by a free bosontheory. We find some of the con- tumorder,duetothefactthatlightexists.[58])Knowing structedspinliquidsarestableandrepresentstablequan- the existence of spin liquids in large-N systems, it is not tumphases,whileothersareunstableatlowenergiesdue such a big leap to go one step further to speculate that to long range interactions caused by gauge fluctuations. spin liquids exist for spin-1/2 systems. 5 C. Spin-charge separation in (doped) spin liquids ductors, the possibility of true spin-charge separation in an electron system is very interesting. The first con- crete example of true spin-charge separation in 2D is Spin-charge separation and the associated gauge the- given by the chiral spin liquid state,[5, 6] where the ory in spin liquids (and in doped spin liquids) are very gauge interaction between the spinons and holons be- important concepts in our attempt to understand the comes short-ranged due to a Chern-Simons term. The properties ofhigh T superconductors.[14, 15, 16, 39, 60] c Chern-Simons term breaks time reversal symmetry and However, the exact meaning of spin-charge separation is givesthespinonsandholonsafractionalstatistics. Later differentfordifferentresearchers. Theterm“spin-charge in 1991, it was realized that there is another way to separation” has at lease in two different interpretations. make the gauge interaction short-ranged through the Inthefirstinterpretation,thetermmeansthatitisbetter Anderson-Higgs mechanism.[38, 43] This led to a mean- to introduce separatespinons (a neutral spin-1/2excita- field theory[38, 40] of the short-ranged Resonating Va- tion) and holons (a spinless excitation with unit charge) lence Bound(RVB) state[47, 48] conjectured earlier. We to understand the dynamical properties of high T su- c will call such a state Z spin liquid state, to stress the perconductors, instead of using the original electrons. 2 unconfinedZ gauge field that appears in the low energy However, there may be long range interaction (possibly, 2 effectivetheoryofthosespinliquids. (Seeremarksatthe evenconfininginteractionsatlongdistance)betweenthe endofthis section. We alsonote thattheZ spinliquids spinons and holons,andthe spinons and holons maynot 2 studied in Ref. [43] all break the 90◦ rotation symmetry be well defined quasiparticles. We will call this inter- and are different from the short-ranged RVB state stud- pretation pseudo spin-charge separation. The algebraic iedRef.[38,40,47,48].) Since theZ gaugefluctuations spinliquidshavethepseudospin-chargeseparation. The 2 are weak and are not confining, the spinons and holons essence of the pseudo spin-charge separation is not that have only short rangedinteractions in the Z spin liquid spin and charge separate. The pseudo spin-charge sepa- 2 state. TheZ spinliquidstatealsocontainsaZ vortex- ration is simply another way to say that the gapless exci- 2 2 like excitation.[38, 62] The spinons and holons can be tationscannotbedescribedbyfreefermions orbosons. In bosons or fermions depending on if they are bound with the second interpretation, the term “spin-charge separa- the Z vortex. tion”meansthatthereareonlyshort rangedinteractions 2 betweenthespinonsandholons. Thespinonsandholons Recently,thetruespin-chargeseparation,theZ2gauge are well defined quasiparticles at least in the dilute limit structure and the Z2 vortex excitations were also pro- oratlowenergies. We willcallthe secondinterpretation posed in a study of quantum disordered superconduct- the true spin-charge separation. The rigid spin liquids ing state in a continuum model[63] and in a Z2 slave- andthe Fermispinliquids havethe truespin-chargesep- boson approach[64]. The resulting liquid state (which aration. was named nodal liquid) has all the novel properties of Electron operator is not a good starting point to de- Z2 spin liquid state such as the Z2 gauge structure and scribe states with pseudo spin-charge separation or true theZ2 vortexexcitation(whichwasnamedvison). From spin-charge separation. To study those states, we usu- the point ofview ofuniversalityclass,the nodalliquidis ally rewrite the electron operator as a product of sev- one kind of Z2 spin liquids. However, the particular Z2 eral other operators. Those operators are called parton spin liquid studied in Ref. [38, 40] and the nodal liquid operators. (The spinon operator and the holon opera- are two different Z2 spin liquids, despite they have the tor are examples of parton operators). We then con- same symmetry. The spinons in the first Z2 spin liquid struct mean-field state in the enlarged Hilbert space of have a finite energy gap while the spinons in the nodal partons. The gauge structure can be determined as the liquidaregaplessandhaveaDirac-likedispersion. Inthis most general transformations between the partons that paper, we will use the projective construction to obtain leave the electron operator unchanged.[61] After identi- moregeneralspinliquids. Wefindthatonecanconstruct fying the gauge structure, we can project the mean-field hundreds of different Z2 spin liquids. Some Z2 spin liq- state onto the physical (ie the gauge invariant) Hilbert uids have finite energy gaps, while others are gapless. space and obtain a strongly correlated electron state. Among those gapless Z2 spin liquids, some have finite This procedure in its general form is called projective Fermi surfaces while others have only Fermi points. The construction. It is a generalization of the slave-boson spinonsneartheFermipointscanhavelinearE(k) k approach.[15, 16, 33, 36, 37, 38, 40] The general pro- or quadratic E(k) k2 dispersions. We find ther∝e a|re| ∝ jective construction and the related gauge structure has morethanoneZ2spinliquidswhosespinonshaveamass- beendiscussedindetailforquantumHallstates.[61]Now less Dirac-like dispersion. Those Z2 spin liquids have we see a third (but technical) meaning of spin-charge the same symmetry but different quantum orders. Their separation: to construct a strongly correlated electron ansatz are give by Eq. (42), Eq. (39), Eq. (88), etc . state, we need to use partons and projective construc- Both chiral spin liquid and Z spin liquid states are 2 tion. The resulting effective theory naturally contains a Mott insulators with one electron per unit cell if not gauge structure. doped. Their internal structures are characterized by a Although, it is not clear which interpretation of spin- new kind of order– topologicalorder,if they are gapped charge separation actually applies to high T supercon- or if the gapless sector decouples. Topological order is c 6 not related to any symmetries and has no (local) or- property of ground state. Thus we should not regardZ 2 der parameters. Thus, the topological order is robust spinliquidsasthespinliquidsconstructedusingZ slave- 2 against all perturbations that can break any symmetries boson approach. A Z spin liquid can be constructed 2 (including random perturbations that break translation from the U(1) or SU(2) slave-boson approaches as well. symmetry).[9, 10] (This point was also emphasized in Aprecisemathematicaldefinitionofthelowenergygauge Ref. [65] recently.) Even though there are no order pa- group will be given in section IVA. rameterstocharacterizethem,thetopologicalorderscan becharacterizedbyothermeasurablequantumnumbers, suchasgroundstatedegeneracyincompactspaceaspro- D. Organization posed in Ref. [9, 10]. Recently, Ref. [65] introduced a very clever experiment to test the ground state degen- In this paper we will use the method outlined in eracy associated with the non-trivial topological orders. Ref. [38, 40] to study gauge structures in various spin In addition to ground state degeneracy, there are other liquid states. In section II we review SU(2) mean-field practicalwaystodetecttopologicalorders. Forexample, theory of spin liquids. In section III, we construct sim- the excitations on top of a topologically ordered state ple symmetric spin liquids using translationally invari- canbedefectsoftheunderlyingtopologicalorder,which ant ansatz. In section IV, projective symmetry group is usually leads to unusual statistics for those excitations. introduced to characterize quantum orders in spin liq- Measuringthestatisticsofthoseexcitationsalsoallowus uids. In section V, we study the transition between dif- to measure topological orders. ferent symmetric spin liquids, using the results obtained The concept of topological order and quantum order in appendix B, where we find a way to construct all the are very important in understanding quantum spin liq- symmetric spin liquids in the neighborhood of some well uids (or any other strongly correlated quantum liquids). known spin liquids. We also study the spinon spectrum In this paper we are going to construct hundreds of dif- togainsomeintuitiveunderstandingonthepropertiesof ferent spin liquids. Those spin liquids all have the same the spin liquids. Using the relation between two-spinon symmetry. To understand those spin liquids, we need to spectrum and quantum order, we propose, in section first learn how to characterize those spin liquids. Those VII, a practical way to use neutron scattering to mea- states break no symmetries and hence have no order pa- sure quantum orders. We study the stability of Fermi rameters. One would get into a wrong track if trying to spin liquids and algebraic spin liquids in section VIII. find an order parameter to characterize the spin liquids. We find that both Fermi spin liquids and algebraic spin Weneedtouseacompletelynewway,suchastopological liquids can exist as zero temperature phases. This is orders and quantum orders, to characterize those states. particularly striking for algebraic spin liquids since their gapless excitations interacts even at lowest energies and In addition to the above Z spin liquids, in this paper 2 there are no free fermionic/bosonic quasiparticle excita- we will also study many other spin liquids with different tions at low energies. We show how quantum order can low energy gauge structures, such as U(1) and SU(2) protectgaplessexcitations. Appendix Acontainsamore gauge structures. We will use the terms Z spin liq- 2 detailed discussionon projective symmetry group, and a uids,U(1)spinliquids,andSU(2)spinliquidstodescribe classification of Z , U(1) and SU(2) spin liquids using them. We would like to stress that Z , U(1), and SU(2) 2 2 the projective symmetry group. Section X summarizes here are gauge groups that appear in the low energy ef- the main results of the paper. fective theoriesofthosespinliquids. They shouldnotbe confused with the Z , U(1), and SU(2) gauge group in 2 slave-boson approach or other theories of the projective II. PROJECTIVE CONSTRUCTION OF 2D construction. The latter are high energy gauge groups. SPIN LIQUIDS – A REVIEW OF SU(2) The high energy gauge groups have nothing to do with SLAVE-BOSON APPROACH the low energy gauge groups. A high energy Z gauge 2 theory (or a Z slave-boson approach) can have a low 2 In this section, we are going to use projective con- energy effective theory that contains SU(2), U(1) or Z 2 struction to construct 2D spin liquids. We are going gauge fluctuations. Even the t-J model, which has no to review a particular projective construction, namely gauge structure at lattice scale, can have a low energy the SU(2) slave-boson approach.[15, 16, 33, 36, 37, 38, effective theory that contains SU(2), U(1) or Z gauge 2 40] The gauge structure discovered by Baskaran and fluctuations. The spin liquids studied in this paper all Anderson[16] in the slave-boson approach plays a cru- contain some kind of low energy gauge fluctuations. De- cialrole in our understanding of strongly correlatedspin spite their different low energy gauge groups, all those liquids. spin liquids can be constructed from any one of SU(2), We will concentrate on the spin liquid states of a pure U(1), or Z slave-boson approaches. After all, all those 2 spin-1/2 model on a 2D square lattice slave-bosonapproachesdescribe the same t-J model and are equivalent to each other. In short, the high energy gaugegroupisrelatedtothewayinwhichwewritedown Hspin = JijSi Sj +... (1) · the Hamiltonian, while the low energy gauge group is a <ij> X 7 where the summation is over different links (ie ij and χ and η in Eq. (7) must satisfy the self consistency ij ij ji are regarded as the same) and ... represenhts piossi- condition Eq. (6) and the site dependent fields al(i) are h i 0 ble terms which contain three or more spin operators. chosen such that Eq. (5) is satisfied by the mean-field Those terms are needed in order for many exotic spin ground state. Such χ , η and al give us a mean-field ij ij 0 liquid states introduced in this paper to become the solution. The fluctuations in χ , η and al(i) describe ij ij 0 ground state. To obtain the mean-field ground state of the collective excitations above the mean-field ground thespinliquids,weintroducefermionicpartonoperators state. f , α=1,2 which carries spin 1/2 and no charge. The The Hamiltonian Eq. (7) and the constraints Eq. (4) iα spin operator S is represented as have a local SU(2) symmetry.[36, 37] The local SU(2) i symmetry becomes explicit if we introduce doublet 1 S = f† σ f (2) i 2 iα αβ iβ IntermsofthefermionoperatorstheHamiltonianEq.(1) ψ = ψψ1 = ff↑† (8) can be rewritten as (cid:18) 2(cid:19) (cid:18) ↓(cid:19) 1 1 and matrix H = J f† f f† f + f† f f† f (3) −2 ij iα jα jβ iβ 2 iα iα jβ jβ Xhiji (cid:18) (cid:19) U = χ†ij ηij =U† (9) HWeereawlsoe haadvdeeduspedroσpeαrβc·oσnαs′tβa′nt=t2erδmαβs′δα′β f−†δfαβδαa′nβ′d. ij ηi†j −χij! ji i iα iα f† f f† f to get the above form. Notice that Using Eq. (8) and Eq. (9) we can rewrite Eq. (5) and hiji iα iα jβ jβ P Eq. (7) as: the Hilbert space of Eq. (3) is generated by the parton P operators f and is larger than that of Eq. (1). The α equivalence between Eq. (1) and Eq. (3) is valid only in ψi†τlψi =0 (10) the subspace where there is exactly one fermion per site. D E Therefore to use Eq. (3) to describe the spin state we need to impose the constraint[15, 16] H = 3J 1Tr(U† U ) (ψ†U ψ + h.c.) mean 8 ij 2 ij ij − i ij j fi†αfiα =1, fiαfiβǫαβ =0 (4) Xhiji (cid:20) (cid:21) The second constraint is actually a consequence of the + alψ†τlψ (11) 0 i i first one. i X Amean-fieldgroundstateat“zeroth”orderisobtained bymakingthefollowingapproximations. Firstwereplace whereτl, l =1,2,3arethePaulimatrices. FromEq.(11) constraint Eq. (4) by its ground-state average wecanseeclearlythattheHamiltonianisinvariantunder a local SU(2) transformation W(i): f† f =1, f f ǫ =0 (5) h iα iαi h iα iβ αβi ψ W(i) ψ Such a constraint can be enforced by including a site i → i dependent and time independent Lagrangian multiplier: Uij W(i) Uij W†(j) (12) → al(i)(f† f 1), l =1,2,3, in the Hamiltonian. At the 0 iα iα− The SU(2) gauge structure is originated from Eq. (2). zeroth order we ignore the fluctuations (ie the time de- pendence) of al. If we included the fluctuations of al, The SU(2) is the most general transformation between 0 0 the partons that leave the physical spin operator un- the constraint Eq. (5) would become the original con- changed. Thus once we write down the parton expres- straint Eq. (4).[15, 16, 36, 37] Second we replace the sion of the spin operator Eq. (2), the gauge structure of operators f† f and f f by their ground-state ex- iα jβ iα iβ thetheoryisdetermined.[61](TheSU(2)gaugestructure pectations value discussed here is a high energy gauge structure.) ηijǫαβ = 2 fiα fjβ , ηij =ηji We note that both components of ψ carry spin-up. − h i χ δ =2 f† f , χ =χ† (6) Thus the spin-rotation symmetry is not explicit in our ij αβ h iα jβi ij ji formalism and it is hard to tell if Eq. (11) describes a again ignoring their fluctuations. In this way we obtain spin-rotationinvariantstateornot. Infact,forageneral the zeroth order mean-field Hamiltonian: U satisfying U = U† , Eq. (11) may not describe a ij ij ji H spin-rotationinvariant state. However, if Uij has a form mean 3 = −8Jij (χjifi†αfjα+ηijfi†αfj†β ǫαβ +h.c) Uij = iρijWij, Xhiji h ρij = real number, −|χij|2−|ηij|2 (7) Wij ∈ SU(2), (13) + a30(fi†αfiα−1)(cid:3)+[(a10+ia20)fiαfiβǫαβ +h.c.] thenEq.(11)willdescribeaspin-rotationinvariantstate. Xi h i This is because the aboveUij canbe rewrittenin a form 8 Eq.(9). Inthis caseEq.(11)canbe rewrittenas Eq.(7) physical properties. This property is usually called the where the spin-rotation invariance is explicit. “gaugesymmetry”. However,fromthe abovediscussion, To obtain the mean-field theory, we have enlarged the we see that the “gaugesymmetry” is not a symmetry. A Hilbert space. Because of this, the mean-field theory symmetry is about two different states having the same is not even qualitatively correct. Let Ψm(Ueiajn) be the properties. Uij and Ui′j are just two labels that label ground state of the Hamiltonian Eq. (1|1) withi energy the samestate,andthesamestatealwayshavethe same E(U ,alτl). It is clear that the mean-field ground state properties. We do not usually call the same state hav- ij i is not even a valid wave-function for the spin system ing the same properties a symmetry. Because the same since it may not have one fermion per site. Thus it is statealwayhavethesameproperties,the“gaugesymme- very important to include fluctuations of al to enforce try”canneverbebroken. Itisverymisleadingtocallthe 0 one-fermion-per-site constraint. With this understand- Anderson-Higgsmechanism“gaugesymmetrybreaking”. ing,we mayobtainavalidwave-functionofthe spinsys- Withthisunderstanding,weseethatasuperconductoris temΨ ( α )byprojectingthemean-fieldstatetothe fundamentally different from a superfluid. A superfluid spin i subspace of{on}e-fermion-per-site: is characterizedby U(1) symmetry breaking, while a su- perconductorhasnosymmetrybreakingonceweinclude Ψ ( α )= 0 f Ψ(Uij) . (14) the dynamicalelectromagnetic gaugefluctuations. A su- spin { i} h | iαi| meani perconductor is actually the first topologically ordered i Y state observed in experiments,[13] which has no symme- NowthelocalSU(2)transformationEq.(12)canhave try breaking, no long range order, and no (local) order a very physical meaning: Ψ(Uij) and Ψ(W(i)UijW†(j)) parameter. However, when the speed of light c = , giverisetothe samespinw| amvee-afnuinction|afmteeranprojectioni: a superconductor becomes similar to a superfluid and∞is characterizedby U(1) symmetry breaking. 0 f Ψ(Uij) = 0 f Ψ(W(i)UijW†(j)) (15) The relation between the mean-field state and the h | iαi| meani h | iαi| mean i physical spin wave function Eq. (14) allows us to con- i i Y Y struct transformation of the physical spin wave-function Thus Uij and Ui′j = W(i)UijW†(j) are just two differ- from the mean-field ansatz. For example the mean-field entlabelswhichlabelthesamephysicalstate. Withinthe state Ψ(Ui′j) with U′ = U produces a phys- mean-field theory, a local SU(2) transformation changes | meani ij i−l,j−l ical spin wave-function which is translated by a dis- amean-fieldstate Ψm(Ueiajn) toadifferentmean-fieldstate tance l from the physical spin wave-function produced Ψm(Uei′ajn) . If the tw| o meain-field states always have the by Ψm(Ueiajn) . The physical state is translationally sym- s|ame phiysical properties, the system has a local SU(2) met|ric if aind only if the translated ansatz U′ and the ij symmetry. However, after projection, the physical spin original ansatz U are gauge equivalent (it does not re- ij quantumstatedescribedbywave-functionΨspin({αi})is quire Ui′j = Uij). We see that the gauge structure can invariant under the local SU(2) transformation. A local complicates our analysis of symmetries, since the phys- SU(2)transformationjusttransformsonelabel,Uij,ofa ical spin wave-function Ψspin( αi ) may has more sym- physicalspinstatetoanotherlabel,Ui′j,whichlabelsthe metries than the mean-field sta{te}Ψ(Uij) before projec- mean exactly the same physical state. Thus after projection, | i tion. local SU(2) transformations become gauge transforma- Let us discuss time reversal symmetry in more detail. tions. The fact that U and U′ label the same physical ij ij A quantum system described by spin state creates a interesting situation when we con- siderthefluctuationsofU aroundamean-fieldsolution ij i~∂ Ψ(t)=HΨ(t) (16) – some fluctuations of U do not change the physical t ij state and are unphysical. Those fluctuations are called hasatimereversalsymmetryifΨ(t)satisfyingthe equa- the pure gauge fluctuations. tion of motion implies that Ψ∗( t) also satisfying the The above discussion also indicates that in order for equation of motion. This requir−es that H = H∗. We themean-fieldtheorytomakeanysense,wemustatleast see that, for time reversal symmetric system, if Ψ is an include the SU(2) gauge (or other gauge) fluctuations eigenstate, then Ψ∗ will be an eigenstate with the same described by al and W in Eq. (13), so that the SU(2) 0 ij energy. gauge structure of the mean-field theory is revealed and Foroursystem,thetimereversalsymmetrymeansthat the physical spin state is obtained. We will include the gaugefluctuations to the zeroth-ordermean-fieldtheory. ifthe mean-fieldwavefunctionΨ(Uij,aliτl) isamean-field mean The new theory will be called the first order mean-field ground state wave function for ansatz (U ,alτl), then ij i theory. It is this first order mean-field theory that rep- Ψ(Uij,aliτl) ∗ will be the mean-field ground state wave mean resents a proper low energy effective theory of the spin liquid. f(cid:16)unction for(cid:17)ansatz (Ui∗j,ali(τl)∗). That is Here,wewouldlikemakearemarkabout“gaugesym- metry” and “gauge symmetry breaking”. We see that Ψ(Uij,aliτl) ∗ =Ψ(Ui∗j,ali(τl)∗) (17) two ansatz U and U′ =W(i)U W†(j) have the same mean mean ij ij ij (cid:16) (cid:17) 9 Forasystemwithtimereversalsymmetry,themean-field symmetric spin liquid. First let us introduce u : ij energy E(U ,alτl) satisfies ij i 3 J U =u (21) E(U ,alτl)=E(U∗,al(τl)∗) (18) 8 ij ij ij ij i ij i For translationally invariant ansatz, we can introduce a Thusifanansatz(U ,alτl)isamean-fieldsolution,then ij i short-hand notation: (U∗,al(τl)∗) is also a mean-field solution with the same ij i mean-field energy. u =uµ τµ u (22) Fromthe abovediscussion,we seethatunder the time ij −i+j ≡ −i+j reversaltransformation, the ansatz transforms as where u1,2,3 are real, u0 is imaginary, τ0 is the identity l l matrix and τ1,2,3 are the Pauli matrices. The fermion U U′ =( iτ2)U∗(iτ2)= U , ij → ij − ij − ij spectrum is determined by Hamiltonian alτl a′lτl =( iτ2)(alτl)∗(iτ2)= alτl. (19) i → i − i − i H = ψ†u ψ +h.c. + ψ†alτlψ (23) Note here we have included an additional SU(2) gauge − i j−i j i 0 i transformationW = iτ2. We also note that under the Xhiji(cid:16) (cid:17) Xi i time reversal transfor−mation, the loop operator trans- In k-space we have forms as P = eiθ+iθlτl ( iτ2)P∗(iτ2) = e−iθ+iθlτl. C → − C H = ψ†(uµ(k) aµ)τµψ (24) We see that the U(1) flux changes the sign while the − k − 0 k SU(2) flux is not changed. Xk Before ending this review section, we would like to where µ=0,1,2,3, point out that the mean-field ansatz of the spin liquids Uij can be divided into two classes: unfrustrated ansatz uµ(k)= uµleil·k, (25) where U only link an even lattice site to an odd lattice ij l X siteandfrustratedansatzwhereU arenonzerobetween ij two even sites and/or two odd sites. An unfrustrated a00 = 0, and N is the total number of site. The fermion ansatz hasonly pure SU(2)flux througheachplaquette, spectrum has two branches and is given by while an frustrated ansatz has U(1) flux of multiple of E (k)=u0(k) E (k) π/2 through some plaquettes in addition to the SU(2) ± ± 0 flux. E (k)= (ul(k) al)2 (26) 0 − 0 s l X III. SPIN LIQUIDS FROM TRANSLATIONALLY The constraints can be obtained from ∂Eground = 0 and INVARIANT ANSATZ ∂al 0 have a form In this section, we will study many simple examples N ψ†τlψ of spin liquids and their ansatz. Through those simple h i ii examples, we gain some understandings on what kind of = ul(k)−al0 ul(k)−al0 =0 (27) spin liquids are possible. Those understandings help us E (k) − E (k) 0 0 to develop the characterizationand classification of spin k,EX−(k)<0 k,EX+(k)<0 liquids using projective symmetry group. which allow us to determine al, l = 1,2,3. It is inter- 0 Using the above SU(2) projective construction, one esting to see that if u0 = 0 and the ansatz is unfrus- i canconstructmanyspinliquidstates. Tolimitourselves, trated, then we can simply choose al = 0 to satisfy the 0 we will concentrate on spin liquids with translation and mean-fieldconstraints(sinceuµ(k)= uµ(k+(π,π))for 90◦ rotation symmetries. Although a mean-field ansatz − unfrustrated ansatz). Such ansatz always have time re- with translationand rotationinvariance alwaysgenerate versalsymmetry. ThisisbecauseU and U aregauge ij ij a spin liquid with translation and rotation symmetries, − equivalent for unfrustrated ansatz. a mean-field ansatz without those invariances can also Now let us study some simple examples. First let us generateaspinliquidwiththosesymmetries.[94]Because assume that only the nearest neighbor coupling u and xˆ ofthis,itisquitedifficulttoconstructallthe translation u are non-zero. In order for the ansatz to describe a yˆ and rotation symmetric spin liquids. In this section we rotationallysymmetric state,the rotatedansatzmustbe will consider a simpler problem. We will limit ourselves gauge equivalent to the original ansatz. One can easily to spin liquids generated from translationally invariant check that the following ansatz has the rotation symme- ansatz: try Ui+l,j+l =Uij, al0(i)=al0 (20) al = 0 0 In this case, we only need to find the conditions under uxˆ = χτ3+ητ1 which the above ansatz can give rise to a rotationally u = χτ3 ητ1 (28) yˆ − 10 since the 90◦ rotation followed by a gauge transforma- theprojective-symmetry-groupclassification,theSU(2)- tion W = iτ3 leave the ansatz unchanged. The above gapless ansatz Eq. (30) is labeled by SU2An0 and the i ansatz also has the time reversal symmetry, since time SU(2)-linear ansatz Eq. (31) by SU2Bn0 (see Eq. (82)). reversal transformation u u followed by a gauge When χ = η = 0, The flux P is non trivial. How- ij ij C →− 6 6 transformation W =iτ2 leave the ansatz unchanged. ever, P commute with P as long as the two loops i C C′ Tounderstandthegaugefluctuationsaroundtheabove C and C′ have the same base point. In this case the mean-field state, we note that the mean-field ansatz SU(2) gauge structure is broken down to a U(1) gauge may generate non-trivial SU(2) flux through plaquettes. structure.[38, 40] The gapless spinon still only appear Those flux may break SU(2) gauge structure down to at isolated k points. We will call such a state U(1)- U(1)orZ gaugestructuresas discussedin Ref.[38, 40]. linear state. (This state was called staggered flux state 2 In particular, the dynamics of the gauge fluctuations in and/ord-wavepairingstateinliterature.) Afteraproper the break down from SU(2) to Z has been discussed in gauge transformation, the U(1)-linear state can also be 2 detail in Ref. [40]. According to Ref. [38, 40], the SU(2) described by the ansatz flux playsa roleof Higgsfields. A non-trivialSU(2)flux correspond to a condensation of Higgs fields which can ui,i+xˆ =iχ ( )iητ3 − − break the gauge structure and give SU(2) and/or U(1) u =iχ+( )iητ3 (32) i,i+yˆ gauge boson a mass. Thus to understand the dynamics − ofthegaugefluctuations,weneedtofindtheSU(2)flux. where the U(1) gauge structure is explicit. Under the The SU(2) flux is defined for loops with a base point. projective-symmetry-group classification, such a state is Theloopstartsandendsatthebasepoint. Forexample, labeled by U1Cn01n (see Eq. (B4) and IVC). The low we can consider the following two loops C with the energy effective theory is described by massless Dirac 1,2 samebasepointi: C =i i+xˆ i+xˆ+yˆ i+yˆ i fermions (the spinons) coupled to a U(1) gauge field. 1 and C is the 90◦ rotatio→n of C →: C = i →i+yˆ→ The above results are all known before. In the follow- 2 1 2 → → i xˆ+yˆ i xˆ i. The SU(2)flux forthe twoloops ing we are going to study a new class of translation and − → − → is defined as rotation symmetric ansatz, which has a form PC1 ≡ui,i+yˆui+yˆ,i+xˆ+yˆui+xˆ+yˆ,i+xˆui+xˆ,i =uy†ˆu†xˆuyˆuxˆ al0 =0 P u u u u =u u†u†u uxˆ =iητ0 χ(τ3 τ1) C2 ≡ i,i−xˆ i−xˆ,i−xˆ+yˆ i−xˆ+yˆ,i+yˆ i+yˆ,i xˆ yˆ xˆ yˆ − − (29) uyˆ =iητ0 χ(τ3+τ1) (33) − with χ and η non-zero. The above ansatz describes the AsdiscussedinRef.[38,40],iftheSU(2)fluxP forall C loops are trivial: P τ0, then the SU(2) gauge struc- SU(2)-gapless spin liquid if χ=0, and the SU(2)-linear C ∝ spin liquid if η =0. ture is unbroken. This is the case when χ = η or when After a 90◦ rotation R , the above ansatz becomes η = 0 in the above ansatz Eq. (28). The spinon in the 90 spin liquid described by η =0 has a large Fermi surface. u = iητ0 χ(τ3+τ1) We will call this state SU(2)-gapless state (This state xˆ − − was called uniform RVB state in literature). The state uyˆ = iητ0 χ(τ3 τ1) (34) − − with χ=η has gaplessspinons only atisolatedk points. The rotated ansatz is gauge equivalent to the origi- We will call such a state SU(2)-linear state to stress the nal ansatz under the gauge transformation G (i) = linear dispersion E k near the Fermi points. (Such a R90 state was called the∝π|-fl|ux state in literature). The low ( )ix(1 iτ2)/√2. After a parity x x transforma- − − → − tion P , Eq. (33) becomes energy effective theory for the SU(2)-linear state is de- x scribedbymasslessDiracfermions(thespinons)coupled u = iητ0 χ(τ3 τ1) to a SU(2) gauge field. xˆ − − − Afterpropergaugetransformations,theSU(2)-gapless uyˆ =iητ0 χ(τ3+τ1) (35) − ansatz can be rewritten as whichisgaugeequivalenttotheoriginalansatzunderthe uxˆ = iχ gaugetransformationGPx(i)=(−)ixi(τ3+τ1)/√2. Un- der time reversal transformation T, Eq. (33) is changed u = iχ (30) yˆ to and the SU(2)-linear ansatz as u = iητ0+χ(τ3 τ1) xˆ − − u = iητ0+χ(τ3+τ1) (36) ui,i+xˆ = iχ yˆ − u = i( )ixχ (31) whichisagaingaugeequivalenttotheoriginalansatzun- i,i+yˆ − derthegaugetransformationG (i)=( )i. (Infactany T − Intheseform,theSU(2)gaugestructureisexplicitsince ansatzwhichonlyhaslinksbetweentwonon-overlapping u iτ0. Herewewouldalsoliketomentionthatunder sublattices (ie the unfrustrated ansatz) is time reversal ij ∝

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