Quantum Mechanics - Methods and Applications

572 Pages·2017·6.4 MB·English

by  Wolfgang Nolting

Wolfgang Nolting
Theoretical
Physics 7
Quantum Mechanics - Methods and
Applications
Theoretical Physics 7
Wolfgang Nolting
Theoretical Physics 7
Quantum Mechanics - Methods
and Applications
123
WolfgangNolting
InstituteofPhysics
Humboldt-UniversityatBerlin
Germany
ISBN978-3-319-63323-7 ISBN978-3-319-63324-4 (eBook)
DOI10.1007/978-3-319-63324-4
LibraryofCongressControlNumber:2017947494
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General Preface
The nine volumes of the series ‘Basic Course: Theoretical Physics’ arethought
tobetextbookmaterialforthestudyofuniversity-levelphysics. Theyareaimed
to impart, in a compact form, the most important skills of theoretical physics
whichcanbe usedasbasisforhandlingmoresophisticatedtopicsandproblems
in the advanced study of physics as well as in the subsequent physics research.
The conceptual design of the presentation is organized in such a way that
Classical Mechanics (volume 1)
Analytical Mechanics (volume 2)
Electrodynamics (volume 3)
Special Theory of Relativity (volume 4)
Thermodynamics (volume 5)
are considered as the theory part of an ‘integrated course’ of experimental and
theoreticalphysicsasisbeingofferedatmanyuniversitiesstartingfromthefirst
semester. Therefore,thepresentationisconsciouslychosentobe veryelaborate
and self-contained, sometimes surely at the cost of certain elegance, so that
the course is suitable even for self-study, at first without any need of secondary
literature. Atanystage,nomaterialisusedwhichhasnotbeendealtwithearlier
in the text. This holds in particular for the mathematical tools, which have
been comprehensively developed starting from the school level, of course more
or less in the form of recipes, such that right from the beginning of the study,
one can solve problems in theoretical physics. The mathematical insertions are
always then plugged in when they become indispensable to proceed further in
theprogramoftheoreticalphysics. Itgoeswithoutsayingthatinsuchacontext,
not all the mathematical statements can be proved and derived with absolute
rigor. Instead, sometimesa referencemustbe madeto anappropriatecoursein
mathematics or to an advanced textbook in mathematics. Nevertheless, I have
tried for a reasonably balanced representation so that the mathematical tools
are not only applicable but also appear at least ‘plausible’.
The mathematical interludes are of course necessary only in the first vol-
umes of this series, which incorporate more or less the material of a bachelor
V
VI GENERAL PREFACE
program. In the second part of the series which comprises the modern aspects
of Theoretical Physics,
Quantum Mechanics: Basics (volume 6)
Quantum Mechanics: Methods and Applications (volume 7)
Statistical Physics (volume 8)
Many-Body Theory (volume 9),
mathematical insertions are no longer necessary. This is partly because, by the
timeonecomestothisstage,theobligatorymathematicscoursesonehastotake
inorderto study physicswouldhaveprovidedthe requiredtools. The fact that
trainingintheoryhasalreadystartedinthefirstsemesteritselfpermitsinclusion
of parts of quantum mechanics and statistical physics in the bachelor program
itself. It is clearthat the contentofthe lastthree volumes cannotbe partofan
‘integrated course’ but rather the subject matter of pure theory lectures. This
holds in particular for ‘Many-Body Theory’ which is offered, sometimes under
different names as, e.g., ‘Advanced Quantum Mechanics’, in the eighth or so
semester of study. In this partnew methods andconcepts beyond basic studies
are introduced and discussed which are developed in particular for correlated
many particle systems which in the meantime have become indispensable for a
student pursuing master’s or a higher degree andfor being able to readcurrent
researchliterature.
Inallthevolumesoftheseries‘BasicCourse: TheoreticalPhysics’ numerous
exercises are included to deepen the understanding and to help correctly apply
the abstractly acquired knowledge. It is obligatory for a student to attempt
on his own to adapt and apply the abstract concepts of theoretical physics to
solve realistic problems. Detailed solutions to the exercises are given at the
end of each volume. The idea is to help a student to overcome any difficulty
at a particular step of the solution or to check one’s own effort. Importantly
these solutions should not seduce the student to follow the ‘easy way out’ as a
substitute for his own effort. At the end of each bigger chapter I have added
self-examination questions which shall serve as a self-test and may be useful
while preparing for examinations.
Ishouldnotforgettothankallthepeoplewhohavecontributedinonewayor
anothertothe successofthe bookseries. The singlevolumesarosemainlyfrom
lectures which I gave at the universities of Muenster, Wuerzburg, Osnabrueck,
and Berlin (Germany), Valladolid (Spain), and Warangal (India). The interest
and constructive criticism of the students provided me the decisive motivation
for preparing the rather extensive manuscripts. After the publication of the
German version I received a lot of suggestions from numerous colleagues for
improvement and this helped to further develop and enhance the concept and
the performance of the series. In particular I appreciate verymuch the support
by Prof. Dr. A. Ramakanth, a long-standing scientific partner and friend, who
helped me in many respects, e.g., whatconcernsthe checkingofthe translation
of the German text into the present English version.
GENERAL PREFACE VII
Special thanks are due to the Springer company, in particular to Dr. Th.
Schneiderandhis team. Iremembermanyuseful motivationsandstimulations.
I have the feeling that my books are well taken care of.
Berlin, Germany Wolfgang Nolting
May 2017
Preface to Volume 7
In the prefaces of the preceding volumes, especially in that of volume 6 (Quan-
tum Mechanics: Basics), which is the first part of Quantum Mechanics, I have
already set out the goal of the basic course in Theoretical Physics. This goal
remainsofcourseunchangedforthe secondpartQuantum Mechanics: Methods
and Applications (volume 7) as well. The vast mass of matter to be presented
makesitimperativethatthematerialhastobedividedintotwoparts. Needless
to say that both parts have to be viewed as a unity. Formal sign for that is the
consecutive numbering of the chapters over both volumes.
The first part deals with the basics and some first applications to rela-
tively simple (one-dimensional) potential problems. We now begin the second
partwith the detaileddiscussionofthe important quantum-mechanicalobserv-
able angular momentum. We will call any vector operator an angular momen-
tum, whoseHermitiancomponentsfulfill acertainsetofcommutationrelations
(Sect.5.1). To this class of operators, there belongs, besides the orbital angu-
lar momentum known from Classical Mechanics, which we can transplant into
Quantum Mechanics by the use of the principle of correspondence, the classi-
cally not understandable spin, for which such an analogy consideration is not
possible. One could be content with postulating the spin, in a certain sense, as
anempirical necessity, and analyzingthe properties andconsequences resulting
from this postulate (Sect.5.2). Since spin, magnetic moment of the spin, and
spin-orbit interaction turn out to be properties, which are justifiable only rel-
ativistically, they therefore need the relativistic Dirac theory (Sect.5.3) for the
rigorous derivation. Furthermore, the spin-orbit interaction gives us the moti-
vationtothink aboutthe rulesfor the addition of angular momenta (Sect.5.4).
With the discussion of the angular momentum, the essential pillars of the
abstract theoretical framework of Quantum Mechanics are now introduced so
that we can turn in the next chapters toward somewhat more application-
orientedproblems. This startsinChap.6 withthe importantcentral potentials.
ForthehistoricaldevelopmentofQuantumMechanics, inparticular,thetheory
of the hydrogen atom has played a decisive role. The orbital electron moves
in the Coulomb field of the positively charged hydrogen nucleus (proton), and
underlies therewith the influence of a special central potential, to which, espe-
cially because of its historical importance, a rather broad space is devoted in
this volume.
IX
X PREFACE TO VOLUME 7
Only very few (realistic) problems of Theoretical Physics can be mathe-
matically rigorously solved. A ‘reasonable’ approximation to a not exactly
solvable problem poses, according to experience, a non-trivial difficulty to the
learner. We therefore discuss in Chap.7 a series of well-established, but con-
ceptually rather different methods: the variational method (Sect.7.1), the dif-
ferentversionsofperturbation theory (Sects.7.2and7.3), andthe semi-classical
WKB-method (phase integral method) (Sect.7.4). In currentscientific research,
one is frequently confronted with the task to develop one’s own methods of
approximation, which are specific just to the problem at hand. Also in such a
case,thesubtleunderstandingofthestandardmethodsandtheexactknowledge
of their regions of validity may guide the way.
The Quantum Theory so far presented and discussed is, strictly speaking,
a one-particle theory, whereas the real world is built up of interacting many-
particlesystems. Thereforewehavetoinvestigate(Chap.8)whatisadditionally
tobetakenintoaccountwhentreatingmany-particlesystems. Thedemarcation
between distinguishable particles and the so-called identical particles will turn
out to be decisively important and will lead to the principle of indistinguisha-
bility of identical particles, which has no analogin Classical Physics. The Pauli
principle (exclusion principle) issurelyitsweightiestconsequence,bywhichthe
total composition of matter is regulated. For the description of many-particle
systems, the formalism of second quantization has proven to be not only very
elegantbutalsoveryoftenratheradvantageous. Themodernresearchliterature
is hardlyreadablewithout the knowledgeofsecondquantization. Inparticular,
in volume 9 of this basic course in Theoretical Physics, the formalism will be
used almost exclusively. It therefore appears to be reasonable to present this
method in some detail.
Thefinalchapterdealswiththescatteringtheory,whichrepresentsanimpor-
tant region of application of Quantum Mechanics. Via microscopic scattering
(collision) processes, far-reaching information can be found about elementary
interactionpotentials, providedthetheorysucceedsinconstructingconnections
between these potentials and the experimentally accessible cross sections.
This volume on Quantum Mechanics arose from lectures I gave at the Ger-
man Universities in Wu¨rzburg, Mu¨nster, and Berlin. The animating interest
of the students in my lecture notes has induced me to prepare the text with
special care. The present one as well as the other volumes are thought to be
the textbook material for the study of basic physics, primarily intended for the
students rather than for the teachers.
I amthankful to the Springercompany,especially toDr. Th. Schneider, for
accepting and supporting the concept of my proposal. The collaboration was
alwaysdelightfulandveryprofessional. Adecisivecontributiontothebookwas
providedbyProf. Dr. A.RamakanthfromtheKakatiyaUniversityofWarangal
(India), a long-standing scientific partner and friend, who helped me in many
respects. Many thanks for it!
Berlin, Germany Wolfgang Nolting
May 2017
Contents
5 Quantum Theory of the Angular Momentum 1
5.1 Orbital Angular Momentum . . . . . . . . . . . . . . . . . . . . . 2
5.1.1 Angular Momentum and Principle
of Correspondence . . . . . . . . . . . . . . . . . . . . . . 2
5.1.2 Rotations and Operator of Angular Momentum . . . . . . 6
5.1.3 Commutation Relations . . . . . . . . . . . . . . . . . . . 10
5.1.4 Eigen-Value Problem . . . . . . . . . . . . . . . . . . . . . 12
5.1.5 Position Representation of the Orbital Angular
Momentum . . . . . . . . . . . . . . . . . . . . . . . . . . 19
5.1.6 Eigen-Functions in Position Representation . . . . . . . . 22
5.1.7 Exercises . . . . . . . . . . . . . . . . . . . . . . . . . . . 28
5.2 Spin . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 33
5.2.1 Operator of the Magnetic Moment . . . . . . . . . . . . . 33
5.2.2 Magnetic Moment and Angular Momentum . . . . . . . . 35
5.2.3 Hilbert Space of the Spin . . . . . . . . . . . . . . . . . . 40
5.2.4 Spin S =1/2 . . . . . . . . . . . . . . . . . . . . . . . . . 44
5.2.5 Exercises . . . . . . . . . . . . . . . . . . . . . . . . . . . 48
5.3 Relativistic Theory of the Electron . . . . . . . . . . . . . . . . . 52
5.3.1 Dirac Equation . . . . . . . . . . . . . . . . . . . . . . . . 53
5.3.2 Dirac Spin Operator . . . . . . . . . . . . . . . . . . . . . 59
5.3.3 Electron Spin (Pauli-Theory) . . . . . . . . . . . . . . . . 63
5.3.4 Spin-Orbit Interaction . . . . . . . . . . . . . . . . . . . . 66
5.3.5 Exercises . . . . . . . . . . . . . . . . . . . . . . . . . . . 72
5.4 Addition of Angular Momenta. . . . . . . . . . . . . . . . . . . . 74
5.4.1 Total Angular Momentum . . . . . . . . . . . . . . . . . . 74
5.4.2 Quantum Numbers of the Total Angular Momentum . . . 76
5.4.3 Clebsch-Gordan Coefficients . . . . . . . . . . . . . . . . . 80
5.4.4 Exercises . . . . . . . . . . . . . . . . . . . . . . . . . . . 83
5.5 Self-Examination Questions . . . . . . . . . . . . . . . . . . . . . 84
6 Central Potential 91
6.1 General Statements . . . . . . . . . . . . . . . . . . . . . . . . . . 92
6.1.1 Radial Equation . . . . . . . . . . . . . . . . . . . . . . . 92
XI