Table Of Content

Volume Contents JANUARY Lectures presented at the 11*" European Conference on Analytical Chemistry (EUROANALYSIS XI), Lisbon, Portugal, 3-9 September 2000 Preface, M. F Camdes Analytical advantages of using electrochemistry for atomic spectrometry E. Bulska In situ speciation measurements. Using diffusive gradients in thin-films (DGT) to determine inorganically and organically complexed metals H. Zhang and W. Davison A glance into the bulk of solvent polymeric pH membranes E. Lindner, R. E. Gyurcsanyi, and B. D. Pendley Affinity electrochemical biosensors for pollution control M. Mascini Devices for ion-sensing and pX measurements J. D. R. Thomas Speciation dynamics and bioavailability of metals. Exploration of the case of two uptake routes H. P. van Leeuwen and J. P. Pinheiro Detecting and circumventing sources of inaccuracy in flow analysis E. A. G. Zagatto, F R. P Rocha, P. B. Martelli, and B. F. Reis Lectures presented at the XVI*" International Symposium on Medicinal Chemistry, Bologna, Italy, 18-22 September 2000 viii Preface, G. Ronsisvalle 55 New developments in anti-HIV chemotherapy E. De Clercq 67 Continuing evolution of the drug discovery process in the pharmaceutical industry E. Ratti and D. Trist Lectures presented at the International Symposium on Green Chemistry, Dethi, India, 10-13 January 2001 x Preface, J. H. Clark CONTENTS OF VOLUME 73 Development of bioreactors for application of biocatalysts in biotransformations and bioremediation S. G. Burton Nanostructured amorphous metals, alloys, and metal oxides as new catalysts for oxidation V. Kesavan, D. Dhar, Y. Koltypin, N. Perkas, O. Palchik, A.G edanken, and S. Chandrasekaran Peroxometal-mediated environmentally favorable route to brominating agents and protocols for bromination of organics U. Bora, M. K. Chaudhuri, D. Dey, and S. S. Dhar Catalysis for green chemistry J. H. Clark Green chemistry. Sustaining a high-technology civilization A. Ghosh, S. S.Gupta, M. J. Bartos, Y. Hangun, L. D. Vuocolo, B. A. Steinhoff, C. A. Noser, D. Horner, S. Mayer, K. Inderhees, C. P. Horwitz, J. Spatz, A. D. Ryabov, S. Mondal, and T. J. Collins Rapid screening and combinatorial methods in homogeneous organometallic catalysis J. A. Loch and R. H. Crabtree Polymer—metal complexes for environmental protection. Chemoremediation in the aqueous homogeneous phase K. E. Geckeler Human exposure to traffic pollution. Experience from Danish studies O. Hertel, S. S. Jensen, H. V. Andersen, F. Palmgren, P. Wahlin, H. Skov, |. V. Nielsen, M. Sorensen, S. Loft, and O. Raaschou-Nielsen Dry media reactions M. Kidwai Using neoteric solvents in oil shale studies M. Koel, S. Ljovin, K. Hollis, and J. Rubin Reactivity and selectivity under microwaves in organic chemistry. Relation with medium effects and reaction mechanisms A. Loupy, L. Perreux, M. Liagre, K. Burle, and M. Moneuse Selective biotransformation reactions on (+)-aryl alkyl ketones, (+)-benzoxazines, and D-arabino- and D-threo-hydroxyalkyltriazoles Raunak, A. K. Prasad, N. A. Shakil, Himanshu, and V. S. Parmar Applications of green chemistry in the manufacture of oligonucleotide drugs Y¥. S. Sanghvi, V. T. Ravikumar, A. N. Scozzari, and D. L. Cole Design, synthesis, and application of chelating polymers for separation and determination of trace and toxic metal ions. A green analytical method R. K. Sharma Recent progress in the chemistry of multicomponent reactions I. Ugi © 2001 IUPAC, Pure and Applied Chemistry 73, iii-xx CONTENTS OF VOLUME 73 Solvent-free accelerated organic syntheses using microwaves R. S. Varma Green twist to an old theme. An eco-friendly approach J. S. Yadav and H. M. Meshram FEBRUARY Lectures presented at the XIX*" International Conference on Organometallic Chemistry (XIX ICOMC), Shanghai, China, 23-28 July 2000 vi Preface, C. T. Qian and X. L. Hou Centennial lectures Organometallic chemistry. Past, present, and future A. Yamamoto Organometallic chemistry at the threshold of a new millennium. Retrospect and prospect J. Halpern Plenary lectures Cooperative bimetallic oxidative addition reactions C. Jin Qin, A. Gavrilova, and B. Bosnich Asymmetric hydrogenation via architectural and functional molecular engineering R. Noyori, M. Koizumi, D. Ishii, and T. Ohkuma Organometallic pentalene complexes F. G. N. Cloke Keynote lectures Some newer aspects of organozirconium chemistry of relevance to organic synthesis. Zr-Catalyzed enantioselective carbometallation E. Negishi Rational design of polymers for optoelectronic interests T.-¥. Luh, R.-M. Chen, T.-¥. Hwu, S. Basu, C.-W. Shiau, W.-Y. Lin, B.-Y. Jin, and C.-C. Hsu Effect of ligands on the divalent palladium-catalyzed carbon-carbon coupling reactions. Highly enantioselective synthesis of optically active y-butyrolactones X. Lu and Q. Zhang New olefin polymerization and copolymerization catalysts. Effect of coordinating functionalities A. Sen © 2001 IUPAC, Pure and Applied Chemistry 73, iii-xx CONTENTS OF VOLUME 73 Racemic catalysis through asymmetric activation K. Mikami, T. Korenaga, Y. Matsumoto, M. Ueki, M. Terada, and S. Matsukawa Chemical nitrogen fixation by using molybdenum and tungsten complexes M. Hidai and Y. Mizobe invited lectures Synthesis of oxygen heterocycles via alkynyltungsten compounds R.-S. Liu Selective preparation of benzene derivatives from three different alkynes and pyridine derivatives from two different alkynes and a nitrile T. Takahashi Fullerenes covalently linked to transition metals with organic ligands V. |. Sokolov, M. N. Nefedova, T. V. Potolokova, and V. V. Bashilov Lewis-acidic organometallic compounds of the lanthanides and the alkaline earth metals as catalysts for the activation of carbonyl groups H. Schumann, M. Glanz, J. Gottfriedsen, S. Dechert, and D. Wolff Asymmetric synthesis by stereocontrol Y. H. Kim, S. M. Kim, and S. W. Youn New methods for the synthesis of transition-metal fullerene complexes D. M. Thompson, J. McLeod, and M. C. Baird Novel polymerization and copolymerization of ethylene, styrene, and/or buta- diene by new organolanthanide-based catalysts Z. Hou, S. Kaita, and Y¥. Wakatsuki Novel coordination behavior of unsaturated hydrocarbon ligands on Pd—Pd bonds H. Kurosawa and T. Murahashi Recent advances in asymmetric catalysis. Synthetic applications to biologically active compounds J.-P. Genet, A. Marinetti, and V. RatovelomananVaid-a l lsolobal displacement methodology for the synthesis of transition-metal cluster complexes containing various biscyclopentadienyl ligands L.-C. Song and D.-S. Guo Copper complexes for catalytic, aerobic oxidation of hydrocarbons S.-I. Murahashi, N. Komiya, Y. Hayashi, and T. Kumano Alkane activation on a multimetallic site H. Suzuki, A. Inagaki, K. Matsubara, and T. Takemori New developments in transition metal-catalyzed synthetic reactions via C-H bond activation Y. Fujiwara and C. Jia © 2001 IUPAC, Pure and Applied Chemistry 73, iii—xx CONTENTS OF VOLUME 73 Asymmetric synthesis with “privileged” ligands M. Bandini, P G. Cozzi, and A. Umani-Ronchi Reactions of d° alkylidene and amide complexes with silanes J. B. Diminnie, X. Liu, H. Cai, Z. Wu, J. R. Blanton, Tianniu Chen, A. A. Tuinman, K. T. Quisenberry, C. E. Vallet, R. A. Zuhr, D. B. Beach, Z. Peng, Y.-D. Wu, T. E. Concolino, A. L. Rheingold, and Z. Xue Chemistry of 1,2-allenyl/propargyl metal species. A personal account S.-M. Ma and A.-B. Zhang Interplay of synthesis and mechanism in asymmetric homogeneous catalysis N. J. Adams, J. Bargon, J. M. Brown, E. J. Farrington, E. Galardon, R. Giernoth, H. Heinrich, B. D. John, and K. Maeda Asymmetric catalysis with “planar-chiral” heterocycles G. C. Fu Rare earth metal-based catalysts for the polymerization of nonpolar and polar monomers J. Okuda, S. Arndt, K. Beckerle, K. C. Hultzsch, P. Voth, and T. P. Spaniol Chemistry of 7°-fullerene metal complexes E. Nakamura and M. Sawamura New class of metallacarboranes incorporating the n’-carborany] ligand Z. Xie New metallocenes of early transition metals with functional groups in organic ligands. Red-ox transformations E. P. Krut’ko, M. V. Borzov, E. N. Veksler, R. S. Kirsanov, A. V. Churakov, and D. A. Lemenovskii New P-chirogenic diphosphines and their use in catalytic asymmetric reactions T. Imamoto IUPAC Recommendations and Technical Reports 377 Names for muonium and hydrogen atoms and their ions (IUPAC Recommendations 2001) W. H. Koppenol Nomenclature of structural and compositional characteristics of ordered microporous and mesoporous materials with inorganic hosts (IUPAC Recommendations 2001) L. B. McCusker, F. Liebau, and G. Engelhardt © 2001 IUPAC, Pure and Applied Chemistry 73, iii-xx CONTENTS OF VOLUME 73 MARCH Lectures presented at the XVIII? IUPAC Symposium on Photochemistry, Dresden, Germany, 22-27 July 2000 Preface, H. J. Kuhn Twentieth century developments in photochemistry. Brief historical sketches H. D. Roth Dynamic solvatochromism in solvent mixtures D. E. Wetzler, C. Chesta, R. Fernandez-Prini, and P. F. Aramendia Photoactive pyrene-containing receptors for transition-metal ions F. Fages, S. Leroy, T. Soujanya, and J.-E. Sohna Sohna Tryptophan rotamers that report the conformational dynamics of proteins J. Fidy, M. Laberge, B. Ulirich, L. Polgar, Z. Szeltner, J. Gallay, and M. Vincent Charge separation and energy transfer in multicomponent porphyrinic arrays L. Flamigni Conjugated polymers. New materials for optoelectronic devices R. H. Friend Looking at the photodynamics of individual fluorescent molecules and proteins M. F. Garcia-Parajo, J.-A. Veerman, L. Kuipers, and N. F. van Hulst Microscopy and optical manipulation of dendrimer-built vesicles T. Gensch, K. Tsuda, G. C. Dol, L. Latterini, J. W. Weener, A. P. H. J. Schenning, J. Hofkens, E. W. Meijer, and F. C. De Schryver Organometallic alkane and noble-gas complexes in conventional and super- Critical fluids G. |. Childs, D. C. Grills, X. Z. Sun, and M. W. George Long-distance charge transport through DNA. An extended hopping model B. Giese, M. Spichty, and S. Wessely New approach to silver halide photography using radical cation chemistry |. R. Gould, J. R. Lenhard, A. A. Muenter, S. A. Godleski, and S. Farid Molecular photovoltaics that mimic photosynthesis M. Gratzel Electron-transfer dyads suitable for novel self-assembled light-harvesting antenna/electron-transfer devices A. R. Holzwarth, M. Katterle, M. G. Muller, ¥.-Z. Ma, and V. Prokhorenko Vital role of entropy in photochirogenesis Y. Inoue, N. Sugahara, and T. Wada Photosensitization by drugs M. A. Miranda © 2001 IUPAC, Pure and Applied Chemistry 73, iii—xx CONTENTS OF VOLUME 73 Important photochemical processes in the atmosphere G. K. Moortgat New polymeric photosensitizers M. Nowakowska, M. Kepczynski, and K. Szczubialka Photophysics of m-conjugated metal—organic oligomers Y. Li, C. E. Whittle, K. A. Walters, K. D. Ley, and K. S. Schanze Luminescent sensors and photonic switches A. P. de Silva, D. B. Fox, T. S. Moody, and S. M. Weir Protein dynamics detected by the time-resolved transient grating technique M. Terazima Singlet and triplet energy splitting in the radical ion pairs generated by photoinduced electron-transfer reactions S. Tero-Kubota 525 Coherent control for ultrafast photochemical reactions R. de Vivie-Riedle, L. Kurtz, and A. Hofmann 529 Quinone methide intermediates in organic photochemistry P. Wan, D. W. Brousmiche, C. Z. Chen, J. Cole, M. Lukeman, and M. Xu 535 Molecular and biomolecular optoelectronics |. Willner and B. Willner 543 Molecular design of luminescent metal-based materials V. W.-W. Yam Lectures presented at the 22" jUPAC International Symposium on the Chemistry of Natural Products, Sao Carlos, Brazil, 3-8 September 2000 Vili Preface, O. A. Gottlieb and M. F. das Gracas Fernandes da Silva 549 Bracken adaptation mechanisms and xenobiotic chemistry M. E. Alonso-Amelot, A. Oliveros, M. P Calcagno, and E. Arellano 555 Bioactive natural products as a potential source of new pharmacophores. A theory of memory Atta-ur-Rahman and M. |. Choudhary Gains achieved by molecular approaches in the area of lignification A.-M. Boudet and M. Chabannes Natural products from around the world J. D. Connolly Efficient stereoselective syntheses of piperidine, pyrrolidine, and indolizidine alkaloids D. Enders and C. Thiebes Chemistry and biotransformations in the Scrophulariaceae family J. A. Garbarino, B. M. Fraga, M. G. Hernandez, M. C. Chamy, and M. Piovano © 2001 IUPAC, Pure and Applied Chemistry 73, iii-xx CONTENTS OF VOLUME 73 Quantitative chemobiology O. R. Gottlieb, M. R. de M. B. Borin, and N. R. S. de Brito Bioactive compounds from coral reef invertebrates T. Higa, J. Tanaka, |. |. Ohtani, M. Musman, M. C. Roy, and |. Kuroda Biodiversity conservation and drug discovery in Suriname. Explorations in nature’s combinatorial library D. G. |. Kingston Recent results in the synthesis of ecologically important bioregulators K. Mori Pheromones and kairomones for contol of pest insects. Some current results from a Swedish research program T. Norin Molecules and macromolecules involved in chemical communication of scarab beetles W. S. Leal Strategies for the isolation and identification of trypanocidal compounds from the Rutales P. C. Vieira, J. Mafezoli, M. T. Pupo, J. B. Fernandes, M. F. das G. F. da Silva, S. de Albuquerque, G. Oliva, and F. Pavao Studies directed toward the preparation of key intermediates for the synthesis of trisporic acids and cassiol M. |. Colombo, J. Zinczuk, M. P Mischne, and E. A. Ruveda APRIL IUPAC Recommendations and Technical Reports 627 Figures-of-merit for the technical development and application of advanced oxidation technologies for both electric- and solar-driven systems (IUPAC Technical Report) J. R. Bolton, K. G. Bircher, W. Tumas, and C. A. Tolman Organic photochromism (IUPAC Technical Report) H. Bouas-Laurent and H. Durr Atomic weights of the elements 1999 (IUPAC Technical Report) T. B. Coplen Lexicon of lipid nutrition (IUPAC Technical Report) J. Beare-Rogers, A. Dieffenbacher, and J. V. Holm Measurement and analysis of results obtained on biological substances with differential scanning calorimetry (IUPAC Technical Report) H.-J. Hinz and F. P Schwarz © 2001 IUPAC, Pure and Applied Chemistry 73, iii—xx CONTENTS OF VOLUME 73 MAY Lectures presented at the 9" IUPAC International Symposium on Solubility Phenomena (9*" ISSP), Hammamet, Tunisia, 25-28 July 2000 Preface, P G. T. Fogg, H. Gamsjager, and M. Gaune-Escard Treatment of Tunisian salt lakes using solubility phase diagrams N. Kbir-Ariguib, D. B. H. Chehimi, and L. Zayani Phase diagrams at high temperature and high pressure. Determination and consequent developments M. Th. Cohen-Adad Thermodynamic modeling of crystal deposition in humans E. Konigsberger and L.-C. Kénigsberger Dissolution and formation of nuclear materials in molten media T. Ogawa and K. Minato Solid-state solubility and its limits. The alkali halide case H. A. J. Oonk Reliable solubility data in the age of computerized chemistry. Why, how, and when? J. Rumble, Jr., A. ¥. Lee, D. Blakeslee, and S. Young Solubility equilibria in multicomponent oceanic salt systems from t = 0 to 200 °C. Model parameterization and databases W. Voigt IUPAC Recommendations and Technical Reports 845 Definitions of basic terms relating to low-molar-mass and polymer liquid crystals (IUPAC Recommendations 2001) M. Baron JUNE IUPAC Recommendations and Technical Reports 897 Blends containing core-shell impact modifiers. Part 1: Structure and tensile deformation mechanisms (IUPAC Technical Report) C. B. Bucknall Blends containing core-shell impact modifiers. Part 2: Melt rheology of rubber-toughened plastics (IUPAC Technical Report) M. Kozlowski and C. B. Bucknall Unit “katal” for catalytic activity (IUPAC Technical Report) R. Dybkaer © 2001 IUPAC, Pure and Applied Chemistry 73, iii—xx CONTENTS OF VOLUME 73 Human exposure to outdoor air pollution (IUPAC Technical Report) O. Hertel, F A. A. M. De Leeuw, O. Raaschou-Nielsen, S. S. Jensen, D. Gee, O. Herbarth, S. Pryor, F. Palmgren, and E. Olsen On the discovery of the elements 110—112 (IUPAC Technical Report) P. J. Karol, H. Nakahara, B. W. Petley, and E. Vogt Retention parameters in chromatography (IUPAC Recommendations 2001) J. A. Garcia Dominguez, J. C. Diez-Masa, and V. A. Davankov Risk assessment for occupational exposure to chemicals. A review of current methodology (IUPAC Technical Report) R. F. M. Herber, J. H. Duffus, J. M. Christensen, E. Olsen, and M. V. Park JULY Lectures presented at the 38" IUPAC Congress/World Chemistry Congress 2001, Brisbane, Australia, 1-6 July 2001 Preface, G. Will Integrating natural product synthesis and combinatorial chemistry A. Ganesan Calixphyrins. Hybrid macrocycles at the structural crossroads between porphyrins and calixpyrroles J. L. Sessler, R. S. Zimmerman, C. Bucher, V. Kral, and B. Andrioletti Unsaturated binuclear homoletpic metal carbonyls M,(CO), (M = Fe, Co, Ni; x = 5, 6, 7, 8). Are multiple bonds between transition metals possible for these molecules? H. F. Schaefer Ill and R. B. King Recent applications of tricarbonyliron-diene complexes to organic synthesis H.-J. Kndélker, A. Braier, D. J. Brécher, S. Cammerer, W. Fréhner, P- Gonser, H. Hermann, D. Herzberg, K. R. Reddy, and G. Rohde Benign by design. New catalysts for an environmentally conscious age J. M. Thomas, R. Raja, G. Sankar, R. G. Bell, and D. W. Lewis New methods for high-throughput synthesis S. Kobayashi and R. Akiyama Applications of “planar-chiral” heterocycles in asymmetric catalysis G. C. Fu New developments in dimethyl carbonate chemistry P. Tundo Strategy for globalization of chemical education based on the Internet Y. Takeuchi, M. M. Ito, and H. Yoshida Crystalline inclusion complexes as media of molecular recognitions and selective reactions F. Toda © 2001 IUPAC, Pure and Applied Chemistry 73, iii-xx