PROTECTION OF SPACE MATERIALS FROM THE SPACE ENVIRONMENT Space Technology Proceedings VOLUME 4 The titles published in this series are listed at the end of this volume. PROTECTION OF SPACE MATERIALS FROM THE SPACE ENVIRONMENT Proceedings of ICPMSE-4, Fourth International Space Conference, held in Toronto, Canada, April 23-24, 1998 Edited by JACOB I. KLEIMAN Integrity Testing Laboratory Inc., Toronto, Canada and RODERICK C. TENNYSON Institute of Aerospace Studies, University of Toronto, Toronto, Canada If SPRTNGER-SCIENCE+BUSINESS MEDIA, B.V. A CLP. Catalogue record for this book is available from the Library of Congress. ISBN 978-94-010-3838-6 ISBN 978-94-010-0714-6 (eBook) DOI 10.1007/978-94-010-0714-6 Printed on acid-free paper All Rights Reserved © 2001 Springer Science+Business Media Dordrecht Originally published by Kluwer Academic Publishers in 2001 Softcover reprint of the hardcover 1st edition 2001 No part of the material protected by this copyright notice may be reproduced or utilized in any form or by any means, electronic or mechanical, including photocopying, recording or by any information storage and retrieval system, without written permission from the copyright owner. TableofContents Acknowledgements ix Introduction xi OrganizingCommittee xiii Section A: AONUV Effects,Evaluationand Modeling 1. Monte Carlo ComputationalModelingofthe Energy DependenceofAtomic Oxygen UndercuttingofProtectedPolymers BruceA.Banks,Thomas1.Stueber, MaryJoNorris 2. Dynamics ofAtomic-Oxygen-InducedDegradationofMaterials 15 T. K.Minton,J. W.Seale,D.1.Garton,andA.K.Frandsen 3. Generalizationofthe PredictiveModel of Erosion ofCarbon-Based 33 MaterialsbyAtomic Oxygen 1.I.Kleiman, Z.Iskanderova, Y.Gudimenko, R.C.Tennyson 4. SpectroscopicEllipsometryCharacterizationofPolymers Modified 51 byAtomic Oxygen and UltravioletRadiation CoreyL.Bungay, Thomas E. Tiwald, MichaelJ. Devries, JohnA. Woollam,KimK.DeGroh 5. Effect ofAtomic Oxygen ExposuresontheTribologicalProperties 73 ofMolybdenum DisulfideLubricants M Tagawa, 1.Ikeda, H.Kinoshita,M Umeno, N.Ohmae 6. Influence ofShieldingUpon the Structureand Properties 85 of PolymerCompositeMaterials, Exposedonthe Surface of the MirOrbitalComplex 0.V. Startsev, v.v. Isupov, E.F.Nikishin 7. CleanlinessSupportofVehicle Fairingsfor Spacecraft 95 V.Sitalo,V. Tikhiy 8. InsituXPS Studies ofKapton Exposedto5eVAtomic Oxygen 103 E.Grossman, Y. Lifshitz,1.T. Wolan, c.x. Mount,G.B. Hojlund vi SectionB: Instrumentation,Sensors,NewTechnologies 9. ALowCost,LightweightReusable SensorforAtomicOxygenDetection 115 1.1. Osborne, G.T. Roberts, S.B.GabrielandA.R.Chambers 10. Large-Scale ECR-CVDPreparationofIntegratedThin-FilmStructures 125 forSpaceApplications RomanV. Kruzelecky, AsokeK.Ghosh, EthelPoireandDariusNikanpour 11. Non-Silicone Inorganic Polymer-BasedCoatingsforAtomicOxygen 137 Protection inLEO- Part2 E.Poire,B.G.Sellars andD.Nguyen 12.Research AspectsofScalingUptheImplantoxTechnology 145 forProtectionofPolymers inSpace ZA.Iskanderova, 1.I.Kleiman, Y. Gudimenko, R.C.Tennyson, 1. G.Brown, O.R.Monteiro, B.A.Banks, M1.Norris SectionC: Thermal Control inLEO 13.AComparisonofSpaceandGround-Based Facility 165 EnvironmentalEffectsforFEPTeflon SharonK.Rutledge, BruceA.Banks, MichaelKitral 14.EvaluationofLowEarthOrbit EnvironmentalEffectsonInternational 181 SpaceStationThermalControl Materials JoyceA.Dever. SharonK. Rutledge,MarkMHasegawa, Charles K.Reed 15. SomeAspectsoftheDegradation ofFEPTeflon Material 197 UndertheActionofVUV,theSunandGroundTestVUVFacilities A.Miltntchouk,M Van Eesbeek 16.EvaluationofCOFMDPSChromicAcidAnodization 211 inLEOEnvironment C.Acket,1.Marco, A.Pail/ous, R.ReuletandV. Viel 17. ADatabasefortheSelectionofSurfacesandMaterials forSpace 229 andGround-based Applications S.H. McCall, A.1. Clark, R.A.Ellis, R.A.Henderson, A.E.Piotrowski, L.A. Piotrowski, MA.Reid,1.W. Rodney,R.P.Breault, ML.McCall 18. ThermalControlMaterialsandCoatingsCurrentlyBeingDeveloped 235 inFranceforUse inLowEarthOrbit F. Guerardand1.C.Guillaumon vii 19. ModificationofThermal Control PaintsbyPhotosil' Technology 243 1.1. Kleiman, Y. Gudimenko, Z. A.Iskanderova, R.C.Tennyson, W.D.Morison SectionD: ChargedParticles/SoftX-Rays/MeteoroidsffhermalCycling 20. SimulatedSolarFlareX-RayandThermalCyclingDurability 253 EvaluationofHSTThermalControlCandidateReplacement Materials Kim. K.deGroh,B.A.Banks,E.A.Sechkar, D.A.Scheiman 21. Radiation-InducedEffectsinSi0 ProtectiveCoatingson 281 2 PolymericSpacecraftMaterials C.Coia, A.C.Fozza, MR. Wertheimer,G.CzeremuszkinandA.Houdayer 22. InfluenceofElectronandProtonFluxesonOpticalProperties 291 ofProtectiveEnamel S.N.Skovorod'ko, A. V. Kurilovich, V. Ya. Mendeleyev, V. N. Vasil'yev 23. MeteoroidHazardintheLEOSpaceEnvironment 295 Ya.S. Yatskiv, V.G.KruchinenkoandYu.l. Voloshchuk 24. CharacterizingtheAnnual MeteoroidStreams 305 MartinBeech 25. OxidationKineticsofVBGroupMetalsbyAtomicand 331 MolecularOxygen A.G.Gusakov,S.A.Raspopov, A.G. Voropayev, ML. Zheludkevich. andA.A.Vecher 26.TheNewApproach inDevelopingMethodsforBetter Protection 339 ofMaterialsandStructuresfrom LEOSpaceEnvironment A.K.Galytsky, A.I.Stegnyy, V.P. GusyninandB.M Shevchuk AuthorIndex 351 SubjectIndex 353 Acknowledgements We would liketo acknowledge the following for their generous support ofICPMSE-4, the Fourth International Conference on Protection ofMaterials and Structures fromthe LowEarthOrbit Space Environment; • The Canadian Space Agency; the Space Station Program Office andtheDirectorateofSpace Mechanics, part oftheDirectorateGeneral of Space Technology; • Materials and ManufacturingOntario (MMO) • ComDev Ltd. • CRESTech, • SPARAerospaceLtd. • ASM International,Ontario Chapter; .The UniversityofToronto Institute forAerospace Studies Aswell, we would liketo acknowledge the efforts oftext editor Daphne Lavers, Delta Blue Communications, Toronto and Dr. Z. Iskanderova from the Integrity Testing Laboratory Inc.forher veryenthusiasticandthorough reviewoftheedited material. Jacob Kleiman,Integrity TestingLaboratoryInc. Conference Chairman ix Introduction This publication presents the proceedings of ICPMSE-4, the fourth international conference on Protection ofMaterials and Structures from the Low Earth Orbit Space Environment,held inTorontoApril 23-24, 1998. The conferencewas hostedand organizedby Integrity TestingLaboratoryInc. (ITL),and held atthe UniversityofToronto's Institute for AerospaceStudies(UTIAS). Twenty two industrial companies, six universities and fourteen government agencies from Canada, USA, United Kingdom, France, Israel, Russia, Ukraine and the Netherlands were represented by over 75 participants indicating increasing international co-operation in this critical arena of protection of materials in space. Twenty-seven speakers, world experts intheir fields, delivered talks on a wide variety oftopics on various aspects ofmaterial protection in space. Representatives from the Canadian, American, European and Israeli space agencies as well as from leading space research laboratories ofmajoraerospace industriesgatheredat UTIAS to discuss the latest developments inthe field ofmaterial and structure protection from the harsh space environment. We are very proud that this meeting is held in Canada. With the launch ofits first satellite, Alouette I, in 1962, Canada firmly established itselfamong the leading nations in space exploration programs. With its seventh astronaut, Dr. Dave Williams, inspace on board the U.S. shuttle Columbiaasthe conferencebegan,Canadacontinues to contribute significant effort to the exploration and conquest ofspace. The Canadian Space Agency, through its numerous programs such as the Strategic Technologies for Automation and Robotics (STEAR), promotes the advancement of strategic space technologies, including those contributing to the longevity ofmaterials and structures inthespace environment. This forum, as in previous years, brought to Toronto a substantial and distinguished representation ofthe scientific communities ofNorth America, Europe and Asia, working in different fields ofprotection ofmaterials and structures from the harsh conditionsofLEO space environment. A briefglance at the achievements in space exploration in the last two years are impressive. The recent findings by Hubble, the breath-taking journey of the Pathfinderon Martianterrain, the stunningpicturesfrom the Galileo mission, those are just a few of the achievements in the last years. It is, without doubt, however, the International Space Station that presently attracts the most effort and attention around the world. Countries from all over the world are involved in the construction of the International Space Station (ISS) Alpha. The main structure ofthe 28-foot-long, 14 foot-wide U.S. laboratory module and the nearly 80,000 lb (36,300 kg) ofhardware were constructed in 1995. This includes solar array panels, rack structures, and hatch assemblies. The signing of an agreement between NASA and the Russian Space Agency (RKA) in 1996 ledto a$5.63 billiondesign and developmentcontractwith the Boeing Corporation. Space assembly began in June, 1998, with the Proton launch of xi xii the Functional Cargo Block (FGB). Canada's contribution is the Mobile Service System(MSS) to provide external station robotics. Japan's contribution isthe Japanese Experiment Module (JEM), and in Europe, the European Space Agency developed both a pressurized laboratory called Columbus Orbital Facility (COF) and the Automated Transfer Vehicle (ATV) forsupplyinglogistics andpropulsion. A very important milestone in the development ofthe ISS was achieved in January of 1998 in Washington when senior government officials from 15 countries signed agreements to establish the framework for cooperation among the partners on thedesign, development,operation and utilization ofthe ISS. Itisalso remarkable that the first four international crews consisting of American astronauts and Russian cosmonauts werenamed bythe U.S.andtheRussianspace agencies. For the ISS and other future space exploration projects,the safety ofthe crew andthe soundness ofthe structures willbe the major concern.Questions about thermal stability, resistance to softandhard radiation sources, andcombined effectsofvacuum ultraviolet, atomic oxygen and micrometeoroids will continue to accumulate with the development of new materials and the increased use of polymers, plastics and composite materials. For these reasons, the ICPMSE-4 meeting initiated in 1991 remainstimelyandnecessary. These proceedings areorganized intofoursections: a)AOIVUVandRadiation Effects,Evaluation andModelling; b) Instrumentation, Sensors, newTechnologies; c)Thermal Control inLEO; d)Charged particles/Soft X-Rays/Meteoroids/ThennalCycling Jacob Kleiman, Chairman/OrganizingCommittee/ICPMSE-4 IntegrityTesting Laboratory Inc., April 1998
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