Table Of Content

SUBJECT INDEX A.E. COSY 128 Boron chalcogenide glasses 236, 247 AlL,O, Borophosphate glasses 228 interaction of V,0O; with 499 Borosilicate glasses 232 interaction of vanadia oxocomplexes Brain, Na MRI 423-5 with 475 Aldehyde group 26 13C NMR 447 Alkali metal vanadates 469 assignment of spectra 2 AIPO,-based molecular sieves, !29Xe NMR coupling constants 4 spectroscopy 98 derivatization 5 Aluminoborate glasses 221 determination of carbon type 2 Aluminosilicate glasses isotopic labelling 6 chief conclusions made from NMR oleanane triterpenoids. See Oleanane studies 199 triterpenoids MAS NMR in 197 shift reagents 4 silicon site speciation and coordination of solvent effects 4 aluminium in 198 CAMELSPIN 378 structure of 197 Carbon-hydrogen coupling constants 4 Amorphous III-V semiconductors 269 Carboxylic group 27 Amorphous arsenic 268 Cartilage, 3Na MRI 424 Amorphous hydrogenated carbon 266 (13C,2H) case 453 Amorphous hydrogenated germanium 265 Chalcogenide glasses Amorphous hydrogenated Si, C:H alloys 266 atomic distribution in binary and ternary III, Amorphous hydrogenated silicon 259 IV, and V 236 deuterium NMR studies of a-Si:D 265 competitive network modification 252 films 259 effect of Al,S, 252 hydrogen environments 261 effect of B.S; 254 isovalent substitution in a-Si:H 265 effect of SiS, 252 spatial distribution of hydrogen 262 non-oxide 235 spin-lattice relaxation by molecular site speciation in binary and ternary III, IV, hydrogen 262 » and V_ 236 Amorphous hydrogenated silicon carbide 266 site speciation in network former/network Amorphous intermetallic systems 277 modifier systems 247 Amorphous metal hydrides 273 Chemical shift anisotropy (CSA) Amorphous metal—metalloid systems 273 interactions 379, 382, 383, 403 Amorphous phosphorus 268 parameters 470 Amorphous silicon nitride 268 relaxation 382, 389, 403 Arsenic chalcogenide glasses 246 . Chemical shift correlation spectroscopy 185 Chemical shift imaging 412, 420, 422 Chemical shift interaction 170 1BNMR 216 Clustering in solids 323 B-radiation detected NMR 542 (3C,14N) pair 447 Bloembergen—Purcell—Pound (BPP) description Cobalt borides 274 of relaxation rate 529 Cobalt phosphides 274 Borate glasses 215 Continuous random network model 165 alkali and alkaline-earth aluminoborate Correlated external random magnetic glasses 221 fields 367 binary alkali 218 COSY 110 further NMR studies 222 CRAMP techniques 453 intermediate range order in alkali 220 Cross-polarization (CP) 184 network modification by intermediate Cyclooleananes 50, 68 oxides 221 network structure in binary alkali 216 Density matrix 383 short and intermediate range order in glassy basis sets 387 BO, 215 DEPT 329, 348, 350, 393 short range order and its analysis via |'B Differential scanning calorimetry (DSC) of NMR 216 glasses 164 Subject Index Diffusion-controlled relaxation (DCR) Heteronuclear multiple-quantum chemical model 534 shift 347 Diffusion studies 365 High-pressure NMR studies, superionic Dipolar coupled spectra 328 conductors (SIC) 541 Dipolar spin-echo double resonance HMQC experiment 323, 348, 350, 351 ; spectroscopy 183 HMQC module 355 Dipolar spin-echo NMR_ 182 HMQC-COSY experiment 351 Dipole dipole relaxation 390, 403 HMQC-HOHAHA experiment 352 Distance geometry (DG) 146 HMQC-NOESY experiment 352 DNA Homonuclear editing 335 backbone torsion angles 138 Hydrogenated amorphous silicon structure and function in living cell 109 local structure of dopants in 267 structure determination 110 silicon speciation and bond angle DNA segments distributions 260 cross peaks and coupling constants in spectra Hydrogenated boron nitride films 268 of 118 Hydroxyl groups 23 J-correlated spectra 119 Double quantum correlation experiments INADEQUATE 8, 313, 339 abundant nuclei 340 INEPT 393 automated spectral analysis 341 Initial rate approximation (IRA) 146 Double quantum (DQ) spectra 124 Inter-residue scalar coupling correlation 358 Double quantum filtered (DQF) COSY 124 Ionic diffusion studies of glassy solid Double rotation (DOR) 182 electrolytes 254 Dynamic angle spinning (DAS) 182 Ionic glass systems 234 Dynamic N = S equilibria 129 Iron borides 273 Isolated spin pair approximation (ISPA) 146 E. COSY 128, 319 EFG tensor 443, 448 J-correlated spectra 114 Electric field gradient (EFG) 437 J-coupling 110 Eyes, 23Na MRI 423, 427 Jump-relaxation model 532, 535 Fluorinated amorphous silicon 265 Knight shift 170 Four-dimensional correlation experiments 354 Kohlrausch-Williams—Watts (KWW) Fourier imaging 418, 421 function 530 Free induction decay (FID) 119, 187, 415, 428 k-space formalism 416 Friedooleananes 68 K3;V;0,, 469 13C NMR chemical shifts 55 KVO, substitution pattern 24 51V NMR spectra 514 calculated spectra 467 GaAs 269 computer simulated spectra 459 Gallium oxide based glasses 234 experimental and calculated spectra 459, 460 GaP 269 KVO,-K,S,0, alloys 510 Germanium-silicon alloys 265 at low S/V ratio 516 Glasses 164 differential scanning calorimetry (DSC) 164 Li,S-P,S; system 249 magic angle spinning (MAS) technique 544 Liquids, relaxation in rotating frame 377 quantitative NMR spectroscopy 186 Locally ordered random packing model 166 Glassy solid electrolytes, ionic diffusion Lungs, 3Na MRI 425 studies 254 Gradient echoes 415, 421 Magic-angle spinning (MAS) 181, 435 Gyromagnetic ratio 167 glasses 544 Magnetic dipole-dipole interaction 172, 381 'H-!3C correlated spectroscopy 8 Magnetic field gradients 359, 414, 417 'H-;H correlated spectroscopy 7 Magnetic resonance imaging (MRI) 412 'H-'H coupling constants, sugar geometries Magnetic resonance techniques 414 from 135 MAS-NMR 181, 184, 187 'H-3'P heteronuclear coupling constants 138 Metal clusters in porous materials, '?7Xe NMR Halide glasses 234 spectroscopy 101 Hartmann-Hahn condition 185 Metal-metalloid systems 277 Heart, 23Na MRI 422, 425, 426 Metallic glasses 272 Heteronuclear 3D and 4D experiments 356, Metavanadates 469, 473 358 Microporous solids, '29Xe NMR spectroscopy 91 Heteronuclear editing 329 Microscopic activation energy 535 Subject Index MINSY experiment 387, 408 NMR studies of superionic conductors Multiple-quantum coherence 296 (SIC) 527 chemical shift and sensitivity to magnetic field NOESY experiment 110, 186, 387, 393 gradients 300 Noncrystalline solids 164 coherence order 300 Non-oxide chalcogenide glasses 235 evolution 304 Noroleananes 68 excitation and detection 305, 311 n-spin filtration 335 inhomogeneous z-pulses 302 Nuclear electric quadrupole interaction 173 magnetic field gradients 302 Nuclear Overhauser enhancement (NOE) 110 manipulation 301 in multispin systems 146 non-selective pulse techniques for excitation simulation of correlated spectra 146 in liquids 307 Nuclear Overhauser enhancement difference phase cycling 301 spectroscopy (NOEDS) 9 precessional frequency 300 Nucleic acids, solution conformations of 109 properties of 300 pulse angle effects 303 170 NMR spectra relaxation-generated 322 pyrosulfates of alkali metals 515 relaxation properties 366 V,0,-K,S,O, samples in molten state 515 scalar and dipolar couplings 301 Oleanane glycosides 70 selective single-quantum pulses 305 Oleanane triterpenoids 1-90 sensitivity to radio frequency pulse phase 13C NMR chemical shifts 28, 61 shifts 301 related to oleanolides and cyclooleananes 50 uniform excitation 307 13C NMR shielding behaviour 9 Multiple-quantum filtered experiments 323 chemical shift (ppm) increments 63 COSY 316 index of 78 NOESY 322 parent skeleton of 3, 63 Multiple-quantum filtration and relaxation 320 substitution pattern 10 Multiple-quantum NMR methods 295 related to oleanolides, cyclooleananes and chemical shift 338 noroleananes 20 models and formalisms 297 Oleananes 9, 70 number of active spins 313 Oleanolides 50 operator formalisms 298 Oleanoloids 27 physical picture 297 Olefinic bond 22 principles of 297 w,-decoupled COSY 128 sensitivity to magnetic field gradients 359 One-dimensional DOUBTFUL 338 Multiple-quantum pulses 305 One-dimensional INADEQUATE 313 Multiple-quantum relaxation times 366 One-dimensional multiple-quantum filtration 314 Multiple quantum spectroscopy (MQSY) 110 Orthovanadates of divalent metals 471 Oxide glass conformer systems 226 23Na chemical shift imaging 411, 430 Oxidooleananes 68 23Na MRI 411, 412 Oxo-group 26 addition of contrast agents 429 Oxoselenatovanadates (V) of alkali metals 505, applications 422 507 calculation of sodium concentrations and Oxosulfatovanadates (V) of alkali metals 505 relaxation times 425 eyes 423, 427 Pachysanane 69 heart 422, 425, 426 P.E. COSY 128 lungs 425 Perturbation theory 437 specific techniques 421 Phosphate glasses 223 tissue contrast 424 anion substitution 224 tumors 424, 428 coordination of other glass constituents Nernst-Einstein equation 533 in 226 NH,VO;, 5'V MAS spectrum 461 network structure in binary and pseudobinary Nickel borides 275 223 Nickel phosphides 275 Phosphorous chalcogenide glasses 238 NMR Hamiltonian 167 Phosphorus-selenium based ternary NMR imaging 364, 377 systems 244 superionic conductors (SIC) 539 Phosphorus-selenium system 238 NMR lineshape 167, 170, 172, 174, 176 Phosphorus-sulfur system 246 temperature-dependent studies 254 Phosphosilicate glasses 226 NMR powder patterns 171 Plasma-enhanced chemical vapor deposition NMR relaxation 366 (PECVD) 259 NMR resonance frequencies 167 Pnictide glasses 270 Subject Index Polymer electrolytes 546 hydrogen bond strength characteristics 207 POMMIE ‘323, 332 identification and quantification of hydrous Potassium vanadate 469 environments 211 Principal axis system (PAS) 443 interaction of water with silicate melts and Product operators 383 glasses 206 Projection reconstruction 418, 421 interaction with water at low temperatures 210 Pulsed-field gradient (PFG) method 535 motional properties 209 Pulsed NMR experiments 178 network structure 190 Pyrosulfates of alkali metals 515 and hydrogen environments in sol-gel Pyrovanadates of divalent metals 471 prepared glasses and amorphous silicas 210 of sol-gel derived silicas and silicate Quadrupolar coupling 326 glasses 213 Quadrupolar nuclei 435 Si) sites formation and analysis by 29Si Quadrupolar relaxation 367 NMR_ 190 Quadrupolar resonance frequency 175 Si speciation of M,O-SiO, glasses 195 Quantitative NMR spectroscopy in glasses 186 Si species distribution and cation clustering in alkaline earth 196 Radial distribution function (RDF) in binary alkaline 192 measurements 260 speciation of water 206 Radio frequency (RF) magnetic fields 377 structural characteristics of hydrous species 206 strong 387, 390 Silicon chalcogenide glasses 236 weak 389 Random close-packing model 166 Simulated annealing (SA) 146 Random coil model 166 Simulation software packages 152 Single-quantum chemical shift 348 Rapid exchange model 104 REDOR (rotational spin echo double SLAP 333 resonance) 184 SL-ROESY experiments 386 Relative transverse relaxation rates 352 (19§n,35/37Cl) pair 451 Relaxation SO, oxidation and multiple-quantum filtration 320 interaction of active component of vanadia as constraint 369 catalysts with support 512 effect of secular and non-secular terms vanadia catalysts for 505 in 386 vanadia complexes in 519 in rotating frame in liquids 377 vanadium catalysts of 518 multiple-quantum coherence 366 Sol-gel derived silicas 213 selection rules 385 Soi-gei process 210 Relaxation equation 379 Solid state ionics 527 Relaxation-generated multiple-quantum NMR problems in 529 coherence 322 Solid state NMR 159 Relaxation matrices 394 fundamentals of 167 RELAY 323 historical background 162 Resonance offset effects 405 studies of glasses 161, 163 Restrained molecular dynamics (RMD) 146 Solution conformations of nucleic acids 109 Reverse detection experiments 350 Spectral densities 381, 394 ROESY experiment 378, 381, 386, 405, 408 Spin echo double resonance (SEDOR) 183 RRR (rotary resonance recoupling) 184 Spin echoes 415, 421 Spin-lattice interaction 382 Spin-lattice relaxation 176, 533, 534 Scalar coupled spectra 327 Spin-lattice relaxation times 180 Scalar relaxation 368 temperature-dependent 256 71§e NMR MAS spectra of oxoselenatovanadates Spin-', magic-angle spinning spectra of (V) of alkali metals 507 solids 435 Selective averaging techniques 181 applications 447 SEMINA 333 (3C,2H) case 453 SHARP 364 (3C,14N) pair 447 SICOS program 119 coupling to same quadrupolar nucleus 444 Silica supported rhodium catalysts 487 coupling to several quadrupolar nuclei 444 Silicate glasses 187 miscellaneous cases 453 and melt structure at high pressures 204 31P interacting with metals 452 and melt structure at high temperatures 202 quadrupolar effects transferred to 435 anion substitution 200 seif-decoupling 446 bond angle distribution in vitreous SiO, 187 (419§n,3537Cl) pair 451 Subject Index theory 437 51V NMR chemical shift parameters 463 use of spinning sidebands 446 51V NMR MAS spectra, calculated and variable-angle experiments 446 experimental 464 Spin operators 381 51V NMR parameters, inter-relation with local Spin order, changes in 385 environment of V nuclei 462 Spin topology filtration 335 51V NMR spectra Sugar geometries from 'H-!H coupling computer simulation 461 constants 135 in high magnetic fields 463 Sugar ring patterns for single conformation of industrial catalysts 512 Superionic conductors (SIC) of KVO,-K,S,0, systems 510, 516 beta-radiation detected NMR 542 of molten V,0, and KVO, 514 coupling model 530 of oxoselenatovanadates (V) of alkali crystalline solids 543 metals 505 diffusion-controlled relaxation (DCR) of oxosulfatovanadates (V) of alkali model 534 metals 505 experimental techniques 535-43 of solids 458 general properties of 528 of V,0-K,S,0, alloys 510 high-pressure NMR studies 541 of V,0;-K,SO, systems 516 jump-relaxation model 532, 535 solids with well characterized structures 462 NMR studies 527, 529, 539 51V solid-state NMR studies of vanadia-based pulsed-field gradient (PFG) method 535 catalysts 457 studies of special substances 543 Vanadates two-level systems 532 of divalent metals 470 of monovalent metals 468 of trivalent metals 473 Taraxerane triterpenoids Vanadia catalysts 475 SO, oxidation 505, 512 13C NMR chemical shifts 54 51V solid-state NMR studies 457 substitution pattern 23 Vanadia complexes Taraxeranes 68 in V,0./MgO catalysts 492 Tellurium oxide based glasses 234 on SiO, 483 Thiosilicate glasses 248 on SnO, 498 Three-dimensional correlation experiments 354 on TiO, 494 Three-dimensional imaging 419 on ZrO, 498 TiO, SO, oxidation 518, 519 interaction of V,0, with 499 Vanadia oxocomplexes, interaction with Al,O, vanadia compicxes 494 surfaces 475 Titania promoted vanadia catalysts 487 Vanadium catalysts for SO, oxidation 518 TmDOTP> 430 TOCSY/HOHAHA magnetization transfer 387, calculated spectrum 461 406, 407 computer simulated spectra 459 Total spin coherence transfer echos 362 experimental spectra 461 Triple quantum filtered, tilted frame ROESY interaction with Al,O, 499 (3QF-T-ROESY) experiment 386 interaction with TiO, 499 Tumors, 23Na MRI 424, 428 51V NMR spectra 514 Two-dimensional correlated spectroscopy V,0./AIPO, catalysts 482 (COSY) 185 Vogel-Tammann-Fulcher (VTF) equation 547 Two-dimensional heteronuclear correlation V,0;-K,S,0, alloys 510 experiments 346 in molten state 515 Two-dimensional homonuclear correlation V,0;-K,SO, systems at low S/V ratio 516 spectroscopy 338 V,0./(TiO,-ZrO,) catalysts 497 Two-dimensional INADEQUATE 8, 339 Two-dimensional NMR 418 Two-dimensional NMR spectra, simulation of 109 129Xe chemical shift, correlation of pore Two-dimensional NMR spectroscopy 7 dimensions with 103 Two-dimensional nuclear Overhauser effect 129X%e NMR spectroscopy spectroscopy 9 AIPO,-based molecular sieves 98 historical background 91 low temperature 105 metal clusters in porous materials 101 Ultra-high intensity grinding (UHIG) 499 microporous solids 91 UNCOSY 323 miscellaneous applications 100 Subject Index Zeeman interaction 167 with one possible adsorption zone 92 Zeeman-perturbed NOR 176 with two or more possible adsorption Zeeman-quadrupole Hamiltonian 437 zones 96 Zeolites Zero-quantum coherence 343 molecular sieves 92 z-filtered double-quantum experiment 343