PROGRESS IN INORGANIC CHEMISTRY EDITED BY STEPHEN J. LIPPARD DEPARTMENT OF CHEMISTRY COLUMBIA UNIVERSITY NEW YORK VOLUME 19 s c c u c o AN I N TE R I E N E@ P B L I A TI N JOHN WILEY & SONS New York 0 London 0 Sydney 0 Toronto PROGRESS IN INORGANIC CHEMISTRY Volume 19 Advisory Board THEODORE L. BROWN UNIVERSITY OF ILLINOIS, URBANA, ILLINOIS JAMES P. COLLMAN STANFORD UNIVERSITY, STANFORD, CALIFORNIA F. ALBERT COTTON TEXAS A&M UNIVERSITY, COLLEGE STATION, TEXAS RILEY SCHAEFFER INDIANA UNIVERSITY, BLOOMINGTON, INDIANA GEOFFREY WILKINSON IMPERIAL COLLEGE OF SCIENCE AND TECHNOLOGY, LONDON, ENGLAND PROGRESS IN INORGANIC CHEMISTRY EDITED BY STEPHEN J. LIPPARD DEPARTMENT OF CHEMISTRY COLUMBIA UNIVERSITY NEW YORK VOLUME 19 s c c u c o AN I N TE R I E N E@ P B L I A TI N JOHN WILEY & SONS New York 0 London 0 Sydney 0 Toronto An Interscience@ Publication Copyright 0 1975, by John Wiley & Sons, Inc. All rights reserved. Published simultaneously in Canada. No part of this book may be reproduced by any means, no1 transmitted, nor translated into a machine language with- out the written permission of the publisher. Library of Congress Catalog Card Number: 59-13035 ISBN 0-471-54089-7 Printed in the United States of America. 10 9 8 7 6 5 4 3 2 1 Contents Oxidation-Reduction and Related Reactions of Metal-Metal Bonds By T. J. Meyer, Department of Chemistry, University ofNorth Carolina, Chapel Hill, North Carolina . . . . . . . . . . . . 1 Transition Metal Complexes Containing Tridentate Amino Acids By S. T. Chow and C. A. McAuliffe, Department of Chemistry, University of Manchester, Manchester, England . . . . . . . . 5 1 Cryogenic Inorganic Chemistry By G. A. Ozin and A. Vander Voet, Lash Miller Chemistry Laboratory, . . Erindale College, Universityo f Toronto, Toronto, Ontario, Canada 105 The Structural and Magnetic Properties of First-Row Transition Metal Dimers Containing Hydroxo, Substituted Hydroxo, and Halogen Bridges By D. J. Hodgson, Department of Chemistry, University of North Carolina, Chapel Hill, North Carolina . . . . . . . . . . . . 1 73 Coordination Chemistry of Indium By D. G. Tuck, Department of Chemistry, University of Windsor, Windsor, Ontario, Canada, and A. Carty, Department of Chemistry, University of Waterloo, Waterloo, Ontario, Canada . . . . . . . 2 43 Subject Index . . . . . . . . . . . . . . . . . . . . . 339 Cumulative Index, Volumes 1-19 . . . . . . . . . . . . . .36 3 PROGRESS IN INORGANIC CHEMISTRY Volume 19