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productivity and omz over the last 40ka in the arabian sea during late quaternary t~655 PDF

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Preview productivity and omz over the last 40ka in the arabian sea during late quaternary t~655

V , a r ia b il it y o f s s t m onsoon PRODUCTIVITY AND OMZ OVER THE LAST 40KA IN THE ARABIAN SEA DURING LATE QUATERNARY A THESIS SUBMITTED TO 60A UNIVERSITY FOR THE AtfARD OF THE DEQREEOF DOCTOR OF PHILOSOPHY' IN MARINE SCIENCES 5 7 7 7 BV / V a X SHTTAL PAULU GOD AD 7^ DR P. DIYAKAR HAIDU RESEARCH 6U II« NATIONAL INSTITUTE OF OCEANOGRAPHY DONA PAULA GOA INDIA GOA UNIVERSITY, TALEI6A0 GOA, INDIA 2014 ~ T - 6 5 5 T ~ 6 5 5 DecRcatecC to My Tarents, SiBCmgs ancCLcrvecCOne Declaration I here By state that the present thesis entitled "Varia6iCity qfSS% Monsoon (Productivity and OMZ over last 40hg in the jlrafnan Sea during late Quaternary" is original contrihution and the same has not een suhmitted on any previous occasions. Ho the 6est of my knowledge, 6 the present study is first comprehensive worf^of its hind for the area mentioned Hhe literature related to the proBlem investigated has 6een cited. <Due acknowledgements have 6een made wherever facilities and suggestions have 6een availed of Shitdl<Paulu (jodad - TT^T *PpT fetUR ^8JR (JisiiPta, qcf ihejiRi* qfcrc') CSIR-national institute of oceanography (Council of Scientific & Industrial Research) Dr. P. Divakar Naidu Chief Scientist CERTIFICATE JAs required under the (joa 'University ordinance O'B-9.9> I certify that the thesis entitCed '‘Variability of SST, Monsoon Productivity andOMZ over last 40ha in the Arabian Sea during (ate Quaternary", submitted by MsShital Taulu (jo dad for the award of the degree of Doctor of Philosophy in Marine Sciences is based on original studies carried out by her under my supervision. The thesis or any part thereof has not been previously submitted for any other degree or diploma in any university or institution. cTRT WF\J TTTcfT 403 004 WH DONA PAULA, GOA - 403 004, India * : 91-(0)832-2450 450 e-mail: [email protected] Regional Centres fax :91-{0)832-2450 602/03 URL : http://www.nio.org Mumbai, Kochi,Visakhapatnam C O N TEN TS Certificates List of Figures vi List of Tables xii Preface xiii Acknowledgement xvi CHAPTER I Introduction 1 . Climatic Variations 1 2. Indian Monsoon 2 3- Oceanography of the Arabian Sea 3 3.1. Southwest Monsoon 4 3.1 J. Surface Circulation 4 3.1.2. Sea Surface Temperature 4 3.1.3. Sea Surface Salinity 6 3.1.4. Productivity 6 3.2. North East monsoon 8 3.2.1. Surface circulation 8 3.2.2 Sea Surface Temperature 9 3.2.3. Sea Surface Salinity 9 j 2 4 Productivity 10 4. Oxygen Minimum Zone 11 5 . Previous research related to the objectives of the present study 13 5.1. Sea surface temperature reconstructions in the Arabian Sea 13 5.2. Reconstruction of Carbonate ion 14 5.2.2. Paleocarbonate ion Proxies 15 5.3. Monsoon productivity and OMZ variability 16 5.4. NE Monsoon and Winter cooling 17 6. Proxies used in the study 17 6.1. Planktonic foraminifer 17 6.2. Oxygen isotopes 19 6.2.1. Oxygen Isotope as a Stratigraphic Tool in 20 Paleoceanograpghy 6.3. Carbon Isotopes (S13C) 21 6.4. Geochemical Elements 22 6.5. Nitrogen isotopes (S15N ) 23 6.6. Calcium carbonate 23 6.7. Organic carbon 23 7. Objectives 24 CHAPTER II Study Area, Material and Methods Geographic Setting of the Arabian Sea 1. 25 2. Sediment Cores 26 Chronologies of Cores 3. 27 4. Methods 29 4.1. Processing of Sediment 29 4.2. Census counts of Planktonic Foraminifera 29 4.3. Oxygen and carbon isotopes 30 4.4. Nitrogen and carbon isotopes 30 4.5. Elemental Analysis 30 4.6. Calcium Carbonate 31 4.7. Planktonic foraminifera Shell weights 31 4.8. Artificial Neural Network 32 11 CHAPTER III Sea Surface Temperature Changes During May and August in the Western Arabian Sea over the last 22kyr: Implications as to Shifting of the Upwelling Season 1. Introduction 34 2. Materials and Methods 35 3. Results 33 4^ Discussion 38 4.1. Difference in SST between May and August 4\ S. Conclusions 42 CHAPTER IV What Controls The Planktonic Foraminifer Shell Weights In The Arabian Sea? I Introduction 43 2. Factors controlling shell calcification on millennial timescales in 45 the Arabian Sea 2.1 Factors controlling shell calcification in the eastern 45 Arabian Sea 2 1 j Quantification of surface water carbonate ion 4g concentrations using shell weights 2.2 Factors controlling shell calcification in the western 52 Arabian Sea 3. Factors affecting shell calcification on a seasonal timescale: a 57 comparison between (sediment trap studies) 4. Conclusion 61 iii CHAPTER V OMZ Variability in the Eastern Arabian Sea: Implications of Productivity 1. Introduction 63 2. Chronology 65 3. Results and Discussion 66 3.1 Early to Late Holocene contrast in productivity, 66 denitrification, OMZ intensity and calcite dissolution. 3.2 Changes in surface productivity, denitrification and bottom- 67 water oxygenation intensity 3.3 Calcite dissolution due to variations in bottom-water 71 oxygenation 3.4 Variations in denitrification, bottom water oxygenation and 74 calcite dissolution during the last 70 kyr. 4. Conclusions 77 CHAPTER VI Variability of Winter Cooling in the NE Arabian Sea: Implications for the NE Monsoon 1. Introduction 7g 2. Material and Methods 79 2.1. Chronology 80 3. SST variation at the core location 80 4. Results 81 4.1. Oxygen and carbon isotopes 81 4.2. Fertile Planktonic foraminifer species 82 4.3. Calcium carbonate 83 4.4. SST 83 IV Discussions 5. 83 5. ]. Variability of Winter Cooling 84 5.2. Relationship between SW and NE Monsoon Variability 86 5.3. Periodicity of NE Monsoon 88 6. Conclusions 90 CHAPTER VII Summary and Conclusions 91 References 96 Publications: 1. Godad, S. P., Naidu, P. D. and Malmgren, B. A. (2010). Sea Surface Temperature Changes During May and August in the Western Arabian Sea over the last 22 kyr: Implications as to Shifting of Upwelling Season. Marine Micropaleontology, doi: 10.1016/j.marmicro.2010.09.006. 2. Naik, S. S., Naidu, P. D., Govil, P., and Godad, S. P. (2010). Relationship between weights of planktonic foraminifer shell and surface water CO 3= concentration during the holocene and last glacial period. Marine Geology, 275, 278-282. 3. Naik, S. S., Godad, S. P. and Naidu, P. D. (2011). Does carbonate ion control planktonic foraminifera shell calcification in upwelling regions? Current Science, 101, No. 10. 4. Naik, S.S., Godad, S. P., Naidu, P. D. and Ramaswamy, V. (2013). A comparison of Globigerinoides ruber calcification between upwelling and non- upwelling regions in the Arabian Sea. J.Earth Syst. Set, 122, No. 4, 1153-1159. 5. Naik, S.S., Godad, S. P., Naidu, P. D. and Tiwari, M. (2013). Early to Late Holocene contrast in Productivity. OMZ intensity and Calcite Dissolution in the Eastern Arabian Sea.The Holocene, Doi:10.1177/09596833614526936. v LIST OF FIGURES Fig. No. Title Fig. 1.1 Low pressure on continent during Summer Monsoon. Fig. 1.2 High Pressure on the Continent during Winter Monsoon. Fig. 1.3 A schematic representation of identified current branches during the Southwest Monsoon,. Current branches indicated are the South Equatorial Current (SEC), South Equatorial Countercurrent (SECC), Northeast and Southeast Madagascar Current (NEMC and SEMC), East African Coast Current (EACC), Somali Current (SC), Southern Gyre (SG) and Great Whirl (GW) and associated upwelling wedges, Socotra Eddy (SE), Ras al Hadd Jet (RHJ) and upwelling wedges off Oman, West Indian Coast Current (WICC), Laccadive High and Low (LH and LL), East Indian Coast Current (EICC), Southwest and Northeast Monsoon Current (SMC and NMC), South Java Current (JC) and Leeuwin Current (LC).(Schott and McCreary,2001). Fig. 1.4 Sea Surface Temperature during South West Monsoon in the Arabian Sea. Fig. 1.5 Sea Surface Salinity during Southwest Monsoon in the Arabian Sea. Fig. 1.6 Productivity during Southwest Monsoon Fig. 1.7 A schematic representation of identified current branches during the Northeast Monsoon, Current branches indicated are the South Equatorial Current (SEC), South Equatorial Countercurrent (SECC), Northeast and Southeast Madagascar Current (NEMC

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dissolved species, namely molybdate (M0O4 ) in oxygenated sea water. Though unreactive Low level winds during the Gulf Shamal. Weather 38
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