Plant Design and Operations Plant Design and Operations Ian Sutton AMSTERDAM(cid:129)BOSTON(cid:129)HEIDELBERG(cid:129)LONDON NEWYORK(cid:129)OXFORD(cid:129)PARIS(cid:129)SANDIEGO SANFRANCISCO(cid:129)SINGAPORE(cid:129)SYDNEY(cid:129)TOKYO GulfProfessionalPublishingisanimprintofElsevier GulfProfessionalPublishingisanimprintofElsevier 225WymanStreet,Waltham,MA02451,USA TheBoulevard,LangfordLane,Kidlington,Oxford,OX51GB,UK Copyright©2015ElsevierInc.Allrightsreserved. Nopartofthispublicationmaybereproducedortransmittedinanyformorbyany means,electronicormechanical,includingphotocopying,recording,oranyinformation storageandretrievalsystem,withoutpermissioninwritingfromthepublisher.Details onhowtoseekpermission,furtherinformationaboutthePublisher’spermissionspolicies andourarrangementswithorganizationssuchastheCopyrightClearanceCenterandthe CopyrightLicensingAgency,canbefoundatourwebsite:www.elsevier.com/permissions. Thisbookandtheindividualcontributionscontainedinitareprotectedundercopyright bythePublisher(otherthanasmaybenotedherein). Notices Knowledgeandbestpracticeinthisfieldareconstantlychanging.Asnewresearch andexperiencebroadenourunderstanding,changesinresearchmethods,professional practices,ormedicaltreatmentmaybecomenecessary. Practitionersandresearchersmustalwaysrelyontheirownexperienceandknowledgein evaluatingandusinganyinformation,methods,compounds,orexperimentsdescribedherein. Inusingsuchinformationormethodstheyshouldbemindfuloftheirownsafetyandthe safetyofothers,includingpartiesforwhomtheyhaveaprofessionalresponsibility. Tothefullestextentofthelaw,neitherthePublishernortheauthors,contributors, oreditors,assumeanyliabilityforanyinjuryand/ordamagetopersonsorproperty asamatterofproductsliability,negligenceorotherwise,orfromanyuseoroperation ofanymethods,products,instructions,orideascontainedinthematerialherein. ISBN:978-0-323-29964-0 BritishLibraryCataloguing-in-PublicationData AcataloguerecordforthisbookisavailablefromtheBritishLibrary LibraryofCongressCataloging-in-PublicationData AcatalogrecordforthisbookisavailablefromtheLibraryofCongress ForinformationonallGulfProfessionalPublishingpublications visitourwebsiteathttp://store.elsevier.com/ TypesetbyMPSLimited,Chennai,India www.adi-mps.com PrintedandboundinUSA CHAPTER 1 Operations CHAPTER OUTLINE Introduction................................................................................................................2 ProfessionalAdvice....................................................................................................3 Regulations,Standards,andGuidance.........................................................................4 Regulations....................................................................................................4 IndustryStandards.........................................................................................4 ISO...................................................................................................................5 ANSI.................................................................................................................5 GuidanceDocuments......................................................................................5 UnitsofMeasurement.................................................................................................5 RiskReduction...........................................................................................................6 RiskAnalysis.................................................................................................6 Quantification................................................................................................6 FlammableandCombustibleMaterials.........................................................................7 FlammableRange...........................................................................................7 FlammableLimits..........................................................................................7 FlashPoint....................................................................................................7 CombustibleLiquids.......................................................................................8 ClassIIliquids...................................................................................................9 ClassIIIliquids..................................................................................................9 FlammableLiquids.........................................................................................9 IgnitionSources...........................................................................................10 AreaClassification....................................................................................................11 Housekeeping...........................................................................................................12 GeneralNeatness.........................................................................................12 ProperPlacement.........................................................................................13 GrassandBrush...........................................................................................13 EquipmentandPiping..................................................................................13 StorageandHandlingofFlammableLiquids...................................................13 Regulationsandstandards.............................................................................14 Handlingrequirements...................................................................................14 NonprocessOperations..............................................................................................15 OutsideStorage............................................................................................15 CoalandCokeStorage..................................................................................15 DrumStorage...............................................................................................16 1 PlantDesignandOperations.DOI:http://dx.doi.org/10.1016/B978-0-323-29964-0.00001-9 ©2015ElsevierInc.Allrightsreserved. 2 CHAPTER 1 Operations Drainage......................................................................................................16 FireProtectionandPrevention.......................................................................16 Cylinders.....................................................................................................16 LoadingRacks.............................................................................................17 SimultaneousOperations...........................................................................................18 ManagingSIMOPs........................................................................................19 SIMOPsMatrix.............................................................................................19 ConductingtheSIMOPs................................................................................20 Kickoffmeeting..............................................................................................20 Communicationmeetings...............................................................................21 Closeout......................................................................................................22 Examples..................................................................................................................22 Example1—FacilityDesign...........................................................................22 Example2—HeatExchanger.........................................................................23 INTRODUCTION The purpose of this book is to provide practical guidance on issues to do with the design, operation and maintenance of process facilities, including chemical plants, oil refineries, offshore facilities and pipelines—with a focus on safety issues. It is organized into the following chapters: Chapter 1 Operations Chapter 2 Maintenance andInspection Chapter 3 Energy ControlProcedures Chapter 4 Occupational Safety Chapter 5 Chemicals Chapter 6 Personal Protective Equipment Chapter 7 Health andIndustrial Hygiene Chapter 8 Human Factors and Ergonomics Chapter 9 Firefighting Chapter 10 Safety inDesign Chapter 11 Siting and Layout Chapter 12 Equipment Chapter 13 Piping andValves Chapter 14 Safety Instrumentation Chapter 15 Transportation Chapter 16 Security Chapter 17 Common Hazards This book is one in a series to do with the management of process facilities, both onshore and offshore. Other titles include Process Risk and Reliability Professional advice 3 Management (PRRM) and Offshore Safety Management. There is a particularly strong overlap between the contents of this book and those of PRRM which dis- cusses the process safety management systems that lie behind much of what is written here. For example, this book’s Chapter 9 (Firefighting) is tightly inte- grated with Chapter 12 (Emergency Management) of PRRM. Another example is to do with the topic of Inherent Safety, the principles of which are discussed in PRRM. This book shows how those principles are applied to design of equipment such aspressure safety reliefvalves,tanks, and stairways. The table ofcontentsfor PRRM is shown asfollows: Chapter1—Risk Management Chapter2—Compliance andStandards Chapter3—Culture and Participation Chapter4—Technical Information Chapter5—Hazard Identification Chapter6—Operating Procedures Chapter7—Training and Competence Chapter8—Prestartup Reviews Chapter9—Asset Integrity Chapter10—Management ofChange Chapter11—Incident Investigationand RootCause Analysis Chapter12—EmergencyManagement Chapter13—Audits andAssessments Chapter14—Consequence Analysis Chapter15—Frequency Analysis Chapter16—Reliability,Availability, andMaintainability Chapter17—Managinga Risk Program Chapter18—Project Management Chapter19—Contractors Chapter20—TheRisk Management Professional PROFESSIONAL ADVICE Thisbookcoversawiderangeofprofessionaltopicssuchashealth,humanfactors,andequipment design.Itgoeswithoutsayingthataproperlyqualifiedprofessionalshouldbeconsultedfor specificadviceinspecializedareassuchasthese. Note:Thisbookalsodescribessomeoftheregulationstodowithsafety,designandoperations. However,becauseeachcountryhasitsownlegalsystemandregulatoryinterpretationsareconstantly changing,qualifiedlegaladviceshouldalwaysbeobtainedforeachparticularsystemandlocation. 4 CHAPTER 1 Operations REGULATIONS, STANDARDS, AND GUIDANCE The design and operation of process facilities is covered by a wide range of regu- lations, industry consensus standards, and guidance documents such as books, company standards, and manufacturer’s information. Many of these documents are referred to and described in this book. The guidance provided here is general in nature; each company and facility should use the material provided as a basis for developingits own standards. REGULATIONS As the name implies, regulations must be followed—they are the law of the land. Theycan benational/federal, state/province, orlocal. In the United States, many of the regulations to do with the safety of process facilities are written and enforced by the Occupational Health and Safety Administration (OSHA). It is often found that OSHA’s rules and the interpreta- tion of those rules are used internationally, even when there is no legal require- ment to do so. The U.K. Health and Safety Executive (HSE) is another regulatory agency whose influence often extends beyond itsown immediate jurisdiction. Information as to how regulations are developed and enforced is provided in Chapter 2of PRRM. INDUSTRY STANDARDS The International Organization for Standardization (ISO) defines a standard as a documented agreement containing technical specifications or other precise criteria to be used consistently as rules, guidelines, or definitions of characteristics, to ensurethat materials, products, processes, andservices are fitfor their purposes. In the process industries, consensus standards are published by bodies such as the American Petroleum Institute (API), the National Fire Protection Association (NFPA), and the American Society of Safety Engineers (ASSE). Generally, the standards are written by industry experts who pool their knowledge and experi- ence while working together on acommittee. ISO also states that standards are developed according to the following principles: (cid:129) Consensus (cid:129) Theviews ofall interestsare taken intoaccount: manufacturers, vendorsand users, consumer groups, testing laboratories, governments, engineering professions, andresearch organizations. (cid:129) Industry-wide (cid:129) Global solutions tosatisfy industries and customers worldwide Units of measurement 5 Althoughcompliancewithindustrystandardsisusuallyvoluntary,manyofthem— suchastheAPI’sRecommendedPractice14C—havebeenincorporatedintolaw. Two organizations, ISO and the American National Standards Institute (ANSI),help with the development and implementation ofstandards. ISO The International Organization for Standardization (ISO) has developed over 17,500 International Standards on a variety of subjects; some 1,100 new ISO standards are published every year. Two groups of standards—ISO 9000 (Quality Management Systems) and ISO 14000 (Environmental Management Systems)—are of particular relevancetotheprocessindustries. The manner in which an organization implements and manages its ISO 9000/ 14000 programs is built aroundthe following four steps: 1. It writes down whatit is going to do. 2. It trains everybody tofollow the standards that have been set. 3. It implements an auditprogram. 4. It suggests meansfor improvingthe present operation. ANSI The ANSI has an accredited Standards Developing Organization. This organiza- tion reviews procedures for writing standards in many of the standards bodies. For example, ANSI will review and accept the manner in which an organization resolves differences of opinion during the consensus phase of writing a new or revised standard. GUIDANCE DOCUMENTS Many companies write internal standards for their own use. Such guidance often reflects that company’s knowledge of unique issues, such as the handling of a specialized chemical. These internal standards supplement the pertinent regula- tions andindustry standards. Guidance can also come from manufacturers and vendors. They know their own equipment or products very well indeed and can often provide excellent advicetodo with operations andsafety. UNITS OF MEASUREMENT The units of measurement used in this book are normally SI (Le Syste`me International d’Unite´s, OI, 2006). However, many industrial standards have been developed by companies working with the traditional English/American units (sometimes referred to as customary units), and these are sometimes quoted here. Also, many of the standards that are currently in use are clearly based on the 6 CHAPTER 1 Operations traditional units. For example, flash points are defined with the round number of 100(cid:1)F (Fahrenheit). This converts tothe more awkward37.8(cid:1)C. RISK REDUCTION The management or risk is central to much of what is written in this book. Decisions to do with topics as varied as vessel entry, the design of fire hydrants and the selection of process chemicals all require an understanding of the risks involved. RISK ANALYSIS The topics of risk analysis and risk management are discussed in depth in PRRM. Equation (1.1) shows the three keyelements ofrisk: Risk 5Consequence(cid:3)PredictedFrequency (1.1) Hazard Equation (1.1) shows that risk can never be zero—a truth not always grasped by members of the general public or the news media. Hazards are always present within all industrial facilities. Those hazards always have undesirable conse- quences, andtheir likelihood ofoccurrence is always finite. In general, the best way to reduce risk is to remove the hazard either by eliminating the item that is causing the risk or by removing persons from the scene of potential incidents. These approaches are summarized in the aphor- isms, “If a tank’s not there, it can’t leak” and “If a man’s not there, he can’t be killed.” If the hazard cannot be removed, the next best step is usually to reduce the consequence of the event. If that cannot be done, then the likelihood or predicted frequency should be reduced. The final and least satisfactory step is to add safe- guards such as safety instrumentation or personal protective equipment (PPE) for the workers. QUANTIFICATION The importance of quantification is pointed out in two well-known quotations. The first, attributed to Peter Drucker, is “What gets measured gets done”. The second, attributed to W. Edwards Deming, is “In God we trust, all others must bring data.” Those managing process facilities should follow the advice of these two industry leaders. All decisions to do with operations, design, and safety should beanalyzed quantitatively, whereverpossible. Flammable and combustible materials 7 FLAMMABLE AND COMBUSTIBLE MATERIALS Thisbookcontainsmanydiscussionstodowiththe controlofflammable and com- bustiblematerials.Theterminologyusedforthistopic—whichcanbeconfusing—is explainedinthefollowingsections. FLAMMABLE RANGE Firesrequirethe presence offuel andair(oxygen)alongwith asourceofignition. These criteria are often referred toas the fire triangle. The fuel has always to be in the form of a vapor (liquids and solids do not burn directly—the fire generates flammable vapors at their surface and it is the vapors that actually burn). Moreover, not all fuel vapor/oxygen mixtures will burn—the concentrations have to lie inside the flammable range, which have upper and lower limits for the concentrations of the fuel in the vapor space. The flammability limits vary according to many factors, of which some of the most important are the pressure and temperature of the mixture and the presence of inert components such assteam,carbon dioxide, or nitrogen. FLAMMABLE LIMITS The flammable range for a fuel is defined by the lower flammable limit (LFL) and the upper flammable limit (UFL). These terms are also referred to as the upper and lower explosive limits. Below the LFL, there is insufficient flammable material for a fire to occur—the mixture is “too lean.” It is the lowest concentra- tion of a flammable vapor in air capable of producing a fire in the presence of an ignition source. The UFL is similar to the LFL except that there is too high a concentration of vapor for afire tooccur—the mixture is said tobe “too rich.” For most flammable hydrocarbons, the LFL is around 2%(cid:4)5%. For simple alkanes, such as methane and ethane, the UFL is in the 10%(cid:4)15% range. Some chemicals, such as hydrogen, ethylene oxide, and acetylene, have much higher values for UFL. Values for flammable limit ranges for many flammable materials are provided by NFPA 704—Standard System for the Identification of the Hazards ofMaterialsfor Emergency Response. FLASH POINT The flash point of a flammable material is defined as the temperature at which a vapor that is inside its flammable range that can be ignited. An ignition source such as a flame or spark is needed to make the material actually burn. It is impor- tant to recognize that an ignition source is required. The flash point is not the same asthe autoignitiontemperature (AIT).