Process advancement in chemistry and chemical engineering research PDF
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Process Advancement in ProcesCsh Aedmvainscterym aenntd i nC hemical Engineering Research BZ Process Advancement in Process Advancement in aa CTbhrhoisae dvm orPCTlaTbpuhinrhhrrmisogsoaietse cceavr t mdevoociyc osoflrau ilasnaaulmsn ptCT amaAngtphepihreen ldidpics y cseovlco ia v cofCapnmat oaniaetnohltanpteuiincaiorpemnsdis-ennlsr imte smceis rnCp av coyp eitiecohefieec o hnnwamereane-ttrearnms-m oledrii dn denivi nEccesvii e ahrc incCpewnla hawe gepehceenletdhimree gdn -eErcrii mmsncceehn aehvaaielesgiiapn ecretprtdwirienntiayn eregon,gs lredirt.s gn ih agECe ceean ihoeRnn rndbraviad igopeeonnl ortorgirsegiieknrn.gri es gsgCiieRenn iaoanbaacevnerraoll cuerdlctrs hrdhie rhion eee snotrssehgganie age s b arrcioiRcnrogchrchatneehehh ltim o fi rscoitnechianes sacel te ncahoraaythernr r enemcdactmehn iihcw sdioast nlrirt tyrea scy sn ah edanean dmrd ci ithsist ts ar ny da nd itsBabkin ZaikovBabkinbkinZaikovikov BabkinZaikov CHECPMHroEICPcSMreHoTsEIcsRSPe MAsYrTods IRca vSAeYandTsn dvsRaca eAnYCnmdd Hcavee ECanmnnMHtde ci EnenICtmCM H iAenEInL CMt A inILC AL CHEMISTRY and CHEMICAL practicbaolr otahapedpr l riocaranitggbioiernon aoaslfd oca orfp anmpntlrgiociebda uetoirtofin ona ncsphs pi enloim cnca ihsttheitormeny ,sis ctt arihnule ce cbtnhuogeroimenk eoi ciefna rscli nilenugngd.g leeCisn om esveioegrrlnieinnicfgguic. l baeCnsoo ttva hnen etrdhiwn erg aor derbesiocteiatcahlars ctl, h hame naoodnrl deetc iucalal ra nd ENGINEERING RESEARCH other oprairgasicsnteaimcl acblo lainpeptrspra,il bcigctuaiactstiaoieolns na,s sp li opqonlufi c itmdahtseoi o d(snietnsrrcun olc ucftd uhmireneomg do iwesf rtasnrtiy en,cr ght hlaeenem m dbi soostoolrelykcu, uittnilhoecenslu s bad)on,e odaskm rs aiiongdrcnipcliuhfaidolcseua,s nsm tsa ionnglednew cicfu irrclyeaassrnte taa lnrlicenhwe arneds earch and ENGINEERING RESEARCH assembolstiheoeslir,d gsoa,r issgeuoisnrt,fah allei cqcre ousoni,rd tifsgriil ibm(niunastlc i oaclunnoddsni tnonrginab n wutohtaipeota ensrrstt rai cuonlcnedts uts hr(oeienl uoscttfliur osudnicnisntg)ug,lr e aei nm mooofor grslepainchnugoiclluee, ss om aragonnaldden crciucar dlyaesinsct adaall nsloi,ndr gme r aaondloeicmcaulelsat,ar ml lico lecular CH ENGEINNGEIENREINERGI NRGES REEASRECAHRCH solids, ascsuosremfampcboelsuie,n asfdsi,ls smg)ea,sm sm aebnosli,dlee l scinq,ua uglnaiadors spae an(srid,nt i lccipqlloueuldsiyd im(nsign e( criwnliucac dtlmueinrda gitane nigrndi oaw lsrsgao,ta lesunritin icaog,nn loedsr )cgs,r oaaynlmsuitctoai olraspnn,hs da)o n,ou darsgm maaonninrdope mhcraroeylutssas.tl laiaclnl inde c rystalline C E composuTonhldides s)a,,i msmu oroslfofea cltcihudeilsssa,, r mfs iaulumnrldftsai d pcaieosnslcdy,i mpfnillaiemnnraioscr p yama nbradotti ocenlrkaei ansisl os( pt,ino asc ripnltuirgcodllmeeins cog (rt iiyenns ccotloaruglmsda,imn naigucn ,ndi noi cmoragritgnaioanennrica ica las,n n.oddr d goiaarngloiacgn uaonem dae motarogllniacgn ometaHEllic CHM CH The aimcro oemsf epthaoriusc nhmdecrsuos)lmt,,i dsmpciosoiuecleninpctdliuissnlt)aas,r r,m yae nonbdlgoe iocpnkuoe leliaysrrm s ta,oe na rpdnicr dpo m omploayotlmietcerey icarmoilcsam ,km smeiarnustgen wlrieicao aclrstrki,yoi nssntig naa lginsnl,de ta hdcneriday al somrtegaiaulnssee, roaaafnml smdo. omndgien renr als. 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Zaikov, DSc Vladimir A. Babkin, DSc CRC Press Apple Academic Press, Inc Taylor & Francis Group 3333 Mistwell Crescent 6000 Broken Sound Parkway NW, Suite 300 Oakville, ON L6L 0A2 Boca Raton, FL 33487-2742 Canada © 2016 by Apple Academic Press, Inc. Exclusive worldwide distribution by CRC Press an imprint of Taylor & Francis Group, an Informa business No claim to original U.S. Government works Version Date: 20151214 International Standard Book Number-13: 978-1-4987-1931-5 (eBook - PDF) This book contains information obtained from authentic and highly regarded sources. Reasonable efforts have been made to publish reliable data and information, but the author and publisher cannot assume responsibility for the validity of all materials or the consequences of their use. The authors and publishers have attempted to trace the copyright holders of all material reproduced in this publication and apologize to copyright holders if permission to publish in this form has not been obtained. If any copyright material has not been acknowledged please write and let us know so we may rectify in any future reprint. Except as permitted under U.S. Copyright Law, no part of this book may be reprinted, reproduced, transmitted, or utilized in any form by any electronic, mechanical, or other means, now known or hereafter invented, including photocopying, microfilming, and recording, or in any information stor- age or retrieval system, without written permission from the publishers. For permission to photocopy or use material electronically from this work, please access www.copy- right.com (http://www.copyright.com/) or contact the Copyright Clearance Center, Inc. (CCC), 222 Rosewood Drive, Danvers, MA 01923, 978-750-8400. CCC is a not-for-profit organization that pro- vides licenses and registration for a variety of users. For organizations that have been granted a photo- copy license by the CCC, a separate system of payment has been arranged. Trademark Notice: Product or corporate names may be trademarks or registered trademarks, and are used only for identification and explanation without intent to infringe. Visit the Taylor & Francis Web site at http://www.taylorandfrancis.com and the CRC Press Web site at http://www.crcpress.com For information about Apple Academic Press product http://www.appleacademicpress.com ABOUT THE EDITORS Gennady E. Zaikov, DSc Head of the Polymer Division, N. M. Emanuel Institute of Biochemical Physics, Russian Academy of Sciences, Moscow, Russia Professor, Moscow State Academy of Fine Chemical Technology, Russia Professor, Kazan National Research Technological University, Kazan, Russia Gennady E. Zaikov, DSc, is Head of the Polymer Division at the N. M. Emanuel Institute of Biochemical Physics, Russian Academy of Sciences, Moscow, Russia, and professor at Moscow State Academy of Fine Chemical Technology, Russia, as well as Professor at Kazan National Research Technological University, Kazan, Russia. He is also a prolific author, researcher, and lecturer. He has received several awards for his work, including the the Russian Federation Scholarship for Outstand- ing Scientists. He has been a member of many professional organizations and on the editorial boards of many international science journals. Vladimir A. Babkin, DSc Professor and Head, Research Department, Volgograd State University of Architec- ture and Engineering, Sebryakovsky Branch, Volgograd, Russia Vladimir Aleksandrovich Babkin, DSc, is Professor and Head of the Research Department at Volgograd State University of Architecture and Engineering, Se- bryakovsky Branch in Volgograd, Russia. Professor Babkin graduated from Bashkir State University in 1976 (Ufa, Russia) as a physicist, specializing in the field of applied quantum chemistry. He is the author of more than 1,200 scientific papers (including 14 monographs.) CONTENTS List of Contributors ..........................................................................................ix List of Abbreviations ......................................................................................xv Preface ..........................................................................................................xvii 1. Bioactive Nitrogen-Containing Compounds with Spatial Carbocyclic Groups: Synthesis, Modeling of Physical Properties and Use for Creation of Inorganic-Organic Hybrid Materials with Specific Properties ..............1 N. Lekishvili, Kh. Barbakadze, D. Zurabishvili, G. Lekishvili, B. Arziani, A. Fainleib, O. Grigorieva, W. Brostow, and T. Datashvili 2. Relationship Between the Structure, Molecular Dynamics and Thermo-Oxidative Stability of Low Density Polyethylene and Butyl Rubber Blends ...............................................................................................21 T. V. Monakhova, L. S. Shibryaeva , N. N. Kolesnikova, A. I. Sergeev, S. G. Karpova, and A. A. Popov 3. A Study on Possibilities for Cellulose-Based Textile Waste Treatment into Powder-Like Fillers for Emulsion Rubbers ........................................37 V. M. Misin 4. Theoretical Estimation of Acid Force of Molecule P-Dimethoxy- Trans-Stilbene by Method Ab Initio ............................................................55 V. A. Babkin, D. S. Andreev, Yu. A. Prochukhan, K. Yu. Prochukhan, and G. E. Zaikov 5. Modification of Polyamide- 6 by N, N'-Bis-Maleamidoacid ......................61 N. R. Prokopchuk, E. T. Krut'ko, and M. V. Zhuravleva 6. Protective Properties of Modified Epoxy Coatings ....................................71 N. R. Prokopchuk, M. V. Zhuravleva, T. A Zharskaya, and E. T Krut'ko 7. Chemical Transformation of Syndiotactic 1,2-Polybutadiene ..................81 M. I. Abdullin, A. B. Glazyrin, O. S. Kukovinets, A. A. Basyrov, and G. E. Zaikov 8. Normalization of the Maintenance of Metals in Objects of an Environment in View of Complex Receipt in an Organism of the Person .............................................................................................................99 J. A. Tunakova, S. V.Novikova, R. A. Shagidullina, and M. I. Artsis 9. Influence of Hydrolysis on Diffusion of Electrolytes ................................111 Ana C. F. Ribeiro, Luís M. P. Veríssimo, Artur J. M. Valente, Ana M. T. D. P. V. Cabralb, and Victor M. M. Lobo viii Contents 10. Ozone Decomposition .................................................................................121 T. Batakliev, V. Georgiev, M. Anachkov, S. Rakovsky, and G. E. Zaikov 11. Ozone Decomposition on the Surface of Metal Oxide Catalyst ..............149 T. Batakliev, V. Georgiev, M. Anachkov, S. Rakovsky, A. Berlin, and G. Zaikov 12. Synthesis of O-Including Compounds by Catalytic Conversation of Olefins...........................................................................................................163 G. Z. Raskildina, N. G. Grigor’eva, B. I. Kutepov, S. S. Zlotsky, and G. E. Zaikov 13. Stress Birefringence of Highly Cross-Linked Polymers of Optoelectronic Application in the Context of Heredity Theory ........................................175 Nikolai V. Ulitin, Ilshat I. Nasyrov, Rafit R. Nabiev, Daria A. Shiyan, Nail K. Nuriev, and Gennady E. Zaikov 14. Investigation of Various Method for Steel Surface Modification ...........191 Igor Novák, Ivan Michalec, Marian Valentin, Milan Marônek, Ladislav Šoltés, Ján Matyašovský, and Peter Jurkovič 15. Sorbtion of Industrial Dyes by Inorganic Rocks from Aqueous Solutions .......................................................................................203 F. F. Niyazi and A. V. Sazonova 16. Some Coordination Compounds of Arsenic and Stibium .......................211 N. Lekishvili, M. Rusia, L. Arabuli, Kh. Barbakadze, I. Didbaridze, M. Samkharadze, G. Jioshvili, K. Giorgadze, and N. Sagaradze 17. Surface-Modified Magnetic Nanoparticles for Cell Labeling .................275 Beata A. Zasonska,Vitalii Patsula,Rostyslav Stoika, and Daniel Horák 18. The Reinforcement of Particulate-Filled Polymer Nanocomposites by Nano-Particles Aggregates .........................................................................289 G. E. Zaikov. G. V. Kozlov, and A. K. Mikitaev 19. A New xf Photosynthesis .............................................................................303 Gennady G. Komissarov 20. Application Able Radicals for Study of Behavior of Biological Systems .........................................................................................................329 M. D. Goldfein, and E. G. Rozantsev 21. Quantum-Chemical Calculation of the Models of Dekacene and Eicosa- cene by Method MNDO Within the Framework of Molecular Graphene Model ............................................................................................................345 V. A. Babkin, V. V. Trifonov, A. P. Knyazev, V. Yu. Dmitriev, D. S. Andreev, A. V. Ignatov, E. S.Titova, O. V. Stoyanov, and G. E. Zaikov Index .............................................................................................................359 LIST OF CONTRIBUTORS M. I. Abdullin Bashkir State University, Ufa 450077, Russia.E-mail: [email protected] M. Anachkov Institute of Catalysis, Bulgarian Academy of Sciences, Bonchev St. #11, Sofia 1113, Bulgaria D. S. Andreev Sebrykov Department, Volgograd State Architect-build University, Akademicheskaya ul., 1, Volgograd 400074, Volgograd Oblast, Russia L. Arabuli Faculty of Exact and Natural Sciences, Institute of Inorganic–Organic Hybrid Compounds and Non- traditional Materials, Ivane Javakhishvili Tbilisi State University, 1 Ilia Chavchavadze Avenue, Tbilisi 0179, Georgia M. I. Artsis N.M.Emanuel Institute of Biochemical Physics, Russian Academy of Sciences,4 Kosygin str., Moscow 119334, Russia. E-mail:[email protected] B. Arziani Tbilisi State Medical University, Tbilisi, Georgia V. A. Babkin Sebrykov Department, Volgograd State Architect-build University, Akademicheskaya ul., 1, Volgograd 400074, Volgograd Oblast, Russia Kh. Barbakadze Faculty of Exact and Natural Sciences, Institute of Inorganic–Organic Hybrid Compounds and Non- traditional Materials, Ivane Javakhishvili Tbilisi State University, 1 Ilia Chavchavadze Avenue, Tbilisi 0179, Georgia A. A. Basyrov Bashkir State University, Ufa 450077, Russia T. Batakliev Institute of Catalysis, Bulgarian Academy of Sciences, Bonchev St. #11, Sofia 1113, Bulgaria. E-mail: [email protected] A. Berlin N.N. Semenov Institute of Chemical Physics, Russian Academy of Sciences, 4 Kosygin str., Moscow 119991, Russia. E-mail:[email protected] W. Brostow Laboratory of Advanced Polymers & Optimized Materials (LAPOM), Department of Materials Science and Engineering, University of North Texas, 1150 Union Circle No.305310, Denton, TX 76203-5017, USA.E-mail: [email protected] A. M. T. D. P. V. Cabral Faculty of Pharmacy, University of Coimbra, 3000-295 Coimbra, Portugal. E-mail:[email protected]
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